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RU2015151436A - COMPOSITION FOR PRODUCING NANOCOMPOSITES WITH A CONTAINABLE POLYMER MATRIX - Google Patents

COMPOSITION FOR PRODUCING NANOCOMPOSITES WITH A CONTAINABLE POLYMER MATRIX Download PDF

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Publication number
RU2015151436A
RU2015151436A RU2015151436A RU2015151436A RU2015151436A RU 2015151436 A RU2015151436 A RU 2015151436A RU 2015151436 A RU2015151436 A RU 2015151436A RU 2015151436 A RU2015151436 A RU 2015151436A RU 2015151436 A RU2015151436 A RU 2015151436A
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RU
Russia
Prior art keywords
composition according
bis
composition
inorganic filler
catalyst
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Application number
RU2015151436A
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Russian (ru)
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RU2638169C2 (en
Inventor
Ольга Евгеньевна Филиппова
Анна Ивановна Барабанова
Original Assignee
Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ)
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Application filed by Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) filed Critical Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ)
Priority to RU2015151436A priority Critical patent/RU2638169C2/en
Publication of RU2015151436A publication Critical patent/RU2015151436A/en
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Publication of RU2638169C2 publication Critical patent/RU2638169C2/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/113—Silicon oxides; Hydrates thereof
    • C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14—Colloidal silica, e.g. dispersions, gels, sols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

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  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)

Claims (9)

1. Композиция для получения нанокомпозитов с перестраиваемой полимерной матрицей, включающая эпоксидный сетчатый полимер, катализатор межцепного обмена и неорганический наполнитель, при следующем соотношении компонентов, вес.%:1. A composition for producing nanocomposites with a tunable polymer matrix, including an epoxy crosslinked polymer, an interchain exchange catalyst and an inorganic filler, in the following ratio, wt.%: полимерpolymer 56-9856-98 катализатор межцепного обменаinterchain catalyst 1.8-3.81.8-3.8 неорганический наполнительinorganic filler 1-401-40
2. Композиция по п. 1, характеризующаяся тем, что в качестве эпоксидного сетчатого полимера используют ароматические или алифатические полимеры.2. The composition according to claim 1, characterized in that aromatic or aliphatic polymers are used as the epoxy cross-linked polymer. 3. Композиция по п. 2, характеризующаяся тем, что в качестве ароматических полимеров используют ДГЭБА, различные бисфенолы, например бисфенол А (4,4'-(пропан-2,2-диил)дифенол), бисфенол АР (1,1-бис(4-гидроксифенил)-1-фенилэтан), бисфенол AF (2,2-бис(4-гидроксифенил)гексафторпропан), глицидиловые производные феноло-формальдегидных новолачных смол.3. The composition according to p. 2, characterized in that DHEA, various bisphenols, for example bisphenol A (4,4 '- (propan-2,2-diyl) diphenol), bisphenol AR (1,1- bis (4-hydroxyphenyl) -1-phenylethane), bisphenol AF (2,2-bis (4-hydroxyphenyl) hexafluoropropane), glycidyl derivatives of phenol-formaldehyde novolac resins. 4. Композиция по п. 2, характеризующаяся тем, что в качестве алифатических полимеров используют ЭБКБЭ, диэпоксиды гексагидробензаль-1,1-бис-(оксиметил)циклогексена, дициклопентенилового эфира, дициклопентадиена, винилциклогексена, эпоксидированные олигомеры дивинила.4. The composition according to p. 2, characterized in that as aliphatic polymers use EBKBE, diepoxides of hexahydrobenzene-1,1-bis- (oxymethyl) cyclohexene, dicyclopentenyl ether, dicyclopentadiene, vinylcyclohexene, epoxidized divinyl oligomers. 5. Композиция по п. 1, характеризующаяся тем, что в качестве катализатора межцепного обмена используют ацетил ацетонат цинка, ацетаты, оксиды и карбонаты различных металлов, алкоксиды натрия, калия и титана, 4(диметиламино)пиридин, 1,8-диазобицикло[5.4.0]ундец-7-ен, бензилдиметиламид, хлорид бензилтриметиламмония.5. The composition according to claim 1, characterized in that zinc acetyl acetate, acetates, oxides and carbonates of various metals, sodium, potassium and titanium alkoxides, 4 (dimethylamino) pyridine, 1,8-diazobicyclo are used as a catalyst for interchain exchange [5.4 .0] undec-7-ene, benzyldimethylamide, benzyltrimethylammonium chloride. 6. Композиция по п. 1, характеризующаяся тем, что в качестве неорганического наполнителя используют сферические наночастицы SiO2 или нанотрубки галлуазита.6. The composition according to claim 1, characterized in that spherical nanoparticles of SiO 2 or nanotubes of halloysite are used as an inorganic filler. 7. Композиция по п. 6, характеризующаяся тем, что сферические наночастицы SiO2 имеют диаметр до 15 нм.7. The composition according to p. 6, characterized in that the spherical nanoparticles of SiO 2 have a diameter of up to 15 nm. 8. Композиция по п. 6, характеризующаяся тем, что нанотрубки имеют длину от 1000 до 1300 нм и диаметр от 30 до 70 нм.8. The composition according to p. 6, characterized in that the nanotubes have a length of from 1000 to 1300 nm and a diameter of from 30 to 70 nm.
RU2015151436A 2015-12-01 2015-12-01 Composition for producing nanocomposites with reconfigurable polymer matrix RU2638169C2 (en)

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RU2015151436A RU2638169C2 (en) 2015-12-01 2015-12-01 Composition for producing nanocomposites with reconfigurable polymer matrix

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Application Number Priority Date Filing Date Title
RU2015151436A RU2638169C2 (en) 2015-12-01 2015-12-01 Composition for producing nanocomposites with reconfigurable polymer matrix

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RU2015151436A true RU2015151436A (en) 2017-06-02
RU2638169C2 RU2638169C2 (en) 2017-12-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114573792A (en) * 2022-03-29 2022-06-03 中海石油(中国)有限公司 Dynamic crosslinking degradable epoxy resin, preparation method and high-temperature plugging application thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007504334A (en) * 2003-09-03 2007-03-01 ゼネラル・エレクトリック・カンパニイ Solvent-modified resin composition and use thereof
CN102791806B (en) * 2010-01-28 2015-04-15 新加坡科技研究局 A nano-composite
MX351929B (en) * 2010-05-31 2017-11-03 Arkema France Star Acid-hardening epoxy thermoset resins and composites that can be hot-processed and recycled.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114573792A (en) * 2022-03-29 2022-06-03 中海石油(中国)有限公司 Dynamic crosslinking degradable epoxy resin, preparation method and high-temperature plugging application thereof
CN114573792B (en) * 2022-03-29 2023-07-18 中海石油(中国)有限公司 Dynamic cross-linked degradable epoxy resin, preparation method thereof and high-temperature plugging application

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