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RU2326838C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2326838C1
RU2326838C1 RU2006143406/03A RU2006143406A RU2326838C1 RU 2326838 C1 RU2326838 C1 RU 2326838C1 RU 2006143406/03 A RU2006143406/03 A RU 2006143406/03A RU 2006143406 A RU2006143406 A RU 2006143406A RU 2326838 C1 RU2326838 C1 RU 2326838C1
Authority
RU
Russia
Prior art keywords
glaze
sio
cao
zno
pbo
Prior art date
Application number
RU2006143406/03A
Other languages
Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006143406/03A priority Critical patent/RU2326838C1/en
Application granted granted Critical
Publication of RU2326838C1 publication Critical patent/RU2326838C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/102—Glass compositions containing silica with 40% to 90% silica, by weight containing lead
    • C03C3/108—Glass compositions containing silica with 40% to 90% silica, by weight containing lead containing boron

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: chemistry.
SUBSTANCE: invention pertains to the technology of silicates, and particularly to fritted glaze compounds, used in making face tiles. The glaze consists of the following components with the given percentage mass ratios: SiO2 59.0-65.0; Al2O3 3.0-5.0; CaO 10.0-12.0; Na2O 2.0-3.0; K2O 2.0-3.0; Co2O3 0.5-2.0; B2O3 10.0-12.0; ZnO 4.0-5.0; PbO 1.0-1.5.
EFFECT: increased frost resistance of the glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, а именно к составам фриттованных глазурей, используемых в производстве облицовочной плитки.The invention relates to the field of technology of silicates, and in particular to compositions of fritted glazes used in the manufacture of facing tiles.

Известна глазурь, включающая, мас.%: SiO2 55,54-59,42; Al2O3 12,81-13,27; Fe2O3 0,39-0,44; MgO 2,28-2,7; CaO 3,42-3,69; Na2O 2,86-3,0; K2O 2,18-2,32; ZnO 4,0-8,0; Co2O3 3,0-5,0; TiO2 0,1; BaO 7,39-9,21 /1/.Glaze is known, including, wt.%: SiO 2 55.54-59.42; Al 2 O 3 12.81-13.27; Fe 2 O 3 0.39-0.44; MgO 2.28-2.7; CaO 3.42-3.69; Na 2 O 2.86-3.0; K 2 O 2,18-2,32; ZnO 4.0-8.0; Co 2 O 3 3.0-5.0; TiO 2 0.1; BaO 7.39-9.21 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 43,6-45,4; Al2O3 4,5-5,1; CaO 3,0-3,52; Na2O 32,8-33,3; K2O 3,33-3,9; Co2O3 1,0-1,6; B2O3 7,6-10,5; Fe2O3 0,1-0,24; SO3 0,1-0,22 /2/.Known glaze containing, in wt.%: SiO 2 43.6-45.4; Al 2 O 3 4.5-5.1; CaO 3.0-3.52; Na 2 O 32.8-33.3; K 2 O 3,33-3,9; Co 2 O 3 1.0-1.6; B 2 O 3 7.6-10.5; Fe 2 O 3 0.1-0.24; SO 3 0.1-0.22 / 2 /.

Цель изобретения состоит в повышении морозостойкости глазури.The purpose of the invention is to increase the frost resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят ZnO и PbO, при следующем соотношении компонентов, мас.%: SiO2 59,0-65,0; Al2O3 3,0-5,0; CaO 10,0-12,0; Na2O 2,0-3,0; K2O 2,0-3,0; Co2O3 0,5-2,0; B2O3 10,0-12,0; ZnO 4,0-5,0; PbO 1,0-1,5.The goal is achieved by the fact that the composition of the glaze is additionally introduced ZnO and PbO, in the following ratio of components, wt.%: SiO 2 59,0-65,0; Al 2 O 3 3.0-5.0; CaO 10.0-12.0; Na 2 O 2.0-3.0; K 2 O 2.0-3.0; Co 2 O 3 0.5-2.0; B 2 O 3 10.0-12.0; ZnO 4.0-5.0; PbO 1.0-1.5.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable Состав №Composition No. Компоненты, мас.%:Components, wt.%: Морозостойкость, циклыFrost resistance cycles SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao Na2ONa 2 O K2OK 2 O Co2O3 Co 2 O 3 B2O3 B 2 O 3 ZnOZno PbOPbo 1one 59,059.0 5,05,0 12,012.0 3,03.0 2,02.0 2,02.0 12,012.0 4,04.0 1,01,0 130-135130-135 22 62,062.0 4,04.0 11,011.0 2,52,5 2,52,5 1,21,2 11,011.0 4,54,5 1,31.3 135-140135-140 33 65,065.0 3,03.0 10,010.0 2,02.0 3,03.0 0,50.5 10,010.0 5,05,0 1,51,5 135-140135-140

Фритту варят при 1400°C, расплав гранулируют в воду. Фритту размалывают с добавкой 1,0% глины, 0,1% электролита K2SiO3 и Na2SiO3, 48,0% воды. Размол проводят до прохождения через сетку №0056. Суспензию наносят на изделия, сушат и обжигают при 1000°С.The frit is boiled at 1400 ° C, the melt is granulated into water. The frit is ground with the addition of 1.0% clay, 0.1% electrolyte K 2 SiO 3 and Na 2 SiO 3 , 48.0% water. Grinding is carried out before passing through the mesh No. 0056. The suspension is applied to the products, dried and fired at 1000 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №876576, С03С 9/00, 1981.1. USSR author's certificate No. 876576, С03С 9/00, 1981.

2. Авторское свидетельство СССР №990704, С03С 9/00, 1982.2. USSR author's certificate No. 990704, С03С 9/00, 1982.

Claims (1)

Глазурь, содержащая SiO2, Al2O3, CaO, Na2O, K2O, Co2O3, B2O3, отличающаяся тем, что дополнительно содержит ZnO и PbO при следующем соотношении компонентов, мас.%:Glaze containing SiO 2 , Al 2 O 3 , CaO, Na 2 O, K 2 O, Co 2 O 3 , B 2 O 3 , characterized in that it additionally contains ZnO and PbO in the following ratio, wt.%: SiO2 SiO 2 59,0-65,059.0-65.0 Al2О3 Al 2 About 3 3,0-5,03.0-5.0 CaOCao 10,0-12,010.0-12.0 Na2ONa 2 O 2,0-3,02.0-3.0 К2ОK 2 O 2,0-3,02.0-3.0 Со2О3 Co 2 O 3 0,5-2,00.5-2.0 В2О3 B 2 O 3 10,0-12,010.0-12.0 ZnOZno 4,0-5,04.0-5.0 PbOPbo 1,0-1,51.0-1.5
RU2006143406/03A 2006-12-07 2006-12-07 Glaze RU2326838C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006143406/03A RU2326838C1 (en) 2006-12-07 2006-12-07 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006143406/03A RU2326838C1 (en) 2006-12-07 2006-12-07 Glaze

Publications (1)

Publication Number Publication Date
RU2326838C1 true RU2326838C1 (en) 2008-06-20

Family

ID=39637356

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006143406/03A RU2326838C1 (en) 2006-12-07 2006-12-07 Glaze

Country Status (1)

Country Link
RU (1) RU2326838C1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2430037C1 (en) * 2010-04-09 2011-09-27 Юлия Алексеевна Щепочкина Glase

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2430037C1 (en) * 2010-04-09 2011-09-27 Юлия Алексеевна Щепочкина Glase

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