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RU2013108527A - METHOD FOR PRODUCING 3,3 '- (3,6-DIOXOACTAN-1,8-DIIL) BIS-1,5,3-DITIAZEPINAN AND ITS APPLICATION AS A MEANS WITH FUNGICIDAL ACTIVITY - Google Patents

METHOD FOR PRODUCING 3,3 '- (3,6-DIOXOACTAN-1,8-DIIL) BIS-1,5,3-DITIAZEPINAN AND ITS APPLICATION AS A MEANS WITH FUNGICIDAL ACTIVITY Download PDF

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RU2013108527A
RU2013108527A RU2013108527/04A RU2013108527A RU2013108527A RU 2013108527 A RU2013108527 A RU 2013108527A RU 2013108527/04 A RU2013108527/04 A RU 2013108527/04A RU 2013108527 A RU2013108527 A RU 2013108527A RU 2013108527 A RU2013108527 A RU 2013108527A
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diamine
bis
dioxaoctane
fungicidal activity
dithihexane
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RU2013108527/04A
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RU2547267C2 (en
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Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Радик Анварович Зайнуллин
Наиля Фауатовна Галимзянова
Елена Борисовна Рахимова
Ринат Арфикович Исмагилов
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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Abstract

1. Способ получения 3,3'-(3,6-диоксаоктан-1,8-диил)бис-1,5,3-дитиазепинана (1):отличающийся тем, что 3,6-диоксаоктан-1,8-диамин подвергают взаимодействию с N,N,N,N-тетраметил-2,5-дитиагексан-1,6-диамином в среде этанол-хлороформ (1:2, объемные) в присутствии катализатора SmCl·6HO при мольном соотношении 3,6-диоксаоктан-1,8-диамин : N,N,N,N-тетраметил-2,5-дитиагексан-1,6-диамин : SmCl·6HO=1:2:(0,03-0,07) при комнатной температуре (~20°C) и атмосферном давлении в течение 2,5-3.5 ч.2. Применение 3,3'-(3,6-диоксаоктан-1,8-диил)бис-1,5,3-дитиазепинана в качестве средства с фунгицидной активностью для борьбы с грибковыми заболеваниями сельскохозяйственных культур, вызываемыми грибом Botrytis cinerea.1. The method of obtaining 3,3 '- (3,6-dioxaoctane-1,8-diyl) bis-1,5,3-dithiazepinane (1): characterized in that 3,6-dioxaoctane-1,8-diamine subjected to interaction with N, N, N, N-tetramethyl-2,5-dithihexane-1,6-diamine in ethanol-chloroform medium (1: 2, volume) in the presence of a catalyst SmCl · 6HO in a molar ratio of 3,6-dioxoctane -1,8-diamine: N, N, N, N-tetramethyl-2,5-dithihexane-1,6-diamine: SmCl6HO = 1: 2: (0.03-0.07) at room temperature ( ~ 20 ° C) and atmospheric pressure for 2.5-3.5 hours. 2. The use of 3,3 '- (3,6-dioxaoctan-1,8-diyl) bis-1,5,3-dithiazepinan as an agent with fungicidal activity for controlling fungal diseases of crops caused by the fungus Botrytis cinerea.

Claims (2)

1. Способ получения 3,3'-(3,6-диоксаоктан-1,8-диил)бис-1,5,3-дитиазепинана (1):1. The method of obtaining 3,3 '- (3,6-dioxaoctane-1,8-diyl) bis-1,5,3-dithiazepinan (1):
Figure 00000001
Figure 00000001
 отличающийся тем, что 3,6-диоксаоктан-1,8-диамин подвергают взаимодействию с N1,N1,N6,N6-тетраметил-2,5-дитиагексан-1,6-диамином в среде этанол-хлороформ (1:2, объемные) в присутствии катализатора SmCl3·6H2O при мольном соотношении 3,6-диоксаоктан-1,8-диамин : N1,N1,N6,N6-тетраметил-2,5-дитиагексан-1,6-диамин : SmCl3·6H2O=1:2:(0,03-0,07) при комнатной температуре (~20°C) и атмосферном давлении в течение 2,5-3.5 ч.characterized in that 3,6-dioxaoctane-1,8-diamine is reacted with N 1 , N 1 , N 6 , N 6 -tetramethyl-2,5-dithihexane-1,6-diamine in ethanol-chloroform (1 : 2, volumetric) in the presence of a SmCl 3 · 6H 2 O catalyst at a molar ratio of 3,6-dioxaoctane-1,8-diamine: N 1 , N 1 , N 6 , N 6 -tetramethyl-2,5-dithihexane-1 , 6-diamine: SmCl 3 · 6H 2 O = 1: 2: (0.03-0.07) at room temperature (~ 20 ° C) and atmospheric pressure for 2.5-3.5 hours. 2. Применение 3,3'-(3,6-диоксаоктан-1,8-диил)бис-1,5,3-дитиазепинана в качестве средства с фунгицидной активностью для борьбы с грибковыми заболеваниями сельскохозяйственных культур, вызываемыми грибом Botrytis cinerea. 2. The use of 3,3 '- (3,6-dioxaoctan-1,8-diyl) bis-1,5,3-dithiazepinan as an agent with fungicidal activity for controlling fungal diseases of crops caused by the fungus Botrytis cinerea.
RU2013108527/04A 2013-02-26 2013-02-26 Method of obtaining 3,3'-(3,6-dioxaoctane-1,8-diyl)bis-1,5,3-dithiazepinane and its application as agent with fungicidal activity RU2547267C2 (en)

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RU2459823C2 (en) * 2010-08-05 2012-08-27 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD FOR SELECTIVE PRODUCTION OF α,ω-BIS-(1,3,5-DITHIAZINAN-5-YL)-3-OXOPENTANE AND α,ω-BIS-(1,3,5-DITHIAZINAN-5-YL)-3,6-DIOXOOCTANE
RU2467006C1 (en) * 2011-06-07 2012-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method of obtaining 3,3'-(1,2-phenylene)-bis-1,5,3-dithiazepinane and 3,3,-[methylene-bis-(1,4-phenylene)]-bis-1,5,3- dithiazepinane
RU2466999C1 (en) * 2011-06-16 2012-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран METHOD OF OBTAINING A, α,ω-BIS-(1, 5, 3-DITHIAZEPINAN-3-YL)ALKANES

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