PL2493946T3 - Wodne formulacje na bazie krystalicznych lub półkrystalicznych polimerów poliuretanowych - Google Patents

Wodne formulacje na bazie krystalicznych lub półkrystalicznych polimerów poliuretanowych

Info

Publication number: PL2493946T3
Authority: PL; Poland
Prior art keywords: crystalline; aqueous formulations; polyurethane polymers; formulations based; semicrystalline polyurethane
Prior art date: 2009-10-29

Application number

PL10766074T

Other languages

English (en)

Inventor

Dirk Achten

Harald Kraus

Wolfgang Arndt

Jörg Büchner

Original Assignee

Bayer Ip Gmbh

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2009-10-29

Filing date

2010-10-25

Publication date

2015-07-31

2010-10-25 Application filed by Bayer Ip Gmbh filed Critical Bayer Ip Gmbh

2015-07-31 Publication of PL2493946T3 publication Critical patent/PL2493946T3/pl

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/06—Polyurethanes from polyesters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/06—Polyurethanes from polyesters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/80—Compositions for aqueous adhesives
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2250/00—Compositions for preparing crystalline polymers
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2896—Adhesive compositions including nitrogen containing condensation polymer [e.g., polyurethane, polyisocyanate, etc.]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31554—Next to second layer of polyamidoester
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31558—Next to animal skin or membrane
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31562—Next to polyamide [nylon, etc.]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
- Y10T428/3158—Halide monomer type [polyvinyl chloride, etc.]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31591—Next to cellulosic

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Dispersion Chemistry (AREA)
Polyurethanes Or Polyureas (AREA)
Adhesives Or Adhesive Processes (AREA)
Compositions Of Macromolecular Compounds (AREA)

PL10766074T 2009-10-29 2010-10-25 Wodne formulacje na bazie krystalicznych lub półkrystalicznych polimerów poliuretanowych PL2493946T3 (pl)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP20090013612 EP2316866A1 (de)	2009-10-29	2009-10-29	Wässrige Zubereitung auf Basis kristalliner oder semikristalliner Polyurethanpolymere
EP20100766074 EP2493946B1 (en)	2009-10-29	2010-10-25	Aqueous formulations based on crystalline or semicrystalline polyurethane polymers
PCT/EP2010/066014 WO2011051199A2 (en)	2009-10-29	2010-10-25	Aqueous formulations based on crystalline or semicrystalline polyurethane polymers

Publications (1)

Publication Number	Publication Date
PL2493946T3 true PL2493946T3 (pl)	2015-07-31

Family

ID=41666587

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PL10766074T PL2493946T3 (pl)	2009-10-29	2010-10-25	Wodne formulacje na bazie krystalicznych lub półkrystalicznych polimerów poliuretanowych

Country Status (11)

Country	Link
US (1)	US8846198B2 (pl)
EP (2)	EP2316866A1 (pl)
JP (1)	JP5872475B2 (pl)
KR (1)	KR101836533B1 (pl)
CN (1)	CN102574967B (pl)
BR (1)	BR112012010053A2 (pl)
DK (1)	DK2493946T3 (pl)
ES (1)	ES2535948T3 (pl)
PL (1)	PL2493946T3 (pl)
TW (1)	TWI496837B (pl)
WO (1)	WO2011051199A2 (pl)

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DE102011077573A1 (de) *	2011-06-15	2012-12-20	Henkel Ag & Co. Kgaa	2K-Polyurethan-Klebstoff mit aliphatischem Vernetzer
DE102012203249A1 (de) *	2012-03-01	2013-09-05	Tesa Se	Verwendung eines latentreaktiven Klebefilms zur Verklebung von eloxiertem Aluminium mit Kunststoff
CA2915012C (en)	2013-07-30	2021-07-13	H.B. Fuller Company	Polyurethane adhesive film
US10640702B2 (en)	2013-08-01	2020-05-05	Covestro Llc	Coated particles and methods for their manufacture and use
MX384988B (es) *	2013-10-15	2025-03-14	Dow Global Technologies Llc	Método de fabricación de laminados que tienen permeabilidad de oxígeno reducida.
US20150112010A1 (en) *	2013-10-18	2015-04-23	Bayer Materialscience Llc	Sealant compositions with a polyurethane dispersion and a hydroxy-functional compound
US9969916B2 (en) *	2013-12-03	2018-05-15	Rohm And Haas Company	Aqueous polyurethane dispsersions
WO2015081486A1 (en) *	2013-12-03	2015-06-11	Rohm And Haas Company	Aqueous polyurethane dispersion
WO2015188067A1 (en) *	2014-06-06	2015-12-10	3M Innovative Properties Company	Polyurethane laminating adhesive composition
WO2016005733A1 (en) *	2014-07-07	2016-01-14	Ocutec Limited	Polyurethanes for contact lenses
JP7041513B2 (ja) *	2014-07-23	2022-03-24	ダウグローバルテクノロジーズエルエルシー	改善された洗い落とし耐性（ｗａｓｈ－ｏｆｆｒｅｓｉｓｔａｎｃｅ）を有する構造用接着剤及びそれを分注するための方法
CN104194706A (zh) *	2014-08-25	2014-12-10	烟台联成高分子材料有限公司	一种双组份水性聚氨酯胶黏剂及其制备方法
ES2620980T3 (es)	2014-09-30	2017-06-30	Henkel Ag & Co. Kgaa	Composiciones que comprenden un material de fibra y un aglutinante termoplástico
US9957427B2 (en)	2014-12-15	2018-05-01	H.B. Fuller Company	Reactive adhesive with enhanced adhesion to metallic surfaces
BR112019005807A2 (pt) *	2016-10-20	2019-06-25	Basf Coatings Gmbh	método para produzir um revestimento, revestimento, substrato, e, uso de um revestimento.
CN107982071A (zh)	2016-10-26	2018-05-04	日晷公司	具有包囊的增湿剂的护发组合物和将延长的湿气释放递送至头发的方法
EP3498746A1 (de)	2017-12-13	2019-06-19	Covestro Deutschland AG	Verfahren zur herstellung von polyurethanpolymeren
CN111465631B (zh) *	2017-12-21	2022-07-12	科思创德国股份有限公司	具有可调节粘合力的基于特殊聚氨酯脲的胶粘剂及其制备和用途
TWI818046B (zh) *	2018-07-16	2023-10-11	德商科思創德意志股份有限公司	施加含有游離ｎｃｏ基團的可熔性聚合物材料的方法
CN114206963B (zh) *	2019-06-13	2025-02-14	科思创德国股份有限公司	水性聚氨酯分散体
EP3795601A1 (en)	2019-09-17	2021-03-24	Covestro Deutschland AG	Aqueous polyurethane dispersion
CN116670192A (zh) *	2020-10-26	2023-08-29	洛德公司	得自无定形组分的半结晶两部分聚氨酯粘合剂
CN113214585B (zh) *	2021-05-25	2022-10-04	东莞市冠力胶业有限公司	一种水性吸塑胶及其制备方法
CN118546327B (zh) *	2024-06-06	2025-02-21	山东鼎信新材料科技有限公司	一种复合型聚氨酯催化剂及其制备方法

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2009
- 2009-10-29 EP EP20090013612 patent/EP2316866A1/de not_active Withdrawn
2010
- 2010-10-25 US US13/503,886 patent/US8846198B2/en active Active
- 2010-10-25 WO PCT/EP2010/066014 patent/WO2011051199A2/en not_active Ceased
- 2010-10-25 KR KR1020127010685A patent/KR101836533B1/ko not_active Expired - Fee Related
- 2010-10-25 PL PL10766074T patent/PL2493946T3/pl unknown
- 2010-10-25 ES ES10766074.8T patent/ES2535948T3/es active Active
- 2010-10-25 CN CN201080049128.7A patent/CN102574967B/zh active Active
- 2010-10-25 JP JP2012535757A patent/JP5872475B2/ja not_active Expired - Fee Related
- 2010-10-25 EP EP20100766074 patent/EP2493946B1/en active Active
- 2010-10-25 DK DK10766074.8T patent/DK2493946T3/en active
- 2010-10-25 BR BR112012010053A patent/BR112012010053A2/pt not_active IP Right Cessation
- 2010-10-28 TW TW099136829A patent/TWI496837B/zh not_active IP Right Cessation

Also Published As

Publication number	Publication date
WO2011051199A3 (en)	2011-10-27
CN102574967B (zh)	2014-12-24
EP2493946B1 (en)	2015-02-25
TW201124472A (en)	2011-07-16
TWI496837B (zh)	2015-08-21
JP5872475B2 (ja)	2016-03-01
KR101836533B1 (ko)	2018-03-08
HK1171775A1 (en)	2013-04-05
EP2493946A2 (en)	2012-09-05
ES2535948T3 (es)	2015-05-19
CN102574967A (zh)	2012-07-11
EP2316866A1 (de)	2011-05-04
JP2013509468A (ja)	2013-03-14
KR20120099419A (ko)	2012-09-10
US20120225302A1 (en)	2012-09-06
DK2493946T3 (en)	2015-05-26
US8846198B2 (en)	2014-09-30
WO2011051199A2 (en)	2011-05-05
BR112012010053A2 (pt)	2016-05-24

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