[go: up one dir, main page]

RU2011103674A - Способ эксплуатации реактора для высокотемпературной конверсии - Google Patents

Способ эксплуатации реактора для высокотемпературной конверсии Download PDF

Info

Publication number
RU2011103674A
RU2011103674A RU2011103674/05A RU2011103674A RU2011103674A RU 2011103674 A RU2011103674 A RU 2011103674A RU 2011103674/05 A RU2011103674/05 A RU 2011103674/05A RU 2011103674 A RU2011103674 A RU 2011103674A RU 2011103674 A RU2011103674 A RU 2011103674A
Authority
RU
Russia
Prior art keywords
catalyst
synthesis gas
promoters
mixtures
zinc
Prior art date
Application number
RU2011103674/05A
Other languages
English (en)
Other versions
RU2516546C2 (ru
Inventor
Нильс Кристиан ШИЕТТ (DK)
Нильс Кристиан ШИЕТТ
Original Assignee
Хальдор Топсеэ А/С (DK)
Хальдор Топсеэ А/С
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Хальдор Топсеэ А/С (DK), Хальдор Топсеэ А/С filed Critical Хальдор Топсеэ А/С (DK)
Publication of RU2011103674A publication Critical patent/RU2011103674A/ru
Application granted granted Critical
Publication of RU2516546C2 publication Critical patent/RU2516546C2/ru

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005Spinels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
    • C01B2203/041In-situ membrane purification during hydrogen production
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1076Copper or zinc-based catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1094Promotors or activators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1. Способ обогащения синтез-газа по водороду, при этом упомянутый выше синтез-газ содержит водород, монооксид углерода, а также пар, путем конверсии монооксида углерода и пара над катализатором, при котором упомянутый выше синтез-газ имеет молярное соотношение кислорода и углерода от 1,69 до 2,25 и при котором упомянутый выше катализатор содержит оксиды цинка и алюминия совместно с одним или более промоторами, а также при котором конверсия монооксида углерода и пара проводится в условиях высокотемпературной конверсии, где синтез-газ имеет температуру от 300°С до 400°С, и давление составляет от 2,3 до 6,5 МПа, а также при котором катализатор содержит в своей активной форме смесь цинк-алюминийоксидной шпинели и оксида цинка в комбинации с промотором в виде щелочного металла, выбранного из группы, состоящей из Na, К, Rb, Cs и их смесей, при этом упомянутый выше катализатор имеет молярное соотношение Zn/Al в пределах от 0,5 до 1,0 и содержание щелочного металла в пределах от 0,4 до 8,0 мас.% в пересчете на массу окисленного катализатора. ! 2. Способ по п.1, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Cu, Ti, Zr, редкоземельных элементов, а также их смесей. ! 3. Способ по п.2, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Сu, а также их смесей. ! 4. Применение катализатора, содержащего оксиды цинка и алюминия совместно с одним или более промоторами, при эксплуатации реактора для конверсии при условиях, в которых синтез-газ, поступающий в реактор, имеет молярное соотношение кислорода и углерода от 1,69 до 2,25, для подавления образования углеводородного побочного продукта. ! 5. Применение по п.4, при котором вышеупомянутые промо

Claims (5)

1. Способ обогащения синтез-газа по водороду, при этом упомянутый выше синтез-газ содержит водород, монооксид углерода, а также пар, путем конверсии монооксида углерода и пара над катализатором, при котором упомянутый выше синтез-газ имеет молярное соотношение кислорода и углерода от 1,69 до 2,25 и при котором упомянутый выше катализатор содержит оксиды цинка и алюминия совместно с одним или более промоторами, а также при котором конверсия монооксида углерода и пара проводится в условиях высокотемпературной конверсии, где синтез-газ имеет температуру от 300°С до 400°С, и давление составляет от 2,3 до 6,5 МПа, а также при котором катализатор содержит в своей активной форме смесь цинк-алюминийоксидной шпинели и оксида цинка в комбинации с промотором в виде щелочного металла, выбранного из группы, состоящей из Na, К, Rb, Cs и их смесей, при этом упомянутый выше катализатор имеет молярное соотношение Zn/Al в пределах от 0,5 до 1,0 и содержание щелочного металла в пределах от 0,4 до 8,0 мас.% в пересчете на массу окисленного катализатора.
2. Способ по п.1, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Cu, Ti, Zr, редкоземельных элементов, а также их смесей.
3. Способ по п.2, при котором упомянутые выше промоторы выбираются из Na, К, Rb, Cs, Сu, а также их смесей.
4. Применение катализатора, содержащего оксиды цинка и алюминия совместно с одним или более промоторами, при эксплуатации реактора для конверсии при условиях, в которых синтез-газ, поступающий в реактор, имеет молярное соотношение кислорода и углерода от 1,69 до 2,25, для подавления образования углеводородного побочного продукта.
5. Применение по п.4, при котором вышеупомянутые промоторы выбираются из Na, К, Rb, Cs, Cu, Ti, Zr, редкоземельных элементов, а также их смесей.
RU2011103674/05A 2008-07-03 2009-06-15 Способ эксплуатации реактора для высокотемпературной конверсии RU2516546C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA200800935 2008-07-03
DKPA200800935 2008-07-03
PCT/EP2009/004288 WO2010000387A1 (en) 2008-07-03 2009-06-15 Process for operating hts reactor

Publications (2)

Publication Number Publication Date
RU2011103674A true RU2011103674A (ru) 2012-08-10
RU2516546C2 RU2516546C2 (ru) 2014-05-20

Family

ID=40983342

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2011103674/05A RU2516546C2 (ru) 2008-07-03 2009-06-15 Способ эксплуатации реактора для высокотемпературной конверсии

Country Status (12)

Country Link
US (1) US8404156B2 (ru)
EP (2) EP2300359B1 (ru)
KR (1) KR101529906B1 (ru)
CN (1) CN102083745B (ru)
BR (1) BRPI0915369B8 (ru)
CA (1) CA2729736C (ru)
ES (2) ES2728916T3 (ru)
MX (1) MX2010014351A (ru)
PL (2) PL2924002T3 (ru)
RU (1) RU2516546C2 (ru)
WO (1) WO2010000387A1 (ru)
ZA (1) ZA201009233B (ru)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2008313C2 (en) 2012-02-17 2013-09-02 Stichting Energie Water gas shift process.
GB201501952D0 (en) * 2015-02-05 2015-03-25 Johnson Matthey Plc Process
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
BR112018008318A2 (pt) 2015-10-29 2018-10-30 Johnson Matthey Public Limited Company precursor de catalisador, métodos para preparar precursor de catalisador e para produzir um catalisador, catalisador de deslocamento água-gás, e, processo para aumentar o teor de hidrogênio
GB201519133D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
MX2018008598A (es) * 2016-02-02 2018-12-10 Topsoe Haldor As Proceso y planta de amoniaco basados en atr.
GB201603298D0 (en) 2016-02-25 2016-04-13 Johnson Matthey Plc Process
AR107702A1 (es) * 2016-02-29 2018-05-23 Haldor Topsoe As Renovación con baja cantidad de vapor / carbono
EA201992025A1 (ru) * 2017-03-07 2020-03-06 Хальдор Топсёэ А/С Способ получения мочевины с контролируемым избытком coи/или nh
KR20200028905A (ko) * 2017-07-13 2020-03-17 할도르 토프쉐 에이/에스 암모니아 합성 가스의 제조를 위한 방법 및 촉매
CN108435182B (zh) * 2017-08-16 2021-01-15 西安向阳航天材料股份有限公司 一种铜系低温变换催化剂的制备方法
PL235786B1 (pl) * 2017-09-29 2020-10-19 Grupa Azoty Spolka Akcyjna Promotowany katalizator cynkowy parowej konwersji tlenku węgla i sposób jego otrzymywania
PL234182B1 (pl) * 2017-09-29 2020-01-31 Inst Nowych Syntez Chemicznych Promotowany katalizator cynkowy parowej konwersji tlenku węgla i sposób jego otrzymywania
DK181937B1 (en) 2020-10-08 2025-04-04 Petroleo Brasileiro Sa Petrobras Methods for preparing high temperature water gas shifting catalyst, catalyst and process for reducing carbon monoxide
US20240002223A1 (en) 2020-11-24 2024-01-04 Topsoe A/S Method of starting-up a water gas shift reactor
KR20230110504A (ko) * 2020-11-24 2023-07-24 토프쉐 에이/에스 Co 풍부 가스로부터 수소의 제조 공정
CN116528973B (zh) * 2020-11-24 2025-08-29 托普索公司 改进的水煤气变换催化剂
US20240024855A1 (en) * 2020-12-09 2024-01-25 Petróleo Brasileiro S.A. – Petrobras Methods for preparing a catalytic converter by displacement of water gas at high temperature and method for reducing carbon monoxide content
US20240116756A1 (en) 2022-10-06 2024-04-11 Air Products And Chemicals, Inc. Process and System for Water-Gas Shift Conversion of Synthesis Gas with High CO Concentration

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2567866B1 (fr) * 1984-07-20 1987-01-02 Shell Int Research Procede de preparation d'un gaz riche en hydrogene
GB8817480D0 (en) * 1988-07-22 1988-08-24 Ici Plc Hydrogen
EP0361648B1 (en) * 1988-07-22 1993-04-07 Imperial Chemical Industries Plc Hydrogen production including a shift reaction process
GB9225372D0 (en) * 1992-12-04 1993-01-27 British Petroleum Co Plc Oxide compositions
ATE251592T1 (de) * 2000-04-27 2003-10-15 Haldor Topsoe As Verfahren zur herstellung eines wasserstoffreichen gases
GB0121680D0 (en) * 2001-09-08 2001-10-31 Ici Plc Catalysts
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
US20040105804A1 (en) * 2002-11-29 2004-06-03 Industrial Technology Research Institute Catalyst for water-gas shift reaction and method for converting carbon monoxide and water to hydrogen and carbon dioxide
EP1445235B1 (en) * 2003-02-05 2012-03-07 Haldor Topsoe A/S Process for treatment of synthesis gas
JP2004321924A (ja) * 2003-04-24 2004-11-18 Toyota Central Res & Dev Lab Inc 水性ガスシフト反応用触媒

Also Published As

Publication number Publication date
AU2009266113A1 (en) 2010-01-07
BRPI0915369A2 (pt) 2015-11-03
EP2300359B1 (en) 2015-08-26
KR20110039422A (ko) 2011-04-18
BRPI0915369B8 (pt) 2020-02-04
MX2010014351A (es) 2011-05-03
CN102083745B (zh) 2014-04-02
KR101529906B1 (ko) 2015-06-18
CA2729736A1 (en) 2010-01-07
US8404156B2 (en) 2013-03-26
EP2924002B1 (en) 2019-04-24
ES2549382T3 (es) 2015-10-27
EP2924002A1 (en) 2015-09-30
US20110101279A1 (en) 2011-05-05
PL2924002T3 (pl) 2019-09-30
PL2300359T3 (pl) 2016-01-29
RU2516546C2 (ru) 2014-05-20
ES2728916T3 (es) 2019-10-29
CA2729736C (en) 2015-09-15
ZA201009233B (en) 2012-04-25
WO2010000387A1 (en) 2010-01-07
BRPI0915369B1 (pt) 2019-09-24
EP2300359A1 (en) 2011-03-30
CN102083745A (zh) 2011-06-01

Similar Documents

Publication Publication Date Title
RU2011103674A (ru) Способ эксплуатации реактора для высокотемпературной конверсии
RU2009125333A (ru) Катализатор для применения в высокотемпературной реакции сдвига и способ обогащения смеси синтез-газа водородом или монооксидом углерода
Ojelade et al. A review on Pd based catalysts for CO2 hydrogenation to methanol: in-depth activity and DRIFTS mechanistic study
Daza et al. CO 2 conversion by reverse water gas shift catalysis: comparison of catalysts, mechanisms and their consequences for CO 2 conversion to liquid fuels
KR102402047B1 (ko) 혼합 금속 철 산화물 및 이의 용도
JP3326753B2 (ja) ガスタービン発電からの排気中の窒素酸化物を減少させる方法
Roh et al. Low temperature and H2 selective catalysts for ethanol steam reforming
US8540898B2 (en) Catalyst for reverse shift reaction and method for producing synthesis gas using the same
CN102198935A (zh) 甲醇水重整制氢的方法
MY155850A (en) Carbon oxides coversion process
Hormilleja et al. Hydrogen from ethanol by steam iron process in fixed bed reactor
UA120174C2 (uk) СПОСІБ ОДЕРЖАННЯ ГАЗОПОДІБНОГО АМІАКУ І СО<sub>2</sub> ДЛЯ СИНТЕЗУ СЕЧОВИНИ
Jia et al. An integrated air–POM syngas/dimethyl ether process from natural gas
KR20150093652A (ko) 산화 이중개질을 통한 메탄 공급원으로부터 메탄올의 효율적, 자기충족적 제조
Wang et al. CaO–ZnO catalyst for selective conversion of methane to C2 hydrocarbons using carbon dioxide as the oxidant
JP2009544464A5 (ru)
KR950005964A (ko) 이산화탄소로 부터 합성가스의 제조방법
JP7686552B2 (ja) 二酸化炭素変換装置及び二酸化炭素変換方法
RU2017118496A (ru) Конверсия метана и этана в синтез-газ и этилен
KR20160112179A (ko) 천연가스 엔진 배기가스 정화용 촉매
RU2008128560A (ru) Способ получения глицеринкарбоната
EA200602028A1 (ru) Катализаторы
CN102451690B (zh) 一种代用天然气的制备方法
NO20030371L (no) En reaktor som omfatter et pakket lag av båren katalysator eller båren katalysatorforlöper, og en anvendelse av reaktoren
CN1321098C (zh) 一种丙烷二氧化碳氧化脱氢制备丙烯的方法