RO78765B - Procedeu pentru prepararea unor derivati de n-trifluoracetil n-fosfonometilglicina - Google Patents
Procedeu pentru prepararea unor derivati de n-trifluoracetil n-fosfonometilglicinaInfo
- Publication number
- RO78765B RO78765B RO98095A RO9809579A RO78765B RO 78765 B RO78765 B RO 78765B RO 98095 A RO98095 A RO 98095A RO 9809579 A RO9809579 A RO 9809579A RO 78765 B RO78765 B RO 78765B
- Authority
- RO
- Romania
- Prior art keywords
- carbon atoms
- radical
- trifluoroacetyl
- general formula
- methylaniline
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- -1 alkyl phenoxy radical Chemical compound 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methylaniline Chemical compound CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- MKJBZNABCZRVPC-UHFFFAOYSA-N 2-[phosphonomethyl-(2,2,2-trifluoroacetyl)amino]acetic acid Chemical class OC(=O)CN(CP(O)(O)=O)C(=O)C(F)(F)F MKJBZNABCZRVPC-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N alpha-methyl toluene Natural products CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 abstract 1
- 238000006073 displacement reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000000269 nucleophilic effect Effects 0.000 abstract 1
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 abstract 1
- LWMPFIOTEAXAGV-UHFFFAOYSA-N piperidin-1-amine Chemical compound NN1CCCCC1 LWMPFIOTEAXAGV-UHFFFAOYSA-N 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/6533—Six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/44—Amides thereof
- C07F9/4403—Amides thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4407—Amides of acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea unor derivati de N-trifluoracetil-N-fosfonometilglicina cu formula generala I: în care R reprezinta o grupare alchil cu 2...10 atomi de carbon sau cloretil, R1 reprezinta radical alcoxi cu 1...3 atomi de carbon în radicalul alchil fenoxi, feniltio, alchilamino cu 1 si 3 atomi de carbon în radicalul alchilmorfolino, N-metilanilina, R2 reprezinta un radical alchiltio cu 1...2 atomi de carbon în radicalul alchilfenoxi, feniltio, fenoxi substituit eventula cu halogen si cu radical metil izopropilamino, N-metilanilina, N-piperidinoamina, cu conditia ca R1 si R2 sa nu reprezinte aceeasi grupa, care consta în aceea ca o diclorura esterica a N-trifluoracetil N-fosfonometil-glicinei cu formula generala II: (vezi formula) în care R are semnificatiile ca în formula I se aduce în reactie prin picurarea cu nucleofili cu formula generala III: (vezi formula) în care R1 si R2 au semnificatiile ca în formula I în prezenta unui solvent organic ales dintre tetrahidrofuran, eter etilic, benzen si în prezenta de trietilamina ca acceptor de acid, în conditii anhidre la o temperatura a camerei.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/922,930 US4180394A (en) | 1978-07-10 | 1978-07-10 | Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the herbicidal use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO78765A RO78765A (ro) | 1984-10-30 |
| RO78765B true RO78765B (ro) | 1984-11-30 |
Family
ID=25447814
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO98095A RO78765B (ro) | 1978-07-10 | 1979-07-09 | Procedeu pentru prepararea unor derivati de n-trifluoracetil n-fosfonometilglicina |
| RO79115573A RO89361A (ro) | 1978-07-10 | 1979-07-09 | Compozitie erbicida solida |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO79115573A RO89361A (ro) | 1978-07-10 | 1979-07-09 | Compozitie erbicida solida |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4180394A (ro) |
| EP (1) | EP0007211B1 (ro) |
| JP (1) | JPS5513293A (ro) |
| AR (1) | AR230749A1 (ro) |
| AU (1) | AU520850B2 (ro) |
| BG (1) | BG30625A3 (ro) |
| BR (1) | BR7904352A (ro) |
| CA (1) | CA1121819A (ro) |
| CS (1) | CS209928B2 (ro) |
| DD (1) | DD144712A5 (ro) |
| DE (1) | DE2966181D1 (ro) |
| DK (1) | DK147915C (ro) |
| HU (1) | HU185006B (ro) |
| IL (1) | IL57749A (ro) |
| MX (1) | MX5594E (ro) |
| PH (1) | PH15633A (ro) |
| PL (1) | PL116631B1 (ro) |
| RO (2) | RO78765B (ro) |
| ZA (1) | ZA793413B (ro) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4353731A (en) * | 1978-07-10 | 1982-10-12 | Monsanto Company | Amide and hydrazide derivatives of N-trifluoroacetyl-N-phosphonomethylglycine |
| US4421549A (en) * | 1979-12-26 | 1983-12-20 | Monsanto Company | Amido and hydrazido derivatives of N-trifluoroacetyl-N-phosphinothioylmethylglycine esters |
| HU186846B (en) * | 1981-03-11 | 1985-09-30 | Monsanto Co | Herbicides containing n-formyl-n-phosphonomethyl-glycine and esters thereof as active substances |
| US4444580A (en) * | 1982-11-01 | 1984-04-24 | Monsanto Company | N-Substituted N-(phosphonomethyl)aminoethanal derivatives as herbicides |
| US4569802A (en) * | 1983-06-27 | 1986-02-11 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4545804A (en) * | 1983-11-21 | 1985-10-08 | Monsanto Company | N(Aminophosphinylmethyl) glycine derivatives |
| US5580841A (en) * | 1985-05-29 | 1996-12-03 | Zeneca Limited | Solid, phytoactive compositions and method for their preparation |
| US5468718A (en) * | 1985-10-21 | 1995-11-21 | Ici Americas Inc. | Liquid, phytoactive compositions and method for their preparation |
| US8470741B2 (en) * | 2003-05-07 | 2013-06-25 | Croda Americas Llc | Homogeneous liquid saccharide and oil systems |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH16509A (en) * | 1971-03-10 | 1983-11-08 | Monsanto Co | N-phosphonomethylglycine phytotoxicant composition |
| US3799758A (en) * | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
| RO67869A (ro) * | 1972-12-11 | 1981-06-22 | Mensanto Co,Us | Procedeu pentru prepararea unor derivati ai n-fosfonometil-gliciu n-oxizilor |
| US3835000A (en) * | 1972-12-21 | 1974-09-10 | Monsanto Co | Electrolytic process for producing n-phosphonomethyl glycine |
| US3933946A (en) * | 1974-11-19 | 1976-01-20 | Monsanto Company | N-hydroxy-N-phosphonomethylglycinates |
| US4047926A (en) * | 1975-05-23 | 1977-09-13 | Monsanto Company | Treatment of sugarcane with N-(perfluoroacyl)-N-phosphonomethyl glycine |
| US3970695A (en) * | 1975-05-23 | 1976-07-20 | Monsanto Company | N-(perfluoroacyl)-N-phosphonomethyl glycine compounds, method of preparing same |
| MX3898E (es) * | 1975-12-29 | 1981-09-10 | Monsanto Co | Procedimiento mejorado para la preparacion de triesteres de n-fosfonometilglicina |
| US4053505A (en) * | 1976-01-05 | 1977-10-11 | Monsanto Company | Preparation of n-phosphonomethyl glycine |
-
1978
- 1978-07-10 US US05/922,930 patent/US4180394A/en not_active Expired - Lifetime
-
1979
- 1979-07-06 AR AR277213A patent/AR230749A1/es active
- 1979-07-06 EP EP79301308A patent/EP0007211B1/en not_active Expired
- 1979-07-06 DE DE7979301308T patent/DE2966181D1/de not_active Expired
- 1979-07-09 MX MX798168U patent/MX5594E/es unknown
- 1979-07-09 AU AU48775/79A patent/AU520850B2/en not_active Ceased
- 1979-07-09 CA CA000331415A patent/CA1121819A/en not_active Expired
- 1979-07-09 RO RO98095A patent/RO78765B/ro unknown
- 1979-07-09 ZA ZA793413A patent/ZA793413B/xx unknown
- 1979-07-09 PL PL1979216975A patent/PL116631B1/pl unknown
- 1979-07-09 IL IL57749A patent/IL57749A/xx unknown
- 1979-07-09 DK DK287779A patent/DK147915C/da not_active IP Right Cessation
- 1979-07-09 DD DD79214211A patent/DD144712A5/de unknown
- 1979-07-09 BG BG044254A patent/BG30625A3/xx unknown
- 1979-07-09 RO RO79115573A patent/RO89361A/ro unknown
- 1979-07-09 BR BR7904352A patent/BR7904352A/pt unknown
- 1979-07-09 JP JP8737979A patent/JPS5513293A/ja active Pending
- 1979-07-09 HU HU79MO1053A patent/HU185006B/hu unknown
- 1979-07-09 CS CS794815A patent/CS209928B2/cs unknown
- 1979-07-09 PH PH22752A patent/PH15633A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5513293A (en) | 1980-01-30 |
| DK287779A (da) | 1980-01-11 |
| CA1121819A (en) | 1982-04-13 |
| AU4877579A (en) | 1980-02-07 |
| IL57749A (en) | 1983-12-30 |
| AR230749A1 (es) | 1984-06-29 |
| PL216975A1 (ro) | 1980-05-05 |
| DE2966181D1 (en) | 1983-10-27 |
| BG30625A3 (en) | 1981-07-15 |
| BR7904352A (pt) | 1980-04-08 |
| EP0007211B1 (en) | 1983-09-21 |
| DK147915B (da) | 1985-01-07 |
| HU185006B (en) | 1984-11-28 |
| US4180394A (en) | 1979-12-25 |
| EP0007211A1 (en) | 1980-01-23 |
| IL57749A0 (en) | 1979-11-30 |
| PH15633A (en) | 1983-03-11 |
| MX5594E (es) | 1983-11-03 |
| RO78765A (ro) | 1984-10-30 |
| AU520850B2 (en) | 1982-03-04 |
| CS209928B2 (en) | 1981-12-31 |
| ZA793413B (en) | 1980-07-30 |
| DD144712A5 (de) | 1980-11-05 |
| RO89361A (ro) | 1986-05-30 |
| DK147915C (da) | 1985-06-17 |
| PL116631B1 (en) | 1981-06-30 |
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