PE20081050A1 - Metodo para obtener un adsorbente para decolorar grasas y/o aceites - Google Patents
Metodo para obtener un adsorbente para decolorar grasas y/o aceitesInfo
- Publication number
- PE20081050A1 PE20081050A1 PE2007001519A PE2007001519A PE20081050A1 PE 20081050 A1 PE20081050 A1 PE 20081050A1 PE 2007001519 A PE2007001519 A PE 2007001519A PE 2007001519 A PE2007001519 A PE 2007001519A PE 20081050 A1 PE20081050 A1 PE 20081050A1
- Authority
- PE
- Peru
- Prior art keywords
- pores
- acid
- diameters
- less
- weight
- Prior art date
Links
- 239000003921 oil Substances 0.000 title abstract 2
- 239000003463 adsorbent Substances 0.000 title 1
- 239000003925 fat Substances 0.000 title 1
- 239000011148 porous material Substances 0.000 abstract 9
- 239000000463 material Substances 0.000 abstract 6
- 239000002253 acid Substances 0.000 abstract 5
- 239000004927 clay Substances 0.000 abstract 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 abstract 1
- 235000006008 Brassica napus var napus Nutrition 0.000 abstract 1
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 abstract 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 abstract 1
- 244000188595 Brassica sinapistrum Species 0.000 abstract 1
- 241000207199 Citrus Species 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 244000020551 Helianthus annuus Species 0.000 abstract 1
- 235000003222 Helianthus annuus Nutrition 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 235000020971 citrus fruits Nutrition 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 239000010779 crude oil Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000005418 vegetable material Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
- B01J20/28073—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28088—Pore-size distribution
- B01J20/28092—Bimodal, polymodal, different types of pores or different pore size distributions in different parts of the sorbent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/10—Refining fats or fatty oils by adsorption
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
- C11C1/08—Refining
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/74—Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Microbiology (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Fats And Perfumes (AREA)
- Edible Oils And Fats (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
QUE COMPRENDE: a) PROVEER UN MATERIAL ARCILLA DE ESTRUCTURA AMORFA SEGUN XRD Y CON AREA SUPERFICIAL ESPECIFICA DE 180 A 300 m2/g Y UN VOLUMEN TOTAL DE POROS DE 0,6 A 0,7 ml/l, DONDE AL MENOS 60% DEL VOLUMEN TOTAL DE POROS ES PROVISTO POR POROS CON DIAMETROS DE AL MENOS 140 A, AL MENOS 40% DEL VOLUMEN TOTAL DE POROS ES PROVISTO POR POROS CON DIAMETROS MENORES DE 250 A, AL MENOS 15% DEL VOLUMEN TOTAL DE POROS ES PROVISTO POR POROS CON DIAMETROS DE 140 A 250 A, Y MENOS DEL 20% DEL VOLUMEN TOTAL DE POROS ESTA FORMADO POR POROS CON DIAMETROS DE MAS DE 800 A; b) ACTIVAR EL MATERIAL ARCILLA POR CONTACTO CON DE 2% A 5% EN PESO DE UN ACIDO Y LIXIVIADO CON DE 15% A 40% EN PESO DE UN ACIDO, DONDE EL ACIDO (FOSFORICO, SULFURICO O CITRICO) ES CALCULADO COMO ACIDO LIBRE DE AGUA Y BASADO EN EL PESO DEL MATERIAL ARCILLA SECO; Y, c) SEPARAR EL MATERIAL ARCILLA DEL ACIDO DESPUES DE LA EXTRACCION, LAVADO, SECADO Y OPCIONALMENTE TRITURADO. EL MATERIAL ARCILLA CONTIENE MENOS DE 10% DE ALUMINIO, CALCULADO COMO Al2O3. EL ACEITE ES ACEITE CRUDO DERIVADO DE MATERIAL ANIMAL O VEGETAL (CANOLA, SEMILLA DE SOJA, SEMILLA DE COLZA, PALMA O GIRASOL), CONTIENE FOSFORO EN UNA CANTIDAD MENOR A 100 ppm, Y ES TRANSESTERIFICADO CON METANOL ANTES DEL TRATAMIENTO CON EL MATERIAL ARCILLA
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06023142A EP1920829A1 (en) | 2006-11-07 | 2006-11-07 | Amorphous adsorbent, method of obtaining the same and its use in the bleaching of fats and/or oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PE20081050A1 true PE20081050A1 (es) | 2008-09-04 |
Family
ID=37949651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PE2007001519A PE20081050A1 (es) | 2006-11-07 | 2007-11-05 | Metodo para obtener un adsorbente para decolorar grasas y/o aceites |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8394975B2 (es) |
| EP (2) | EP1920829A1 (es) |
| JP (1) | JP5679659B2 (es) |
| CN (1) | CN101547737B (es) |
| AR (1) | AR063586A1 (es) |
| BR (1) | BRPI0716007B1 (es) |
| CA (1) | CA2668729C (es) |
| CO (1) | CO6210747A2 (es) |
| EC (1) | ECSP099391A (es) |
| ES (1) | ES2444891T3 (es) |
| MX (1) | MX2009004865A (es) |
| PE (1) | PE20081050A1 (es) |
| WO (1) | WO2008055675A1 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4393579B1 (ja) * | 2008-09-18 | 2010-01-06 | 水澤化学工業株式会社 | 新規な活性白土及び動植物の油脂類もしくは鉱物油の脱色剤 |
| AU2013202443B2 (en) * | 2009-12-04 | 2014-01-23 | Archer Daniels Midland Company | Glycidyl ester reduction in oil |
| EP2377612A1 (en) | 2010-04-19 | 2011-10-19 | Süd-Chemie Ag | Adsorbent for adsorption of basic compounds |
| EP2447342A1 (en) | 2010-10-26 | 2012-05-02 | Süd-Chemie AG | Method for Biodiesel and Biodiesel Precursor Production |
| EP2491795A1 (en) | 2011-02-22 | 2012-08-29 | Süd-Chemie AG | Feed additive |
| RU2507500C1 (ru) * | 2012-09-03 | 2014-02-20 | Шлюмберже Текнолоджи Б.В. | Способ измерения весовой концентрации глинистого материала в образце пористой среды |
| CN102806063B (zh) * | 2012-09-04 | 2014-09-17 | 中国科学院兰州化学物理研究所盱眙凹土应用技术研发中心 | 棕榈油脱胶脱色用凹凸棒黏土吸附剂的制备方法 |
| PT3110543T (pt) | 2014-02-28 | 2018-03-23 | Clariant Int Ltd | Terra de branqueamento ativada por ácido modificado a seco, processo para a sua produção e uso |
| BR112018005003B1 (pt) * | 2015-09-15 | 2022-11-01 | Nutriquest, Llc | Uso de uma argila antimicrobiana, bem como métodos para controlar micróbios patogênicos em um ambiente de um animal e bactérias durante a fermentação |
| EP3381548A1 (en) * | 2017-03-31 | 2018-10-03 | Clariant International Ltd | Adsorbent and packaging material |
| CN106975443B (zh) * | 2017-05-02 | 2019-05-21 | 宝鸡文理学院 | 一种磁改性膨润土吸附剂的制备方法及应用 |
| EP3736041A4 (en) * | 2018-01-04 | 2021-02-24 | Asahi Kasei Kabushiki Kaisha | POROUS FORMING |
| CN112930322A (zh) * | 2018-11-06 | 2021-06-08 | 有限会社索尔地 | 烧结造粒黏土及其制造方法 |
| WO2020243704A1 (en) | 2019-05-31 | 2020-12-03 | Nutriquest, Llc | Therapeutic clay compositions and methods of using |
| EP3791954A1 (en) * | 2019-09-11 | 2021-03-17 | Clariant Produkte (Deutschland) GmbH | Method for purification of liquid compositions containing at least one sphingolipid |
| CN113318701B (zh) * | 2021-05-20 | 2023-05-23 | 河源市食品检验所 | 去除土榨花生油中黄曲霉毒素b1的吸附剂及其制备方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5008226A (en) * | 1989-05-16 | 1991-04-16 | Engelhard Corporation | Process for making acid activated bleaching earth using high susceptibility source clay and novel bleaching earth product |
| US5053169A (en) * | 1989-08-08 | 1991-10-01 | W. R. Grace & Co.-Conn. | Method for refining wax esters using amorphous silica |
| GB9017344D0 (en) * | 1990-08-08 | 1990-09-19 | Laporte Industries Ltd | Absorbents and a method for their production |
| DE19505579A1 (de) * | 1995-02-18 | 1996-08-22 | Sued Chemie Ag | Adsorbens zur Behandlung von Ölen und/oder Fetten |
| US5869415A (en) | 1995-06-12 | 1999-02-09 | Sud-Chemie Ag | Process for activating layered silicates |
| BR9810572A (pt) | 1997-07-07 | 2000-09-19 | Oil Dri Corp Of America | Argila de branqueamento e método de fabricação. |
| US5883035A (en) | 1997-11-05 | 1999-03-16 | Engelhard Corporation | Mesoporous silicoaluminate products and production thereof by controlled acid extraction of aluminum from calcium bentonite clay |
| US5997732A (en) | 1997-12-22 | 1999-12-07 | Chevron U.S.A. Inc. | Clay treatment process for white mineral oil |
| MXPA02001636A (es) | 1999-08-18 | 2003-07-14 | Biox Corp | Proceso en una sola fase para la produccion de metil esteres de acidos grasos a partir de mezclas de trigliceridos y acidos grasos. |
| US7250214B2 (en) * | 2001-08-09 | 2007-07-31 | Waters Investments Limited | Porous inorganic/organic hybrid monolith materials for chromatographic separations and process for their preparation |
| DE10324561A1 (de) * | 2003-05-30 | 2004-12-16 | Süd-Chemie AG | Semi-synthetische Bleicherde |
| EP1670882B1 (en) | 2003-10-09 | 2009-12-02 | The Dallas Group of America, Inc. | Purification of biodiesel with adsorbent materials |
| DE10356894A1 (de) * | 2003-12-05 | 2005-07-07 | Süd-Chemie AG | Oberflächenreiche Tone zur Herstellung von Bleicherden sowie Aktivierungsverfahren dieser Tone |
| JP4426272B2 (ja) * | 2003-12-11 | 2010-03-03 | 水澤化学工業株式会社 | バイオ燃料の製造方法 |
| US20050188607A1 (en) * | 2004-01-31 | 2005-09-01 | Lastella Joseph P. | System for removal of methanol from crude biodiesel fuel |
| DE102004060587A1 (de) * | 2004-12-16 | 2006-07-06 | Süd-Chemie AG | Bentonite zur Störstoffbindung in der Papierherstellung |
| SE529160C2 (sv) * | 2004-12-27 | 2007-05-15 | Svenska Aerogel Ab | En metod för framställning av agglomerat av utfällt silikamaterial, ett mikroporöst material innefattande sådana agglomerat och användning därav |
| DE102005012638A1 (de) * | 2005-03-18 | 2006-09-21 | Süd-Chemie AG | Granulate aus natürlichen Schichtmineralien und Verfahren zu deren Herstellung |
| US7279147B2 (en) * | 2005-05-25 | 2007-10-09 | Selma Turkay | Method of producing an adsorbent from rice hull ash |
| ATE521408T1 (de) * | 2005-06-08 | 2011-09-15 | Sued Chemie Ag | Aktivierungsverfahren von oberflächenreichen tonen zur herstellung von bleicherden |
| CA2617071A1 (en) | 2005-07-29 | 2007-02-01 | Pos Pilot Plant Corp. | Single-stage esterification of oils and fats |
| US20070175092A1 (en) * | 2005-11-28 | 2007-08-02 | Ames Randall S | Continuous flow biodiesel processor |
| US20070151146A1 (en) | 2005-12-29 | 2007-07-05 | Inmok Lee | Processes of Producing Biodiesel and Biodiesel Produced Therefrom |
| US9109170B2 (en) * | 2006-02-02 | 2015-08-18 | Reg Biofuels, Llc | Biodiesel cold filtration process |
-
2006
- 2006-11-07 EP EP06023142A patent/EP1920829A1/en not_active Withdrawn
-
2007
- 2007-11-05 PE PE2007001519A patent/PE20081050A1/es active IP Right Grant
- 2007-11-06 AR ARP070104942A patent/AR063586A1/es active IP Right Grant
- 2007-11-07 MX MX2009004865A patent/MX2009004865A/es active IP Right Grant
- 2007-11-07 ES ES07819665.6T patent/ES2444891T3/es active Active
- 2007-11-07 EP EP07819665.6A patent/EP2099561B1/en not_active Revoked
- 2007-11-07 JP JP2009535626A patent/JP5679659B2/ja not_active Expired - Fee Related
- 2007-11-07 US US12/513,918 patent/US8394975B2/en active Active
- 2007-11-07 WO PCT/EP2007/009655 patent/WO2008055675A1/en not_active Ceased
- 2007-11-07 BR BRPI0716007-0A patent/BRPI0716007B1/pt active IP Right Grant
- 2007-11-07 CN CN2007800413712A patent/CN101547737B/zh not_active Expired - Fee Related
- 2007-11-07 CA CA2668729A patent/CA2668729C/en active Active
-
2009
- 2009-06-05 EC EC2009009391A patent/ECSP099391A/es unknown
- 2009-06-05 CO CO09058691A patent/CO6210747A2/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AR063586A1 (es) | 2009-02-04 |
| WO2008055675A1 (en) | 2008-05-15 |
| JP5679659B2 (ja) | 2015-03-04 |
| CO6210747A2 (es) | 2010-10-20 |
| MX2009004865A (es) | 2009-12-14 |
| JP2010508147A (ja) | 2010-03-18 |
| BRPI0716007B1 (pt) | 2017-10-24 |
| ECSP099391A (es) | 2009-09-29 |
| CA2668729A1 (en) | 2008-05-15 |
| EP1920829A1 (en) | 2008-05-14 |
| CA2668729C (en) | 2014-09-23 |
| EP2099561A1 (en) | 2009-09-16 |
| EP2099561B1 (en) | 2013-11-06 |
| CN101547737A (zh) | 2009-09-30 |
| US8394975B2 (en) | 2013-03-12 |
| BRPI0716007A2 (pt) | 2016-04-19 |
| ES2444891T3 (es) | 2014-02-27 |
| CN101547737B (zh) | 2013-07-17 |
| US20100094035A1 (en) | 2010-04-15 |
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