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RU2005127587A - Композиции гидрогеля для отбеливания зубов - Google Patents

Композиции гидрогеля для отбеливания зубов Download PDF

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Publication number
RU2005127587A
RU2005127587A RU2005127587/15A RU2005127587A RU2005127587A RU 2005127587 A RU2005127587 A RU 2005127587A RU 2005127587/15 A RU2005127587/15 A RU 2005127587/15A RU 2005127587 A RU2005127587 A RU 2005127587A RU 2005127587 A RU2005127587 A RU 2005127587A
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Prior art keywords
composition according
composition
peroxide
group
polymer
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RU2005127587/15A
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RU2358783C2 (ru
Inventor
Парминдер СИНГХ (US)
Парминдер СИНГХ
Гари В. КЛИРИ (US)
Гари В. КЛИРИ
Сри МУДУМБА (US)
Сри МУДУМБА
Михаил Майорович Фельдштейн (RU)
Михаил Майорович Фельдштейн
Данир Фанизович БАЙРАМОВ (RU)
Данир Фанизович БАЙРАМОВ
Original Assignee
Кориум Интернэшнл (Us)
Кориум Интернэшнл
Институт Нефтехимического Синтеза Им. А.В. Топчиева (Ru)
Институт нефтехимического синтеза им. А.В. Топчиева
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/38—Percompounds, e.g. peracids
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    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
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    • A61C19/063—Medicament applicators for teeth or gums, e.g. treatment with fluorides
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    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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    • A—HUMAN NECESSITIES
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    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
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    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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    • A61Q11/02—Preparations for deodorising, bleaching or disinfecting dentures
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    • A61K2800/26—Optical properties
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Claims (61)

1. Композиция, содержащая
(a) набухающий в воде водонерастворимый полимер,
(b) смесь гидрофильного полимера и комплементарного олигомера, способного к образованию водородной связи с гидрофильным полимером, и
(c) отбеливающий агент.
2. Композиция по п.1, в которой набухающий в воде водонерастворимый полимер представляет собой сложный эфир целлюлозы или полимер или сополимер на основе акрилата.
3. Композиция по п.2, в которой сложный эфир целлюлозы состоит, по меньшей мере, из одного полимера целлюлозы, содержащего мономерные звенья неэтерифицированной целлюлозы, мономерные звенья ацетата целлюлозы и либо мономерные звенья бутирата целлюлозы, либо мономерные звенья пропионата целлюлозы.
4. Композиция по п.3, в которой полимер целлюлозы представляет собой ацетат бутират целлюлозы.
5. Композиция по п.3, в которой полимер целлюлозы представляет собой ацетат пропионат целлюлозы.
6. Композиция по п.3, в которой композиция сложного эфира целлюлозы содержит смесь ацетат бутирата целлюлозы и ацетат пропионата целлюлозы.
7. Композиция по п.2, в которой полимер или сополимер на основе акрилата выбирается из полимеров и сополимеров акриловой кислоты, метакриловой кислоты, метилакрилата, этилакрилата, метилметакрилата или этилметакрилата.
8. Композиция по п.7, в которой набухающий в воде полимер представляет собой сополимер метакриловой кислоты и метилметакрилата.
9. Композиция по п.8, в которой сополимер имеет отношение свободных карбоксильных групп к сложноэфирным группам в пределах примерно 1:1-1:2.
10. Композиция по п.1, в которой гидрофильный полимер выбирается из группы, состоящей из поли(N-виниллактамов), поли(N-виниламидов), поли(N-алкилакриламидов), полиакриловых кислот, полиметакриловых кислот, поливинилового спирта, поливиниламина и их сополимеров и смесей.
11. Композиция по п.10, в которой гидрофильный полимер выбирается из группы, состоящей из поли(N-виниллактамов), поли(N-виниламидов), поли(N-алкилакриламидов) и их сополимеров и смесей.
12. Композиция по п.11, в которой гидрофильный полимер представляет собой поли(N-виниллактам).
13. Композиция по п.11, в которой гидрофильный полимер представляет собой гомополимер поли(N-виниллактама).
14. Композиция по п.10, в которой поли(N-виниллактам) выбирается из группы, состоящей из поливинилпирролидона, поливинилкапролактама и их смесей.
15. Композиция по п.14, в которой поли(N-виниллактам) представляет собой поливинилпирролидон.
16. Композиция по п.14, в которой поли(N-виниллактам) представляет собой поливинилкапролактам.
17. Композиция по п.10, в которой гидрофильный полимер имеет среднечисленную молекулярную массу в пределах приблизительно 100000-2000000.
18. Композиция по п.10, в которой гидрофильный полимер имеет среднечисленную молекулярную массу в пределах приблизительно 500000-1500000.
19. Композиция по п.1, в которой комплементарный олигомер имеет молекулярную массу в пределах примерно 45-800.
20. Композиция по п.19, в которой комплементарный олигомер имеет молекулярную массу в пределах примерно 45-600.
21. Композиция по п.19, в которой комплементарный олигомер выбирается из группы, состоящей из полиспиртов, мономерных и олигомерных алкиленгликолей, полиалкиленгликолей, полиалкиленгликолей с карбоксильными концевыми группами, полиалкиленгликолей с концевыми аминогруппами, эфирных спиртов, алкандиолов и угольных кислот.
22. Композиция по п.21, в которой комплементарный олигомер выбирается из группы, состоящей из полиалкиленгликолей и полиалкиленгликолей с карбоксильными концевыми группами.
23. Композиция по п.22, в которой комплементарный олигомер выбирается из группы, состоящей из полиэтиленгликоля и полиэтиленгликоля с карбоксильными концевыми группами.
24. Композиция по п.22, в которой комплементарный олигомер представляет собой полиэтиленгликоль.
25. Композиция по п.1, в которой отбеливающий агент выбирается из группы, состоящей из пероксидов, хлоритов металлов, перборатов, перкарбонатов, пероксикислот и их сочетаний.
26. Композиция по п.25, в которой отбеливающий агент представляет собой пероксид, выбранный из группы, состоящей из перекиси водорода, пероксида кальция, пероксида мочевины и их смесей.
27. Композиция по п.25, в которой пероксид представляет собой органический пероксид.
28. Композиция по п.27, в которой органический пероксид выбирается из группы, состоящей из диалкилпероксидов, диацилпероксидов, сложных перэфиров, пердикарбонатов, кетонпероксидов и гидропероксидов.
29. Композиция по п.28, в которой диалкилпероксид представляет собой трет-бутилпероксид или 2,2-бис(трет-бутилперокси)пропан.
30. Композиция по п.28, в которой диацилпероксид представляет собой бензоилпероксид или ацетилпероксид.
31. Композиция по п.28, в которой сложный перэфир представляет собой трет-бутил пербензоат или трет-бутил пер-2-этилгексаноат.
32. Композиция по п.28, в которой пердикарбонат представляет собой дицетилпероксидикарбонат или дициклогексилпероксидикарбонат.
33. Композиция по п.28, в которой кетонпероксид представляет собой циклогексанонпероксид или метилэтилкетонпероксид.
34. Композиция по п.28, в которой гидропероксид представляет собой куменгидропероксид или трет-бутилгидропероксид.
35. Композиция по п.25, в которой отбеливающий агент представляет собой хлорит металла, выбранный из группы, состоящей из хлорита кальция, хлорита бария, хлорита магния, хлорита лития, хлорита натрия, хлорита калия, гипохлорита и двуокиси хлора.
36. Композиция по п.1, дополнительно содержащая флаворант.
37. Композиция по п.36, в которой флаворант выбирается из группы, состоящей из винтергрена, перечной мяты, курчавой мяты, ментола, фруктовых флаворантов, ванили, корицы, специй, ароматизирующих масел и олеосмол и их сочетаний.
38. Композиция по п.1, дополнительно содержащая подсластитель, выбранный из группы, состоящей из сахарозы, фруктозы, аспартама, ксилитола и сахарина.
39. Композиция по п.1, дополнительно содержащая, по меньшей мере, одну добавку, выбранную из группы, состоящей из наполнителей, консервантов, регуляторов pH, умягчителей, загустителей, окрашивающих веществ, пигментов, красителей, отражающих частиц, флаворантов, подсластителей, стабилизаторов, упрочняющих агентов, агентов для уменьшения липкости и усилителей проницаемости.
40. Композиция по п.1, в которой относительные количества набухающего в воде, водонерастворимого полимера, гидрофильного полимера и комплементарного олигомера выбираются таким образом, чтобы сделать композицию полупрозрачной.
41. Композиция по п.1, где композиция является твердой.
42. Композиция по п.41, которая содержит примерно 0,1-60 мас.% отбеливающего агента.
43. Композиция по п.41, которая содержит примерно 1-20 мас.% набухающего в воде водонерастворимого полимера.
44. Композиция по п.41, которая содержит примерно 20-80 мас.% гидрофильного полимера.
45. Композиция по п.41, которая содержит примерно 10-50 мас.% комплементарного олигомера.
46. Композиция по п.41, которая дополнительно содержит поглощающий наполнитель.
47. Композиция по п.41, в которой композиция представляет собой самоклеящийся материал и поглощает воду.
48. Композиция по п.1, где композиция представляет собой жидкость или гель.
49. Композиция по п.48, которая содержит примерно 0,1-60 мас.% отбеливающего агента.
50. Композиция по п.48, которая содержит примерно 0,1-40 мас.% набухающего в воде водонерастворимого полимера.
51. Композиция по п.48, которая содержит примерно 0,1-20 мас.% гидрофильного полимера.
52. Композиция по п.48, которая содержит примерно 0,05-20 мас.% комплементарного олигомера.
53. Способ отбеливания зубов, включающий нанесение композиции по п.1 на зубы, нуждающиеся в отбеливании, и
удаление композиции, когда достигается желаемая степень отбеливания.
54. Способ по п.53, в котором композиция увлажняется перед нанесением на зубы.
55. Способ по п.53, в котором композиция содержит снимаемую прокладку и снимаемая прокладка удаляется перед нанесением композиции на зубы.
56. Способ по п.53, в котором желаемая степень отбеливания достигается через заданный период времени.
57. Способ по п.56, в котором заданный период времени составляет от примерно 10 мин до примерно 24 ч.
58. Способ по п.57, в котором заданный период времени составляет от примерно 10 мин до примерно 8 ч.
59. Способ по п.58, в котором заданный период времени составляет примерно 30 мин - 1 ч.
60. Способ по п.53, в котором композиция может носиться в течение продолжительного периода времени.
61. Способ по п.53, в котором композиция наносится в виде жидкости или геля.
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