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SU1180054A1 - Method of cleaning gases,containing sulfur dioxide,from fluorum-containing admixtures - Google Patents

Method of cleaning gases,containing sulfur dioxide,from fluorum-containing admixtures Download PDF

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Publication number
SU1180054A1
SU1180054A1 SU843726358A SU3726358A SU1180054A1 SU 1180054 A1 SU1180054 A1 SU 1180054A1 SU 843726358 A SU843726358 A SU 843726358A SU 3726358 A SU3726358 A SU 3726358A SU 1180054 A1 SU1180054 A1 SU 1180054A1
Authority
SU
USSR - Soviet Union
Prior art keywords
sulfur dioxide
cleaning gases
fluorum
absorber
admixtures
Prior art date
Application number
SU843726358A
Other languages
Russian (ru)
Inventor
Вячеслав Николаевич Ченцов
Вадим Сергеевич Епифанов
Наталья Ивановна Шарыпина
Геннадий Федорович Пинаев
Людмила Матвеевна Раздорских
Юрий Михайлович Соловьев
Original Assignee
Воскресенский филиал Научно-исследовательского института по удобрениям и инсектофунгицидам им.проф.Я.В.Самойлова
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Publication date
Application filed by Воскресенский филиал Научно-исследовательского института по удобрениям и инсектофунгицидам им.проф.Я.В.Самойлова filed Critical Воскресенский филиал Научно-исследовательского института по удобрениям и инсектофунгицидам им.проф.Я.В.Самойлова
Priority to SU843726358A priority Critical patent/SU1180054A1/en
Application granted granted Critical
Publication of SU1180054A1 publication Critical patent/SU1180054A1/en

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Abstract

СПОСОБ ОЧИСТКИ ГАЗОВ, СОДЕРЖАЩИХ ДИОКСИД СЕРЫ, ОТ ФТОРСОДЕРЖАЩИХ ПРИМЕСЕЙ контактированием с измельченным кальцийсодержащим поглотителем при повышенных температурах, отличающийс  тем, что, с целью повышени  степени очистки и уменьшени  потерь диоксида серы, очистку ведут при 400-670°С с поддержанием в газе концентрации кислорода в интервале 0,01-0,05 об.% и в качестве поглотител  используют оксид кальци .A METHOD FOR CLEANING GASES CONTAINING SULFUR DIOXIDE FROM FLUORINE-CONTAINING IMPURITIES by contacting with crushed calcium-containing absorber at elevated temperatures, characterized in that, in order to increase the level of sulfur dioxide loss, they clean up at a temperature difference of 400-6 ° C and have a temperature difference of 10.66 ° C; oxygen concentrations in the range of 0.01-0.05% by volume and calcium oxide as the absorber.

Description

Изобретение относитс  к способам очистки SOj-содержащих газов от фторсодержащих примесей и может найти применение в производстве серной кислоты.This invention relates to methods for purifying SOj-containing gases from fluorine-containing impurities and may find use in the manufacture of sulfuric acid.

Цель изобретени  - повышение степени очистки и уменьшение потерь диоксида серы.The purpose of the invention is to increase the degree of purification and reduce the loss of sulfur dioxide.

Пример. Очистка от фтора и его соединений газа, получаемого при термохимиlecKOM разложении фосфопшса.Example. Purification of fluorine and its compounds gas produced by thermochemolcom decomposition of phosphocing.

На очистку подают газ, содержаший 6,00/ SO 2,, 800 мг/нм фтора (0,08%), 0,03% О с температурой . После контактировани  с известью фракционного состава 0,010 ,20 мм содержание 50 и фтора составл ет 5,98% и 7 мг/нм (0,001%), соответственно . Степень очистки от фтора составл ет 99%, потери SOj. 0,5%.A gas containing 6.00 / SO 2 ,, 800 mg / nm of fluorine (0.08%), 0.03% O with temperature is fed to the purification. After contacting a fractional composition of 0.010, 20 mm with lime, the content of 50 and fluorine is 5.98% and 7 mg / nm (0.001%), respectively. The degree of purification from fluorine is 99%, loss of SOj. 0.5%.

Результаты других примеров приведены в таблиде.The results of other examples are given in the table.

Claims (1)

СПОСОБ ОЧИСТКИ ГАЗОВ, СОДЕРЖАЩИХ ДИОКСИД СЕРЫ, ОТ ФТОРСОДЕРЖАЩИХ ПРИМЕСЕЙ контактированием с измельченным кальцийсодержащим поглотителем при повышенных температурах, отличающийся тем, что, с целью повышения степени очистки и уменьшения потерь диоксида серы, очистку ведут при 400-670°С с поддержанием в газе концентрации кислорода в интервале 0,01-0,05 об.% и в качестве поглотителя используют оксид кальция.METHOD FOR CLEANING GASES CONTAINING Sulfur dioxide from fluorine-containing impurities by contacting with a crushed calcium-containing absorber at elevated temperatures, characterized in that, in order to increase the degree of purification and reduce losses of sulfur dioxide, purification is carried out at 400-670 ° С with oxygen concentration in the range of 0.01-0.05 vol.% and calcium oxide is used as an absorber.
SU843726358A 1984-04-12 1984-04-12 Method of cleaning gases,containing sulfur dioxide,from fluorum-containing admixtures SU1180054A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU843726358A SU1180054A1 (en) 1984-04-12 1984-04-12 Method of cleaning gases,containing sulfur dioxide,from fluorum-containing admixtures

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU843726358A SU1180054A1 (en) 1984-04-12 1984-04-12 Method of cleaning gases,containing sulfur dioxide,from fluorum-containing admixtures

Publications (1)

Publication Number Publication Date
SU1180054A1 true SU1180054A1 (en) 1985-09-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
SU843726358A SU1180054A1 (en) 1984-04-12 1984-04-12 Method of cleaning gases,containing sulfur dioxide,from fluorum-containing admixtures

Country Status (1)

Country Link
SU (1) SU1180054A1 (en)

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Патент JP № 54-35190, кл. В 01 D 53/34, 1979. Патент GB № 787017, кл. 1 *

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