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RU2018137169A - Простые полиэфирамины на основе 1,3-диспиртов - Google Patents

Простые полиэфирамины на основе 1,3-диспиртов Download PDF

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RU2018137169A
RU2018137169A RU2018137169A RU2018137169A RU2018137169A RU 2018137169 A RU2018137169 A RU 2018137169A RU 2018137169 A RU2018137169 A RU 2018137169A RU 2018137169 A RU2018137169 A RU 2018137169A RU 2018137169 A RU2018137169 A RU 2018137169A
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formula
mixture
ethers
ethers according
polyether amine
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RU2018137169A
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Бьерн ЛУДОЛЬФ
Зофиа ЭБЕРТ
Кристиан АЙДАМСХАУС
Стефано СКЬЯЛЛА
Брайан Джозеф ЛОКНЕЙН
Кэри Мэри ХЭНКЕ
Гэйли Мэри ФРАНКЕНБАХ
Джэй Фрэнк НЭШ
Майкл Пэтрик ХЭЙЕС
Мануэль Дж. ВЕНЕГАС
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Басф Се
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    • C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C217/42—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having etherified hydroxy groups and at least two amino groups bound to the carbon skeleton
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    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
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    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
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    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33365—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing cyano group
    • C08G65/33368—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing cyano group acyclic
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
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Claims (23)

1. Смесь простых эфираминов, содержащая по меньшей мере 90% массовых, в пересчете на общую массу этой смеси простых эфираминов, амина Формулы (I) и/или (II),
Figure 00000001
Figure 00000002
где R1 - R12 независимо друг от друга выбираются из Н, алкила, цилокалкила, арила, алкиларила или арилалкила,
где по меньшей мере один из R1 - R6 и по меньшей мере один из R7 - R12 отличается от Н,
где А1 - А9 независимо друг от друга выбираются из линейных или разветвленных алкандиильных групп, имеющих от 2 до 18 атомов углерода, предпочтительно 2-10 атомов углерода, наиболее предпочтительно 2-5 атомов углерода,
где Z1 - Z4 независимо друг от друга выбираются из -ОН и линейного -OCH2CH2CH2NH2, причем степень аминирования каждого из простых эфираминов Формулы (I) и Формулы (II) равняется или составляет больше 50%, и где сумма х + у находится в диапазоне от 2 до 200, причем х ≥ 1 и у ≥ 1; и x1 + y1 находится в диапазоне от 2 до 200, предпочтительно 2-20, наиболее предпочтительно 2-10,
причем x1 ≥ 1 и y1 ≥ 1.
2. Смесь простых эфираминов по п. 1, где эта смесь простых эфираминов содержит по меньшей мере 95% массовых, в пересчете на общую массу смеси простых эфираминов, амина Формулы (I) и/или (II).
3. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) х + у находится в диапазоне от 2 до 20.
4. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) х + у находится в диапазоне от 3 до 20.
5. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) степень аминирования находится в диапазоне от 60% до 95%.
6. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) A1 - А9 независимо друг от друга выбирают из группы, состоящей из этилена, пропилена или бутилена.
7. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) каждый из A1 - А9 представляет собой пропилен.
8. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) R1, R2, R5, R6, R7, R8, R11 и R12 представляют собой Н, a R3, R4, R9 и R10 независимо друг от друга выбирают из ал кила с 1-16 атомами углерода или арила.
9. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) R1, R2, R5, R6, R7, R8, R11 и R12 представляют собой Н, a R3, R4, R9 и R10 независимо друг от друга выбирают из бутильной группы, этильной группы, метильной группы, пропильной группы или фенильной группы.
10. Смесь простых эфираминов по п. 1, где в указанном простом полиэфирамине Формулы (I) или Формулы (II) каждый из R3 и R9 представляют собой этильную группу, каждый из R1, R2, R5, R6, R7, R8, R11, R12 представляют собой Н, каждый из R4 и R10 представляют собой бутильную группу.
11. Смесь простых эфираминов по п. 1, где простой полиэфирамин Формулы (I) или Формулы (II) имеет среднемассовую молекулярную массу от примерно 290 до примерно 1000 г/моль.
12. Смесь простых эфираминов по любому одному из пп. 1-11, где простой полиэфирамин Формулы (I) или Формулы (II) является вступившим в реакцию с кислотой.
13. Применение смеси простых эфираминов по пп. 1-12 в средствах личной гигиены.
14. Применение смеси простых эфираминов по пп. 1-12 в шампунях и композициях для мытья тела.
15. Применение смеси простых эфираминов по пп. 1-12 в качестве отверждающего агента для эпоксидных смол или в качестве реагента в производстве полимеров.
16. Применение смеси простых эфираминов по пп. 1-12 в полиуретанах, полимочевинах и в качестве термопластичных полиамидных клеев.
RU2018137169A 2016-03-24 2017-03-14 Простые полиэфирамины на основе 1,3-диспиртов RU2018137169A (ru)

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PCT/EP2017/055943 WO2017162477A1 (en) 2016-03-24 2017-03-14 Polyetheramines based on 1,3-dialcohols

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US8071814B2 (en) * 2006-12-06 2011-12-06 Clariant Finance (Bvi) Limited Process for preparing polyetheramines
CN105102600A (zh) * 2013-03-28 2015-11-25 宝洁公司 包含聚醚胺、去垢性聚合物和羧甲基纤维素的清洁组合物
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