SE9303034D0 - Methods and apparatus for the absorption of hydrogen sulphide - Google Patents
Methods and apparatus for the absorption of hydrogen sulphideInfo
- Publication number
- SE9303034D0 SE9303034D0 SE9303034A SE9303034A SE9303034D0 SE 9303034 D0 SE9303034 D0 SE 9303034D0 SE 9303034 A SE9303034 A SE 9303034A SE 9303034 A SE9303034 A SE 9303034A SE 9303034 D0 SE9303034 D0 SE 9303034D0
- Authority
- SE
- Sweden
- Prior art keywords
- hydrogen sulphide
- absorption
- stage
- gas
- sulphide
- Prior art date
Links
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title abstract 7
- 238000010521 absorption reaction Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 6
- 239000007789 gas Substances 0.000 abstract 4
- 239000000243 solution Substances 0.000 abstract 3
- 239000004291 sulphur dioxide Substances 0.000 abstract 3
- 235000010269 sulphur dioxide Nutrition 0.000 abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 2
- 239000012670 alkaline solution Substances 0.000 abstract 2
- 238000002485 combustion reaction Methods 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/06—Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
- D21C11/08—Deodorisation ; Elimination of malodorous compounds, e.g. sulfur compounds such as hydrogen sulfide or mercaptans, from gas streams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/64—Thiosulfates; Dithionites; Polythionates
- C01B17/66—Dithionites or hydrosulfites (S2O42-)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
A method and an apparatus for selectively removing, by liquid absorption, hydrogen sulphide from a gas containing both hydrogen sulphide and carbon dioxide, are disclosed. In a first stage of the method, the gas (3) is in a container (1) contacted, in at least one step, with a carbonate-containing alkaline solution whose pH is adjusted during the absorption by the addition of a hydroxide, such as sodium hydroxide. In a second stage of the method, the gas is combusted in a combustion device (32) for converting the hydrogen sulphide remaining in the gas to sulphur dioxide, which then is absorbed in an alkali-containing solution, such as a sodium hydroxide solution, in a wet cleaner (36). By combining the absorption of hydrogen sulphide in a carbonate-containing solution in a first stage, and the combustion of the remaining hydrogen sulphide to sulphur dioxide and the absorption of the formed sulphur dioxide in an alkaline solution in a second stage, one may attain a total hydrogen-sulphide separation of high selectivity, high degree of separation and good process economy.
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9303034A SE501782C2 (en) | 1993-09-17 | 1993-09-17 | Method and apparatus for selectively removing hydrogen sulfide from a gas |
| PCT/SE1994/000829 WO1995007750A1 (en) | 1993-09-17 | 1994-09-07 | Method and apparatus for absorbing hydrogen sulphide |
| CA002171342A CA2171342A1 (en) | 1993-09-17 | 1994-09-07 | Method and apparatus for absorbing hydrogen sulphide |
| JP7509118A JPH09502651A (en) | 1993-09-17 | 1994-09-07 | Hydrogen sulfide absorption method and equipment |
| BR9407636A BR9407636A (en) | 1993-09-17 | 1994-09-07 | Method and apparatus for absorbing hydrogen sulfide |
| CN94193932A CN1066634C (en) | 1993-09-17 | 1994-09-07 | Method and apparatus for absorbing hydrogen sulphide |
| RU96108406A RU2119375C1 (en) | 1993-09-17 | 1994-09-07 | Method and apparatus for selectively separating hydrogen sulfide |
| AU77125/94A AU7712594A (en) | 1993-09-17 | 1994-09-07 | Method and apparatus for absorbing hydrogen sulphide |
| NO961016A NO305277B1 (en) | 1993-09-17 | 1996-03-13 | Method and device for absorption of hydrogen sulphide |
| FI961237A FI961237A0 (en) | 1993-09-17 | 1996-03-15 | Methods and apparatus for the absorption of hydrogen sulphide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9303034A SE501782C2 (en) | 1993-09-17 | 1993-09-17 | Method and apparatus for selectively removing hydrogen sulfide from a gas |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| SE9303034D0 true SE9303034D0 (en) | 1993-09-17 |
| SE9303034L SE9303034L (en) | 1995-03-18 |
| SE501782C2 SE501782C2 (en) | 1995-05-15 |
Family
ID=20391129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE9303034A SE501782C2 (en) | 1993-09-17 | 1993-09-17 | Method and apparatus for selectively removing hydrogen sulfide from a gas |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPH09502651A (en) |
| CN (1) | CN1066634C (en) |
| AU (1) | AU7712594A (en) |
| BR (1) | BR9407636A (en) |
| CA (1) | CA2171342A1 (en) |
| FI (1) | FI961237A0 (en) |
| NO (1) | NO305277B1 (en) |
| RU (1) | RU2119375C1 (en) |
| SE (1) | SE501782C2 (en) |
| WO (1) | WO1995007750A1 (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09183618A (en) * | 1995-12-28 | 1997-07-15 | Kansai Electric Power Co Inc:The | Production of gypsum |
| RU2176266C1 (en) * | 2000-03-27 | 2001-11-27 | Дочернее открытое акционерное общество "Гипрогазцентр" | Method of treatment and dehydration of natural and associated petroleum gas with high content of hydrogen sulfide |
| RU2201792C2 (en) * | 2001-05-28 | 2003-04-10 | Открытое акционерное общество "АВИСМА титано-магниевый комбинат" | Method of treating titanium-magnesium production effluent gases |
| RU2331461C2 (en) * | 2003-09-09 | 2008-08-20 | Флуор Корпорейшн | Improved use and solovent recovery |
| FI119915B2 (en) * | 2003-10-03 | 2011-06-15 | Metsae Botnia Ab Oy | Removal of sulfur from the smell gases of a cellulose factory |
| CA2455011C (en) | 2004-01-09 | 2011-04-05 | Suncor Energy Inc. | Bituminous froth inline steam injection processing |
| FI118629B (en) | 2005-06-15 | 2008-01-31 | Metso Power Oy | Method and apparatus for removing carbon dioxide from flue gases containing sulfur dioxide |
| RU2320398C2 (en) * | 2006-04-13 | 2008-03-27 | Общество с ограниченной ответственностью Нефтегаз-Сталь Экспертно-научно-внедренческая компания ООО "НЕФТЕГАЗ-СТАЛЬ-ЭНВК" | Method of removing hydrocarbon product from hydrogen sulfide |
| US7964170B2 (en) | 2007-10-19 | 2011-06-21 | Fluegen, Inc. | Method and apparatus for the removal of carbon dioxide from a gas stream |
| RU2394635C2 (en) * | 2008-06-16 | 2010-07-20 | Юрий Викторович Кушелев | Method of gas cleaning and device to this end |
| DE102008062387A1 (en) * | 2008-12-17 | 2010-07-01 | Uhde Gmbh | Process for the purification of industrial gases and production of sour gases |
| KR20140006881A (en) * | 2011-01-18 | 2014-01-16 | 커먼웰쓰 사이언티픽 앤드 인더스트리얼 리서치 오가니제이션 | Process for capturing acid gases |
| CN102895862B (en) * | 2012-10-25 | 2014-12-17 | 四川皇龙智能破碎技术股份有限公司 | Method and system for removing hydrogen sulfide from coal gas through single tower |
| CN103381334B (en) * | 2013-07-17 | 2015-07-15 | 山东大学 | Method and device for removing hydrogen sulfide through steel slag |
| CN103436301B (en) * | 2013-09-13 | 2015-02-25 | 上海电力学院 | Combined dust removal and desulfurization system for coal gas |
| CN104492227B (en) * | 2014-12-11 | 2016-09-14 | 西安长庆科技工程有限责任公司 | A kind of for processing containing H2the absorption of S-acid gas and CIU and method |
| CN104984652A (en) * | 2015-07-11 | 2015-10-21 | 河北新启元能源技术开发股份有限公司 | Treating device for tail gas in acidifying refinement of alkaline residues and treating process thereof |
| CN105293852B (en) * | 2015-12-04 | 2017-08-25 | 山西省生态环境研究中心 | The method of the synchronous coupling odor purification of sludge organism leaching conditioning |
| US10370176B2 (en) * | 2017-09-12 | 2019-08-06 | Wd-40 Company | Child resistant aerosol actuator |
| CN108671701A (en) * | 2018-05-17 | 2018-10-19 | 浙江卫星能源有限公司 | A kind of sulfur method of hydrogen sulfide containing gas |
| CN109589760B (en) * | 2018-11-07 | 2021-04-27 | 合肥通用机械研究院有限公司 | Device and method for rapidly treating hydrogen sulfide for laboratory |
| KR102466873B1 (en) * | 2021-03-29 | 2022-11-17 | 주식회사 시뮬레이션테크 | CO2 Reduction Equipment Using Scrubber For Ship |
| CN114452803B (en) * | 2022-01-12 | 2023-03-24 | 中国科学院过程工程研究所 | Method and system for treating pyrolysis gas generated by pyrolysis of waste tires |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE47516C1 (en) * | 1920-01-01 | |||
| US3236589A (en) * | 1961-02-03 | 1966-02-22 | Reinhall Rolf Bertil | Method of working up cellulose waste liquor containing sodium and sulfur |
| SE448173B (en) * | 1985-06-03 | 1987-01-26 | Croon Inventor Ab | PROCEDURE FOR THE RECOVERY OF CELLULOSA DISPOSAL CHEMICALS BY PYROLYSIS |
| US5284550A (en) * | 1992-06-18 | 1994-02-08 | Combustion Engineering, Inc. | Black liquier gasification process operating at low pressures using a circulating fluidized bed |
| SE470516B (en) * | 1992-11-05 | 1994-06-27 | Chemrec Ab | Purifying gas from the gasification of black liquor |
| SE9300533L (en) * | 1993-02-18 | 1994-08-19 | Flaekt Ab | Methods and apparatus for the absorption of hydrogen sulphide |
-
1993
- 1993-09-17 SE SE9303034A patent/SE501782C2/en not_active IP Right Cessation
-
1994
- 1994-09-07 JP JP7509118A patent/JPH09502651A/en active Pending
- 1994-09-07 AU AU77125/94A patent/AU7712594A/en not_active Abandoned
- 1994-09-07 BR BR9407636A patent/BR9407636A/en not_active IP Right Cessation
- 1994-09-07 WO PCT/SE1994/000829 patent/WO1995007750A1/en not_active Ceased
- 1994-09-07 RU RU96108406A patent/RU2119375C1/en not_active IP Right Cessation
- 1994-09-07 CA CA002171342A patent/CA2171342A1/en not_active Abandoned
- 1994-09-07 CN CN94193932A patent/CN1066634C/en not_active Expired - Fee Related
-
1996
- 1996-03-13 NO NO961016A patent/NO305277B1/en not_active IP Right Cessation
- 1996-03-15 FI FI961237A patent/FI961237A0/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NO305277B1 (en) | 1999-05-03 |
| BR9407636A (en) | 1997-01-28 |
| NO961016D0 (en) | 1996-03-13 |
| FI961237A7 (en) | 1996-03-15 |
| CN1066634C (en) | 2001-06-06 |
| NO961016L (en) | 1996-03-13 |
| JPH09502651A (en) | 1997-03-18 |
| CN1133568A (en) | 1996-10-16 |
| SE9303034L (en) | 1995-03-18 |
| RU2119375C1 (en) | 1998-09-27 |
| AU7712594A (en) | 1995-04-03 |
| SE501782C2 (en) | 1995-05-15 |
| CA2171342A1 (en) | 1995-03-23 |
| FI961237A0 (en) | 1996-03-15 |
| WO1995007750A1 (en) | 1995-03-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NUG | Patent has lapsed |