RU2007107492A - Пигмент на основе диоксида титана и способ его получения - Google Patents
Пигмент на основе диоксида титана и способ его получения Download PDFInfo
- Publication number
- RU2007107492A RU2007107492A RU2007107492/15A RU2007107492A RU2007107492A RU 2007107492 A RU2007107492 A RU 2007107492A RU 2007107492/15 A RU2007107492/15 A RU 2007107492/15A RU 2007107492 A RU2007107492 A RU 2007107492A RU 2007107492 A RU2007107492 A RU 2007107492A
- Authority
- RU
- Russia
- Prior art keywords
- pigment
- shell
- silicon dioxide
- titanium dioxide
- dense
- Prior art date
Links
- 239000000049 pigment Substances 0.000 title claims abstract 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract 12
- 239000004408 titanium dioxide Substances 0.000 title claims abstract 6
- 238000004519 manufacturing process Methods 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 20
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract 10
- 229910052751 metal Inorganic materials 0.000 claims abstract 8
- 239000002184 metal Substances 0.000 claims abstract 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000000725 suspension Substances 0.000 claims abstract 3
- 229910052718 tin Inorganic materials 0.000 claims abstract 3
- 239000010936 titanium Substances 0.000 claims abstract 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 3
- 239000004033 plastic Substances 0.000 claims abstract 2
- 229920003023 plastic Polymers 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- WMWXXXSCZVGQAR-UHFFFAOYSA-N dialuminum;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3] WMWXXXSCZVGQAR-UHFFFAOYSA-N 0.000 claims 1
- 239000003973 paint Substances 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 239000002966 varnish Substances 0.000 claims 1
- 229910052681 coesite Inorganic materials 0.000 abstract 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract 3
- 229910052682 stishovite Inorganic materials 0.000 abstract 3
- 229910052905 tridymite Inorganic materials 0.000 abstract 3
- 238000000576 coating method Methods 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3653—Treatment with inorganic compounds
- C09C1/3661—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Claims (12)
1. Пигмент на основе диоксида титана, частицы которого содержат плотную оболочку из диоксида кремния с включенными атомами металла, отличающийся тем, что плотная оболочка из диоксида кремния нанесена в виде нескольких слоев, а внутренний слой включает незначительное количество атомов металла.
2. Пигмент по п.1, отличающийся тем, что плотная оболочка из диоксида кремния включает олово, цирконий или титан или их смеси.
3. Пигмент по п.1, отличающийся тем, что частицы дополнительно содержат внешнюю оболочку из гидрата оксида алюминия.
4. Пигмент по п.1, отличающийся тем, что в плотной оболочке из диоксида кремния содержится от 2,0 до 6,0 мас.%, предпочтительно от 2,5 до 4,0 мас.% SiO2 в перерасчете на общую массу пигмента.
5. Пигмент по любому из пп.1-4, отличающийся тем, что в плотной оболочке из диоксида кремния содержится от 0,1 до 3,0 мас.%, предпочтительно от 0,1 до 1,0 мас.% металла в перерасчете на оксид, к общей массе пигмента.
6. Пигмент по п.3, отличающийся тем, что во внешней оболочке содержится от 0,5 до 6,0 мас.%, предпочтительно от 1,0 до 4,0 мас.% Al2О3 в перерасчете на общую массу пигмента.
7. Способ получения пигмента на основе диоксида титана, частицы которого содержат плотную оболочку из диоксида кремния с включенными атомами металла, отличающийся тем, что компоненты оболочки добавляют в суспензию последовательно.
8. Способ по п.7, отличающийся тем, что в плотную оболочку из диоксида кремния включают олово, цирконий или титан или их смеси.
9. Способ по п.7, отличающийся тем, что величину рН в суспензии диоксида титана на первом этапе добавления компонентов, включающих кремний и металл, задают по крайней мере равным 9, предпочтительно по меньшей мере 10 и наиболее предпочтительно по крайней мере 11.
10. Способ по п.9, отличающийся тем, что после добавления компонентов, включающих кремний и металл, величину рН понижают до уровня ниже 9, предпочтительно до уровня ниже 8.
11. Способ по любому из пп.7-10, отличающийся тем, что формируют внешнюю оболочку из гидрата оксида алюминия.
12. Применение пигмента на основе диоксида титана по любому из пп.1-6 в составе лаков, красок или пластмасс.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004037271.3 | 2004-07-31 | ||
| DE102004037271A DE102004037271A1 (de) | 2004-07-31 | 2004-07-31 | Witterungsstabiles Titandioxid-Pigment und Verfahren zu seiner Herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2007107492A true RU2007107492A (ru) | 2008-09-10 |
| RU2458094C2 RU2458094C2 (ru) | 2012-08-10 |
Family
ID=34972382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2007107492/05A RU2458094C2 (ru) | 2004-07-31 | 2005-06-23 | Пигмент на основе диоксида титана и способ его получения |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US7682441B2 (ru) |
| EP (1) | EP1771519B1 (ru) |
| JP (1) | JP4976289B2 (ru) |
| KR (1) | KR101158347B1 (ru) |
| CN (1) | CN1969019B (ru) |
| AT (1) | ATE380849T1 (ru) |
| AU (1) | AU2005269044B2 (ru) |
| BR (1) | BRPI0513415B1 (ru) |
| DE (2) | DE102004037271A1 (ru) |
| ES (1) | ES2297732T3 (ru) |
| MX (1) | MX2007001086A (ru) |
| MY (1) | MY142070A (ru) |
| PL (1) | PL1771519T3 (ru) |
| RU (1) | RU2458094C2 (ru) |
| SI (1) | SI1771519T1 (ru) |
| TW (1) | TWI377233B (ru) |
| UA (1) | UA86259C2 (ru) |
| WO (1) | WO2006012950A1 (ru) |
| ZA (1) | ZA200609340B (ru) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SA111320424B1 (ar) * | 2006-01-30 | 2014-05-11 | كرونوس انترناشونال انك | جسيمات خضاب ثاني أكسيد التيتانيوم المزوَّدة مع طبقة كثيفة ومشابة من ثاني أكسيد السيليكون SiO2 وطرق تصنيعها |
| US7763110B2 (en) * | 2006-01-30 | 2010-07-27 | Kronos International Inc | Titanium dioxide pigment particles with doped, dense SiO2 skin and methods for their manufacture |
| US7905953B2 (en) * | 2006-01-30 | 2011-03-15 | Kronos International Inc | Titanium dioxide pigment particles with doped, dense SiO2 skin and methods for their manufacture |
| KR101340904B1 (ko) * | 2006-01-30 | 2013-12-13 | 크로노스 인터내셔널, 인코포레이티드 | 도핑된 치밀한 ＳｉＯ₂ 표피를 갖는 이산화티탄 안료 입자및 이의 제조방법 |
| JP4749200B2 (ja) * | 2006-03-31 | 2011-08-17 | 三井化学株式会社 | 高屈折率樹脂組成物 |
| JP4749201B2 (ja) * | 2006-03-31 | 2011-08-17 | 三井化学株式会社 | 半導体発光素子封止用組成物 |
| DE102006029284A1 (de) * | 2006-06-23 | 2007-12-27 | Kronos International, Inc. | Verfahren zur Identifizierung und Verifizierung von Titandioxid-Pigmentpartikel enthaltenden Produkten |
| JP5209861B2 (ja) * | 2006-09-27 | 2013-06-12 | 石原産業株式会社 | 二酸化チタン白色顔料及びその製造方法 |
| US7935753B2 (en) * | 2006-11-13 | 2011-05-03 | Tronox Llc | Surface treated pigment |
| US7238231B1 (en) | 2006-11-16 | 2007-07-03 | Tronox Llc | Process for manufacturing zirconia-treated titanium dioxide pigments |
| US8951607B2 (en) * | 2007-05-03 | 2015-02-10 | Tronox, Llc | Making co-precipitated mixed oxide-treated titanium dioxide pigments |
| US10870740B2 (en) | 2007-08-12 | 2020-12-22 | Toyota Jidosha Kabushiki Kaisha | Non-color shifting multilayer structures and protective coatings thereon |
| US10788608B2 (en) | 2007-08-12 | 2020-09-29 | Toyota Jidosha Kabushiki Kaisha | Non-color shifting multilayer structures |
| US10690823B2 (en) | 2007-08-12 | 2020-06-23 | Toyota Motor Corporation | Omnidirectional structural color made from metal and dielectric layers |
| EP2217665B1 (en) * | 2007-11-16 | 2011-06-29 | Basf Se | Bright interference pigments |
| GB0808239D0 (en) * | 2008-05-07 | 2008-06-11 | Tioxide Group Services Ltd | Compositions |
| DE102008058351A1 (de) * | 2008-11-20 | 2010-06-02 | Kronos International, Inc. | Oberflächenbehandelte Titandioxid-Pigmente für Kunststoffe und Verfahren zur Herstellung |
| EP2540672B1 (en) | 2010-02-22 | 2016-12-07 | Sakai Chemical Industry Co., Ltd. | Composite particles and process for production thereof |
| JP5489976B2 (ja) * | 2010-12-17 | 2014-05-14 | 本田技研工業株式会社 | 複層塗膜形成方法 |
| TWI483901B (zh) * | 2012-04-27 | 2015-05-11 | Cristal Usa Inc | 以ＴｉＯ２爲基質的清洗顆粒及製造和使用該以ＴｉＯ２爲基質的清洗顆粒之方法 |
| US9163130B2 (en) * | 2012-06-12 | 2015-10-20 | Sachtleben Chemie Gmbh | Method for the production of ZnS particles having a metal oxide coating and a cobalt content, products obtained thereby, and use of said products |
| RU2555484C2 (ru) * | 2013-10-08 | 2015-07-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Томский государственный университет систем управления и радиоэлектроники" | Пигмент на основе порошка диоксида титана, модифицированного наночастицами |
| EP2886612A1 (de) * | 2013-12-17 | 2015-06-24 | Kronos International, Inc. | Verfahren zur Oberflächenbeschichtung von anorganischen Partikeln, insbesondere Titandioxid-Partikeln |
| DE112015001639B4 (de) | 2014-04-01 | 2023-12-14 | Toyota Jidosha Kabushiki Kaisha | Nicht-farbverschiebende mehrschichtige strukturen |
| DE102015112412A1 (de) * | 2014-08-15 | 2016-02-18 | Toyota Jidosha Kabushiki Kaisha | Die Farbe nicht verändernde Mehrschichtstrukturen und schützende Beschichtung hierauf |
| EP2987834A1 (de) * | 2014-08-18 | 2016-02-24 | Kronos International, Inc. | Verfahren zur Oberflächenbeschichtung von anorganischen Partikeln mit Siliciumdioxid und mindestens einer weiteren anorganischen Verbindung |
| US10220676B2 (en) * | 2016-02-04 | 2019-03-05 | GM Global Technology Operations LLC | Air quality estimation methods and systems |
| WO2019065956A1 (ja) * | 2017-09-28 | 2019-04-04 | 株式会社フジミインコーポレーテッド | 水酸化アルミニウム被覆炭化珪素粒子粉体の製造方法、ならびに当該粉体および分散媒を含む分散体の製造方法 |
| EP3626885A1 (en) * | 2018-09-21 | 2020-03-25 | Kronos International, Inc. | Laminate pigment with spacing properties and high uv-greying stability |
| KR102194888B1 (ko) * | 2018-10-17 | 2020-12-24 | 한국다이요잉크 주식회사 | 잉크젯용 잉크 조성물 |
| CN110286082B (zh) * | 2019-06-25 | 2021-12-14 | 河南佰利联新材料有限公司 | 一种钛白粉耐候性快速测试方法及应用 |
| EP4227370A1 (en) * | 2022-02-09 | 2023-08-16 | Kronos International, Inc. | Color-neutral rutile pigment particle |
| CN115537104B (zh) * | 2022-11-04 | 2023-11-24 | 浙江绿环新材料科技有限公司 | 一种环保型高反射率粉末涂料及其制备工艺 |
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| US2913419A (en) * | 1956-04-18 | 1959-11-17 | Du Pont | Chemical process and composition |
| US3928057A (en) * | 1974-05-30 | 1975-12-23 | Du Pont | TiO{HD 2 {B Pigment coated with porous alumina/silica and dense silica |
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| GB2108098B (en) * | 1981-10-30 | 1985-03-20 | Tioxide Group Plc | Improved pigments and their preparation |
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| EP0495777A4 (en) * | 1989-10-12 | 1992-09-30 | Industrial Progress, Inc. | Structural aggregate pigments |
| RU2042693C1 (ru) * | 1993-06-19 | 1995-08-27 | Нина Николаевна Стремилова | Способ модифицирования пигментного диоксида титана |
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| US6776835B2 (en) * | 1998-08-14 | 2004-08-17 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Multilayer pigments based on coated metal platelets |
| US6695906B2 (en) * | 2000-04-12 | 2004-02-24 | Millennium Inorganic Chemicals, Inc. | Continuous processes for producing titanium dioxide pigments |
| AU2001255327A1 (en) * | 2000-04-12 | 2001-10-30 | Millennium Inorganic Chemicals, Inc. | Continuous processes for producing titanium dioxide pigments |
| US6342099B1 (en) * | 2000-05-01 | 2002-01-29 | Millennium Inorganic Chemicals, Inc. | Coated titanium dioxide pigments and processes for production and use |
| DE10137831A1 (de) * | 2001-08-02 | 2003-02-13 | Merck Patent Gmbh | Mehrschichtige Interferenzpigmente |
| DE10153197A1 (de) * | 2001-10-27 | 2003-05-08 | Merck Patent Gmbh | Pigment mit Metallglanz |
| US6783586B2 (en) * | 2001-11-01 | 2004-08-31 | E. I. Du Pont De Nemours And Company | Easy to disperse, high durability TiO2 pigment and method of making same |
-
2004
- 2004-07-31 DE DE102004037271A patent/DE102004037271A1/de not_active Withdrawn
-
2005
- 2005-06-21 US US11/158,761 patent/US7682441B2/en active Active
- 2005-06-23 KR KR1020077002226A patent/KR101158347B1/ko not_active Expired - Lifetime
- 2005-06-23 PL PL05760729T patent/PL1771519T3/pl unknown
- 2005-06-23 CN CN2005800192462A patent/CN1969019B/zh not_active Expired - Lifetime
- 2005-06-23 EP EP05760729A patent/EP1771519B1/de not_active Expired - Lifetime
- 2005-06-23 RU RU2007107492/05A patent/RU2458094C2/ru not_active Application Discontinuation
- 2005-06-23 UA UAA200703720A patent/UA86259C2/ru unknown
- 2005-06-23 AT AT05760729T patent/ATE380849T1/de not_active IP Right Cessation
- 2005-06-23 BR BRPI0513415-3A patent/BRPI0513415B1/pt active IP Right Grant
- 2005-06-23 WO PCT/EP2005/006797 patent/WO2006012950A1/de not_active Ceased
- 2005-06-23 DE DE502005002245T patent/DE502005002245D1/de not_active Expired - Lifetime
- 2005-06-23 ES ES05760729T patent/ES2297732T3/es not_active Expired - Lifetime
- 2005-06-23 AU AU2005269044A patent/AU2005269044B2/en not_active Ceased
- 2005-06-23 SI SI200530157T patent/SI1771519T1/sl unknown
- 2005-06-23 MX MX2007001086A patent/MX2007001086A/es active IP Right Grant
- 2005-06-23 JP JP2007524197A patent/JP4976289B2/ja not_active Expired - Lifetime
- 2005-07-06 TW TW094122820A patent/TWI377233B/zh not_active IP Right Cessation
- 2005-07-15 MY MYPI20053256A patent/MY142070A/en unknown
-
2006
- 2006-11-09 ZA ZA200609340A patent/ZA200609340B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2458094C2 (ru) | 2012-08-10 |
| KR101158347B1 (ko) | 2012-06-22 |
| CN1969019A (zh) | 2007-05-23 |
| DE102004037271A1 (de) | 2006-03-23 |
| US7682441B2 (en) | 2010-03-23 |
| PL1771519T3 (pl) | 2008-05-30 |
| ATE380849T1 (de) | 2007-12-15 |
| JP2008508404A (ja) | 2008-03-21 |
| UA86259C2 (ru) | 2009-04-10 |
| TW200604298A (en) | 2006-02-01 |
| EP1771519B1 (de) | 2007-12-12 |
| ZA200609340B (en) | 2007-12-27 |
| SI1771519T1 (sl) | 2008-06-30 |
| EP1771519A1 (de) | 2007-04-11 |
| AU2005269044B2 (en) | 2010-07-08 |
| CN1969019B (zh) | 2012-09-19 |
| TWI377233B (en) | 2012-11-21 |
| JP4976289B2 (ja) | 2012-07-18 |
| AU2005269044A1 (en) | 2006-02-09 |
| WO2006012950A1 (de) | 2006-02-09 |
| KR20070039104A (ko) | 2007-04-11 |
| US20060032402A1 (en) | 2006-02-16 |
| BRPI0513415A (pt) | 2008-05-06 |
| MX2007001086A (es) | 2007-04-19 |
| BRPI0513415B1 (pt) | 2019-03-26 |
| DE502005002245D1 (de) | 2008-01-24 |
| ES2297732T3 (es) | 2008-05-01 |
| MY142070A (en) | 2010-08-30 |
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