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RU2009141367A - Ароматические уретанакрилаты, имеющие высокий показатель преломления - Google Patents

Ароматические уретанакрилаты, имеющие высокий показатель преломления Download PDF

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RU2009141367A
RU2009141367A RU2009141367/04A RU2009141367A RU2009141367A RU 2009141367 A RU2009141367 A RU 2009141367A RU 2009141367/04 A RU2009141367/04 A RU 2009141367/04A RU 2009141367 A RU2009141367 A RU 2009141367A RU 2009141367 A RU2009141367 A RU 2009141367A
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olefinically unsaturated
compounds
urethane
isocyanates
optionally
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Николас ШТЕККЕЛЬ (DE)
Николас ШТЕККЕЛЬ
Фридрих-Карл БРУДЕР (DE)
Фридрих-Карл БРУДЕР
Ян ВАЙКАРД (DE)
Ян ВАЙКАРД
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Байер МатириальСайенс АГ (DE)
Байер Матириальсайенс Аг
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Abstract

1. Голографическая среда, полученная из олефиноненасыщенных ароматических уретанов, имеющая показатель преломления при λ=532 нм≥1,5. ! 2. Голографическая среда по п.1, отличающаяся тем, что олефиноненасыщенные ароматические уретаны представляют собой уретанакрилаты и/или уретанметакрилаты. ! 3. Способ получения олефиноненасыщенных ароматических уретанов, причем этот способ содержит стадии ! A) взаимодействия одного или нескольких ароматических полиизоцианатов с ! Б) одним или несколькими соединениями, реакционноспособными по отношению к изоцианатам, имеющими, по меньшей мере, одну сшиваемую излучением олефиноненасыщенную двойную связь, ! B) необязательно, одним или несколькими соединениями, реакционноспособными по отношению к изоцианатам, которые не содержат сшиваемых облучением олефиноненасыщенных двойных связей, ! Г) необязательно, одним или несколькими наполнителями из наночастиц и ! Д) необязательно, одним или несколькими стабилизаторами, где олефиноненасыщенные ароматические уретаны имеют показатель преломления при λ=532 нм≥1,5. ! 4. Способ по п.3, где одно или несколько соединений, выбранных из группы, состоящей из 1,4-фенилендиизоцианата, 2,4- и/или 2,6-толуилендиизоцианата, 1,5-нафтилендиизоцианата, 2,4'- или 4,4'-дифенилметандиизоцианата, трифенилметан-4,4',4''-триизоцианата и трис(п-изоцианатофенил)тиофосфата, одного или нескольких вторичных продуктов указанных выше мономерных изоцианатов, имеющих уретановые, мочевинные, карбодиимидные, ацилмочевинные, изоциануратные, аллофанатные, биуретные, оксадиазинтрионные, уретдионные или иминооксадиазиндионные структуры, и смесей указанных выше соединений, использ�

Claims (12)

1. Голографическая среда, полученная из олефиноненасыщенных ароматических уретанов, имеющая показатель преломления при λ=532 нм≥1,5.
2. Голографическая среда по п.1, отличающаяся тем, что олефиноненасыщенные ароматические уретаны представляют собой уретанакрилаты и/или уретанметакрилаты.
3. Способ получения олефиноненасыщенных ароматических уретанов, причем этот способ содержит стадии
A) взаимодействия одного или нескольких ароматических полиизоцианатов с
Б) одним или несколькими соединениями, реакционноспособными по отношению к изоцианатам, имеющими, по меньшей мере, одну сшиваемую излучением олефиноненасыщенную двойную связь,
B) необязательно, одним или несколькими соединениями, реакционноспособными по отношению к изоцианатам, которые не содержат сшиваемых облучением олефиноненасыщенных двойных связей,
Г) необязательно, одним или несколькими наполнителями из наночастиц и
Д) необязательно, одним или несколькими стабилизаторами, где олефиноненасыщенные ароматические уретаны имеют показатель преломления при λ=532 нм≥1,5.
4. Способ по п.3, где одно или несколько соединений, выбранных из группы, состоящей из 1,4-фенилендиизоцианата, 2,4- и/или 2,6-толуилендиизоцианата, 1,5-нафтилендиизоцианата, 2,4'- или 4,4'-дифенилметандиизоцианата, трифенилметан-4,4',4''-триизоцианата и трис(п-изоцианатофенил)тиофосфата, одного или нескольких вторичных продуктов указанных выше мономерных изоцианатов, имеющих уретановые, мочевинные, карбодиимидные, ацилмочевинные, изоциануратные, аллофанатные, биуретные, оксадиазинтрионные, уретдионные или иминооксадиазиндионные структуры, и смесей указанных выше соединений, используют в A).
5. Способ по п.3, где одно или несколько соединений из группы, состоящей из акрилатов, метакрилатов, малеинатов, фумаратов, малеимидов, акриламидов, виниловых простых эфиров, пропениловых простых эфиров, аллиловых простых эфиров и соединений, содержащих дициклопентадиенильные звенья, которые имеют, по меньшей мере, одну группу, реакционноспособную по отношению к изоцианатам на молекулу, используют в Б).
6. Способ по п.3, где одно или несколько соединений из группы, состоящей из 2-гидроксиэтилакрилата, гидроксипропилакрилата, 4-гидроксибутилакрилата, поли(ε-капролактон)моно(мет)акрилата, пентаэритритилтриакрилата и продукта реакции акриловой кислоты с глицидилметакрилатом, используют в Б).
7. Способ по п.3, где одно или несколько соединений, выбранных из 9-(2-гидроксиэтил)-9Н-карбазола, гидроксиметилнафталина, N-(2-гидроксиэтил)фталимида, 2-фенилэтанола, (п-хлор)фенилэтанола, 2-(п-хлорфенил)этанола, трифенилметанола и/или нафталинтиометанола, используют в В).
8. Олефиноненасыщенные ароматические уретаны, получаемые по любому из пп.3-7.
9. Уретан(мет)акрилаты, содержащие, по меньшей мере, одно структурное звено формул
Figure 00000001
и
Figure 00000002
в которых Х представляет собой кислород, аминогруппу или серу, а R содержит, по меньшей мере, 30 мол.% олефиноненасыщенных углеводородных радикалов, необязательно, содержащих гетероатомы, и не более 70 мол.% углеводородных радикалов, необязательно, содержащих гетероатомы, которые не содержат олефиноненасыщенных групп.
10. Уретан(мет)акрилаты по п.9, где олефиноненасыщенные углеводородные радикалы, необязательно, содержащие гетероатомы, представляют собой радикалы этилакрилата, пропилакрилата и/или бутилакрилата, и углеводородные радикалы, необязательно, содержащие гетероатомы, которые не содержат олефиноненасыщенных групп, представляют собой радикалы 9Н-карбазола, 9-этил-9Н-карбазола, нафталина, метилнафталина, N-этилфталимида, бензола, этилбензола, (п-хлор)этилбензола и/или трифенилметана.
11. Уретан(мет)акрилаты по п.9, полученные взаимодействием трис(п-изоцианатофенил)тиофосфата и/или трифенилметан-4,4',4''-триизоцианата с реакционноспособными по отношению к изоцианатам соединениями, имеющими, по меньшей мере, одну сшиваемую излучением олефиноненасыщенную двойную связь.
12. Голографическая среда, полученная из а) олефиноненасыщенных уретанов по п.8 или уретан(мет)акрилатов по п.9, б) изоцианатного компонента, в) реакционноспособного по отношению к изоцианатам компонента, и г) фотоинициатора.
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Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010523775A (ja) * 2007-04-11 2010-07-15 バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト イミノオキサジアジンジオンを含む放射線架橋性および熱架橋性のｐｕ系
WO2008125200A1 (en) * 2007-04-11 2008-10-23 Bayer Materialscience Ag Radiation-crosslinking and thermally crosslinking pu systems based on isocyanate-reactive block copolymers
WO2008125229A1 (en) * 2007-04-11 2008-10-23 Bayer Materialscience Ag Advantageous recording media for holographic applications
US20100270767A1 (en) * 2007-10-04 2010-10-28 Morph Technologies, Inc. Vehicular suspension components
WO2009045415A1 (en) * 2007-10-04 2009-04-09 E. I. Du Pont De Nemours And Company Internal combustion engine covers
US20100290899A1 (en) * 2007-10-04 2010-11-18 Morph Technologies, Inc. Vehicular turbocharger components
WO2009045436A1 (en) 2007-10-04 2009-04-09 E.I. Du Pont De Nemours And Company Vehicular transmission parts
EP2193664B1 (en) 2007-10-04 2013-02-20 Integran Technologies Vehicular electrical and electronic housings
US8431673B2 (en) * 2007-11-19 2013-04-30 Cytec Surface Specialties S.A. Radiation curable compositions
ATE493383T1 (de) 2008-08-08 2011-01-15 Bayer Materialscience Ag Phenylisocyanat-basierte urethanacrylate mit hohem brechungsindex
WO2010037515A1 (de) * 2008-10-01 2010-04-08 Bayer Materialscience Ag Medien für volumenholographische aufzeichnung basierend auf sich selbstentwickelndem polymer
IL200722A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Photopolymer compositions for optical elements and visual displays
IL200996A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Photopolymer formulations having a low crosslinking density
IL200995A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Polyether-based polyurethane formulations for the production of holographic media
WO2010037496A1 (de) * 2008-10-01 2010-04-08 Bayer Materialscience Ag Prepolymerbasierte polyurethanformulierungen zur herstellung holografischer medien
IL200997A0 (en) * 2008-10-01 2010-06-30 Bayer Materialscience Ag Special polyether-based polyurethane formulations for the production of holographic media
EP2218742A1 (de) * 2009-02-12 2010-08-18 Bayer MaterialScience AG Photopolymerzusammensetzungen als verdruckbare Formulierungen
EP2218744A1 (de) * 2009-02-12 2010-08-18 Bayer MaterialScience AG Methode zur Herstellung von holografischen Photopolymeren auf Polymerfolien
EP2218743A1 (de) * 2009-02-12 2010-08-18 Bayer MaterialScience AG Prepolymerbasierte Polyurethanformulierungen zur Herstellung holographischer Filme
US8284234B2 (en) 2009-03-20 2012-10-09 Absolute Imaging LLC Endoscopic imaging using reflection holographic optical element for autostereoscopic 3-D viewing
US8323854B2 (en) * 2009-04-23 2012-12-04 Akonia Holographics, Llc Photopolymer media with enhanced dynamic range
JP5483065B2 (ja) * 2009-09-28 2014-05-07 川崎化成工業株式会社 アントラセン骨格を有するエポキシアクリレート及びその製造法
EP2496620B1 (en) * 2009-11-02 2014-06-25 Ocutec Limited Polymers for contact lenses
TWI488908B (zh) 2009-11-03 2015-06-21 Bayer Materialscience Ag 製造全像膜的方法
EP2497081B1 (de) 2009-11-03 2013-10-16 Bayer Intellectual Property GmbH Verfahren zur herstellung von holographischen medien
EP2317511B1 (de) * 2009-11-03 2012-03-07 Bayer MaterialScience AG Photopolymerformulierungen mit einstellbarem mechanischem Modul Guv
EP2496617B1 (de) 2009-11-03 2015-02-25 Bayer Intellectual Property GmbH Urethane als additive in einer photopolymer-formulierung
PL2497082T3 (pl) 2009-11-03 2013-12-31 Bayer Ip Gmbh Fluorouretany jako dodatek w formulacji fotopolimerowej
US8771903B2 (en) * 2009-11-03 2014-07-08 Bayer Materialscience Ag Method for producing a holographic film
KR101747467B1 (ko) * 2009-11-03 2017-06-14 코베스트로 도이칠란드 아게 굴절률이 높고 이중 결합 밀도가 감소된 우레탄 아크릴레이트
US8889322B2 (en) * 2009-11-03 2014-11-18 Bayer Materialscience Ag Photopolymer formulation having different writing comonomers
JP5793147B2 (ja) * 2009-11-03 2015-10-14 バイエル・マテリアルサイエンス・アクチェンゲゼルシャフトＢａｙｅｒ ＭａｔｅｒｉａｌＳｃｉｅｎｃｅ ＡＧ 新規な非結晶化メタクリレート、その製造方法およびその使用
CN102947885A (zh) * 2010-01-28 2013-02-27 拜耳材料科技股份有限公司 高速dvd
WO2011091550A1 (en) 2010-01-28 2011-08-04 Bayer Materialscience Ag High speed dvds
WO2011095441A1 (de) * 2010-02-02 2011-08-11 Bayer Materialscience Ag Photopolymer-formulierung mit triazin-basierten schreibmonomeren
WO2011095442A1 (de) * 2010-02-02 2011-08-11 Bayer Materialscience Ag Photopolymer-formulierung mit ester-basierten schreibmonomeren
EP2368934A1 (de) * 2010-03-26 2011-09-28 Bayer MaterialScience AG Polymerschichtenverbund mit verbesserter Haftung der Schichten
EP2372454A1 (de) * 2010-03-29 2011-10-05 Bayer MaterialScience AG Photopolymer-Formulierung zur Herstellung sichtbarer Hologramme
WO2011140198A2 (en) 2010-05-05 2011-11-10 The Board Of Trustees Of The University Of Illinois Compounds and methods of treating brain disorders
JP6088971B2 (ja) * 2010-08-11 2017-03-01 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ 二官能性（メタ）アクリレート書込モノマー
JP2012077278A (ja) * 2010-10-04 2012-04-19 Pelnox Ltd 光学材料用樹脂組成物およびその硬化物
JP5859280B2 (ja) * 2011-11-14 2016-02-10 新日鉄住金化学株式会社 感光性材料、ホログラフィック記録媒体、及びホログラフィック記録方法
JP6062732B2 (ja) * 2012-12-19 2017-01-18 株式会社Adeka 新規化合物及び着色感光性組成物
TR201809751T4 (tr) * 2013-10-17 2018-07-23 Covestro Deutschland Ag Holografi ortamlarının üretimi için düşük TG değerine sahip boratları içeren fotopolimer formülasyonu.
WO2015161969A1 (de) 2014-04-25 2015-10-29 Bayer Material Science Ag Aromatische glykolether als schreibmonomere in holographischen photopolymer-formulierungen
TWI576666B (zh) * 2014-09-24 2017-04-01 旭化成電子材料股份有限公司 感光性樹脂組合物、感光性樹脂積層體、樹脂圖案之製造方法、硬化膜及顯示裝置
TWI579839B (zh) * 2015-02-17 2017-04-21 駿康科技有限公司 資訊記錄媒體記錄層之形成方法
JP6208398B2 (ja) * 2015-09-10 2017-10-04 三井化学東セロ株式会社 粘着剤組成物及びその製造方法並びに粘着フィルム
CN105418674A (zh) * 2015-11-10 2016-03-23 中国乐凯集团有限公司 一种高折射率树脂及其应用
US11718580B2 (en) 2019-05-08 2023-08-08 Meta Platforms Technologies, Llc Fluorene derivatized monomers and polymers for volume Bragg gratings
US20210155584A1 (en) * 2019-11-27 2021-05-27 Facebook Technologies, Llc Aromatic substituted methane-core monomers and polymers thereof for volume bragg gratings
US11780819B2 (en) 2019-11-27 2023-10-10 Meta Platforms Technologies, Llc Aromatic substituted alkane-core monomers and polymers thereof for volume Bragg gratings
US20210155639A1 (en) * 2019-11-27 2021-05-27 Facebook Technologies, Llc Thiophosphate and phosphine sulfide derivatized monomers and polymers for volume bragg gratings
US11879024B1 (en) 2020-07-14 2024-01-23 Meta Platforms Technologies, Llc Soft mold formulations for surface relief grating fabrication with imprinting lithography
US20220153895A1 (en) * 2020-11-13 2022-05-19 Facebook Technologies, Llc Substituted propane-core monomers and polymers thereof for volume bragg gratings
US20220153693A1 (en) * 2020-11-13 2022-05-19 Facebook Technologies, Llc Substituted mono- and poly-phenyl-core monomers and polymers thereof for volume bragg gratings
CN113621121B (zh) * 2021-07-15 2022-08-23 中联重科股份有限公司 聚氨酯组合物和聚氨酯材料的制备方法及应用
CN114213626B (zh) * 2021-12-09 2023-04-28 江苏三木化工股份有限公司 一种植物油基光固化聚氨酯丙烯酸酯的制备方法
CN114231163A (zh) * 2021-12-22 2022-03-25 武汉工程大学 一种聚氨酯类有机无机复合材料及其制备方法和应用
CN115785756B (zh) * 2022-12-12 2023-07-28 江苏视科新材料股份有限公司 一种折光指数可调节的防蓝光涂层材料的制备方法
CN115785811B (zh) * 2022-12-12 2023-07-28 江苏视科新材料股份有限公司 一种高折射率防蓝光材料和防蓝光滤光片

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5916987A (en) 1996-05-29 1999-06-29 Mitsui Chemicals, Inc. Thiol and Sulfur-containing O-(meth) acrylate compounds and use thereof
US6232038B1 (en) * 1998-10-07 2001-05-15 Mitsubishi Chemical Corporation Photosensitive composition, image-forming material and image-forming method employing it
DE69916750T2 (de) * 1998-11-17 2005-01-05 Showa Denko K.K. Photohärtbare Zusammensetzung
EP1014113A3 (en) * 1998-12-21 2001-05-09 Dsm N.V. Photo curable resin composition and optical parts
HUP0203434A3 (en) * 1999-11-18 2010-01-28 Ppg Ind Ohio Optical resin composition
KR100453344B1 (ko) 2000-09-22 2004-10-20 미쯔이카가쿠 가부시기가이샤 아크릴산 에스테르화합물 및 그 용도
US6780546B2 (en) 2001-08-30 2004-08-24 Inphase Technologies, Inc. Blue-sensitized holographic media
EP1548039B1 (en) * 2002-07-29 2008-08-13 Mitsui Chemicals, Inc. Photopolymerizable composition and use thereof
JP3852613B2 (ja) * 2003-02-12 2006-12-06 三菱化学株式会社 感光性組成物、並びにそれを用いた画像形成材料、画像形成材、及び画像形成方法
JP2004295058A (ja) * 2003-02-14 2004-10-21 Mitsubishi Chemicals Corp 感光性組成物
JP3896098B2 (ja) * 2003-06-27 2007-03-22 株式会社東芝 ホログラム記録媒体およびその作製方法
JP2006307159A (ja) * 2005-03-28 2006-11-09 Toyo Ink Mfg Co Ltd 硬化性高屈折率材料及び該硬化性高屈折率材料を用いてなる積層体
JP4675197B2 (ja) * 2005-09-20 2011-04-20 富士フイルム株式会社 溶媒非含有の光記録用組成物及びその製造方法、並びに光記録媒体

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