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RU2314269C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2314269C1
RU2314269C1 RU2006120854/03A RU2006120854A RU2314269C1 RU 2314269 C1 RU2314269 C1 RU 2314269C1 RU 2006120854/03 A RU2006120854/03 A RU 2006120854/03A RU 2006120854 A RU2006120854 A RU 2006120854A RU 2314269 C1 RU2314269 C1 RU 2314269C1
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RU
Russia
Prior art keywords
glaze
zro
cao
mgo
sio
Prior art date
Application number
RU2006120854/03A
Other languages
Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006120854/03A priority Critical patent/RU2314269C1/en
Application granted granted Critical
Publication of RU2314269C1 publication Critical patent/RU2314269C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: composition of non-fritted glazes which are used for manufacture of tiles.
SUBSTANCE: proposed glaze contains the following components, mass-%: SiO2, 48.0-52.0; Al2O3, 6.0-10.0; K2O, 3.0-4.0; Na2O, 1.0-2.0; CaO, 6.0-10.0; Fe2O3, 0.5-1.5; ZnO, 4.0-6.0; MgO, 4.0-6.0; BaO, 2.5-3.5; TiO2, 3.0-5.0; P2O5, 0.5-1.5; ZrO2, 4.0-6.0; SrO, 5.5-7.5.
EFFECT: enhanced heat resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, а именно к составам нефриттованных глазурей, используемых в производстве облицовочной плитки.The invention relates to the field of technology of silicates, namely, compositions of jade glazes used in the manufacture of tiles.

Известна глазурь, состава, мас.%: Al2O3 10,21-14,92; K2O 1,12-8,8; Na2O 3,4-7,2; CaO 6,38-8,87; Fe2O3 1,19-1,51; MgO 0,02-0,59; ZrO2 5,9-6,56; B2O3 0,01-10,91; SO3 0,39-0,81; SiO2 - остальное /1/.Known glaze composition, wt%: Al 2 O 3 10,21-14,92;. K 2 O 1.12-8.8; Na 2 O 3,4-7,2; CaO 6.38-8.87; Fe 2 O 3 1.19-1.51; MgO 0.02-0.59; ZrO 2 5.9-6.56; B 2 O 3 0.01-10.91; SO 3 0.39-0.81; SiO 2 - the rest / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 48,75-67,25; Al2O3 9,25-13,51; K2O 3,5-6,31; Na2O 0,73-2,09; CaO 6,52-8,65; Fe2O3 2,3-2,45; ZnO 1,4-5,43; MgO 5,1-5,4; BaO 2,4-5,21; TiO2 1,5-2,2 /2/.Known glaze containing, in wt.%: SiO 2 48.75-67.25; Al 2 O 3 9.25-13.51; K 2 O 3,5-6,31; Na 2 O, 0.73-2.09; CaO 6.52-8.65; Fe 2 O 3 2.3-2.45; ZnO 1.4-5.43; MgO 5.1-5.4; BaO 2.4-5.21; TiO 2 1.5-2.2 / 2 /.

Цель изобретения - повышение термостойкости глазури.The purpose of the invention is to increase the heat resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят P2O5, ZrO2, SrO при следующем соотношении компонентов, мас.%: SiO2 48,0-52,0; Al2O3 6,0-10,0; K2O 3,0-4,0; Na2O 1,0-2,0; CaO 6,0-10,0; Fe2O3 0,5-1,5; ZnO 4,0-6,0; MgO 4,0-6,0; BaO 2,5-3,5; TiO2 3,0-5,0; P2O5 0,5-1,5; ZrO2 4,0-6,0; SrO 5,5-7,5.The goal is achieved in that the composition of the glaze is additionally introduced P 2 O 5 , ZrO 2 , SrO in the following ratio of components, wt.%: SiO 2 48,0-52,0; Al 2 O 3 6.0-10.0; K 2 O 3.0-4.0; Na 2 O 1.0-2.0; CaO 6.0-10.0; Fe 2 O 3 0.5-1.5; ZnO 4.0-6.0; MgO 4.0-6.0; BaO 2.5-3.5; TiO 2 3.0-5.0; P 2 O 5 0.5-1.5; ZrO 2 4.0-6.0; SrO 5.5-7.5.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас %:Components, wt%: Термостойкость, циклыHeat resistance cycles SiO2 SiO 2 Al2O3 Al 2 O 3 K2OK 2 O Na2ONa 2 O CaOCao Fe2O3 Fe 2 O 3 ZnOZno MgOMgO BaOBao TiO2 TiO 2 P2O5 P 2 O 5 ZrO2 ZrO 2 SrOSro 1one 48,048.0 10,010.0 3,03.0 2,02.0 6,06.0 1,51,5 4,04.0 6,06.0 2,52,5 5,05,0 0,50.5 4,04.0 7,57.5 ~25~ 25 22 50,050,0 8,08.0 3,53,5 1,51,5 8,08.0 1,01,0 5,05,0 5,05,0 3,03.0 4,04.0 1,01,0 4,04.0 6,06.0 ~25~ 25 33 52,052.0 6,06.0 4,04.0 1,01,0 10,010.0 0,50.5 6,06.0 4,04.0 3,53,5 3,03.0 1,51,5 6,06.0 5,55.5 ~25~ 25

Компоненты глазури с добавкой 0,2% электролита и 47% воды размалывают до остатка не более 0,2% на сетке №005. Глазурную суспензию наносят на изделия и закрепляют обжигом при 1100°С.Glaze components with the addition of 0.2% electrolyte and 47% water are ground to a residue of not more than 0.2% on mesh No. 005. The glaze suspension is applied to the products and fixed by firing at 1100 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1318562, С32С 8/02, 1987.1. USSR author's certificate No. 1318562, C32C 8/02, 1987.

2. Авторское свидетельство СССР №1486501, С04В 41/86, 1989.2. USSR author's certificate No. 1486501, С04В 41/86, 1989.

Claims (1)

Глазурь, содержащая SiO2, Al2O3, K2O, Na2O, CaO, Fe2O3, ZnO, MgO, BaO, TiO2, отличающаяся тем, что дополнительно содержит Р2O5, ZrO2, SrO, при следующем соотношении компонентов, мас.%: SiO2 48,0-52,0; Al2O3 6,0-10,0; K2O 3,0-4,0; Na2O 1,0-2,0; CaO 6,0-10,0; Fe2O3 0,5-1,5; ZnO 4,0-6,0; MgO 4,0-6,0; BaO 2,5-3,5; TiO2 3,0-5,0; P2O5 0,5-1,5; ZrO2 4,0-6,0; SrO 5,5-7,5.Glaze containing SiO 2 , Al 2 O 3 , K 2 O, Na 2 O, CaO, Fe 2 O 3 , ZnO, MgO, BaO, TiO 2 , characterized in that it further comprises P 2 O 5 , ZrO 2 , SrO , in the following ratio of components, wt.%: SiO 2 48,0-52,0; Al 2 O 3 6.0-10.0; K 2 O 3.0-4.0; Na 2 O 1.0-2.0; CaO 6.0-10.0; Fe 2 O 3 0.5-1.5; ZnO 4.0-6.0; MgO 4.0-6.0; BaO 2.5-3.5; TiO 2 3.0-5.0; P 2 O 5 0.5-1.5; ZrO 2 4.0-6.0; SrO 5.5-7.5.
RU2006120854/03A 2006-06-13 2006-06-13 Glaze RU2314269C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006120854/03A RU2314269C1 (en) 2006-06-13 2006-06-13 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
RU2314269C1 true RU2314269C1 (en) 2008-01-10

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006120854/03A RU2314269C1 (en) 2006-06-13 2006-06-13 Glaze

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU310874A1 (en) * Научно исследовательский , конструкторско технологический институт SEMI-CONDUCTING EYE
SU399471A1 (en) * 1971-12-01 1973-10-03 GLAZE
SU1318562A1 (en) * 1985-11-19 1987-06-23 Московский химико-технологический институт им.Д.И.Менделеева Glaze
SU1486501A1 (en) * 1987-09-11 1989-06-15 Gnii Stroitelnoj Keramiki Glaze

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU310874A1 (en) * Научно исследовательский , конструкторско технологический институт SEMI-CONDUCTING EYE
SU399471A1 (en) * 1971-12-01 1973-10-03 GLAZE
SU1318562A1 (en) * 1985-11-19 1987-06-23 Московский химико-технологический институт им.Д.И.Менделеева Glaze
SU1486501A1 (en) * 1987-09-11 1989-06-15 Gnii Stroitelnoj Keramiki Glaze

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