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KR900701735A - 2-아미노카르복실산 및 그의 유도체, 그의 제조방법 및 의약으로서의 그의 용도 - Google Patents

2-아미노카르복실산 및 그의 유도체, 그의 제조방법 및 의약으로서의 그의 용도

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KR900701735A
KR900701735A KR1019900701383A KR900701383A KR900701735A KR 900701735 A KR900701735 A KR 900701735A KR 1019900701383 A KR1019900701383 A KR 1019900701383A KR 900701383 A KR900701383 A KR 900701383A KR 900701735 A KR900701735 A KR 900701735A
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hydrogen
octadecyloxy
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트로스트만 우베
하르텐쉬타인 요하네스
루돌프 클라우스
쉐히텔레 크리스토프
오스발트 하르트무트
바인하이머 귄터
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테오도르 슈베르트, 이보 만스만
괴덱계 악티엔게젤샤프트
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Abstract

내용 없음

Description

2-아미노카르복실산 및 그의 유도체, 그의 제조방법 및 의약으로서의 그의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 다음 일반식 (Ⅰ)의 2-아미노카르복실산 및 유도체와 약리적으로 허용되는 그의 염 (단, DB-A 1 518362호에 개시될 화합물은 제외)
    상기식 중, R1은 직쇄 또는 분지쇄의, 탄소원자 20개이하의 포화 또는 불포화 알킬기이고, R2및 R3은 같거나 다르고, 수소 또는 단소원자 4개 이하의 직쇄 또는 분지쇄 알킬기이며, R4는 수소 메틸 히드록시메틸 벤질, 히드록시벤질, 탄소원자 4개 이하의 카르복실기, 히드록시알킬기 또는 알콕시카르보닐기이고, R5는 수소 또는 탄소원자 4개 이하의 전쇄 또는 분지쇄 알킬기임.
  2. 제1항에 있어서, R1이 옥틸-또는 옥타데실기, 서로 같거나 다른, R2및 R3은 수소 또는 메틸기, R4가 수소, 메틸, 히드록시메틸, 히드록시에틸, 벤질, 히드록시벤질, 시카르보닐기이고, R5는 수소 또는 에틸기인 것이 특징인 일반식(Ⅰ)의 화합물.
  3. 제1항에 있어서, 즉 2-〔N-메틸-N-(3-옥타데실옥시-2-히드록시프로필)〕-아미노-3-히드록시프로피온산 염산염; 2-〔N-메틸-N-(3-틸옥시-2-히드록시프로필)〕-아미노-3-히드록시프로피온산; 2-〔N-메틸-N-(3-옥타데실옥시-2-히드록시프로필)〕-아미노-3-히드록시프로피온산 에틸 에스테르;(±)-2-N-(3-옥타데실옥시-2-히드록시프로필)-아미노아세트산 염산염; 2-N-(3-옥타데실옥시-2-히드록시프로필)-아미노-3-히드록시프로피온산 염산염: 2-N-(3-옥타데실옥시-2-메톡시프로필)-아미노프로피온산 에틸 에스테르 옥살산염; 2-N-(3-옥타데실옥시-2-메톡시프로필)-아미노-3-히드록시부티르산; 2-N-(3-옥타데실옥시-2-히드록시프로필)-아미노말론산 디에틸 에스테르; 2-N-(3-옥타데실옥시-2-히드록시프로필)-아미노-3-페닐-프로피온산인 일반식(Ⅰ)의 화합물.
  4. a) 다음 일반식(Ⅱ)의 아미노 화합물을
    (상기 식중, R1, R2및 R3은 상기 정의와 같음) 다음 일반식(Ⅲ)의 화합물과 반응시켜 일반식 (Ⅰ)의 화합물로 만들거나 또는,
    (상기식중, R4및 R5는 상기 정의와 같고, Z는 예컨데 토실기 또는 할로겐 원자와 같이 쉽게 제거가능한 기임)
    b) 다음 일반식(Ⅳ)의 에폭사이드를
    (상기식증 R1은 상기 정의와 같음) 다음 일반식(Ⅴ)의 화합물과
    〔상기식중 R3및 R5는 상기 정의와 같고 R6는 수소, 메틸 벤질 또는 카르복실기 또는 다음 일반식(Ⅵ) 또는 (Ⅵa)의 화학기
    (상기식중, R7은 예컨대 벤질, 클로로벤질, 2,6-디클로로벤질 또는 3급-부틸과 같이 쉽게 분열될 수 있는 보호기임)임〕반응시켜 다음 일반식(Ⅶ)의 화합물을 생성시킨 다음
    (상기식중, R1, R3, R5및 R6은 상기 정의와 같음)
    R2가 수소가 아닌 경우에는, 이 화합물을 공지 방법으로 알킬화시켜 다음 일 반식 (Ⅷ) 의 화합물을 생성시키고
    (상기식중, R1, R2, R3, R5및 R6은 상기 정의와 같음) 이어서 일반식 (Ⅷ) 의 이 화합물들을 상기 정의한 보호기를 산분해시키거나 가수소분해시킴으로써 일반식 (Ⅰ) 의 화합물로 만드는 것을 특징으로하는 제1항에 따른 일반식 (Ⅰ)의 화학물의 제조방법.
  5. 다음 일반식 (Ⅰ)의 2-아미노카르복실산 및 유도체와 약리적으로 허용되는 그의 염의 단백질 카나아제 C의 저해 및 그에 따른 수축, 분리 및 증식과정의 조절용도.
    상기식 중, R1은 직쇄 또는 분지쇄의, 탄소원자 20개이하의 포화 또는 불포화 알킬기이고, R2및 R3은 같거나 다르고, 수소 또는 탄소원자 4개 이하의 직쇄 또는분지쇄 알킬기이며, R4는 수소, 메틸, 히드록시메틸, 벤질, 히드록시벤질, 탄소원자4개 이하의 카르복실기, 히드록시알킬기 또는 알콕시카르보닐기이고, R5는 수소 또는 탄소원자 4개 이하의 직쇄 또는 분지쇄 알킬기이다.
  6. 제5항에 있어서, 혈전병, 동맥경화증, 고혈압과 같은 심장 및 혈관계 질환, 염증성 경과, 알레르기, 암, 바이러스성 질병 및 중추신경계의 퇴행적 손상의 예방 및/또는 치료를 위한 일반식(Ⅰ)의 화합물의 용도.
  7. 제5항에 있어서, 혈전병, 동맥경화증, 근긴장항진과 같은 심장 및 혈관계 질환, 염증성 경과, 알레르기, 암, 바이러스성 질병 및 중추신경계의 퇴행적 손상의 예방 및/또는 치료하기 위한 의약을 제조하는데 있어서의 일반식(Ⅰ)의 화합물의 용도.
  8. 통상적인 보조제 및 첨가제 외에, 제1항에 따른 일반식(Ⅰ)의 화합물을 함유함을 특징으로 하는 의약.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900701383A 1988-10-31 1989-10-30 2-아미노카르복실산 및 그의 유도체, 그의 제조방법 및 의약으로서의 그의 용도 Withdrawn KR900701735A (ko)

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Application Number Priority Date Filing Date Title
DE3836987A DE3836987A1 (de) 1988-10-31 1988-10-31 2-aminocarbonsaeuren und deren derivate, verfahren zu deren herstellung und deren verwendung als arzneimittel
PCT/EP1989/001293 WO1990005130A1 (de) 1988-10-31 1989-10-30 2-aminocarbonsäure-derivate, ihre herstellung und verwendung als arzneimittel
DEP3836987,7 1989-10-31

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CA1146695A (en) * 1979-03-01 1983-05-17 Shinichi Ishikura Polymeric resin and coating composition comprising same
EP0053434B1 (en) * 1980-11-28 1986-08-27 American Hospital Supply Corporation Compounds and method for treatment or prophylaxis of cardiac disorders
US4450173A (en) * 1980-11-28 1984-05-22 American Hospital Supply Corporation Compounds and method for treatment or prophylaxis of cardiac disorders
OA06199A (fr) * 1981-05-13 1981-06-30 Berol Kemi Ab Procédé de flottation de minéraux phosphatés et composé destiné à ce procédé.
SE441740B (sv) * 1983-05-27 1985-11-04 Berol Kemi Ab Forfarande for flotation av fosfatmalm
SE452120B (sv) * 1984-04-04 1987-11-16 Berol Kemi Ab Forfarande for skumflotation samt flotationsmedel herfor
DE3625738A1 (de) * 1986-07-30 1988-02-11 Goedecke Ag 2-acyloxypropylamin-derivate, verfahren zu deren herstellung und deren verwendung
DE3836987A1 (de) * 1988-10-31 1990-05-23 Goedecke Ag 2-aminocarbonsaeuren und deren derivate, verfahren zu deren herstellung und deren verwendung als arzneimittel

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CN1042347A (zh) 1990-05-23
AU635908B2 (en) 1993-04-08
JPH04502149A (ja) 1992-04-16
DE58906571D1 (de) 1994-02-10
DD289520A5 (de) 1991-05-02
DE3836987A1 (de) 1990-05-23
PT92155B (pt) 1995-07-18
EP0367205A1 (de) 1990-05-09
DK65691D0 (da) 1991-04-11
WO1990005130A1 (de) 1990-05-17
HU896587D0 (en) 1991-07-29
EP0367205B1 (de) 1993-12-29
US5401875A (en) 1995-03-28
AU4514389A (en) 1990-05-28
EP0440731A1 (de) 1991-08-14
PT92155A (pt) 1990-05-31
DK65691A (da) 1991-04-11
ZA898274B (en) 1990-07-25
ATE99282T1 (de) 1994-01-15
ES2060722T3 (es) 1994-12-01

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