KR20160017725A - Pear soap composition manufaturing by unripe fruit - Google Patents

Abstract

The present invention relates to a soap composition using a marine algae and a method for producing the same, and more particularly, to a soap composition using a marine algae and a method for producing the same, which comprises a powder or an extract of marine algae which can be discarded as an active ingredient, Excellent soap compositions and methods of making the same.

Description

TECHNICAL FIELD [0001] The present invention relates to a soap composition and a method for manufacturing the same,

The present invention relates to a soap composition using a marine algae and a method for producing the same, and more particularly, to a soap composition using a marine algae and a method for producing the same, which comprises a powder or an extract of marine algae which can be discarded as an active ingredient, Excellent soap compositions and methods of making the same.

Pears contain many polyphenols, such as quercetin and luteolin, which have anticancer and antioxidant properties and are known to be excellent in preventing cough and asthma. The embryo rate is 80 ~ 85%, the moisture content is about 85% and the heat is about 51.. The main ingredient of calories is carbohydrate and the sweetness of sugar is 10 ~ 13%. Generally, the most abundance of sucrose is contained in the order of fructose, glucose, and sorbitol. The content of organic acid in the flesh of the abdomen is about 0.2%. The protein content of the pear is around 0.3%, which is not different from other fruits, but it is excellent in constipation prevention and dressing due to high dietary fiber content.

Among the flavonoids, which are functional substances contained in the abdomen, quercetin has anticancer or antioxidant activity, and luteolin is also widely known as a dandruff effect that regulates bronchitis, sputum and cough. On the other hand, the polyphenol compounds contained in the pear were also found to have excellent anticancer effects.

Especially, it is known that the juice obtained from 20 to 60 days after full bloom contains a large amount of various functional substances such as arbutin, which is known to be effective for skin whitening, polyphenol compounds and flavonoids, which are antioxidants. However, the whole of the shrimp is abandoned in the process of harvesting the shrimp, and a method is needed to utilize it.

As a reference to a technique utilizing a conventional pear flavor, Korean Patent No. 10-1392395 discloses a polyphenol which is contained in an amount of 2 to 3 times as much as that of a young pear, that is 80 to 100 days old, , It has been disclosed that a lot of polyphenol-containing pancreatic juices can be prepared by extracting the pancreatic juice by boiling in water for about 3 hours. In Korean Patent Laid-Open No. 10-2013-0004456, the pancreatic juice is fermented with the yeast strain activity And then dried to prepare a health functional food composition having antiparasitic antihypertensive active antioxidative activity or anti-gastro-intestinal activity of a dark brown powder using a young marine algae.

Under these circumstances, the inventors of the present invention have found that a soap composition having excellent skin texture and whitening effect while having a skin whitening effect by adding powders or extracts of marine oils as an effective ingredient of soap, And the present invention has been completed.

It is an object of the present invention to provide a soap composition excellent in skin whitening effect by using powders or extracts of marine oils which can be discarded when they are adversely affected.

Another object of the present invention is to provide a method for producing a soap composition excellent in skin whitening effect by using a powder or extract of a marine oil which can be discarded at the time of an enemy.

In order to solve the above-mentioned problems, the present invention provides a soap composition comprising 1 to 20.0% by weight based on the total weight of the soap composition.

The present invention can increase the utilization of the powdery or extract powder from the marine oil as an effective ingredient of the soap composition.

As used herein, the term " marigold "refers to a young marine prior to harvest.

In the present invention, the marine licorice may be preferably 20 to 120 days, more preferably 30 to 60 days after bloom.

In the present invention, there is an effect that a soap having an excellent skin whitening effect can be provided by using a marine licorice. Specifically, the content of arbutin, inhibition of tyrosinase, and inhibition of melanin biosynthesis vary depending on the developmental stage of the embryo. Especially, arbutin content, tyrosinase inhibitory activity and melanin biosynthesis inhibitory rate are different from each other So that it is possible to provide a soap which is more excellent in skin whitening effect.

Particularly, in the present invention, in general, in a fruit farm, the use of an egg yolk that has passed 30 to 60 days after full bloom around May to June, that is, It is possible to improve the income of farmers by processing them for use.

In the present invention, the marine algae can be prepared in the form of powder or extract.

In the present invention, the blight oil and the powder may be obtained by pulverizing the pear blight and freezing or drying with hot air and then pulverizing.

In the present invention, it is possible to provide a soap excellent in feeling of cleansing due to the scrub effect due to bovine cells, especially when using a blight oil and powder. In particular, in one example of the present invention, it was confirmed that the feeling of washing feeling was superior to that of the prototype when using a blight oil and powder, and that the feeling of touch feeling was more excellent when 3-6 wt% was added.

The term "extract" used in the present invention refers to an extract obtained by extraction treatment with marine oil, a diluted solution or concentrate of the extract, a dried product obtained by drying the extract, a controlled preparation or purified product of the extracted solution, , The extract itself and extracts of all the formulations that can be formed using the extract.

In the scutellum extract of the present invention, the method for extracting the scutellum is not particularly limited, and may be extracted according to a method commonly used in the art. Non-limiting examples of the extraction method include hydrothermal extraction, ultrasonic extraction, filtration, and reflux extraction. These may be performed alone or in combination with two or more methods.

In the present invention, the kind of the extraction solvent used for extracting the marine oil is not particularly limited, and any solvent known in the art can be used. Nonlimiting examples of the extraction solvent include water, alcohols or mixed solvents thereof. When alcohol is used as a solvent, C ₁ to C ₄ alcohols may be more preferably used. The root extract and the extract of the present invention may preferably be a water extract.

In the present invention, it is possible to provide a soap having a low skin irritation, particularly when using a marine extract and an extract. In particular, in one example of the present invention, skin irritation was lower than that of the prototype when using a root extract and an extract, and skin irritation was lowered particularly when 1.5 to 3% by weight was added.

In the present invention, the soap composition may contain 1 to 20.0% by weight based on the total weight of the soap composition, as described above. By including the marine oil, the powder or the extract in the above-mentioned content range, it is possible to provide a soap having excellent quality characteristics and favorable taste while exhibiting skin whitening effect. Particularly, in the present invention, it was confirmed that the oil, the powder or the extract was contained in an amount of 1.5 to 6.0% by weight based on the total weight of the soap composition, And 4).

The present invention also provides a process for producing soap using a blight oil, a powder or an extract.

The soap using the blight oil, the powder or the extract according to the present invention can be produced by a method of pouring the soap solution obtained by melting, high temperature method or low temperature method into a predetermined soap mold.

That is, the present invention provides a method for producing a soap using a blight oil and a powder or an extract comprising the following steps.

1) preparing a guar gum and a powder or extract (step 1);

2) preparing a soap solution containing base oil and caustic soda and containing the oil and the powder or extract in an amount of 1 to 20.0% by weight of the total mass of the soap (step 2); And

3) pouring the soap solution into a mold to solidify (step 3).

The step 1 is a step of preparing a blight oil, a powder or an extract, and preparing a blight oil and a powder or an extract for use as an active ingredient of the soap.

The days and days after full bloom with the marine algae, blight oil, powder and the method of producing the extract are the same as those described in the above-described soap composition.

The step 2 is a step of preparing a soap solution containing base oil and caustic soda and containing the oil, the powder or the extract in an amount of 1 to 20.0% by weight of the total mass of the soap, And a step of preparing a soap solution containing a certain amount of the extract.

In step 2 above, the soap solution may further comprise additives that may be used in the soap, in addition to base oil, caustic soda, and bulk oil and powders or extracts. Specifically, glycerin, vitamin E and orange oil may be used as the additive, but the present invention is not limited thereto.

Step 3 is a step of solidifying the soap solution by pouring the soap solution into a molding mold, and solidifying the soap solution by pouring the soap solution into a molding mold for molding into a soap product.

More specifically, a method for producing soap using a blight oil, a powder or an extract of the present invention by melt blending will be described with reference to FIG.

First, dip the transparent soap base down and dip in a bath at 70-80 ° C. An additive such as glycerin and vitamin E is added to the soap base solution, and the soap solution is obtained by mixing the oil and the powder or the extract. The soap solution is poured into a soap bar and hardened to obtain soap.

In the present invention, the soap base may be a fatty acid soap base, a synthetic surfactant soap base, or a mixture of the fatty acid soap base and a synthetic surfactant soap base.

In the present invention, the fatty acid-based soap base is an animal oil selected from vegetable oil selected from coconut, castor oil, palm oil, palm oil, soybean oil, avocado, castor oil, sunflower, rice bran oil, cottonseed oil, almond, corn, grape seed, Can be obtained singly or in combination and can be easily obtained through saponification reaction with an alkali salt. As the synthetic surfactant soap base, conventional ones selected from sodium laurylsulfonate, sodium salt of alkylbenzenesulfonate, sodium cocoyl isethionate, and alkali metal salts of acyl glutamate can be used. The fatty acid-based soap base and the synthetic surfactant-based soap base may be mixed with each other.

The soap base to be used in the embodiment of the present invention is preferably transparent and may be a commercially available one. The fatty acid may be heated and dissolved at 65 to 68 ° C, and then an alkali salt may be added at 82 to 87 ° C to saponify , It is possible to use the one obtained by taking the upper part of the calves and washing the same several times with deep brine, and vacuum drying the same to have a moisture content of about 15%.

Hereinafter, a method for producing a soap using a blight oil, a powder or an extract of the present invention by a high-temperature method will be described.

First, sugar and distilled water are poured into a heat-resistant container to prepare a primary solution. Add the base oil prepared in the stainless steel beaker and heat to prepare the secondary mixed emulsion. Separately, caustic soda is mixed into distilled water to prepare a tertiary mixed solution. When the secondary mixed emulsion and the tertiary mixed solution reach a temperature of about 60 to 70 ° C, the mixture is stirred and traced. After the tracing process, the mixture is hot-watered at 70-80 ° C, and then it is quickly pulverized at 70-80 ° C until the soap is completely dissolved while pouring glycerin and ethanol thereto. Add a heated primary solution to the mashed soap solution and stir gently. When the soap temperature reaches 40 ~ 65 ℃, add the prepared gum, powder or extract, and additives such as vitamin E and mix. The thus prepared mixed solution is poured into a soap mold. After soaking the soap, it is cut into a suitable shape and size, and it is finished in a final product after aging process for 2 to 3 weeks.

At this time, the amount of the net soap (base oil + caustic soda) is determined in the range of about 70 to 90% by weight, preferably about 80% by weight of the total amount based on 1 kg of the soap, The saponification value for each type is calculated. The weight ratio of net soap and solvent is about 50:50 to 60:40, preferably about 55:45. At this time, the solvent is ethanol, distilled water, and glycerin (added in an amount of 8 to 12% by weight of the total weight of the soap). The amount of distilled water to be dissolved in the sugar is 6 to 10% by weight, preferably 8% by weight, of the combined weight of the net soap and the solvent. The amount of the distilled water to be dissolved in the sugar is not less than the weight of the solvent (caustic soda lye water + ethanol + glycerin) The total amount of the distilled water to dissolve the soda and the distilled water to dissolve the sugar is determined at about 12 to 20% by weight of the total soap weight.

Examples of the base oil that can be used in the present invention include vegetable oils selected from coconut, castor oil, palm oil, palm oil, soybean oil, avocado, castor oil, sunflower, rice bran oil, cottonseed oil, almond, corn and grape seed.

Hereinafter, a method for producing a soap using a blight oil, a powder or an extract of the present invention by a low temperature method will be described.

First, the base oil is heated to about 45 to 55 ° C to prepare a primary solution. Separately, caustic soda is mixed with distilled water to prepare a secondary mixed solution. The primary mixed solution and the secondary mixed solution are mixed and stirred while proceeding with a trace. Add an additive such as glycerin and vitamin E, mix the oil and the powder or extract, pour it into the soap mold, and saponify for a certain time. Then, it is cut into a suitable shape and size, and finished with the final product after aging period of 4 to 6 weeks.

Here, the description of each component used in the low temperature method is the same as that already described in the high temperature method.

The present invention has the effect of producing a soap composition having excellent skin properties and good whiteness while having a skin whitening effect by adding powders or extracts of marine oils which can be discarded at the time of an enemy as an active ingredient of soap. Particularly, the present invention has the effect of improving the income of the farm household by processing the fresh milk liquor which can be discarded at the time of adulteration, into a new use without disposing.

Brief Description of the Drawings Fig. 1 is a photographic view schematically showing a process for producing soap using a blight, a powder or an extract of the present invention by melt swelling.
Fig. 2 is a graph showing the results of investigation of tyrosinase inhibitory activity by breeding date of embryonated cultivars.
FIG. 3 is a graph showing the cytotoxicity measurement results of the breeding species of the embryos according to developmental stages.
Fig. 4 is a photograph showing the appearance of a soap prepared by adding a root extract, an extract or a powder of the present invention. Fig.

It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are not restrictive of the invention, as claimed.

Experimental Example 1: Analysis of arbutin content by pear development stage

Arbutin (hydroquinone-D-glucopyranside) is found in many plants and is a relatively stable whitening substance. It is known that the main mechanism of action is inhibition of tyrosinase activity and formation of melanin pigment during melanin synthesis.

In this experimental example, the arbutin content was determined by the developmental stage of the breeding variety of the embryo, and the results are shown in Table 1 below.

Days after full bloom (days) Content (mg / g) 30 40.6 ± 0.97 60 29.5 ± 0.36 90 10.9 ± 1.44 120 12.4 ± 1.23 150 8.4 ± 0.36 Enemy 9.4 ± 0.47

From Table 1, it can be seen that as the fruit grows from 40.6 mg / g to 9.3 mg / g from the 30th day after full bloom to the good harvest season, the content decreases. However, it can be seen that arbutin is contained at a relatively high concentration from 29.5 to 40.6 mg / g from May to June, that is, from 30 to 60 days after full bloom.

Experimental Example 2: Analysis of tyrosinase inhibitory activity by pear development stage

The synthesis of melanin in cells is very complex and controlled by various enzymes and substances. Among them, tyrosinase, a kind of polymerase that regulates the rate determining step, is the most important enzyme. The function of this enzyme has not yet been completely clarified, and a lot of research has been conducted on the pathway of melanin biosynthesis. Tyrosinase is an enzyme involved in the conversion of L-tyrosine to L-dopaquionone via L-tyrosine, which is the most important initial rate determining step in the melanin biosynthesis pathway in the human body. It is activated when the skin is exposed to ultraviolet light Thereby accelerating skin aging and allowing dark brown pigment substances to be deposited on the skin. Therefore, it is widely used to evaluate the effect of whitening ingredients.

In this experiment, tyrosinase inhibitory activities of the breeding varieties were investigated. The results are shown in Fig.

2, it can be confirmed that tyrosinase inhibitory activity is scarcely present after 60 days in full bloom.

Experimental Example 3: Measurement of inhibition rate of melanin biosynthesis by the growth stage

Melanin protects the skin from ultraviolet rays. However, if it is stimulated by active oxygen, tyrosinase is activated and it is gradually changed to produce melanin which is a black brown copolymer. Kozic acid and arbutin inhibit tyrosinase activity and produce melanin pigment Is used as a whitening component.

In order to examine the inhibitory effect of melanocytes on the melanin formation by the developmental stage of embryo callus, in this experiment, the effect of embryo and extract on melanogenesis was examined by using melanocytes, Melanin production was measured.

Specifically, the amount of melanin in the cells was measured after the simultaneous treatment of α-MSH and the extracts with α-MSH in murine melanoma melanocyte (B16F1 cells), and compared with the control without α-MSH treatment. The results are shown in Table 2 below.

Days after full bloom (days) Melanin biosynthesis inhibition rate 30 58.9 + - 9.00 60 37.6 ± 5.79 90 21.8 ± 4.05 120 26.9 ± 2.25 150 7.4 ± 4.82 Enemy 5.3 ± 4.03

From Table 2, it can be seen that the inhibition rate of melanin biosynthesis is decreased from 58.9% to 5.3% from 30 days after full bloom to full bloom, as the fruit grows.

Experimental Example 4: Cytotoxicity measurement at the time of pear development

After MTT [3- (4,5-dimethylthiazol-2-yl) -2,5-diphenyl tetrazolium bromide] reagent is absorbed into cells, it forms formazan by succinate dehydrogenase of mitochondria. Activity, broadly refers to the activity of the cell.

In this experimental example, the cytotoxicity of the embryo-cultivar was determined by MTT assay, which is a typical method for measuring the cell growth rate through MTT, and the results are shown in FIG.

3, the survival rate was 80% or more even at a high concentration of 500 μg / mL over the entire development period, and thus the possibility of development with general food, health-functional foods and cosmetics was shown. In particular, The stability was confirmed to be excellent.

Preparation Example 1: Preparation of a castor oil and a powder

Dried mung bean paste was cut into chunks and dried in a freeze dryer, and finely ground to a blender to prepare a mung bean powder.

Production Example 2: Preparation of a castor oil extract and an extract

The blighted oil and powder (2 g) prepared in Preparation Example 1 were added to 100 ml of water and immersed at 60 ° C for 6 hours, followed by filtration to remove the solids to prepare a castor oil extract.

EXAMPLES 1-4: Preparation of soaps using castor oil extract and extract

First, the soap base (transparent soap base, herbasoap, Korea) was diced and dissolved at 70 DEG C for 30 minutes, and vitamin E was added in an amount of 0.5% based on the total soap mass to prepare a soap base solution.

Meanwhile, the roots and extracts prepared in Preparation Example 2 were prepared in amounts corresponding to 1.5 wt%, 3 wt%, 6 wt% and 15 wt% of the total soap mass, respectively Each of the orange oils (sweet orange, Austal herba, Australia) was added in an amount of 0.5 wt% based on the total soap mass After adding and mixing, A mixture of the extract and orange oil was obtained.

To the soap base solution, A mixture of the extract and orange oil was added and mixed to prepare a soap solution.

The soap solution was poured into a mold and hardened to prepare a soap using a castor oil extract and an extract.

Fig. 4 shows the appearance of the soap prepared by adding the extract of the castor oil and the extract prepared as described above.

Example 5-8: Preparation of soap using castor oil and powder

First, the soap base (transparent soap base, herbasoap, Korea) was diced and melted at 70 DEG C for 30 minutes. Then, glycerin and vitamin E were added in amounts of 0.5% based on the total soap mass, .

To the soap base solution, the blight oil and powder prepared in Preparation Example 1 were added in amounts corresponding to 1.5 wt%, 3 wt%, 6 wt% and 15 wt% of the total soap mass, respectively, and mixed to prepare a soap solution .

The soap solution was poured into a mold and hardened to prepare a soap using cast oil and powder.

Fig. 4 shows the appearance of the soap added with the blight oil and the powder prepared as described above.

Experimental Example 5: Quality characteristics and chromaticity of the soap of the present invention

The quality characteristics and the chromaticity of the soap prepared by Examples 1 to 8 and the soap added with the extract and the oil and the powder were examined. For comparison, prototypes (cucumber soap, Dongsan C & N, Korea) were used as a control.

The results are shown in Table 3 below.

division Dietary ingredients
Content (% by weight) Hardness
(g) Moisture content
(%) pH weight
(g) Hunter value L a b Prototype 48.7 23.4 8.72 68.7 59.7 -1.58 2.8 Example 1 extract 1.5 47.1 24.5 8.64 69.1 59.0 -1.50 3.1 Example 2 extract 3 45.5 25.1 8.55 69.9 57.7 -1.36 3.7 Example 3 extract 6 46.9 24.7 8.53 69.7 56.9 -1.80 5.1 Example 4 extract 15 42.9 28.5 8.53 73.0 55.0 -1.77 7.1 Example 5 powder 1.5 56.8 24.5 8.81 69.3 43.0 -3.54 15.9 Example 6 powder 3 55.2 23.1 8.77 67.2 37.2 -2.70 13.7 Example 7 powder 6 55.8 23.5 8.68 70.4 31.5 -2.92 10.3 Example 8 powder 15 51.0 22.8 8.65 69.7 30.0 -3.82 9.0

As shown in Table 3, the hardness and pH of the shoe sole were increased as the amount of the extract was increased, and the moisture content and the weight were increased. The mechanical chromaticity of the soap was lower than that of the commercial soap.

As a result of examination of the quality characteristics of the soap added with oil and powder through Table 3, the weight increased and the hardness, moisture content and pH tended to decrease as the amount of powder added increased. The mechanical chromaticity was decreased as the amount of powder added was larger than that of ordinary commercial soap, and the lightness, redness and yellowness were lowered.

Experimental Example 6: Preference Evaluation of Soap of the Present Invention

The preference of the soybean flour and the soap added with the extract prepared in Examples 1 to 8 and the soybean flour and the soap added with the powder were examined. For comparison, prototypes (cucumber soap, Dongsan C & N, Korea) were used as a control.

At this time, the preference score was measured on a 9 point scale.

The results are shown in Table 4 below.

division Dietary ingredients
Content (% by weight) Exterior Brittle Skin irritation Three senses Overall preference Prototype 6.88 6.75 4.88 5.50 5.25 Example 1 extract 1.5 6.22 7.33 3.00 5.89 6.44 Example 2 extract 3 5.44 6.44 2.33 5.22 5.22 Example 3 extract 6 4.89 6.11 4.33 5.11 5.11 Example 4 extract 15 5.22 6.56 4.56 5.59 5.33 Example 5 powder 1.5 6.56 7.44 3.89 6.00 6.89 Example 6 powder 3 6.22 7.11 4.11 6.89 6.33 Example 7 powder 6 5.89 7.00 4.33 6.33 5.67 Example 8 powder 15 4.33 6.11 5.56 6.22 4.78

As shown in Table 4, the degree of preference of appearance was lowered as the addition amount of the extract increased, but when 1.5% by weight was added, the spreadability was better and the skin irritation was lowest when added at 3% by weight Able to know. Washing sensation was lower as the amount of addition was increased, and the overall preference was 1.5% by weight.

As shown in Table 4, the degree of preference of the appearance was lowered as the addition amount of powder was increased, but when the added amount of powder was 1.5 to 6% by weight, the spreadability of the soap was good, and the skin irritation had a large amount of powder The higher the quality, the better. Washing sensation was better when added with powder, because of the scouring effect due to cellulite cells, and was best when added at 3 wt%. The overall preference was 1.5% by weight.

Claims (13)

A soap composition comprising a castor oil, powder or extract in an amount of 1 to 20.0% by weight based on the total weight of the soap composition.
The soap composition according to claim 1, wherein the castor oil has passed 20 to 120 days after full bloom.
The soap composition according to claim 1, wherein the bait is discarded at the enemy.
The soap composition according to claim 1, wherein the soap composition has a skin whitening effect.
The soap composition according to claim 1, wherein the casting oil and the powder are obtained by sieving the casting oil and then freezing or drying by hot air blowing.
The soap composition according to claim 1, wherein the root extract and the extract are obtained by extracting the root extract with water, a C ₁ to C ₄ alcohol or a mixed solvent thereof.
The soap composition according to any one of claims 1 to 5, wherein the oil, powder or extract is contained in an amount of 1.5 to 6.0% by weight based on the whole composition.
A method for producing a soap using a blight oil, a powder or an extract comprising the steps of:
Preparing a castor oil and a powder or an extract (step 1);
Preparing a soap solution containing a base oil and caustic soda and containing the blight oil and the powder or extract in an amount of 1 to 20.0% by weight of the total mass of the soap (step 2); And
And pouring the soap solution into a mold to solidify the solution (step 3).
9. The method of claim 8, wherein the bay oil has passed 20 to 120 days after full bloom.
9. The method of claim 8, wherein the marrow is abandoned at the enemy.
9. The method according to claim 8, wherein the blight oil and the powder are obtained by shredding the blighted oil and freezing or drying after hot air drying.
The method of claim 8, wherein the fold Yukwa extract method of the ship Yukwa water, that obtained by extraction with alcohol, or a mixed solvent of the C ₁ to C _4.
9. The method according to claim 8, wherein in step 2, the blight oil and the powder or extract are mixed in an amount of 1.5 to 6.0 wt% of the total mass of the soap.

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