RU2018146437A - Композиция для добычи углеводородных флюидов из подземного месторождения - Google Patents
Композиция для добычи углеводородных флюидов из подземного месторождения Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims 9
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- 239000012530 fluid Substances 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 title 1
- 239000004593 Epoxy Substances 0.000 claims 8
- 125000002947 alkylene group Chemical group 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 125000000753 cycloalkyl group Chemical group 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 3
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims 3
- HVBSAKJJOYLTQU-UHFFFAOYSA-N 4-aminobenzenesulfonic acid Chemical compound NC1=CC=C(S(O)(=O)=O)C=C1 HVBSAKJJOYLTQU-UHFFFAOYSA-N 0.000 claims 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229920000642 polymer Polymers 0.000 claims 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- WAMBUHSSUGGLJO-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;2-(oxiran-2-ylmethoxymethyl)oxirane Chemical compound C1OC1COCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 WAMBUHSSUGGLJO-UHFFFAOYSA-N 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- LUSFFPXRDZKBMF-OCAPTIKFSA-N [(1s,3r)-3-(hydroxymethyl)cyclohexyl]methanol Chemical compound OC[C@H]1CCC[C@@H](CO)C1 LUSFFPXRDZKBMF-OCAPTIKFSA-N 0.000 claims 1
- LUSFFPXRDZKBMF-YUMQZZPRSA-N [(1s,3s)-3-(hydroxymethyl)cyclohexyl]methanol Chemical compound OC[C@H]1CCC[C@H](CO)C1 LUSFFPXRDZKBMF-YUMQZZPRSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- OBESRABRARNZJB-UHFFFAOYSA-N aminomethanesulfonic acid Chemical compound NCS(O)(=O)=O OBESRABRARNZJB-UHFFFAOYSA-N 0.000 claims 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 150000004985 diamines Chemical group 0.000 claims 1
- 125000004990 dihydroxyalkyl group Chemical group 0.000 claims 1
- 150000002118 epoxides Chemical class 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- UZHDDUOPWFLWPC-UHFFFAOYSA-M sodium;aminomethanesulfonate Chemical compound [Na+].NCS([O-])(=O)=O UZHDDUOPWFLWPC-UHFFFAOYSA-M 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
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- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/58—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids
- C09K8/588—Compositions for enhanced recovery methods for obtaining hydrocarbons, i.e. for improving the mobility of the oil, e.g. displacing fluids characterised by the use of specific polymers
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- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/182—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
- C08G59/184—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents with amines
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/24—Di-epoxy compounds carbocyclic
- C08G59/245—Di-epoxy compounds carbocyclic aromatic
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4064—Curing agents not provided for by the groups C08G59/42 - C08G59/66 sulfur containing compounds
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/44—Amides
- C08G59/46—Amides together with other curing agents
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/5006—Amines aliphatic
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/504—Amines containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
- C08G59/56—Amines together with other curing agents
- C08G59/60—Amines together with other curing agents with amides
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- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
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- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
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Claims (31)
1. Композиция, содержащая продукты реакции:
(i) эпоксидсодержащего соединения, имеющего в среднем более одной эпоксидной группы на молекулу,
(ii) первичного аминосульфоната,
(iii) необязательно олигомера первичного моноаминалкиленоксида, и
(iv) необязательно первичного моноамина, вторичного диамина, моногидроксиалкила первичного моноамина, дигидроксиалкила первичного моноамина, тригидроксиалкила первичного моноамина, моногидроксициклоалкила первичного моноамина, дигидроксициклоалкила первичного моноамина или тригидроксициклоалкила первичного моноамина.
2. Композиция по п. 1, отличающаяся тем, что
(i) эпоксидсодержащее соединение представлено формулой:
где Q выбран из двухвалентной ароматической группы -Ar-; Ar-L-Ar, где L выбран из прямой связи, C1-С8 алкилена, -SO2-, -S-, >С=0 или -О-; двухвалентной циклоалифатической группы K, содержащей от 4 до 8 атомов углерода, или -R1-K-R2-, где R1 и R2 независимо представляют собой C1-С3 алкиленовую группу;
(ii) первичный аминосульфонат представлен формулой:
где Z представляет собой алифатическую, циклоалифатическую, полициклоалифатическую или ароматическую углеводородную группу, необязательно замещенную одной или более алкильными группами, и
М представляет собой любой одновалентный катион; и
(iii) при его наличии, олигомер первичного моноаминалкиленоксида представлен формулой:
где R3 представляет собой -Н, C1-С12 алкил или циклоалкил,
R4 представляет собой ковалентную связь, C1-С12 алкил или циклоалкил,
R5 и R6 независимо представляют собой -Н, C1-С12 алкил или циклоалкил, и
х и у независимо имеют значение от 0 до 400.
3. Композиция по п. 1, отличающаяся тем, что молярное отношение эпоксид-содержащего соединения (i) к первичному аминосульфонату (ii) составляет от 5:1 до 1:5.
4. Композиция по п. 1, отличающаяся тем, что продукт реакции имеет среднюю молекулярную массу от 300 до 100000.
5. Композиция по п. 1, отличающаяся тем, что олигомер первичного моноаминалкиленоксида присутствует в количестве от 1 до 15 процентов эквивалентов аминного водорода для протекания реакции с эпоксидными эквивалентами компонента (i), эпоксидсодержащего соединения.
6. Композиция по п. 1, отличающаяся тем, что эпоксидсодержащее соединение выбрано из диглицидилового эфира 4,4'-изопропилидендифенола (бисфенола А); цис-1,3-циклогександиметанола; транс-1,3-циклогександиметанола; цис-1,4-циклогександиметанола; или транс-1,4-циклогександиметанола.
7. Композиция по п. 1, отличающаяся тем, что первичный аминосульфонат выбран из натриевой соли сульфаниловой кислоты; калиевой соли сульфаниловой кислоты; натриевой соли аминометансульфоновой кислоты; или калиевой соли аминометансульфоновой кислоты.
8. Композиция по п. 5, отличающаяся тем, что для олигомера первичного моноаминалкиленоксида R3 и R5 представляют собой -СН3, R4 представляет собой -СН2-, R5 представляет собой -Н, и х и у независимо имеют значение от 0 до 75, при условии, что по меньшей мере один из х или у равен или больше 1.
9. Способ получения сульфированного эпоксидного полимера, включающий стадии:
(1) добавления избытка или эквивалентного количества эпоксидсодержащего соединения и эквивалентного количества или избытка первичного аминосульфоната,
(2) необязательно добавления олигомера первичного моноаминалкиленоксида, другой добавки, катализатора и/или растворителя,
(3) смешивания компонентов с получением реакционной смеси, и
(4) приведения во взаимодействие реакционной смеси при такой температуре и в течение такого времени, которые достаточны для получения сульфированного эпоксидного полимера, имеющего среднюю молекулярную массу от 300 до 100000.
10. Способ по п. 9, представляющий собой периодический или непрерывный процесс.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662352758P | 2016-06-21 | 2016-06-21 | |
| US62/352,758 | 2016-06-21 | ||
| PCT/US2017/036273 WO2017222814A1 (en) | 2016-06-21 | 2017-06-07 | Composition for recovering hydrocarbon fluids from a subterranean reservoir |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2018146437A true RU2018146437A (ru) | 2020-06-26 |
| RU2018146437A3 RU2018146437A3 (ru) | 2020-10-14 |
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| RU2018146437A RU2018146437A (ru) | 2016-06-21 | 2017-06-07 | Композиция для добычи углеводородных флюидов из подземного месторождения |
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| Country | Link |
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| US (1) | US20190194525A1 (ru) |
| EP (1) | EP3472259A1 (ru) |
| CN (1) | CN109312221A (ru) |
| RU (1) | RU2018146437A (ru) |
| WO (1) | WO2017222814A1 (ru) |
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| WO2025129586A1 (zh) * | 2023-12-21 | 2025-06-26 | 中国石油化工股份有限公司 | 水性热固性树脂及其制备方法、树脂组合物、蜂窝状树脂制品及其制备方法与应用 |
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| US4317757A (en) * | 1980-01-25 | 1982-03-02 | Shell Oil Company | Water-thinnable epoxy resin-sulphanilic acid binder compositions |
| DE3162413D1 (en) * | 1980-05-22 | 1984-04-05 | Shell Int Research | Aqueous coating powder suspensions, preparation and use |
| US4379872A (en) * | 1980-08-22 | 1983-04-12 | Nippon Paint Co., Ltd. | Amphoteric amino sulfonate derivatives of epoxy resins |
| US4366295A (en) | 1981-06-01 | 1982-12-28 | The Dow Chemical Company | Stable precatalyzed epoxy resin compositions |
| CA2538753C (en) * | 2003-09-12 | 2013-04-16 | Nalco Energy Services, L.P. | Method and composition for recovering hydrocarbon fluids from a subterranean reservoir |
| WO2013117211A1 (en) * | 2012-02-06 | 2013-08-15 | Nokia Siemens Networks Oy | Customer experience management interaction with caching |
| CN103848956A (zh) * | 2012-11-30 | 2014-06-11 | 亿利资源集团有限公司 | 一种亲水性树脂组合物及其制备方法和应用 |
| CN103849117B (zh) * | 2012-11-30 | 2016-01-27 | 亿利资源集团有限公司 | 一种压裂支撑剂及其制备方法 |
| JP2015059376A (ja) * | 2013-09-20 | 2015-03-30 | 東レ株式会社 | 地下からの気体状炭化水素及び／または液体状炭化水素の採取方法 |
-
2017
- 2017-06-07 CN CN201780036257.4A patent/CN109312221A/zh active Pending
- 2017-06-07 US US16/310,201 patent/US20190194525A1/en not_active Abandoned
- 2017-06-07 RU RU2018146437A patent/RU2018146437A/ru not_active Application Discontinuation
- 2017-06-07 WO PCT/US2017/036273 patent/WO2017222814A1/en not_active Ceased
- 2017-06-07 EP EP17731031.5A patent/EP3472259A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US20190194525A1 (en) | 2019-06-27 |
| CN109312221A (zh) | 2019-02-05 |
| EP3472259A1 (en) | 2019-04-24 |
| RU2018146437A3 (ru) | 2020-10-14 |
| WO2017222814A1 (en) | 2017-12-28 |
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| Date | Code | Title | Description |
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| FA92 | Acknowledgement of application withdrawn (lack of supplementary materials submitted) |
Effective date: 20210205 |