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RU2329210C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2329210C1
RU2329210C1 RU2006146176/03A RU2006146176A RU2329210C1 RU 2329210 C1 RU2329210 C1 RU 2329210C1 RU 2006146176/03 A RU2006146176/03 A RU 2006146176/03A RU 2006146176 A RU2006146176 A RU 2006146176A RU 2329210 C1 RU2329210 C1 RU 2329210C1
Authority
RU
Russia
Prior art keywords
glaze
cao
tio
mno
mgo
Prior art date
Application number
RU2006146176/03A
Other languages
Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006146176/03A priority Critical patent/RU2329210C1/en
Application granted granted Critical
Publication of RU2329210C1 publication Critical patent/RU2329210C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/102—Glass compositions containing silica with 40% to 90% silica, by weight containing lead
    • C03C3/108—Glass compositions containing silica with 40% to 90% silica, by weight containing lead containing boron

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: chemistry.
SUBSTANCE: glaze can be used in production of construction ceramics. The glaze consists of the following components in the given percentage mass ratios: SiO2 47.5-53.0; Al2O3 4.0-6.0; B2O3 12.0-16.0; CaO 8.0-12.0; Na2O 2.0-4.0; K2O 2.0-4.0; MgO 2.0-4.0; MnO 0.5-1.0; Fe2O3 3.5-5.0; TiO2 2.0-4.0; ZnO 2.0-4.0; PbO 0.5-1.0.
EFFECT: frost resistance of glaze is increase to 110-120 cycles.
1 tbl

Description

Изобретение относится к области технологии силикатов и касается составов нефриттованных глазурей, используемых в производстве строительной керамики.The invention relates to the field of technology of silicates and relates to compositions of jade glazes used in the manufacture of building ceramics.

Извесина глазурь, включающая, мас.%: SiO2 63,2-64,7; Al2O3 10,72-12,02; CaO 6,77-8,71; Na2O 2,23-4,25; K2O 2,44-5,67; MgO 0,14-0,31; MnO 4,09-6,54; Fe2O3 2,87-3,86; TiO2 0,2-0,31; SO3 0,77-0,95 /1/.Lime glaze, including, wt.%: SiO 2 63.2-64.7; Al 2 O 3 10.72-12.02; CaO 6.77-8.71; Na 2 O, 2.23-4.25; K 2 O 2,44-5,67; MgO 0.14-0.31; MnO 4.09-6.54; Fe 2 O 3 2.87-3.86; TiO 2 0.2-0.31; SO 3 0.77-0.95 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 45,15-48,93; Al2O3 14,12-17,58; B2O3 7,4-23,31; CaO 5,25-12,04; Na2O 4,11-5,15; K2O 1,5-1,64; MgO 1,15-2,89; MnO 0,63-0,73; Fe2O3 4,2-5,84; TiO2 0,58-0,63 /2/.Known glaze containing, in wt.%: SiO 2 45.15-48.93; Al 2 O 3 14.12-17.58; B 2 O 3 7.4-23.31; CaO 5.25-12.04; Na 2 O 4.11-5.15; K 2 O 1.5-1.64; MgO 1.15-2.89; MnO 0.63-0.73; Fe 2 O 3 4.2-5.84; TiO 2 0.58-0.63 / 2 /.

Цель изобретения - повышение морозостойкости глазури.The purpose of the invention is to increase frost resistance of glaze.

Цель достигается тем, что в состав глазури дополнительно вводят ZnO и PbO при следующем соотношение компонентов, мас.%: SiO2 47,5-53,0; Al2O3 4,0-6,0; B2O3 12,0-16,0; CaO 8,0-12,0; Na2O 2,0-4,0; K2O 2,0-4,0; MgO 2,0-4,0; MnO 0,5-1,0; Fe2O3 3,5-5,0; TiO2 2,0-4,0; ZnO 2,0-4,0; PbO 0,5-1,0.The goal is achieved by the fact that ZnO and PbO are additionally added to the glaze in the following ratio of components, wt.%: SiO 2 47.5-53.0; Al 2 O 3 4.0-6.0; B 2 O 3 12.0-16.0; CaO 8.0-12.0; Na 2 O 2,0-4,0; K 2 O 2.0-4.0; MgO 2.0-4.0; MnO 0.5-1.0; Fe 2 O 3 3.5-5.0; TiO 2 2.0-4.0; ZnO 2.0-4.0; PbO 0.5-1.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

СоставStructure Компоненты, мас.%Components, wt.% SiO2 SiO 2 Al2O3 Al 2 O 3 B2O3 B 2 O 3 CaOCao Na2ONa 2 O K2OK 2 O MgOMgO MnOMnO Fe2O3 Fe 2 O 3 TiO2 TiO 2 ZnOZno PbOPbo 1one 53,053.0 4,04.0 16,016,0 8,08.0 2,02.0 2,02.0 4,04.0 0,50.5 3,53,5 4,04.0 2,02.0 1,01,0 22 50,350.3 5,05,0 14,014.0 10,010.0 3,03.0 3,03.0 3,03.0 0,750.75 4,24.2 3,03.0 3,03.0 0,750.75 33 47,547.5 6,06.0 12,012.0 12,012.0 4,04.0 4,04.0 2,02.0 1,01,0 5,05,0 2,02.0 4,04.0 0,50.5

Компоненты размалывают с добавкой 0,1-0,2% электролита и 45-50% воды до прохождения через сетку №0056. Суспензию наносят на изделия, сушат, закрепляют обжигом при 1000°С. Морозостойкость глазури составит 110-120 циклов.The components are ground with the addition of 0.1-0.2% electrolyte and 45-50% water until passing through mesh No. 0056. The suspension is applied to the product, dried, fixed by firing at 1000 ° C. Frost resistance of the glaze will be 110-120 cycles.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1488287, С04В 41/86, 1989.1. USSR author's certificate No. 1488287, С04В 41/86, 1989.

2. Авторское свидетельство СССР №857032, С03С 9/00, 1981.2. USSR author's certificate No. 857032, С03С 9/00, 1981.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, В2О3, CaO, Na2O, К2О, MgO, MnO, Fe2О3, TiO2, отличающаяся тем, что дополниетельно содержит ZnO и PbO при следующем соотношении компонентов, мас.%: SiO2 47,5-53,0; Al2О3 4,0-6,0; В2О3 12,0-16,0; CaO 8,0-12,0; Na2O 2,0-4,0; К2О 2,0-4,0; MgO 2,0-4,0; MnO 0,5-1,0; Fe2О3 3,5-5,0; TiO2 2,0-4,0; ZnO 2,0-4,0; PbO 0,5-1,0.Glaze containing SiO 2 , Al 2 O 3 , B 2 O 3 , CaO, Na 2 O, K 2 O, MgO, MnO, Fe 2 O 3 , TiO 2 , characterized in that it additionally contains ZnO and PbO in the following ratio components, wt.%: SiO 2 47.5-53.0; Al 2 O 3 4.0-6.0; B 2 O 3 12.0-16.0; CaO 8.0-12.0; Na 2 O 2,0-4,0; K 2 O 2.0-4.0; MgO 2.0-4.0; MnO 0.5-1.0; Fe 2 O 3 3.5-5.0; TiO 2 2.0-4.0; ZnO 2.0-4.0; PbO 0.5-1.0.
RU2006146176/03A 2006-12-25 2006-12-25 Glaze RU2329210C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006146176/03A RU2329210C1 (en) 2006-12-25 2006-12-25 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006146176/03A RU2329210C1 (en) 2006-12-25 2006-12-25 Glaze

Publications (1)

Publication Number Publication Date
RU2329210C1 true RU2329210C1 (en) 2008-07-20

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RU2006146176/03A RU2329210C1 (en) 2006-12-25 2006-12-25 Glaze

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2417168C1 (en) * 2010-01-11 2011-04-27 Юлия Алексеевна Щепочкина Glase

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU857032A1 (en) * 1979-08-22 1981-08-23 Государственный научно-исследовательский институт строительной керамики Enamel
US4361654A (en) * 1980-09-29 1982-11-30 Ngk Insulators, Ltd. Porcelain enamel frit for sheet iron ground coat
FR2732960B1 (en) * 1995-04-14 1997-06-20 Eurokera NO LEAD-FREE ENAMELS FOR THE DECORATION OF LOW-EXPANSION VITROCERAMICS

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU857032A1 (en) * 1979-08-22 1981-08-23 Государственный научно-исследовательский институт строительной керамики Enamel
US4361654A (en) * 1980-09-29 1982-11-30 Ngk Insulators, Ltd. Porcelain enamel frit for sheet iron ground coat
FR2732960B1 (en) * 1995-04-14 1997-06-20 Eurokera NO LEAD-FREE ENAMELS FOR THE DECORATION OF LOW-EXPANSION VITROCERAMICS

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2417168C1 (en) * 2010-01-11 2011-04-27 Юлия Алексеевна Щепочкина Glase

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