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RU2007130918A - Способ промышленного получения углеводородов - Google Patents

Способ промышленного получения углеводородов Download PDF

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RU2007130918A
RU2007130918A RU2007130918/04A RU2007130918A RU2007130918A RU 2007130918 A RU2007130918 A RU 2007130918A RU 2007130918/04 A RU2007130918/04 A RU 2007130918/04A RU 2007130918 A RU2007130918 A RU 2007130918A RU 2007130918 A RU2007130918 A RU 2007130918A
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oil
hydrocarbons
fats
temperature
mpa
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RU2007130918/04A
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RU2397199C2 (ru
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Дмитрий Юрьевич МУРЗИН (FI)
Дмитрий Юрьевич МУРЗИН
Ива КУБИЦКОВА (CZ)
Ива КУБИЦКОВА
Матиас СНОРЕ (FI)
Матиас СНОРЕ
П йви МЯКИ-АРВЕЛА (FI)
Пяйви МЯКИ-АРВЕЛА
Юкка МЮЛЛЮОЙЯ (FI)
Юкка Мюллюойя
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Несте Ойл Ойй (Fi)
Несте Ойл Ойй
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
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    • C10G3/42—Catalytic treatment
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
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    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
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  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Claims (18)

1. Способ селективного получения углеводородов, пригодных для дизельного топлива, характеризующийся тем, что в данном способе есть стадии, на которых проводится реакция декарбоксилирования/декарбонилирования, посредством введения сырья, происходящего из возобновляемых источников, и содержащего в себе С8-С24 жирные кислоты, производные С8-С24 жирных кислот, или их сочетание, и, при желании, сольвент или смесь сольвентов, во взаимодействие с гетерогенным катализатором, при необходимости, предварительно обработанным, который содержит в себе один или несколько металлов, принадлежащих к группе VIII, выбранный из платины, палладия, никеля, иридия, рутения и родия на носителе, выбранном из оксидов, мезопористых веществ, углеродсодержащих носителей и структурных носителей катализатора, при температуре 200-400°С и давлении от 0,1 до 15 МПа, для получения смеси углеводородов в качестве продукта.
2. Способ по п.1, характеризующийся тем, что температура составляет 250-350°С и давление составляет 0,1-5 МПа.
3. Способ по п.1 или 2, характеризующийся тем, что перед вступлением в контакт с сырьем гетерогенный катализатор предварительно обработан водородом при температуре 100-500°C.
4. Способ по любому из пп.1 и 2, характеризующийся тем, что перед вступлением в контакт с сырьевым материалом гетерогенный катализатор предварительно обработан водородом при температуре 150-250°C.
5. Способ по любому из пп.1 и 2, характеризующийся тем, что продукт является изомеризованным при давлении в диапазоне 2-15 МПа, предпочтительно 3-10 МПа и при температуре между 200 и 500°C, предпочтительно между 280 и 400°C, в присутствии катализатора изомеризации.
6. Способ по п.5, характеризующийся тем, что продукт является изомеризованным при давлении в диапазоне 3-10 МПа, и при температуре между 280 и 400°C.
7. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что реакция декарбоксилирования/декарбонилирования проводится в жидкой фазе.
8. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что данными возобновляемыми источниками являются жиры и масла растений, и/или животных, и/или рыб, и соединения, полученные из них.
9. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что сырье выбрано из древесных, растительных и овощных жиров и масел, жиров, содержащихся в растениях, выведенных с помощью генных манипуляций, животных жиров и масел, жиров и масел рыб, и переработанных пищевых жиров, и их смесей.
10. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что сырьевой материал выбран из рапсового масла, сурепного масла, масла канолы, таллового масла, подсолнечного масла, соевого масла, конопляного масла, оливкового масла, льняного масла, горчичного масла, пальмового масла, арахисового масла, касторового масла, кокосового масла, свиного сала, говяжьего или бараньего жира, китового жира, и жиров, содержащихся в молоке.
11. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что сырье содержит в себе триглицеридную фракцию рапсового масла, льняного масла, подсолнечного масла, говяжьего или бараньего жира и свиного сала, или фракции таллового масла.
12. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что производные жирных кислот содержат в себе эфиры жирных кислот, триглицериды жирных кислот и соли металлов жирных кислот.
13. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что металлом группы VIII является платина или палладий.
14. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что носитель выбран из Al2O3, SiO2, Cr2O3, MgO, TiO2, активированного угля, углеродных волокон, углеродных нанотрубок, прикрепленных к монолитам и углеродных материй.
15. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что носитель выбран из активированного угля, углеродных волокон, углеродных нанотрубок, прикрепленных к монолитам и углеродных материй.
16. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что растворитель выбран из группы, состоящей из углеводородов, предпочтительно, углеводородов парафинового ряда, изопарафинов, нафтеновых и ароматических углеводородов с температурой кипения в диапазоне 150-350°C и рециклированный технологический поток, состоящий из углеводородов и их сочетания.
17. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что в сырье добавлено 0,1-40 об.% водорода.
18. Способ по любому из пп.1, 2 или 6, характеризующийся тем, что в сырье добавлено 2-15 об.% водорода.
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JP2008526928A (ja) 2008-07-24
CN101103093B (zh) 2012-06-13
RU2397199C2 (ru) 2010-08-20
EP1681337A1 (en) 2006-07-19
PL1681337T3 (pl) 2011-05-31
EP1681337B1 (en) 2010-12-01
DE602005025079D1 (de) 2011-01-13
WO2006075057A2 (en) 2006-07-20
EP1681337B2 (en) 2020-05-13
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WO2006075057A3 (en) 2006-12-28
ATE490298T1 (de) 2010-12-15
PT1681337E (pt) 2010-12-24
CN101103093A (zh) 2008-01-09
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DK1681337T3 (da) 2011-03-07
CA2593277A1 (en) 2006-07-20
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BRPI0606320A2 (pt) 2009-06-16
CA2593277C (en) 2012-10-23

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