RU2216534C2 - Применение моногидрата ацетилацетоната цинка в качестве стабилизатора галогенсодержащих полимеров и способ его получения - Google Patents

Применение моногидрата ацетилацетоната цинка в качестве стабилизатора галогенсодержащих полимеров и способ его получения Download PDF

Info

Publication number: RU2216534C2
Authority: RU; Russia
Prior art keywords: halogen; solvent; compounds; zinc; acetylacetone
Prior art date: 1998-03-12

Application number

RU2000125688/04A

Other languages

English (en)

Russian (ru)

Other versions

RU2000125688A (ru

Inventor

Франсуаз ЭНРИО (FR)

Франсуаз ЭНРИО

Original Assignee

Родиа Шими

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-03-12

Filing date

1999-03-12

Publication date

2003-11-20

1998-03-12 Priority claimed from FR9803067A external-priority patent/FR2775971B1/fr

1998-08-06 Priority claimed from FR9810138A external-priority patent/FR2782087B1/fr

1999-03-12 Application filed by Родиа Шими filed Critical Родиа Шими

2002-11-10 Publication of RU2000125688A publication Critical patent/RU2000125688A/ru

2003-11-20 Application granted granted Critical

2003-11-20 Publication of RU2216534C2 publication Critical patent/RU2216534C2/ru

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229920000642 polymer Polymers 0.000 title claims abstract description 50
229910052736 halogen Inorganic materials 0.000 title claims abstract description 33
150000002367 halogens Chemical class 0.000 title claims abstract description 33
238000000034 method Methods 0.000 title claims abstract description 27
239000003381 stabilizer Substances 0.000 title claims abstract description 9
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 title abstract description 4
IPCXNCATNBAPKW-UHFFFAOYSA-N zinc;hydrate Chemical compound O.[Zn] IPCXNCATNBAPKW-UHFFFAOYSA-N 0.000 title 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
239000000126 substance Substances 0.000 claims abstract description 12
239000011701 zinc Substances 0.000 claims abstract description 11
238000002425 crystallisation Methods 0.000 claims abstract 4
230000008025 crystallization Effects 0.000 claims abstract 4
239000000203 mixture Substances 0.000 claims description 51
150000001875 compounds Chemical class 0.000 claims description 41
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 35
239000002904 solvent Substances 0.000 claims description 33
NHXVNEDMKGDNPR-UHFFFAOYSA-N zinc;pentane-2,4-dione Chemical compound [Zn+2].CC(=O)[CH-]C(C)=O.CC(=O)[CH-]C(C)=O NHXVNEDMKGDNPR-UHFFFAOYSA-N 0.000 claims description 24
238000006243 chemical reaction Methods 0.000 claims description 13
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
238000009835 boiling Methods 0.000 claims description 7
229940007718 zinc hydroxide Drugs 0.000 claims description 7
229910021511 zinc hydroxide Inorganic materials 0.000 claims description 7
239000011787 zinc oxide Substances 0.000 claims description 6
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 9
229910052725 zinc Inorganic materials 0.000 abstract description 9
239000003795 chemical substances by application Substances 0.000 abstract description 3
230000000694 effects Effects 0.000 abstract description 3
230000006641 stabilisation Effects 0.000 abstract 1
238000011105 stabilization Methods 0.000 abstract 1
-1 zinc acetylacetonate monohydrate Chemical class 0.000 description 33
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 20
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 18
239000011230 binding agent Substances 0.000 description 18
239000000047 product Substances 0.000 description 14
229910052784 alkaline earth metal Inorganic materials 0.000 description 13
239000002253 acid Substances 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
239000004800 polyvinyl chloride Substances 0.000 description 9
239000011575 calcium Substances 0.000 description 8
229920000915 polyvinyl chloride Polymers 0.000 description 8
150000003254 radicals Chemical class 0.000 description 8
239000004408 titanium dioxide Substances 0.000 description 8
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150000007524 organic acids Chemical class 0.000 description 6
230000000087 stabilizing effect Effects 0.000 description 6
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
239000000654 additive Substances 0.000 description 5
125000001931 aliphatic group Chemical group 0.000 description 5
125000000217 alkyl group Chemical group 0.000 description 5
229910052791 calcium Inorganic materials 0.000 description 5
229910052500 inorganic mineral Inorganic materials 0.000 description 5
239000011777 magnesium Substances 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
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229920005862 polyol Polymers 0.000 description 5
150000003077 polyols Chemical class 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
125000003118 aryl group Chemical group 0.000 description 4
239000013078 crystal Substances 0.000 description 4
238000001125 extrusion Methods 0.000 description 4
229910052718 tin Inorganic materials 0.000 description 4
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FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
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150000001342 alkaline earth metals Chemical class 0.000 description 3
229910052788 barium Inorganic materials 0.000 description 3
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
229910052793 cadmium Inorganic materials 0.000 description 3
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000000194 fatty acid Chemical class 0.000 description 3
229930195729 fatty acid Chemical class 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
239000000314 lubricant Substances 0.000 description 3
229910052749 magnesium Inorganic materials 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
150000004682 monohydrates Chemical class 0.000 description 3
230000007935 neutral effect Effects 0.000 description 3
239000004014 plasticizer Substances 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
IQBLWPLYPNOTJC-FPLPWBNLSA-N (z)-4-(2-ethylhexoxy)-4-oxobut-2-enoic acid Chemical compound CCCCC(CC)COC(=O)\C=C/C(O)=O IQBLWPLYPNOTJC-FPLPWBNLSA-N 0.000 description 2
229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
150000005840 aryl radicals Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
230000007547 defect Effects 0.000 description 2
GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 2
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
229910001701 hydrotalcite Inorganic materials 0.000 description 2
229960001545 hydrotalcite Drugs 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
SNPREOFRPYTKLP-UHFFFAOYSA-N lead(2+);silicate Chemical compound [Pb+2].[Pb+2].[O-][Si]([O-])([O-])[O-] SNPREOFRPYTKLP-UHFFFAOYSA-N 0.000 description 2
SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical compound C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 description 2
238000000465 moulding Methods 0.000 description 2
239000003921 oil Substances 0.000 description 2
235000019198 oils Nutrition 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
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150000002989 phenols Chemical group 0.000 description 2
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
238000010992 reflux Methods 0.000 description 2
238000003756 stirring Methods 0.000 description 2
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VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
JJWLMSCSLRJSAN-TYYBGVCCSA-L (e)-but-2-enedioate;lead(2+) Chemical compound [Pb+2].[O-]C(=O)\C=C\C([O-])=O JJWLMSCSLRJSAN-TYYBGVCCSA-L 0.000 description 1
ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 1
LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical compound ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 description 1
MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
KEQXNNJHMWSZHK-UHFFFAOYSA-L 1,3,2,4$l^{2}-dioxathiaplumbetane 2,2-dioxide Chemical compound [Pb+2].[O-]S([O-])(=O)=O KEQXNNJHMWSZHK-UHFFFAOYSA-L 0.000 description 1
BPXVHIRIPLPOPT-UHFFFAOYSA-N 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)N(CCO)C(=O)N(CCO)C1=O BPXVHIRIPLPOPT-UHFFFAOYSA-N 0.000 description 1
LAYAKLSFVAPMEL-UHFFFAOYSA-N 1-ethenoxydodecane Chemical compound CCCCCCCCCCCCOC=C LAYAKLSFVAPMEL-UHFFFAOYSA-N 0.000 description 1
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VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical class CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
CVBUKMMMRLOKQR-UHFFFAOYSA-N 1-phenylbutane-1,3-dione Chemical compound CC(=O)CC(=O)C1=CC=CC=C1 CVBUKMMMRLOKQR-UHFFFAOYSA-N 0.000 description 1
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
PHBCDAHASFSLMJ-UHFFFAOYSA-N 2-hydroxybenzotriazole Chemical class C1=CC=CC2=NN(O)N=C21 PHBCDAHASFSLMJ-UHFFFAOYSA-N 0.000 description 1
239000004135 Bone phosphate Substances 0.000 description 1
RMJFUTZKSDHQAL-UHFFFAOYSA-J C(CC)(=O)[O-].[Cd+2].[Cd+2].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CC)(=O)[O-] Chemical class C(CC)(=O)[O-].[Cd+2].[Cd+2].C(CC)(=O)[O-].C(CC)(=O)[O-].C(CC)(=O)[O-] RMJFUTZKSDHQAL-UHFFFAOYSA-J 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
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239000005977 Ethylene Substances 0.000 description 1
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235000004431 Linum usitatissimum Nutrition 0.000 description 1
240000006240 Linum usitatissimum Species 0.000 description 1
229930195725 Mannitol Natural products 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical group OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
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229910004298 SiO 2 Inorganic materials 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
239000004904 UV filter Substances 0.000 description 1
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YLFRJROMPGNJRP-UHFFFAOYSA-L [dibutyl(3-sulfanylpropanoyloxy)stannyl] 3-sulfanylpropanoate Chemical compound [O-]C(=O)CCS.[O-]C(=O)CCS.CCCC[Sn+2]CCCC YLFRJROMPGNJRP-UHFFFAOYSA-L 0.000 description 1
YSCDKUPSJMMGGT-UHFFFAOYSA-L [dibutyl-[2-(6-methylheptylsulfanyl)acetyl]oxystannyl] 2-(6-methylheptylsulfanyl)acetate Chemical compound CC(C)CCCCCSCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CSCCCCCC(C)C YSCDKUPSJMMGGT-UHFFFAOYSA-L 0.000 description 1
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238000012662 bulk polymerization Methods 0.000 description 1
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OZECDDHOAMNMQI-UHFFFAOYSA-H cerium(3+);trisulfate Chemical compound [Ce+3].[Ce+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O OZECDDHOAMNMQI-UHFFFAOYSA-H 0.000 description 1
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UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
NZZIMKJIVMHWJC-UHFFFAOYSA-N dibenzoylmethane Chemical compound C=1C=CC=CC=1C(=O)CC(=O)C1=CC=CC=C1 NZZIMKJIVMHWJC-UHFFFAOYSA-N 0.000 description 1
WCRDXYSYPCEIAK-UHFFFAOYSA-N dibutylstannane Chemical compound CCCC[SnH2]CCCC WCRDXYSYPCEIAK-UHFFFAOYSA-N 0.000 description 1
239000012975 dibutyltin dilaurate Substances 0.000 description 1
PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical class C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 1
HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 1
NCGVOBCQNQWJRR-UHFFFAOYSA-L dioctyltin(2+);2-(6-methylheptylsulfanyl)acetate Chemical compound CC(C)CCCCCSCC([O-])=O.CC(C)CCCCCSCC([O-])=O.CCCCCCCC[Sn+2]CCCCCCCC NCGVOBCQNQWJRR-UHFFFAOYSA-L 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
150000002118 epoxides Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
229940013317 fish oils Drugs 0.000 description 1
235000011087 fumaric acid Nutrition 0.000 description 1
150000002238 fumaric acids Chemical class 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid group Chemical group C(CCCCC)(=O)O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
238000000265 homogenisation Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical group 0.000 description 1
AVVSGTOJTRSKRL-UHFFFAOYSA-L hydrogen phosphate;lead(2+) Chemical compound [Pb+2].OP([O-])([O-])=O AVVSGTOJTRSKRL-UHFFFAOYSA-L 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229940070765 laurate Drugs 0.000 description 1
150000002611 lead compounds Chemical class 0.000 description 1
PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 1
YJOMWQQKPKLUBO-UHFFFAOYSA-L lead(2+);phthalate Chemical compound [Pb+2].[O-]C(=O)C1=CC=CC=C1C([O-])=O YJOMWQQKPKLUBO-UHFFFAOYSA-L 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
150000002689 maleic acids Chemical class 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
238000010907 mechanical stirring Methods 0.000 description 1
HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
239000000178 monomer Substances 0.000 description 1
239000012170 montan wax Substances 0.000 description 1
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical compound CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 description 1
229940049964 oleate Drugs 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000002530 phenolic antioxidant Substances 0.000 description 1
WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
239000004597 plastic additive Substances 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
235000019422 polyvinyl alcohol Nutrition 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
229910052761 rare earth metal Inorganic materials 0.000 description 1
150000002910 rare earth metals Chemical class 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
229940066675 ricinoleate Drugs 0.000 description 1
229960001860 salicylate Drugs 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
239000003549 soybean oil Substances 0.000 description 1
235000012424 soybean oil Nutrition 0.000 description 1
238000004528 spin coating Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 1
125000005591 trimellitate group Chemical group 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000012463 white pigment Substances 0.000 description 1
239000000811 xylitol Substances 0.000 description 1
HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
235000010447 xylitol Nutrition 0.000 description 1
229960002675 xylitol Drugs 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/716—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/77—Preparation of chelates of aldehydes or ketones
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/92—Ketonic chelates
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

RU2000125688/04A 1998-03-12 1999-03-12 Применение моногидрата ацетилацетоната цинка в качестве стабилизатора галогенсодержащих полимеров и способ его получения RU2216534C2 (ru)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
FR9803067		1998-03-12
FR9803067A FR2775971B1 (fr)	1998-03-12	1998-03-12	Preparation de sels metalliques de composes de type beta-dicarbonyles, a partir des oxydes metalliques
FR9810138A FR2782087B1 (fr)	1998-08-06	1998-08-06	Utilisation d'acetylacetonate de zinc monohydrate comme stabilisant de polymeres halogenes et son procede de preparation
FR9810138		1998-08-06

Publications (2)

Publication Number	Publication Date
RU2000125688A RU2000125688A (ru)	2002-11-10
RU2216534C2 true RU2216534C2 (ru)	2003-11-20

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RU2000125688/04A RU2216534C2 (ru)	1998-03-12	1999-03-12	Применение моногидрата ацетилацетоната цинка в качестве стабилизатора галогенсодержащих полимеров и способ его получения

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EP (1)	EP1062269A1 (fr)
JP (1)	JP2002506101A (fr)
KR (1)	KR20010034596A (fr)
CN (1)	CN1299392A (fr)
AU (1)	AU734455B2 (fr)
BR (1)	BR9908725A (fr)
CA (1)	CA2322984A1 (fr)
NO (1)	NO20004532L (fr)
PL (1)	PL342854A1 (fr)
RU (1)	RU2216534C2 (fr)
TR (1)	TR200003427T2 (fr)
WO (1)	WO1999046322A1 (fr)

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DE3431409A1 (de) *	1984-08-27	1986-02-27	Fa. Heinrich Wellmeyer, 4518 Bad Laer	Strassenbaufahrzeug
FR2879610B1 (fr) *	2004-12-20	2007-06-15	Rhodia Chimie Sa	Ingredient de stabilisation de polymeres halogenes comprenant un compose beta-dicarbonyle
CN101157605B (zh) *	2007-10-19	2010-06-09	扬州市兴业助剂有限公司	一种乙酰丙酮铜的生产方法
CN106317087A (zh) *	2016-08-19	2017-01-11	怀化学院	金属乙酰丙酮化物的制备方法
CN107056597A (zh) *	2017-05-27	2017-08-18	湖州市菱湖新望化学有限公司	一种固相法生产乙酰丙酮锌的工艺及装置
CN107056598A (zh) *	2017-05-27	2017-08-18	湖州市菱湖新望化学有限公司	一种固相法生产乙酰丙酮钙的工艺及装置
CN108034075A (zh) *	2017-12-29	2018-05-15	东莞市汉维科技股份有限公司	一种pvc基材色母用加工助剂的制备工艺

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FR1524717A (fr) *	1967-05-26	1968-05-10	Grace W R & Co	Nouvelles compositions de polymères chlorés stabilisées par des complexes métalliques de composés bêta-dicarbonylés
FR1576711A (fr) *	1967-08-03	1969-08-01
US4221687A (en) *	1977-07-07	1980-09-09	Argus Chemical Corp.	Anti-yellowing composition

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FR2747684B1 (fr) *	1996-04-23	1998-07-24	Rhone Poulenc Chimie	Stabilisation de polymeres halogenes vis-a-vis de la lumiere

1999
- 1999-03-12 CN CN99805696A patent/CN1299392A/zh active Pending
- 1999-03-12 AU AU27346/99A patent/AU734455B2/en not_active Ceased
- 1999-03-12 EP EP99907704A patent/EP1062269A1/fr not_active Withdrawn
- 1999-03-12 CA CA002322984A patent/CA2322984A1/fr not_active Abandoned
- 1999-03-12 RU RU2000125688/04A patent/RU2216534C2/ru not_active IP Right Cessation
- 1999-03-12 KR KR1020007010090A patent/KR20010034596A/ko not_active Abandoned
- 1999-03-12 JP JP2000535695A patent/JP2002506101A/ja active Pending
- 1999-03-12 BR BR9908725-1A patent/BR9908725A/pt not_active Application Discontinuation
- 1999-03-12 TR TR2000/03427T patent/TR200003427T2/xx unknown
- 1999-03-12 WO PCT/FR1999/000568 patent/WO1999046322A1/fr not_active Ceased
- 1999-03-12 PL PL99342854A patent/PL342854A1/xx not_active Application Discontinuation
2000
- 2000-09-11 NO NO20004532A patent/NO20004532L/no not_active Application Discontinuation

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FR1524717A (fr) *	1967-05-26	1968-05-10	Grace W R & Co	Nouvelles compositions de polymères chlorés stabilisées par des complexes métalliques de composés bêta-dicarbonylés
FR1576711A (fr) *	1967-08-03	1969-08-01
US4221687A (en) *	1977-07-07	1980-09-09	Argus Chemical Corp.	Anti-yellowing composition

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Also Published As

Publication number	Publication date
CA2322984A1 (fr)	1999-09-16
NO20004532L (no)	2000-11-10
BR9908725A (pt)	2000-11-21
KR20010034596A (ko)	2001-04-25
AU734455B2 (en)	2001-06-14
AU2734699A (en)	1999-09-27
EP1062269A1 (fr)	2000-12-27
TR200003427T2 (tr)	2001-05-21
PL342854A1 (en)	2001-07-16
JP2002506101A (ja)	2002-02-26
NO20004532D0 (no)	2000-09-11
WO1999046322A1 (fr)	1999-09-16
CN1299392A (zh)	2001-06-13

Publication	Publication Date	Title
RU2216534C2 (ru)	2003-11-20	Применение моногидрата ацетилацетоната цинка в качестве стабилизатора галогенсодержащих полимеров и способ его получения
US5234981A (en)	1993-08-10	Halogenated polymer compositions stabilized with the aid of an inorganic additive
US5714095A (en)	1998-02-03	Composition for chlorine-containing polymer based on beta-diketone and acetylacetonate
JP4208962B2 (ja)	2009-01-14	オーバーベースｐｖｃ安定剤の製造方法
US6482887B1 (en)	2002-11-19	Coated calcium or magnesium acetylacetonate, and its use for stabilizing halogenated polymers
US6455621B1 (en)	2002-09-24	Composition based on calcium of magnesium acetylacetonate and free or chelated β-diketones, preparation and use
US6448314B1 (en)	2002-09-10	Use of monohydrate zinc acetylacetonate as halogenated polymer stabilizer and preparation method
JPH11502253A (ja)	1999-02-23	安定化された塩化ビニルポリマー組成物
CN101124269B (zh)	2012-05-23	包括β-二羰基化合物的用于卤代聚合物稳定化的成分
FR2747684A1 (fr)	1997-10-24	Stabilisation de polymeres halogenes vis-a-vis de la lumiere
JP2004504434A (ja)	2004-02-12	不飽和ヘテロ環状化合物を含有するハロゲン系重合体安定化組成物
CZ20003281A3 (cs)	2001-02-14	Použití monohydrátu acetylacetonátu zinečnatého jako stabilizátoru pro halogenované polymery a způsob jeho přípravy
US20060122296A1 (en)	2006-06-08	Use of silylated beta-dicarbonyl compounds as halogenated polymer stabilisers
MXPA99011159A (en)	2000-09-04	COMPOSITION BASED ON CALCIUM OF MAGNESIUM ACETYLACETONATE AND FREE OR CHELATED&bgr;-DIKETONES, PREPARATION AND USE
MXPA99011160A (en)	2000-09-04	Coated calcium or magnesium acetylacetonate, and its use for stabilising halogenated polymers
ZA200209864B (en)	2003-06-12	Stabilising halogenated polymers with pyrroles or derivatives thereof and compositions containing them.
CZ9904333A3 (cs)	2000-12-13	Prostředek na bázi acetylacetonátu hořečnatého nebo vápenatého a volných nebo chelatovaných β-diketonů, způsob jeho přípravy a jeho použití

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