PE20050558A1 - Recuperacion de metales preciosos utilizando un lixiviante de tiocianato - Google Patents
Recuperacion de metales preciosos utilizando un lixiviante de tiocianatoInfo
- Publication number
- PE20050558A1 PE20050558A1 PE2004000347A PE2004000347A PE20050558A1 PE 20050558 A1 PE20050558 A1 PE 20050558A1 PE 2004000347 A PE2004000347 A PE 2004000347A PE 2004000347 A PE2004000347 A PE 2004000347A PE 20050558 A1 PE20050558 A1 PE 20050558A1
- Authority
- PE
- Peru
- Prior art keywords
- dissolved
- thiocyanate
- precious metals
- solution
- ferric iron
- Prior art date
Links
- 239000010970 precious metal Substances 0.000 title abstract 6
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 title abstract 5
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 title abstract 5
- 238000011084 recovery Methods 0.000 title abstract 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 abstract 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 5
- 238000002386 leaching Methods 0.000 abstract 5
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 4
- 239000011707 mineral Substances 0.000 abstract 4
- 238000000605 extraction Methods 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000011236 particulate material Substances 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/08—Obtaining noble metals by cyaniding
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0073—Leaching or slurrying with acids or salts thereof containing nitrogen
- C22B15/0076—Cyanide groups
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
- C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
QUE COMPRENDE: a) LIXIVIAR UN MATERIAL MINERAL QUE CONTIENE METALES PRECIOSOS, CON UNA SOLUCION DE TIOCIANATO QUE COMPRENDE TIOCIANATO DISUELTO Y HIERRO FERRICO DISUELTO, PARA DISOLVER LOS METALES PRECIOSOS EN COMPLEJOS DE METALES PRECIOSOS-TIOCIANATO Y PARA REDUCIR EL HIERRO FERRICO DISUELTO EN HIERRO FERROSO DISUELTO; b) RECUPERAR AL MENOS UNA PORCION DE METALES PRECIOSOS DE LA SOLUCION DE LIXIVIACION, MEDIANTE CONTACTO CON UNA FASE DE EXTRACCION ORGANICA AL CUAL SE TRANSFIEREN LOS METALES PRECIOSOS O CON UNA RESINA DE INTERCAMBIO IONICO O CON CIANURO DISUELTO, COMPRENDIENDO EL EFLUENTE ESTERIL DE DICHA SOLUCION UNA CONCENTRACION DE HIERRO FERRICO DISUELTO MENOR A LA DE LA ALIMENTACION; Y, c) INCREMENTAR LA CONCENTRACION DE HIERRO FERRICO DISUELTO EN LA SOLUCION DE LIXIVIACION, CON RELACION A LA CONCENTRACION DE HIERRO FERRICO DISUELTO EN EL EFLUENTE ESTERIL, OXIDANDO EL HIERRO FERROSO A SU FORMA FERRICA CON PERSULFATO. LA SOLUCION DE LIXIVIACION SE MANTIENE EN UN pH ENTRE 1 Y 3 DURANTE EL PROCESO DE RECUPERACION, LA RELACION MOLAR DE HIERRO FERRICO DISUELTO A TIOCIANATO DISUELTO ES DE AL MENOS 2, Y LA CONCENTRACION DE TIOCIANATO DISUELTO EN LA SOLUCION NO ES MAYOR A 0,03 mol/L. LA FASE DE EXTRACCION ORGANICA INCLUYE UN AGENTE DE EXTRACCION QUE CONTIENE FOSFORO. ANTES DE LIXIVIAR SE PREPARA EL MATERIAL MINERAL FORMANDO UNA PILA QUE COMPRENDE MATERIAL PARTICULADO CON MINERALES SULFUROSOS, Y BIO-OXIDANDO DICHO MATERIAL PARA DESCOMPONER LOS MINERALES SULFUROSOS
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46079503P | 2003-04-04 | 2003-04-04 | |
| US47004503P | 2003-05-12 | 2003-05-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PE20050558A1 true PE20050558A1 (es) | 2005-07-13 |
Family
ID=33303028
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PE2004000347A PE20050558A1 (es) | 2003-04-04 | 2004-04-01 | Recuperacion de metales preciosos utilizando un lixiviante de tiocianato |
Country Status (11)
| Country | Link |
|---|---|
| US (4) | US7285256B2 (es) |
| EP (1) | EP1629129A4 (es) |
| AR (2) | AR043821A1 (es) |
| AU (1) | AU2004230680B2 (es) |
| BR (1) | BRPI0409082A (es) |
| CA (2) | CA2693271C (es) |
| CL (1) | CL2004000703A1 (es) |
| EA (1) | EA009842B1 (es) |
| MX (1) | MXPA05010715A (es) |
| PE (1) | PE20050558A1 (es) |
| WO (1) | WO2004092448A2 (es) |
Families Citing this family (38)
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|---|---|---|---|---|
| US7285256B2 (en) * | 2003-04-04 | 2007-10-23 | Newmont Usa Limited | Precious metal recovery using thiocyanate lixiviant |
| TW201705980A (zh) | 2004-04-09 | 2017-02-16 | 艾伯維生物技術有限責任公司 | 用於治療TNFα相關失調症之多重可變劑量療法 |
| US7604783B2 (en) * | 2004-12-22 | 2009-10-20 | Placer Dome Technical Services Limited | Reduction of lime consumption when treating refractor gold ores or concentrates |
| PE20071046A1 (es) * | 2005-03-21 | 2007-12-21 | Bioheap Ltd | Lixiviacion por pilas de minerales de sulfuros |
| BRPI0610058A2 (pt) | 2005-05-16 | 2010-05-25 | Abbott Biotech Ltd | uso de inibidor de tnf para tratamento da poliartrite erosiva |
| US8061888B2 (en) | 2006-03-17 | 2011-11-22 | Barrick Gold Corporation | Autoclave with underflow dividers |
| RU2310692C1 (ru) * | 2006-04-05 | 2007-11-20 | Государственное образовательное учреждение высшего профессионального образования "Оренбургский государственный университет" | Способ регенерации анионообменных смол, насыщенных золотом |
| US9605064B2 (en) | 2006-04-10 | 2017-03-28 | Abbvie Biotechnology Ltd | Methods and compositions for treatment of skin disorders |
| US9624295B2 (en) | 2006-04-10 | 2017-04-18 | Abbvie Biotechnology Ltd. | Uses and compositions for treatment of psoriatic arthritis |
| US8252254B2 (en) | 2006-06-15 | 2012-08-28 | Barrick Gold Corporation | Process for reduced alkali consumption in the recovery of silver |
| GEP20166440B (en) * | 2009-12-04 | 2016-03-10 | Barrick Gold Corp | Separation of copper minerals from pyrite using air-metabisulfite treatment |
| EP3290534B1 (en) | 2010-11-22 | 2023-10-25 | Barrick Gold Corporation | Alkaline and acid pressure oxidation of precious metal-containing materials |
| US8985902B2 (en) * | 2011-08-16 | 2015-03-24 | Golder Associates, Inc. | System and method for treating an excavation activity |
| US20140230604A1 (en) * | 2011-10-04 | 2014-08-21 | Fine Gold Recovery Pty Ltd. | Recovery of metals from ores |
| CN103987664B (zh) | 2011-12-06 | 2017-03-08 | 德尔塔阀门公司 | 龙头中的臭氧分配 |
| WO2014124422A1 (en) * | 2013-02-11 | 2014-08-14 | Neylon Richard | Methods for treating carbon materials including carbonaceous ores |
| CA2869575C (en) | 2013-11-01 | 2021-07-20 | Corem | Cyanide-leaching process |
| WO2016165027A1 (en) | 2015-04-17 | 2016-10-20 | University Of British Columbia | Process for leaching metal sulfides with reagents having thiocarbonyl functional groups |
| CN115093008B (zh) | 2015-12-21 | 2024-05-14 | 德尔塔阀门公司 | 包括消毒装置的流体输送系统 |
| WO2017185158A1 (en) * | 2016-04-28 | 2017-11-02 | Eldorado Gold Corporation | Method for reducing arsenic content in arsenic-bearing gold material |
| GB2551980A (en) * | 2016-06-30 | 2018-01-10 | Commw Scient Ind Res Org | Method and system for low level metal analysis of mineral samples |
| PE20240830A1 (es) | 2016-10-19 | 2024-04-22 | Jetti Resources Llc | Procesos para lixiviar sulfuros metalicos con reactivos que tienen grupos funcionales tiocarbonilo |
| SG11201903153PA (en) | 2016-10-31 | 2019-05-30 | Mint Innovation Ltd | Metal recovery process |
| US11634788B2 (en) | 2016-11-03 | 2023-04-25 | Mint Innovation Limited | Process for recovering metal |
| KR102649787B1 (ko) | 2017-10-17 | 2024-03-21 | 민트 이노베이션 리미티드 | 전자 폐기물로부터 금속을 회수하는 방법 |
| JP7168181B2 (ja) * | 2017-12-27 | 2022-11-09 | ハイモ株式会社 | 金の回収方法及び金回収設備 |
| CN108359793A (zh) * | 2018-03-16 | 2018-08-03 | 云锡文山锌铟冶炼有限公司 | 还原浸出装置 |
| CN109499625B (zh) * | 2018-11-06 | 2021-09-28 | 长春黄金研究院有限公司 | 一种载金树脂高效洗脱方法 |
| CN109781717A (zh) * | 2018-12-31 | 2019-05-21 | 太原瑞麟贵金属回收有限公司 | 溶液中贵金属的检铁方法 |
| RU2749310C2 (ru) * | 2019-09-05 | 2021-06-08 | Акционерное общество "Иркутский научно-исследовательский институт благородных и редких металлов и алмазов" АО "Иргиредмет" | Способ переработки сульфидного золотомедного флотоконцентрата |
| RU2758915C2 (ru) * | 2020-03-03 | 2021-11-03 | Федеральное государственное автономное образовательное учреждение высшего образования "Уральский федеральный университет имени первого Президента России Б.Н. Ельцина" | Способ извлечения золота из золотосодержащего сырья |
| US20240002971A1 (en) * | 2020-08-29 | 2024-01-04 | Arizona Board of Arizona on Behalf of the University of Arizona | Direct leaching from sulfidic refractory ores or concentrates |
| US12247266B2 (en) | 2020-09-18 | 2025-03-11 | Jetti Resources, Llc | Extraction of base metals using carbonaceous matter and a thiocarbonyl functional group reagent |
| MX2023003207A (es) | 2020-09-18 | 2023-04-27 | Jetti Resources Llc | Extracto de metales base con un agente humectante y un reactivo de grupo funcional de tiocarbonilo. |
| CN112375911B (zh) * | 2020-11-02 | 2022-07-05 | 昆明理工大学 | 一种直接用活性炭回收(Au(S2O3)23-)的方法 |
| CN116287754B (zh) * | 2023-02-07 | 2025-02-14 | 中南大学 | 一种金银提取剂及其制备方法 |
| CN116173890B (zh) * | 2023-03-21 | 2024-05-17 | 湖北三峡实验室 | 一种磷石膏吸附剂的制备方法 |
| CN118910418A (zh) * | 2024-08-16 | 2024-11-08 | 郴州崇畅生物科技有限公司 | 从固体废物和低品位矿石中绿色提取回收铂族金属的方法 |
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| GB1050303A (es) * | 1964-12-14 | 1900-01-01 | ||
| US3545964A (en) * | 1968-04-18 | 1970-12-08 | Atomic Energy Commission | Gold recovery process |
| US3793429A (en) * | 1972-02-18 | 1974-02-19 | Kennecott Copper Corp | Nitric acid process for recovering metal values from sulfide ore materials containing iron sulfides |
| AU548252B2 (en) * | 1982-05-04 | 1985-12-05 | Inco Ltd. | Leaching of uranium from its ore |
| ZW21384A1 (en) * | 1984-01-12 | 1985-05-08 | Mineral Tech Council | The regeneration of thiocyanate resins |
| GB2180829B (en) | 1985-09-20 | 1989-08-16 | Aurotech N L | Precious metal extraction |
| CA1306613C (en) * | 1987-05-15 | 1992-08-25 | Guy Deschenes | Recovery of gold from aqueous solutions |
| GB8810736D0 (en) | 1988-05-06 | 1988-06-08 | Interox Chemicals Ltd | Heap leaching |
| US5093091A (en) * | 1988-12-19 | 1992-03-03 | American Cyanamid Company | Method of removing iron from concentrated alum solutions |
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| GB9002311D0 (en) | 1990-02-02 | 1990-04-04 | Rio Tinto Minerals Dev | Separation process |
| NZ237011A (en) * | 1990-02-23 | 1992-06-25 | Cra Services | Extraction and recovery of gold by treatment with an acidic lixiviant solution |
| US5158603A (en) * | 1990-03-06 | 1992-10-27 | Henkel Research Corporation | Process of extracting anions with quaternary amines |
| CA2013537A1 (en) * | 1990-03-30 | 1991-09-30 | Farouk T. Awadalla | Recovery of gold from solution by reduction-precipitation with stabilized alkali metal borohydride |
| US5071477A (en) * | 1990-05-03 | 1991-12-10 | American Barrick Resources Corporation of Toronto | Process for recovery of gold from refractory ores |
| US5127942A (en) * | 1990-09-21 | 1992-07-07 | Newmont Mining Corporation | Microbial consortium treatment of refractory precious metal ores |
| US5244493A (en) * | 1990-09-21 | 1993-09-14 | Newmont Gold Co. | Biometallurgical treatment of precious metal ores having refractory carbon content |
| US5147617A (en) * | 1991-05-21 | 1992-09-15 | Freeport-Mcmoran Inc. | Process for recovery of gold from gold ores using a complexing pretreatment and sulfurous acid leaching |
| US5246486A (en) * | 1991-07-10 | 1993-09-21 | Newmont Gold Co. | Biooxidation process for recovery of gold from heaps of low-grade sulfidic and carbonaceous sulfidic ore materials |
| US5332559A (en) * | 1991-07-10 | 1994-07-26 | Newmont Gold Co. | Biooxidation process for recovery of metal values from sulphur-containing ore materials |
| RU2070588C1 (ru) | 1993-12-27 | 1996-12-20 | Акционерное общество Уральский научно-исследовательский и проектный институт медной промышленности "Унипромедь" | Способ извлечения благородных металлов из руд и концентратов |
| US5458866A (en) * | 1994-02-14 | 1995-10-17 | Santa Fe Pacific Gold Corporation | Process for preferentially oxidizing sulfides in gold-bearing refractory ores |
| RU2081193C1 (ru) | 1994-05-31 | 1997-06-10 | Поташников Юрий Моисеевич | Способ перколяционного извлечения серебра и золота из руд и отвалов |
| US5536480A (en) * | 1994-11-29 | 1996-07-16 | Santa Fe Pacific Gold Corporation | Method for treating mineral material having organic carbon to facilitate recovery of gold and silver |
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| US5698170A (en) * | 1995-11-22 | 1997-12-16 | Placer Dome, Inc. | Hydrometallurgical process for copper-containing materials |
| US5914441A (en) * | 1996-06-12 | 1999-06-22 | Yellowstone Environmental Science, Inc. | Biocatalyzed anaerobic oxidation of metal sulfides for recovery of metal values |
| US5851499A (en) * | 1996-09-11 | 1998-12-22 | Newmont Gold Company | Method for pressure oxidizing gold-bearing refractory sulfide ores having organic carbon |
| CA2293691C (en) * | 1997-06-09 | 2006-11-07 | Hw Process Technologies, Inc. | Method for separating and isolating precious metals from non precious metals dissolved in solutions |
| US6379919B1 (en) * | 1999-05-28 | 2002-04-30 | Oxidor Corporation Inc | Method for isolating thiocyanate resistant bacteria |
| US6344068B1 (en) * | 2000-04-04 | 2002-02-05 | Barrick Gold Corporation | Process for recovering gold from thiosulfate leach solutions and slurries with ion exchange resin |
| US6660059B2 (en) * | 2000-05-19 | 2003-12-09 | Placer Dome Technical Services Limited | Method for thiosulfate leaching of precious metal-containing materials |
| US6395063B1 (en) * | 2000-09-29 | 2002-05-28 | Newmont Mining Corporation | Method and system for pressure oxidation of sulfide gold ores involving enhanced oxygen-sulfide contact |
| US6441642B1 (en) * | 2001-02-20 | 2002-08-27 | Cypress Semiconductor Corp. | Multiplexers for efficient PLD logic blocks |
| US6451088B1 (en) | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Method for improving metals recovery using high temperature leaching |
| US6641642B2 (en) | 2001-12-21 | 2003-11-04 | Newmont Usa Limited | High temperature pressure oxidation of ores and ore concentrates containing silver using controlled precipitation of sulfate species |
| US7722840B2 (en) | 2002-11-15 | 2010-05-25 | Placer Dome Technical Services Limited | Method for thiosulfate leaching of precious metal-containing materials |
| US7285256B2 (en) * | 2003-04-04 | 2007-10-23 | Newmont Usa Limited | Precious metal recovery using thiocyanate lixiviant |
-
2003
- 2003-08-28 US US10/651,184 patent/US7285256B2/en not_active Expired - Lifetime
-
2004
- 2004-03-25 EP EP04758966A patent/EP1629129A4/en not_active Withdrawn
- 2004-03-25 WO PCT/US2004/009213 patent/WO2004092448A2/en not_active Ceased
- 2004-03-25 CA CA2693271A patent/CA2693271C/en not_active Expired - Lifetime
- 2004-03-25 MX MXPA05010715A patent/MXPA05010715A/es active IP Right Grant
- 2004-03-25 AU AU2004230680A patent/AU2004230680B2/en not_active Ceased
- 2004-03-25 CA CA2520039A patent/CA2520039C/en not_active Expired - Lifetime
- 2004-03-25 EA EA200501574A patent/EA009842B1/ru not_active IP Right Cessation
- 2004-03-25 BR BRPI0409082-9A patent/BRPI0409082A/pt not_active Application Discontinuation
- 2004-04-01 CL CL200400703A patent/CL2004000703A1/es unknown
- 2004-04-01 AR ARP040101101A patent/AR043821A1/es active IP Right Grant
- 2004-04-01 PE PE2004000347A patent/PE20050558A1/es active IP Right Grant
-
2007
- 2007-10-03 US US11/866,890 patent/US7537640B2/en not_active Expired - Lifetime
- 2007-10-05 US US11/868,378 patent/US7559973B2/en not_active Expired - Lifetime
-
2009
- 2009-06-01 US US12/476,084 patent/US7947108B2/en not_active Expired - Fee Related
-
2010
- 2010-11-30 AR ARP100104421A patent/AR079172A2/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| US7285256B2 (en) | 2007-10-23 |
| EP1629129A2 (en) | 2006-03-01 |
| AR043821A1 (es) | 2005-08-17 |
| CA2520039C (en) | 2010-05-25 |
| US7947108B2 (en) | 2011-05-24 |
| BRPI0409082A (pt) | 2006-04-18 |
| WO2004092448A3 (en) | 2005-12-29 |
| EA200501574A1 (ru) | 2006-06-30 |
| CA2693271C (en) | 2012-05-29 |
| US20040197249A1 (en) | 2004-10-07 |
| EA009842B1 (ru) | 2008-04-28 |
| US20080066577A1 (en) | 2008-03-20 |
| AR079172A2 (es) | 2011-12-28 |
| MXPA05010715A (es) | 2006-04-18 |
| CA2520039A1 (en) | 2004-10-28 |
| AU2004230680B2 (en) | 2010-07-01 |
| US7537640B2 (en) | 2009-05-26 |
| US20080066578A1 (en) | 2008-03-20 |
| EP1629129A4 (en) | 2008-05-28 |
| WO2004092448A2 (en) | 2004-10-28 |
| CL2004000703A1 (es) | 2005-03-18 |
| US20090288521A1 (en) | 2009-11-26 |
| AU2004230680A1 (en) | 2004-10-28 |
| US7559973B2 (en) | 2009-07-14 |
| CA2693271A1 (en) | 2004-10-28 |
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