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RU2304132C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2304132C1
RU2304132C1 RU2006112680/03A RU2006112680A RU2304132C1 RU 2304132 C1 RU2304132 C1 RU 2304132C1 RU 2006112680/03 A RU2006112680/03 A RU 2006112680/03A RU 2006112680 A RU2006112680 A RU 2006112680A RU 2304132 C1 RU2304132 C1 RU 2304132C1
Authority
RU
Russia
Prior art keywords
glaze
zro
cao
sio
tio
Prior art date
Application number
RU2006112680/03A
Other languages
Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006112680/03A priority Critical patent/RU2304132C1/en
Application granted granted Critical
Publication of RU2304132C1 publication Critical patent/RU2304132C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: facing tile coatings.
SUBSTANCE: glaze contains next relation of components, mass %: SiO2, 54.0 - 56.0; Al2O3, 2.0 - 4.0; B203, 6.0 - 8.0; CaO, 9.0 -10.0; K2O, 1.8 - 2.8; ZrO2, 14.0 -16.0; TiO2, 6.0 - 8.0; As2 O3, 0.1 - 0.2. Glaze includes in addition component selected from group CoO, NiO, Cr2O3, 0.5 - 1.5.
EFFECT: improved heat resistance and cold resistance of glaze.
2 cl, 1 tbl

Description

Изобретение относится к технологии силикатов, а именно к составам глазури, которая может быть эффективно использована для покрытия облицовочной плитки.The invention relates to the technology of silicates, namely to the compositions of the glaze, which can be effectively used to cover tiles.

Известна глазурь, содержащая SiO2, Al2O3, CaO, K2O, ZrO2 и другие компоненты /1/.Known glaze containing SiO 2 , Al 2 O 3 , CaO, K 2 O, ZrO 2 and other components / 1 /.

Известна глазурь следующего состава, мас.%: SiO2 56-62,5; Al2O3 2,5-5,0; B2O3 11,0-14,0; CaO 2-6; MgO 1,5-5,0; K2O 0,5-3,0; Na2O 6,0-9,0; ZrO2 7,5-11,0 /2/. Термостойкость такой глазури 220-230°С, морозостойкость около 50 циклов.Glaze of the following composition is known, wt.%: SiO 2 56-62.5; Al 2 O 3 2.5-5.0; B 2 O 3 11.0-14.0; CaO 2-6; MgO 1.5-5.0; K 2 O 0.5-3.0; Na 2 O 6.0-9.0; ZrO 2 7.5-11.0 / 2 /. Heat resistance of such a glaze 220-230 ° C, frost resistance of about 50 cycles.

Цель изобретения - повышение термостойкости и морозостойкости глазури.The purpose of the invention is to increase the heat resistance and frost resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят TiO2 и As2O3, при следующем соотношении компонентов, мас.%: SiO2 54,0-56,0; Al2O3 2,0-4,0; B2O3 6,0-8,0; CaO 9,0-10,0; K2O 1,8-2,8; ZrO2 14,0-16,0; TiO2 6,0-8,0; As2O3 0,1-0,2. С целью повышения декоративных свойств глазурь дополнительно содержит компонент из группы CoO, NiO, Cr2O3 0,5-1,5.The goal is achieved by the fact that TiO 2 and As 2 O 3 are additionally added to the glaze composition, in the following ratio of components, wt.%: SiO 2 54.0-56.0; Al 2 O 3 2.0-4.0; B 2 O 3 6.0-8.0; CaO 9.0-10.0; K 2 O 1.8-2.8; ZrO 2 14.0-16.0; TiO 2 6.0-8.0; As 2 O 3 0.1-0.2. In order to increase the decorative properties, the glaze additionally contains a component from the group CoO, NiO, Cr 2 O 3 0.5-1.5.

В таблице приведены составы глазури.The table shows the glaze compositions.

СоставStructure Компоненты, мас.%:Components, wt.%:   SiO2 SiO 2 Al2O3 Al 2 O 3 B2O3 B 2 O 3 CaOCao K2OK 2 O ZrO2 ZrO 2 TiO2 TiO 2 As2O3 As 2 O 3 CoOCoo NiONio Cr2O3 Cr 2 O 3 1one 54,054.0 4,04.0 7,57.5 9,09.0 2,82,8 14,014.0 8,08.0 0,20.2 0,50.5 -- -- 22 56,056.0 3,03.0 6,06.0 9,59.5 2,42,4 15,015.0 7,07.0 0,10.1 -- 1,01,0 -- 33 54,554.5 2,02.0 8,08.0 10,010.0 1,81.8 16,016,0 6,06.0 0,20.2 -- -- 1,51,5

Термостойкость глазури составит ~350°С, а морозостойкость ~150 циклов для всех приведенных в таблице составов.The temperature resistance of the glaze will be ~ 350 ° C, and frost resistance ~ 150 cycles for all the compositions listed in the table.

Компоненты глазури сплавляют при 1300°С с последующей грануляцией в воду. Фритту размалывают мокрым способом с добавкой 4-6% глины. Полученную суспензию наносят на изделия и обжигают при 1000°C.Glaze components are fused at 1300 ° C followed by granulation into water. The frit is ground wet with the addition of 4-6% clay. The resulting suspension is applied to products and fired at 1000 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №612908, С03С 9/00, 1976.1. USSR copyright certificate No. 612908, С03С 9/00, 1976.

2. Авторское свидетельство СССР №765223, С03С 9/00, 1980.2. USSR Author's Certificate No. 765223, С03С 9/00, 1980.

Claims (2)

1. Глазурь, содержащая SiO2, Al2О3, В2О3, CaO, К2O, ZrO2, отличающаяся тем, что дополнительно содержит TiO2 и As2О3 при следующем соотношении компонентов, мас.%:1. Glaze containing SiO 2 , Al 2 O 3 , B 2 O 3 , CaO, K 2 O, ZrO 2 , characterized in that it additionally contains TiO 2 and As 2 O 3 in the following ratio of components, wt.%: SiO2 SiO 2 54,0-56,054.0-56.0 Al2О3 Al 2 About 3 2,0-4,02.0-4.0 В2О3 B 2 O 3 6,0-8,06.0-8.0 СаОCaO 9,0-10,09.0-10.0 K2OK 2 O 1,8-2,81.8-2.8 ZrO2 ZrO 2 14,0-16,014.0-16.0 TiO2 TiO 2 6,0-8,06.0-8.0 As2O3 As 2 O 3 0,1-0,20.1-0.2
2. Глазурь по п.1, отличающаяся тем, что дополнительно содержит компонент из группы СоО, NiO, Cr2О3 0,5-1,5.2. Glaze according to claim 1, characterized in that it further comprises a component from the group of CoO, NiO, Cr 2 O 3 0.5-1.5.
RU2006112680/03A 2006-04-17 2006-04-17 Glaze RU2304132C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006112680/03A RU2304132C1 (en) 2006-04-17 2006-04-17 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006112680/03A RU2304132C1 (en) 2006-04-17 2006-04-17 Glaze

Publications (1)

Publication Number Publication Date
RU2304132C1 true RU2304132C1 (en) 2007-08-10

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006112680/03A RU2304132C1 (en) 2006-04-17 2006-04-17 Glaze

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB710064A (en) * 1951-11-01 1954-06-02 British Thomson Houston Co Ltd Improvements in and relating to silicon enamel pigments
SU1761735A1 (en) * 1991-01-03 1992-09-15 Рубежанский филиал Днепропетровского химико-технологического института им.Ф.Э.Дзержинского Composition for application of glazed coating to ceramic tile

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB710064A (en) * 1951-11-01 1954-06-02 British Thomson Houston Co Ltd Improvements in and relating to silicon enamel pigments
SU1761735A1 (en) * 1991-01-03 1992-09-15 Рубежанский филиал Днепропетровского химико-технологического института им.Ф.Э.Дзержинского Composition for application of glazed coating to ceramic tile

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