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RU98118226A - METHOD FOR PRODUCING ORGANIC COMPOUNDS EXCELLENT BY TRITIUM AND ORGANIC COMPOUND EXCELLENT BY TRITIUM - Google Patents

METHOD FOR PRODUCING ORGANIC COMPOUNDS EXCELLENT BY TRITIUM AND ORGANIC COMPOUND EXCELLENT BY TRITIUM

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Publication number
RU98118226A
RU98118226A RU98118226/04A RU98118226A RU98118226A RU 98118226 A RU98118226 A RU 98118226A RU 98118226/04 A RU98118226/04 A RU 98118226/04A RU 98118226 A RU98118226 A RU 98118226A RU 98118226 A RU98118226 A RU 98118226A
Authority
RU
Russia
Prior art keywords
reactor
tritium
pdo
producing
evacuation
Prior art date
Application number
RU98118226/04A
Other languages
Russian (ru)
Other versions
RU2163903C2 (en
Inventor
В.П. Шевченко
Н.Ф. Мясоедов
И.Ю. Нагаев
Original Assignee
Институт молекулярной генетики РАН
Filing date
Publication date
Application filed by Институт молекулярной генетики РАН filed Critical Институт молекулярной генетики РАН
Priority to RU98118226A priority Critical patent/RU2163903C2/en
Priority claimed from RU98118226A external-priority patent/RU2163903C2/en
Publication of RU98118226A publication Critical patent/RU98118226A/en
Application granted granted Critical
Publication of RU2163903C2 publication Critical patent/RU2163903C2/en

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Claims (3)

1. Способ получения высокомеченных тритием органических соединений путем получения тритиевой воды при выдерживании PdO или смеси PdO с PdO/Al2O3 в атмосфере газообразного трития при нагревании, осуществления взаимодействия исходного органического вещества с полученной тритиевой водой в среде диоксана в смеси с триэтиламином, включающий вакуумирование реактора перед его заполнением газообразным тритием, замораживание реактора при его повторном вакуумировании, отличающийся тем, что в реактор вносят весь необходимый набор твердых и жидких компонентов реакционной смеси, вакуумированию перед заполнением газообразным тритием подвергают реактор, предварительно замороженный в месте расположения в нем твердых и жидких компонентов реакционной смеси, затем замораживание переносят в верхнюю часть реактора, а нагреванию подвергают его нижнюю часть, после повторного вакуумирования вновь замораживают нижнюю часть реактора, выдерживают его замороженным, затем замораживание прекращают и выдерживают реактор в течение 12-20 часов при температуре 18-25°С.1. A method of producing highly tritiated organic compounds by producing tritium water while keeping PdO or a mixture of PdO with PdO / Al 2 O 3 in an atmosphere of gaseous tritium upon heating, reacting the starting organic substance with the obtained tritium water in a dioxane mixture mixed with triethylamine, including evacuation of the reactor before filling it with gaseous tritium, freezing of the reactor during its repeated evacuation, characterized in that the reactor contains all the necessary set of solid and liquid components of the reaction mixture, the reactor is subjected to evacuation before filling with gaseous tritium, previously frozen at the location of the solid and liquid components of the reaction mixture, then freezing is transferred to the upper part of the reactor, and the lower part is subjected to heating, and the lower part of the reactor is again frozen, keep it frozen, then the freeze is stopped and the reactor is kept for 12-20 hours at a temperature of 18-25 ° C. 2. Способ по п.1, отличающийся тем, что выдерживание реактора при 18-25°С совмещают с перемешиванием его содержимого. 2. The method according to claim 1, characterized in that the aging of the reactor at 18-25 ° C is combined with mixing of its contents. 3. Высокомеченное тритием органическое соединение формулы I
Figure 00000001
3. Highly tritiated organic compound of formula I
Figure 00000001
RU98118226A 1998-10-05 1998-10-05 Method of incorporation of tritium label in organic compounds and highly tritium-labeled methyl-(e)-{2-[6-(2-cyanophenoxy)- -pyrimidine-4-yloxy]phenyl]}-3-methoxyacrylate RU2163903C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU98118226A RU2163903C2 (en) 1998-10-05 1998-10-05 Method of incorporation of tritium label in organic compounds and highly tritium-labeled methyl-(e)-{2-[6-(2-cyanophenoxy)- -pyrimidine-4-yloxy]phenyl]}-3-methoxyacrylate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU98118226A RU2163903C2 (en) 1998-10-05 1998-10-05 Method of incorporation of tritium label in organic compounds and highly tritium-labeled methyl-(e)-{2-[6-(2-cyanophenoxy)- -pyrimidine-4-yloxy]phenyl]}-3-methoxyacrylate

Publications (2)

Publication Number Publication Date
RU98118226A true RU98118226A (en) 2000-06-27
RU2163903C2 RU2163903C2 (en) 2001-03-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU98118226A RU2163903C2 (en) 1998-10-05 1998-10-05 Method of incorporation of tritium label in organic compounds and highly tritium-labeled methyl-(e)-{2-[6-(2-cyanophenoxy)- -pyrimidine-4-yloxy]phenyl]}-3-methoxyacrylate

Country Status (1)

Country Link
RU (1) RU2163903C2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2398755C1 (en) * 2009-03-27 2010-09-10 Учреждение Российской академии наук Институт молекулярной генетики РАН (ИМГ РАН) 5-(1,1-dimethylheptyl)-2-[5-hydroxy-2-(3-hydroxypropyl)cyclohexyl]phenol uniformly labelled with tritium

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2206565C1 (en) * 2001-12-14 2003-06-20 Институт молекулярной генетики РАН Highly tritium-labeled ethyl-(r)-1-(1-phenethyl)-1h-imidazole-5-carboxylate and method for its preparing

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6470490A (en) * 1987-09-10 1989-03-15 Kyowa Hakko Kogyo Kk Mitomycins and production thereof
FR2635683B1 (en) * 1988-09-01 1990-11-09 Cird NEW COMPOUND MARKED WITH TRITIUM, ITS PREPARATION AND ITS APPLICATION IN PARTICULAR IN THE DETERMINATION OF THE AFFINITY OF RETINOIDS FOR THEIR NUCLEAR RECEPTORS AND THEIR CYTOSOLIC BINDING PROTEIN
IE74711B1 (en) * 1990-07-27 1997-07-30 Ici Plc Fungicides
GB2253624A (en) * 1991-01-30 1992-09-16 Ici Plc Pyrimidine fungicides
RU2083579C1 (en) * 1994-09-05 1997-07-10 Институт молекулярной генетики РАН Alprazolam high-labeled with tritium and a method of its preparing

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2398755C1 (en) * 2009-03-27 2010-09-10 Учреждение Российской академии наук Институт молекулярной генетики РАН (ИМГ РАН) 5-(1,1-dimethylheptyl)-2-[5-hydroxy-2-(3-hydroxypropyl)cyclohexyl]phenol uniformly labelled with tritium

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