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RU2019116587A - Каталитическая система для депарафинизации - Google Patents

Каталитическая система для депарафинизации Download PDF

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Publication number
RU2019116587A
RU2019116587A RU2019116587A RU2019116587A RU2019116587A RU 2019116587 A RU2019116587 A RU 2019116587A RU 2019116587 A RU2019116587 A RU 2019116587A RU 2019116587 A RU2019116587 A RU 2019116587A RU 2019116587 A RU2019116587 A RU 2019116587A
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Prior art keywords
catalyst
dewaxing
zsm
zeolite
dewaxing catalyst
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RU2019116587A
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English (en)
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RU2768876C2 (ru
RU2019116587A3 (ru
Inventor
Херманус ЙОНГКИНД
Марчелло Стефано РИГУТТО
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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Publication of RU2019116587A publication Critical patent/RU2019116587A/ru
Publication of RU2019116587A3 publication Critical patent/RU2019116587A3/ru
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/703—MRE-type, e.g. ZSM-48
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00—Catalysts comprising molecular sieves
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7461—MRE-type, e.g. ZSM-48
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

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  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Claims (9)

1. Каталитическая система для депарафинизации углеводородного сырья, содержащая по меньшей мере две каталитических секции, при этом первая секция содержит первый катализатор депарафинизации, а последующая секция содержит второй катализатор депарафинизации, при этом первый катализатор депарафинизации представляет собой катализатор на основе цеолита ZSM–12, а второй катализатор депарафинизации представляют собой катализатор на основе цеолита EU–2 и/или ZSM–48.
2. Каталитическая композиция по п.1, отличающаяся тем, что указанный цеолит ZSM–12 присутствует в указанной первой каталитической композиции депарафинизации в количестве не менее 10 масс. % и не более 70 масс. %, и указанная первая каталитическая композиция депарафинизации дополнительно содержит связующее в количестве не менее 30 масс. % и не более 90 масс. %, при этом такой масс.% основан на сухой массе указанной композиции.
3. Каталитическая система по п.1 или 2, отличающаяся тем, что указанный цеолит EU–2 и/или ZSM–48 присутствует в указанной второй каталитической композиции депарафинизации в количестве не менее 15 масс. % и не более 70 масс. %, и указанная вторая каталитическая композиция депарафинизации дополнительно содержит связующее в количестве не менее 30 масс. % и не более 85 масс. %, при этом такой масс. % основан на сухой массе указанной композиции.
4. Каталитическая система по любому из пп.1–3, отличающаяся тем, что первый катализатор депарафинизации и второй катализатор депарафинизации каждый содержат компонент благородного металла.
5. Каталитическая система по любому из пп. 1–4, отличающаяся тем, что цеолит ZSM–12 имеет молярное соотношение диоксида кремния к оксиду алюминия не менее 50:1 и не более 250:1.
6. Каталитическая система по любому из пп. 1–5, отличающаяся тем, что цеолит EU–2 и/или ZSM–48 имеет молярное отношение диоксида кремния к оксиду алюминия не менее 60:1 и не более 300:1.
7. Каталитическая система по любому из пп. 1–6, отличающаяся тем, что объемное отношение первого катализатора депарафинизации ко второму катализатору депарафинизации находится в диапазоне от 10:90 до 90:10.
8. Способ депарафинизации углеводородного сырья, включающий приведение в контакт углеводородного сырья с каталитической системой по любому из пп. 1–7 при температуре от 200°C до 450°C и давлении от 5 до 200 х 105 Па.
9. Способ по п.8, отличающийся тем, что исходное сырье представляет собой парафиносодержащее сырье, которое кипит в диапазоне смазочного масла, имеющего температуру перегонки 10% при 200°С или выше, при измерении в соответствии с ASTM D–2887–93.
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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3096149A1 (en) 2018-04-17 2019-10-24 Shell Internationale Research Maatschappij B.V. Catalyst system for dewaxing
KR20250014031A (ko) * 2023-07-18 2025-02-03 에스케이이노베이션 주식회사 윤활기유를 제조하는 방법 및 이에 의해 제조된 윤활기유

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3140249A (en) 1960-07-12 1964-07-07 Socony Mobil Oil Co Inc Catalytic cracking of hydrocarbons with a crystalline zeolite catalyst composite
NL273446A (ru) 1961-12-21
US3140253A (en) 1964-05-01 1964-07-07 Socony Mobil Oil Co Inc Catalytic hydrocarbon conversion with a crystalline zeolite composite catalyst
US3832449A (en) 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US4205053A (en) 1979-02-01 1980-05-27 Mobil Oil Corporation Manufacture of nitrogenous zeolites
US4452769A (en) 1979-03-21 1984-06-05 Mobil Oil Corporation Method of preparing crystalline zeolite
AU542052B2 (en) 1980-06-12 1985-02-07 Imperial Chemical Industries Ltd. Zeoliteeuz and its use as a catalyst
GB2077709B (en) 1980-06-12 1983-12-07 Ici Ltd Zeolite eu-2
US4391785A (en) 1981-12-21 1983-07-05 Mobil Oil Corporation Preparation of ZSM-12 type zeolites
US4482531A (en) 1983-04-29 1984-11-13 Mobil Oil Corporation Synthesis of ZSM-12 zeolite
US4552739A (en) 1983-12-09 1985-11-12 Mobil Oil Corporation Method of preparing crystalline zeolite ZSM-12 and product
US4539193A (en) 1984-05-23 1985-09-03 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
US4552738A (en) 1984-05-25 1985-11-12 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
US4585637A (en) 1984-06-26 1986-04-29 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
US4585746A (en) 1984-06-27 1986-04-29 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
US4767522A (en) * 1984-11-28 1988-08-30 Mobil Oil Corporation Distillate dewaxing process with mixed zeolites
US4599162A (en) * 1984-12-21 1986-07-08 Mobil Oil Corporation Cascade hydrodewaxing process
EP0188898B1 (en) * 1984-12-21 1990-09-19 Mobil Oil Corporation Cascade dewaxing process
US5157191A (en) 1986-01-03 1992-10-20 Mobil Oil Corp. Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index
US5080878A (en) 1989-07-11 1992-01-14 Mobil Oil Corp. Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index
US4753910A (en) 1987-02-17 1988-06-28 Mobil Oil Corporation Dealumination of aluminosilicate zeolites
US5075269A (en) 1988-12-15 1991-12-24 Mobil Oil Corp. Production of high viscosity index lubricating oil stock
US5246568A (en) * 1989-06-01 1993-09-21 Mobil Oil Corporation Catalytic dewaxing process
US5075259A (en) 1989-08-22 1991-12-24 Motorola, Inc. Method for forming semiconductor contacts by electroless plating
US5021141A (en) 1990-09-14 1991-06-04 Mobil Oil Corp. Synthesis of crystalline ZSM-12 type structure
US5192521A (en) 1991-11-19 1993-03-09 Mobil Oil Corp. Synthesis of crystalline silicate ZSM-12
US5242676A (en) 1992-05-11 1993-09-07 Mobil Oil Corp. Selective surface dealumination of zeolites using dicarboxylic acid
US5234872A (en) 1992-05-11 1993-08-10 Mobil Oil Corp. Method for producing zeolites with reduced surface acidity
US5430000A (en) 1993-08-25 1995-07-04 Mobil Oil Corporation Method for preparing titania-bound zeolite catalysts
RU2140819C1 (ru) 1993-12-23 1999-11-10 Арко Кемикал Текнолоджи, Л.П. Титансодержащий цеолит, способ его получения (варианты), способ эпоксидирования олефинов и дичетвертичное аммониевое соединение для получения титансодержащего цеолита
MX9703769A (es) 1994-11-23 1998-05-31 Exxon Chemical Patents Inc Proceso de conversion de hidrocarburos usando un catalizador de ceolita ligado a ceolita.
US5601751A (en) 1995-06-08 1997-02-11 Micron Display Technology, Inc. Manufacturing process for high-purity phosphors having utility in field emission displays
MY125670A (en) 1995-06-13 2006-08-30 Shell Int Research Catalytic dewaxing process and catalyst composition
CN1225113A (zh) 1996-07-15 1999-08-04 切夫里昂美国公司 用于润滑油加氢转化的分层催化剂体系
US6051129A (en) 1998-07-24 2000-04-18 Chevron U.S.A. Inc. Process for reducing haze point in bright stock
JP2002530470A (ja) 1998-11-16 2002-09-17 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 接触的脱蝋方法
PL191080B1 (pl) 1998-11-18 2006-03-31 Shell Int Research Sposób katalitycznego usuwania wosku
US7261805B2 (en) * 1999-02-24 2007-08-28 Exxonmobil Research And Engineering Company Process for catalytic dewaxing and catalytic cracking of hydrocarbon streams
AU6566800A (en) 1999-07-27 2001-02-13 Shell Internationale Research Maatschappij B.V. Method for impregnation of molecular sieve-binder extrudates
US6652832B2 (en) 2001-02-05 2003-11-25 Exxonmobil Oil Corporation Synthesis of ZSM-12
US7704379B2 (en) 2002-10-08 2010-04-27 Exxonmobil Research And Engineering Company Dual catalyst system for hydroisomerization of Fischer-Tropsch wax and waxy raffinate
US20040108245A1 (en) 2002-10-08 2004-06-10 Zhaozhong Jiang Lube hydroisomerization system
US20040065582A1 (en) 2002-10-08 2004-04-08 Genetti William Berlin Enhanced lube oil yield by low hydrogen pressure catalytic dewaxing of paraffin wax
US6893624B2 (en) 2002-11-15 2005-05-17 Exxonmobil Chemical Patents Inc. High activity small crystal ZSM-12
US6923949B1 (en) 2004-03-05 2005-08-02 Exxonmobil Research And Engineering Company Synthesis of ZSM-48 crystals with heterostructural, non ZSM-48, seeding
US7271118B2 (en) 2004-07-29 2007-09-18 Exxonmobil Chemical Patents Inc. Xylenes isomerization catalyst system and use thereof
US7482300B2 (en) 2005-12-13 2009-01-27 Exxonmobil Research And Engineering Company High activity ZSM-48 and methods for dewaxing
US20070138060A1 (en) * 2005-12-16 2007-06-21 Palmer Thomas R Upgrading of peroxide treated petroleum streams
EP2676614B1 (en) 2006-10-26 2016-03-09 AMS Research Corporation Surgical articles for treating pelvic conditions
EP2027917A1 (en) 2007-07-31 2009-02-25 Shell Internationale Researchmaatschappij B.V. Catalyst composition, its preparation and use
EP2075314A1 (en) 2007-12-11 2009-07-01 Shell Internationale Research Maatschappij B.V. Grease formulations
US8030240B2 (en) 2007-12-28 2011-10-04 Exxonmobil Research And Engineering Company Multiple molecular sieve catalyst for sour service dewaxing
US8263517B2 (en) 2007-12-28 2012-09-11 Exxonmobil Research And Engineering Company Hydroprocessing catalysts with low surface area binders
US8182672B2 (en) 2007-12-28 2012-05-22 Exxonmobil Research And Engineering Company Process for preparing lube basestocks having superior low temperature properties at high VI
US8263519B2 (en) 2007-12-28 2012-09-11 Exxonmobil Research And Engineering Company Sour service dewaxing catalyst without separate hydrogenation function
DK2362892T3 (da) 2008-11-06 2019-07-15 Exxonmobil Res & Eng Co Hydrogenbehandling af biodieselbrændstoffer og blandinger
US8298403B2 (en) * 2008-12-16 2012-10-30 Exxonmobil Research And Engineering Company Dewaxing catalysts and processes
US8377286B2 (en) 2008-12-31 2013-02-19 Exxonmobil Research And Engineering Company Sour service hydroprocessing for diesel fuel production
US8202506B2 (en) 2009-11-17 2012-06-19 Exxonmobil Research And Engineering Company High activity small crystal ZSM-12
US8906224B2 (en) 2009-12-23 2014-12-09 Exxonmobil Research And Engineering Company Sweet or sour service catalytic dewaxing in block mode configuration
US8840779B2 (en) 2010-02-09 2014-09-23 Exxonmobil Research And Engineering Company Dewaxing catalysts
WO2011131635A1 (en) 2010-04-19 2011-10-27 Shell Internationale Research Maatschappij B.V. Process for the preparation of a catalyst support
KR101857312B1 (ko) * 2010-10-25 2018-06-25 쉘 인터내셔날 리써취 마트샤피지 비.브이. 탄화수소 전환 촉매 조성물
WO2013090534A1 (en) * 2011-12-16 2013-06-20 Shell Oil Company A titania-bound zsm-12 zeolite composition and method of making and using such composition
BR112014020414B1 (pt) 2012-02-29 2020-05-26 Shell International Research Maatschappij B.V. Composição de catalisador, método de preparar a mesma e processo de desparafinação catalítica de uma alimentação de óleo de hidrocarboneto
WO2016107914A1 (en) * 2014-12-31 2016-07-07 Shell Internationale Research Maatschappij B.V. Process for preparing a base oil having a reduced cloud point
KR101692547B1 (ko) * 2016-04-26 2017-01-03 에스케이이노베이션 주식회사 중질기유의 헤이즈 저감 방법 및 헤이즈가 저감된 수소 첨가 이성화 촉매계

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