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RU2329963C1 - Strontium glaze - Google Patents

Strontium glaze Download PDF

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Publication number
RU2329963C1
RU2329963C1 RU2006146194/03A RU2006146194A RU2329963C1 RU 2329963 C1 RU2329963 C1 RU 2329963C1 RU 2006146194/03 A RU2006146194/03 A RU 2006146194/03A RU 2006146194 A RU2006146194 A RU 2006146194A RU 2329963 C1 RU2329963 C1 RU 2329963C1
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RU
Russia
Prior art keywords
glaze
sro
cao
mgo
tio
Prior art date
Application number
RU2006146194/03A
Other languages
Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006146194/03A priority Critical patent/RU2329963C1/en
Application granted granted Critical
Publication of RU2329963C1 publication Critical patent/RU2329963C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: chemistry.
SUBSTANCE: invention is used for coating of facing plates, products of decorative-artistic purposes. Glaze is composed of, mass%: SiO2 50.0-54.0; Al2O3 8.0-10.0; B2O3 10.0-12.0; SrO 10.0-12.0; CaO 1.0-2.0; K2O 1.0-2.0; Na2O 1.0-2.0; MgO 1.0-2.0; TiO2 2.0-3.0; ZrO2 2.0-3.0; SnO2 1.0-2.0. The positive effect: the heat resistance of the glaze is 15-17 thermal cycles.
EFFECT: increasing the heat resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов и касается составов фриттованных глазурей, используемых для покрытия облицовочной плитки, изделий декоративно-художественного назначения.The invention relates to the field of technology of silicates and relates to compositions of fritted glazes used to cover tiles, decorative and artistic products.

Известна глазурь, включающая, мас.%: SiO2 51,65-52,0; Al2O3 6,49-6,58; B2O3 16,8-17,8; SrO 14,05-14,18; CaO 1,73-1,79; K2O 1,64-1,69; Na2O 1,06-1,16; MgO 0,21-0,29; TiO2 0,11-0,16; ZnO 4,8-5,0; Fe2O3 0,21-0,28 /1/.Known glaze, including, wt.%: SiO 2 51,65-52,0; Al 2 O 3 6.49-6.58; B 2 O 3 16.8-17.8; SrO 14.05-14.18; CaO 1.73-1.79; K 2 O 1.64-1.69; Na 2 O 1.06-1.16; MgO 0.21-0.29; TiO 2 0.11-0.16; ZnO 4.8-5.0; Fe 2 O 3 0.21-0.28 / 1 /.

Известна глазурь, включающая, мас.%: SiO2 50,21-52,6; Al2O3 7,5-7,96; B2O3 12,07-12,66; SrO 11,27-11,81; CaO 1,87-1,92; K2O 0,31-0,38; Na2O 11,86-12,43; MgO 0,21-0,25; TiO2 0,1-4,57 /2/.Known glaze, including, wt.%: SiO 2 50,21-52,6; Al 2 O 3 7.5-7.96; B 2 O 3 12.07-12.66; SrO 11.27-11.81; CaO 1.87-1.92; K 2 O 0.31-0.38; Na 2 O 11.86-12.43; MgO 0.21-0.25; TiO 2 0.1-4.57 / 2 /.

Целью изобретения является повышение термостойкости глазури.The aim of the invention is to increase the heat resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят ZrO2 и SnO2, при следующем соотношении компонентов, мас.%: SiO2 50,0-54,0; Al2O3 8,00-10,00; B2O3 10,0-12,0; SrO 10,0-12,0; CaO 1,0-2,0; K2O 1,0-2,0; Na2O 1,0-2,0; MgO 1,0-2,0; TiO2 2,0-3,0; ZrO2 2,0-3,0; SnO2 1,0-2,0.The goal is achieved by the fact that ZrO 2 and SnO 2 are additionally added to the glaze, in the following ratio of components, wt.%: SiO 2 50.0-54.0; Al 2 O 3 8.00-10.00; B 2 O 3 10.0-12.0; SrO 10.0-12.0; CaO 1.0-2.0; K 2 O 1.0-2.0; Na 2 O 1.0-2.0; MgO 1.0-2.0; TiO 2 2.0-3.0; ZrO 2 2.0-3.0; SnO 2 1.0-2.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

  СоставStructure Компоненты, мас.%:Components, wt.%: Термостойкость, циклыHeat resistance cycles SiO2 SiO 2 Al2O3 Al 2 O 3 B2O3 B 2 O 3 SrOSro CaOCao K2OK 2 O Na2ONa 2 O MgOMgO TiO2 TiO 2 ZrO2 ZrO 2 SnO2 Sno 2 1one 50,050,0 10,010.0 10,010.0 12,012.0 1,01,0 1,01,0 2,02.0 2,02.0 3,03.0 3,03.0 1,01,0 15-1715-17 22 52,052.0 9,09.0 11,011.0 11,011.0 1,51,5 1,51,5 1,51,5 1,51,5 2,52,5 2,52,5 1,51,5 15-1715-17 33 54,054.0 8,08.0 12,012.0 10,010.0 2,02.0 2,02.0 1,01,0 1,01,0 2,02.0 2,02.0 2,02.0 15-1715-17

Фритту варят при 1300°C, расплав гранулируют в воду. Фритту с добавкой 3,0% глины, 0,2% электролита, 47,0% воды размалывают до полного прохождения через сито №0056. Суспензию наносят на изделия, сушат и закрепляют обжигом при 950°C.The frit is boiled at 1300 ° C, the melt is granulated into water. The frit with the addition of 3.0% clay, 0.2% electrolyte, 47.0% water is ground until it passes through a No. 0056 sieve. The suspension is applied to the products, dried and fixed by firing at 950 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №372188, С03С 9/00, 1973.1. USSR author's certificate No. 372188, С03С 9/00, 1973.

2. Авторское свидетельство СССР №700477, С03С 9/00, 1979.2. Copyright certificate of the USSR No. 700477, C03C 9/00, 1979.

Claims (1)

Стронциевая глазурь, содержащая SiO2, Al2О3, В2О3, SrO, CaO, K2О, Na2O, MgO, TiO2, отличающаяся тем, что дополнительно содержит ZrO2 и SnO2 при следующем соотношении компонентов, мас.%: SiO2 50,0-54,0; Al2О3 8,0-10,0; В2О3 10,0-12,0; SrO 10,0-12,0; CaO 1,0-2,0; K2O 1,0-2,0; Na2O 1,0-2,0; MgO 1,0-2,0; TiO2 2,0-3,0; ZrO2 2,0-3,0; SnO2 1,0-2,0.Strontium glaze containing SiO 2 , Al 2 O 3 , B 2 O 3 , SrO, CaO, K 2 O, Na 2 O, MgO, TiO 2 , characterized in that it additionally contains ZrO 2 and SnO 2 in the following ratio of components, wt.%: SiO 2 50,0-54,0; Al 2 O 3 8.0-10.0; B 2 O 3 10.0-12.0; SrO 10.0-12.0; CaO 1.0-2.0; K 2 O 1.0-2.0; Na 2 O 1.0-2.0; MgO 1.0-2.0; TiO 2 2.0-3.0; ZrO 2 2.0-3.0; SnO 2 1.0-2.0.
RU2006146194/03A 2006-12-25 2006-12-25 Strontium glaze RU2329963C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006146194/03A RU2329963C1 (en) 2006-12-25 2006-12-25 Strontium glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006146194/03A RU2329963C1 (en) 2006-12-25 2006-12-25 Strontium glaze

Publications (1)

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RU2329963C1 true RU2329963C1 (en) 2008-07-27

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU700477A1 (en) * 1977-08-02 1979-11-30 Ивановский Химико-Технологический Институт Stroncium enamel
US4361654A (en) * 1980-09-29 1982-11-30 Ngk Insulators, Ltd. Porcelain enamel frit for sheet iron ground coat
FR2732960B1 (en) * 1995-04-14 1997-06-20 Eurokera NO LEAD-FREE ENAMELS FOR THE DECORATION OF LOW-EXPANSION VITROCERAMICS
WO1998035917A1 (en) * 1997-02-18 1998-08-20 Technology Partners Inc. Metal-ceramic composite coatings, materials, methods and products

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU700477A1 (en) * 1977-08-02 1979-11-30 Ивановский Химико-Технологический Институт Stroncium enamel
US4361654A (en) * 1980-09-29 1982-11-30 Ngk Insulators, Ltd. Porcelain enamel frit for sheet iron ground coat
FR2732960B1 (en) * 1995-04-14 1997-06-20 Eurokera NO LEAD-FREE ENAMELS FOR THE DECORATION OF LOW-EXPANSION VITROCERAMICS
WO1998035917A1 (en) * 1997-02-18 1998-08-20 Technology Partners Inc. Metal-ceramic composite coatings, materials, methods and products

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