KR20130134856A - Composition for improving hair styling having volume ability of permanent wave and straight - Google Patents
Composition for improving hair styling having volume ability of permanent wave and straight Download PDFInfo
- Publication number
- KR20130134856A KR20130134856A KR1020120058701A KR20120058701A KR20130134856A KR 20130134856 A KR20130134856 A KR 20130134856A KR 1020120058701 A KR1020120058701 A KR 1020120058701A KR 20120058701 A KR20120058701 A KR 20120058701A KR 20130134856 A KR20130134856 A KR 20130134856A
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- KR
- South Korea
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- hair
- hair styling
- cysteine
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
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Abstract
본 발명은 환원제, 알칼리제, 알콜, 보습제, 유화제, 가수분해 실크 단백질, 알로에 베라잎 추출물 및 헤나 추출물을 포함하는, 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물로서, 상기 조성물의 헤어 스타일링 볼륨은 하루 내지 이틀 정도 지속되도록 하는 것을 특징으로 하는, 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물에 관한 것이다.The present invention is a composition for improving hair styling having a permanent wave and straight volume, including a reducing agent, an alkali agent, an alcohol, a humectant, an emulsifier, a hydrolyzed silk protein, an aloe vera leaf extract, and a henna extract, wherein the hair styling volume of the composition is It relates to a composition for improving hair styling having a permanent wave and a straight volume, characterized in that it lasts for one to two days.
Description
본 발명은 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물에 관한 것이다. 더욱 상세하게는 환원제, 알칼리제, 알콜, 보습제, 유화제, 가수분해 실크 단백질, 알로에 베라잎 추출물 및 헤나 추출물을 포함하여 화학적 시술로 인한 모발손상과 두피자극으로 발생하는 알러지성 피부염 및 피부가려움을 완화/예방할 수 있으며, 모발을 퍼머넌트웨이브 및 스트레이트시 우수한 볼륨을 갖도록 함으로써 간편하게 모발 스타일링이 가능한 모발 스타일링 개선용 조성물에 관한 것이다.
The present invention relates to a composition for improving hair styling having a permanent wave and a straight volume. More specifically, allergy dermatitis and scalp irritation caused by hair damage and scalp irritation caused by chemical procedures, including reducing agents, alkalis, alcohols, humectants, emulsifiers, hydrolyzed silk proteins, aloe vera leaf extracts and henna extracts The present invention relates to a composition for improving hair styling, which can be prevented and the hair can be easily styled by having the hair have excellent volume during permanent wave and straightening.
모발은 3개 층으로 구성되어 있는데 모발의 가장 바깥층에서부터 모표피, 모피질, 모수질로 되어 있으며 모발의 주된 부분인 모피질은 주로 케라틴이라고 하는 탄력성이 풍부한 섬유상의 경단백질로 되어 있다. 모발의 케라틴은 각종 아미노산이 결합하여 이루어진 폴리펩타이드로 연결되어 있으며 이 폴리펩타이드와 리펩타이드 사이는 시스틴 결합, 염결합, 수소결합 등의 측쇄로 된 고분자물질로 되어 있고 다른 단밸질에 비하여 황의 함유량이 많다. 모발은 이 같은 구조의 케라틴으로 구성되어 있기 때문에 탄력성이 있어서 구부려도 다시 원래대로 되돌아오는 성질을 지니고 있다. 이러한 모발의 탄력성을 측쇄의 절단에 의해 일시적으로 상실시킨후 해로운 위치로 재결합을 시킴에 따라 원하는 웨이브를 형성시키는 것이 퍼머넌트 웨이브 및 스트레이트용 펌제의 원리이다.Hair consists of three layers, from the outermost layer of hair to the epidermis, the cortex and the medulla. The main part of the hair, the cortex, is mainly composed of elastic, fibrous, light protein called keratin. The hair keratin is linked with a polypeptide consisting of various amino acids. The polypeptide and the polypeptide are made of side chain polymers such as cystine bonds, salt bonds and hydrogen bonds, and contain more sulfur than other proteins. . Hair is composed of keratin with this structure, so it has elasticity and returns to its original state when bent. The principle of permanent wave and straight perm is to form a desired wave as the hair is temporarily lost by the cleavage of the side chain and then recombined to a detrimental position.
모발에 웨이브 및 스트레이트 등의 펌 효과를 부여하는 퍼머넌트웨이브 및 스트레이트용 펌(perm)제는 일반적으로 환원성 제1제와 산화성 제2제로 구성되는데, 구체적으로는 티오글리콜산, 티오글리콜산의 염류, 티오글리콜산 에스테르, 시스테인, 시스테인의 염류 및 시스테인의 아세틸 유도체 등의 환원성 물질을 함유한 환원성 제1제로 모발 내 시스틴 결합을 환원시키고, 여기에 과산화수소수 또는 브롬산 나트륨의 산화성 물질을 함유한 산화성 제2제로 산화 재결합으로 웨이브 및 스트레이트 등을 형성하게 된다. 또한, 그 효과 및 사용성을 높이기 위하여 알칼리제, 침투제, 안정제, 습윤제, 양모제, 착색제, 유화제, 향료 등을 사용하고 있다(도 1 및 도 2 참조).Permanent wave and perm agents for imparting a perm effect such as wave and straight to hair are generally composed of a reducing first agent and an oxidizing second agent. Specifically, salts of thioglycolic acid and thioglycolic acid, A reducing first agent containing a reducing agent such as thioglycolic acid ester, cysteine, salts of cysteine and acetyl derivative of cysteine to reduce the cystine bond in the hair, and to it an oxidizing agent containing an oxidizing substance of hydrogen peroxide or sodium bromide. As a second agent, oxidative recombination forms waves and straight lines. In addition, an alkali agent, a penetrant, a stabilizer, a wetting agent, a wool agent, a coloring agent, an emulsifier, a fragrance, etc. are used in order to raise the effect and usability (refer FIG. 1 and FIG. 2).
환원성 제1제는 주제 및 사용법에 따라 티오글리콜산 또는 그 염류를 주성분으로 한 냉이욕식 퍼머넌트 웨이브제, 시스테인을 주성분으로 한 냉이욕식 퍼머넌트 웨이브제, 티오글리콜산 또는 그 염류를 주성분으로 한 가온이욕식 퍼머넌트웨이브제, 시스테인 또는 그 염류를 주성분으로 한 가온이욕식 퍼머넌트웨이브제, 티오글리콜산 또는 그 염류를 주성분으로 한 냉이욕식 축모교정용, 티오글리콜산 또는 그 염류를 주성분으로 한 냉일욕식 퍼머넌트 웨이브제, 티오글리콜산 또는 그 염류를 주성분으로 한 제1제를 사용할 때 조제하는 발열 이욕식 퍼머넌트 웨이브제, 티오글리콜산 또는 그 염류를 주성분으로 한 가온이욕식 축모교정용, 티오글리콜산 또는 염류를 주성분으로 하는 고온정발용 열기구를 사용하는 가온이욕식으로 구분되어 있으며, 제형상으로 액상, 로션상, 크림상으로 분류되고 있다.The reducing first agent is a cold bath permanent wave agent mainly composed of thioglycolic acid or salts thereof, or a cold bath permanent wave agent mainly composed of cysteine, a warming bath formula mainly containing thioglycolic acid or salts thereof according to the subject matter and the usage. Permanent wave agent, cysteine or salt-based heating permanent type permanent wave agent, thioglycolic acid or salts thereof for cold bath type hair straightening, cold bath type permanent wave agent mainly containing thioglycolic acid or salts thereof Exothermic-type permanent wave agent prepared when using a thioglycolic acid or a salt thereof as a main ingredient, a warming-type type of hair straightening correction mainly based on thioglycolic acid or a salt thereof, and thioglycolic acid or a salt as a main ingredient It is divided into a heating bath type using a hot air balloon for hairdressing, In the image it is classified as a liquid, a lotion, cream.
이러한 환원성 제1제는 알칼리제를 필수성분으로 사용하고 있으며, 알칼리제로서는 암모니아수나, 에탄올아민, 트리에탄올 아민 등의 아미노알콜류를 사용하고 있는데, 이러한 알칼리제의 사용으로 환원성 제1제의 pH는 8.9~10.0 범위로 알칼리성 영역을 구성한다. 상기와 같이 알칼리성을 나타내는 환원성 제1제는 알칼리제의 사용으로 모발을 효과적으로 팽윤시키게 되고, 팽윤된 모발 내로 환원성 제1제가 모발 내부로 쉽게 침투할 수 있지만, 이러한 모발의 팽윤은 결국 모발 손상의 원인이 된다.The reducing first agent uses an alkali agent as an essential component, and as the alkali agent, aminoalcohols such as ammonia water, ethanolamine, and triethanol amine are used, and the pH of the reducing first agent is in the range of 8.9 to 10.0 due to the use of the alkali agent. Constitutes an alkaline region. As described above, the reducing first agent that exhibits alkalinity effectively swells the hair by using an alkali agent, and the reducing first agent can easily penetrate into the hair into the swollen hair, but such swelling of the hair eventually causes hair damage. do.
또한, 산화성 제2제는 산화제로 과산화수소수 및 브롬산나트륨의 사용으로 팽윤되어진 모발을 쉽게 산화시킬 수 있지만 모발 손상 및 두피 자극의 원인이 되며, 시술시간 또한 30분 이상을 필요로 하고 있다. 즉, 기존의 퍼머넌트웨이브 및 스트레이트너용 환원성 및 산화성 제제는 모발의 케라틴 결합을 환원절단 산화 재결합시키는 화학적 시술을 30분 이상 적용함에 따라 모발의 손상 및 두피자극을 야기하고, 또한 장시간 모발의 과도한 팽윤으로 시술 후 환원제 및 환원 후 환원성 물질이 팽윤된 모발에 잔류하여 나쁜 냄새를 남기게 된다.In addition, the oxidizing second agent can easily oxidize the swollen hair by using hydrogen peroxide and sodium bromide as an oxidizing agent, but it causes hair damage and irritation of the scalp, and the procedure time also requires 30 minutes or more. That is, the conventional reducing and oxidizing agents for permanent wave and straighteners cause hair damage and scalp irritation by applying a chemical procedure for reducing cut oxidative recombination of hair keratin bonds for at least 30 minutes, and also cause excessive hair swelling for a long time. After the procedure, the reducing agent and the reducing material after the reduction remain in the swollen hair and leave a bad smell.
한편, 상기한 기존의 환원성 제1제 및 산화성 제2제의 두피 및 모발 손상 등의 문제점을 해결하기 위하여 비타민 등 많은 기능성 물질들을 첨가하여 사용하는 방법 등이 제시되었으나, 이들 기능성 성분들은 펌제를 구성하는 환원제, 산화제 및 알칼리제 등에 의하여 분해 또는 파괴되거나, 심지어는 수용액 상에서도 분해되는 경향이 있어 펌제와 혼합사용이 불가능한 문제점이 있었다. 이러한 문제점을 해결하고 상기 기능성 물질의 유효성을 높이기 위한 연구의 일환으로 W/O형 유화, 리포좀, 마이크로 캡슐방식을 선택하여 제제화하는 방법이 제시되고 있으나, 그 유효성은 확보되지 않았다.
On the other hand, in order to solve the problems such as the scalp and hair damage of the existing reducing first agent and the oxidative second agent, a method of adding and using many functional substances such as vitamins has been proposed, but these functional components constitute a pump agent. There is a problem in that the decomposition or destruction by the reducing agent, the oxidizing agent and the alkaline agent, or even in the aqueous solution tends to be decomposed, so that the mixed use with the pump agent is impossible. As a part of the research to solve this problem and increase the effectiveness of the functional substance, a method of formulating a W / O type emulsification, liposome, and microcapsule method has been proposed, but its effectiveness has not been secured.
한편, 모발은 미관상 남성, 여성의 특징을 나타내는 중요한 역할을 하여 같은 사람이라도 헤어 스타일을 변화시킴으로써 또 다른 인상을 줄 수 있게 된다. 이에 따라, 모발에 광택을 제공할 수 있고, 헝클어진 모발을 정리 정돈할 수 있으면서 모발을 손쉽게 스타일링할 수 있는 제제가 개발되어 사용되어 왔다. 그러나, 기존의 모발 스타일링 제제는 펌제에 비해, 웨이브나 스트레이트 형성 효율성이 낮은 단점이 있었다. 또한, 모발의 형태를 고정하기 위해, 드라이, 아이롱, 롯드 등의 헤어 스타일링 기기를 이용하지만, 단시간 내에 머리가 풀리게 되어 헤어 스타일을 오랫동안 유지하기 어려운 문제가 있었다.
On the other hand, the hair plays an important role in the appearance of the male and female aesthetic appearance, and even the same person can give another impression by changing the hairstyle. Accordingly, preparations that can provide gloss to the hair and to clean up the matted hair while easily styling the hair have been developed and used. However, conventional hair styling formulations have a disadvantage in that the efficiency of wave or straight formation is lower than that of the pump. In addition, in order to fix the shape of the hair, a hair styling device such as dry, iron, rod, etc. is used, but there is a problem that it is difficult to maintain the hairstyle for a long time because the hair is released in a short time.
본 발명의 목적은 모발 및 두피의 보습, 보호효과가 개선될 뿐만 아니라, 두피자극에 의한 알러지성 피부염 및 피부가려움을 효과적으로 완화/예방할 수 있는 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물을 제공하는 것이다.It is an object of the present invention to provide a composition for improving hair styling having a permanent wave and straight volume that can effectively alleviate / prevent allergic dermatitis and skin itching caused by scalp irritation, as well as improving the moisturizing and protective effects of hair and scalp. It is.
본 발명의 다른 목적은 인체에 무해하고 이취가 없는 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물을 제공하는 것이다.Another object of the present invention is to provide a composition for improving hair styling having a permanent wave and a straight volume that is harmless to the human body and is free of odors.
본 발명의 또 다른 목적은 상기 조성물을 포함하는 모발 스타일링 제제를 제공하는 것이다.Another object of the present invention is to provide a hair styling preparation comprising the composition.
본 발명의 또 다른 목적은 상기 조성물을 포함하는 모발 스타일링 제제의 제조방법을 제공하는 것이다.
Still another object of the present invention is to provide a method for preparing a hair styling formulation comprising the composition.
본 발명의 하나의 관점은 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물에 관한 것이다. 상기 조성물은 환원제, 알칼리제, 알콜, 보습제, 유화제, 가수분해 실크 단백질, 알로에 베라잎 추출물 및 헤나 추출물을 포함한다.One aspect of the present invention relates to a composition for improving hair styling having a permanent wave and a straight volume. The composition comprises a reducing agent, an alkali agent, an alcohol, a humectant, an emulsifier, a hydrolyzed silk protein, an aloe vera leaf extract and a henna extract.
상기 환원제는 시스테인, 시스테인 염류, 아세틸시스테인, 티오글리콜 산, 티오글리콜산 염류, 티오아세트산, 티오글리세롤 및 이들의 혼합물로 이루어진 군으로부터 선택되고, 상기 알칼리제는 에탄올아민, 수산화나트륨, 수산화칼륨, 탄산나트륨, 탄산칼륨 및 이들의 혼합물로 이루어진 군으로부터 선택되고, 상기 알콜은 에틸알콜, 프로필알콜, 이소프로필알콜, 부틸알콜 및 이들의 혼합물로부터 선택되고, 상기 보습제는 디메치콘, 아모디메치콘, 디메치콘코폴리올 및 이들의 혼합물에서 선택되고, 상기 유화제는 라우레스-23에서 선택되는 것을 특징으로 한다.The reducing agent is selected from the group consisting of cysteine, cysteine salts, acetylcysteine, thioglycolic acid, thioglycolic acid salts, thioacetic acid, thioglycerol and mixtures thereof, and the alkali agent is ethanolamine, sodium hydroxide, potassium hydroxide, sodium carbonate, Potassium carbonate and mixtures thereof, the alcohol is selected from ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol and mixtures thereof, and the humectant is dimethicone, amodimethicone, dimethicone Polyols and mixtures thereof, and the emulsifier is selected from laureth-23.
상기 조성물은 당약 추출물, 시카카이 추출물, 녹차 추출물 및 인디언 구즈베리 추출물로 구성된 군으로부터 선택되는 하나 이상의 추출물을 추가로 포함할 수 있다.The composition may further comprise one or more extracts selected from the group consisting of sugar extracts, shikakai extracts, green tea extracts and Indian gooseberry extracts.
상기 조성물은 판테놀, 피탄트리올, 토코페릴아세테이트, 올리브오일, 호호바오일 또는 동백오일을 추가로 포함할 수 있다.The composition may further comprise panthenol, phytantriol, tocopheryl acetate, olive oil, jojoba oil or camellia oil.
상기 조성물의 각 구성 성분은 조성물 총 중량을 기준으로 환원제 0.1~30중량%, 알칼리제 0.1~10중량%, 알콜 0.1~50중량%, 보습제 0.1~20중량%, 유화제 0.1~10중량%, 가수분해 실크 단백질 0.0001~5중량%, 알로에 베라잎 추출물 0.1~10중량% 및 헤나 추출물 0.1~10중량%으로 함유되는 것을 특징으로 한다.Each component of the composition is 0.1-30% by weight reducing agent, 0.1-10% by weight alkaline agent, 0.1-50% by weight alcohol, 0.1-20% by weight moisturizer, 0.1-10% by weight emulsifier, hydrolysis based on the total weight of the composition 0.0001 to 5% by weight of the silk protein, aloe vera leaf extract is characterized in that it contains 0.1 to 10% by weight and henna extract 0.1 to 10% by weight.
상기 알로에 베라잎 추출물 및 헤나 추출물의 각 함량은 조성물 총 중량에 대하여 각각 0.0001 내지 10 중량%인 것을 특징으로 한다.Each of the aloe vera leaf extract and henna extract is characterized in that 0.0001 to 10% by weight relative to the total weight of the composition.
상기 시스테인은 L-시스테인 또는 DL-시스테인이고, 시스테인 염류는 L-시스테인염산염 또는 DL-시스테인염산염 일 수 있다.The cysteine may be L-cysteine or DL-cysteine, and the cysteine salt may be L-cysteine hydrochloride or DL-cysteine hydrochloride.
상기 조성물은 L-시스테인 염류 0.1~8중량%, DL-시스테인 염류 0.1~8중량%, 티오글리콜산 0.1~8중량%, 모노에탄올아민 0.1~8중량%, 에틸알콜 0.1~50중량%, 디메치콘 0.1~10중량%, 아모디메치콘 0.1~10중량% 및 라우레스-23 0.1~10중량%으로 조성되는 것을 특징으로 한다.The composition is 0.1-8% by weight of L-cysteine salt, 0.1-8% by weight DL-cysteine salt, 0.1-8% by weight thioglycolic acid, 0.1-8% by weight monoethanolamine, 0.1-50% by weight ethyl alcohol, dimethicone It is characterized in that the composition is composed of 0.1 to 10% by weight of Chicon, 0.1 to 10% by weight of Amodimethicone and Laureth-23.
상기 조성물은 4.0 내지 8.0 범위의 pH를 갖는 것을 특징으로 한다.The composition is characterized by having a pH in the range of 4.0 to 8.0.
본 발명의 다른 관점은 상기 모발 스타일링 개선용 조성물을 함유하는 모발 스타일링 제제에 관한 것이다.Another aspect of the present invention relates to a hair styling preparation containing the composition for improving hair styling.
상기 제제는 1제형 액상 타입인 것을 특징으로 한다.The preparation is characterized in that the one-part liquid type.
본 발명의 또 다른 관점은 상기 모발 스타일링 개선용 조성물을 이용한 모발 스타일링 법에 관한 것이다. 상기 모발 스타일링법은 (a) 모발을 세척한 후, 건조하는 단계; (b) 상기 모발 스타일링 개선용 조성물을 건조된 모발에 도포하는 단계; 및 (c) 헤어 스타일링 기기로 모발을 웨이브 또는 스트레이트하여 스타일링하는 단계;를 포함하며, 상기 스타일링의 볼륨은 하루 내지 이틀 정도 지속되는 것을 특징으로 한다.
Another aspect of the present invention relates to a hair styling method using the composition for improving hair styling. The hair styling method includes the steps of (a) washing the hair and then drying the hair; (b) applying the composition for improving hair styling to dried hair; And (c) styling the hair by wave or straightening the hair with a hair styling device, wherein the volume of the styling lasts for one to two days.
본 발명에 따른 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 조성물은 환원제 외에 가수분해 실크 단백질 및 천연 식물성분을 함유함으로써, 일반적인 펌제에 비해 모발이나 두피를 자극하지 않아 모발을 손상시키지 않고 화학적 시술에 의한 모발 손상 및 손상되어진 모발의 회복과 두피자극으로 인한 알러리성 피부염 및 피부 가려움을 현저하게 완화/예방할 수 있다. 또한 상기 조성물을 모발에 도포 후, 모발 스타일링 기기를 이용하여 웨이브 또는 스트레이트를 시술하면, 빠른 시간 내에 안정성, 탄력 및 볼륨감이 우수하고 자연스러운 컬이나 스트레이트를 형성하므로, 신속하고 간편하게 원하는 스타일로 만들 수 있는 장점을 갖는다.
The hair styling composition having a permanent wave and straight volume according to the present invention contains hydrolyzed silk protein and natural plant components in addition to the reducing agent, and thus does not irritate the hair or the scalp as compared to a general pump, and does not damage the hair without chemical damage. It can significantly alleviate / prevent allergic dermatitis and skin itching due to the recovery of damaged and damaged hair and scalp irritation. In addition, if the composition is applied to the hair and then wave or straight is processed using a hair styling device, it can be quickly and easily made into a desired style since it has excellent stability, elasticity and volume, and forms a natural curl or straight within a short time. That has the advantage.
도 1은 펌제가 모발에 적용되는 메커니즘을 나타낸 것이다.
도 2는 모발에 펌 효과가 나타나는 메카니즘을 개략적으로 나타낸 것이다.
도 3은 웨이브형성 효율측정을 위한 시험기구의 평면도를 나타낸 것이다.
도 4는 웨이브형성 효율측정을 위한 시험기구의 측면도를 나타낸 것이다.Figure 1 shows the mechanism by which the pump is applied to the hair.
Figure 2 schematically shows the mechanism by which the firm effect appears in the hair.
3 shows a plan view of a test apparatus for measuring wave formation efficiency.
Figure 4 shows a side view of the test apparatus for measuring the wave formation efficiency.
이하, 본 발명의 구성을 보다 상세히 설명한다.Hereinafter, the configuration of the present invention will be described in more detail.
본 발명의 모발 스타일링 개선용 조성물은 일반적인 펌제의 구성성분인 환원제 및 알칼리제에 알콜, 가수분해 실크 단백질, 알로에 베라잎 추출물 및 헤나 추출물을 추가로 포함시킴으로써, 모발 및 두피의 손상을 최소화하면서도 환원제에 의한 모발 볼륨을 갖도록 함을 특징으로 한다. 또한, 본 발명의 조성물은 모발 스타일링을 개선시키기 위한 것으로, 모발의 퍼머넌트웨이브 및 스트레이트 볼륨을 가지지만, 통상의 펌제가 아니며, 추가적인 산화제를 필요로 하지 않고, 모발에 도포 후 별도의 세척과정이 불필요한 특징을 갖는다. 또한, 상기 조성물의 모발 볼륨의 지속 시간은 약 하루 내지 이틀 정도이며, 시간이 지나거나 세발 이후에는 원래의 상태로 회복되게 된다.
The composition for improving hair styling of the present invention further includes alcohol, hydrolyzed silk protein, aloe vera leaf extract, and henna extract in reducing and alkaline agents, which are components of a general pump, thereby minimizing damage to hair and scalp, Characterized in that it has a hair volume. In addition, the composition of the present invention is intended to improve hair styling, has a permanent wave and straight volume of hair, but is not a conventional pumping agent, does not require additional oxidant, and does not require a separate washing process after application to the hair. Has characteristics. In addition, the duration of the hair volume of the composition is about one to two days, and after a period of time or after three hairs will be restored to its original state.
본 발명에서, 상기 환원제는 모발의 케라틴 단백질 중 시스틴 결합을 끊어 모발의 형태를 변형시킬 수 있도록 해 주는 물질이다. 본 발명에 이용될 수 있는 환원제로는 모발의 시스틴 결합을 환원시켜 절단시킬 수 있는 물질이면, 특별히 제한되지 않으나, 일반적임 펌제에 사용되는 환원성 물질을 사용할 수 있으며, 구체적으로는 시스테인, 시스테인 염류, 아세틸시스테인, 티오글리콜산, 티오글리콜산 염류, 티오아세트산, 티오글리세롤 및 이들의 혼합물이 가능하며, 바람직하게는 시스테인 염류 및 티오글리콜산이다.In the present invention, the reducing agent is a substance that can change the shape of the hair by breaking the cystine bonds in the keratin protein of the hair. The reducing agent that can be used in the present invention is not particularly limited as long as it is a material capable of reducing and cutting cystine bonds of hair, but can be used as a reducing agent used in general pumping agents. Specifically, cysteine, cysteine salts, Acetylcysteine, thioglycolic acid, thioglycolic acid salts, thioacetic acid, thioglycerol and mixtures thereof are possible, preferably cysteine salts and thioglycolic acid.
또한, 상기 시스테인은 L-시스테인 또는 DL-시스테인이고, 시스테인 염류는 L-시스테인염산염 또는 DL-시스테인염산염 일 수 있다.
In addition, the cysteine may be L-cysteine or DL-cysteine, and the cysteine salt may be L-cysteine hydrochloride or DL-cysteine hydrochloride.
또한, 상기 환원제의 조성물 내 함량은 원하는 스타일링의 강도나 제형 등에 따라 달라질 수 있으나, 바람직하게는 조성물 총 중량을 기준으로 0.1 내지 30중량%로 포함될 수 있다.In addition, the content of the reducing agent in the composition may vary depending on the strength or formulation of the desired styling, but may preferably be included in 0.1 to 30% by weight based on the total weight of the composition.
더욱 바람직하게는 L-시스테인 염류 0.1 내지 8중량%, DL-시스테인 염류 0.1 내지 8중량%, 티오글리콜산 0.1 내지 8중량%의 조성을 가질 수 있다. 환원제의 함량이 너무 적으면, 향상된 환원력, 즉, 웨이브나 스트레이트 성형력과 모발의 볼륨감이 저하되고, 환원제의 함량이 30중량%를 초과하면, 지나친 모발 손상이 우려되는 문제가 있다.
More preferably, the composition may have a composition of 0.1 to 8% by weight of L-cysteine salt, 0.1 to 8% by weight of DL-cysteine salt, and 0.1 to 8% by weight of thioglycolic acid. If the content of the reducing agent is too small, the improved reducing power, that is, the wave or straight forming power and the volume of the hair is reduced, if the content of the reducing agent exceeds 30% by weight, there is a problem that excessive hair damage.
본 발명에서 알칼리제는 상기 환원제와 더불어 모발의 변형성 즉, 모발에 향상된 볼륨을 부가시켜주기 위한 물질로서, 모발 중의 염 결합을 절단하여 팽윤시킴으로써 조성물 내 구성성분들이 모발 안까지 침투하는 것을 촉진하고, 환원제의 작용을 돕는 역할을 한다. 본 발명에 이용될 수 있는 알칼리제로는 에탄올아민, 수산화나트륨, 수산화칼륨, 탄산나트륨, 탄산칼륨 및 이들의 혼합물을 이용할 수 있으며, 바람직하게는 에탄올아민이나, 이에 제한되는 것은 아니다. 또한, 상기 알칼리제의 조성물 내 함량은 원하는 스타일링의 강도나 제형 등에 따라 달라질 수 있으나, 바람직하게는 조성물 총 중량을 기준으로 0.1 내지 10중량%로 포함될 수 있고, 더욱 바람직하게는 모노에탄올아민을 0.1 내지 8중량%로 포함할 수 있다. 알칼리제의 함량이 10중량%를 초과하면, 두피 및 모발이 지나치게 손상되는 문제가 있다.
In the present invention, the alkali agent is a material for adding the deformability of the hair, ie, an improved volume to the hair, together with the reducing agent, and promotes penetration of the components in the composition into the hair by cutting and swelling the salt bond in the hair. It helps to work. As the alkaline agent that can be used in the present invention, ethanolamine, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and mixtures thereof may be used, and preferably ethanolamine, but is not limited thereto. In addition, the content of the alkali agent may vary depending on the strength or formulation of the desired styling, but may preferably be included in an amount of 0.1 to 10% by weight based on the total weight of the composition, and more preferably 0.1 to 10% monoethanolamine. It may include 8% by weight. If the content of the alkali agent exceeds 10% by weight, there is a problem that the scalp and hair is excessively damaged.
본 발명의 조성물은 알콜을 포함하는데, 이는 본 발명의 조성물이 적정 수준의 액상 제형을 갖도록 하며, 여러 가지 구성 성분들이 균질하게 퍼져있을 수 있도록 하는 용제의 역할을 한다. 또한, 이러한 알콜 용제는 모발의 웨이브 형성 효능을 증가시키게 된다. 본 발명에 이용될 수 있는 알콜로는 에틸알콜, 프로필알콜, 이소프로필알콜, 부틸알콜 및 이들의 혼합물을 이용할 수 있으며, 바람직하게는 에틸알콜이나, 이에 제한되는 것은 아니다. 상기 알콜의 조성물 내 함량은 제형에 따라 달라질 수 있나, 바람직하게는 조성물 총 중량을 기준으로 0.1 내지 50중량%로 포함될 수 있고, 더욱 바람직하게는 20 내지 30중량%이다.
The composition of the present invention comprises an alcohol, which allows the composition of the present invention to have an appropriate level of liquid formulation and serves as a solvent to allow the various components to be homogeneously spread. In addition, these alcoholic solvents increase the wave forming efficacy of the hair. As alcohols that may be used in the present invention, ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol and mixtures thereof may be used, preferably ethyl alcohol, but is not limited thereto. The content of the alcohol in the composition may vary depending on the formulation, but may preferably be included in 0.1 to 50% by weight, more preferably 20 to 30% by weight based on the total weight of the composition.
본 발명에서, 상기 보습제는 두피 및 모발에 보습효과를 제공하기 위한 것으로서, 이러한 효과를 낼 수 있는 물질이면, 특별히 제한되지 않으며, 통상의 모발 스타일링제에 포함될 수 있는 공지의 성분을 이용할 수 있고, 예를 들면, 디메치콘, 아모디메치콘, 디메치콘코폴리올 및 이들의 혼합물 등이 가능하며, 바람직하게는 디메치콘 및 아모디메치콘을 혼합하여 사용할 수 있다. 또한, 상기 보습제의 조성물 내 함량은 바람직하게는 조성물 총 중량을 기준으로 0.1 내지 10중량%로 포함될 수 있고, 더욱 바람직하게는 디메치콘 0.1~10중량% 및 아모디메치콘 0.1~10중량%이다.
In the present invention, the moisturizing agent is to provide a moisturizing effect to the scalp and hair, if the material that can produce such an effect is not particularly limited, it is possible to use known ingredients that can be included in conventional hair styling agents, For example, dimethicone, amodimethicone, dimethicone copolyol, mixtures thereof, and the like are possible, and preferably, dimethicone and amodimethicone may be mixed and used. In addition, the content in the composition of the moisturizing agent may preferably be included in 0.1 to 10% by weight based on the total weight of the composition, more preferably 0.1 to 10% by weight of dimethicone and 0.1 to 10% by weight of amodimethicone. .
본 발명에서 이용될 수 있는 유화제로는 통상의 모발 스타일링제에 포함될 수 있는 유화제가 가능하며, 예를 들면, 라우레스-23을 사용할 수 있다.
Emulsifiers that can be used in the present invention may be emulsifiers that can be included in conventional hair styling agents, for example, laureth-23 can be used.
본 발명의 조성물은 상기한 환원제, 알칼리제, 알콜, 보습제 및 유화제 외에 모발이나 두피를 보호하기 위한 추가의 구성성분, 즉, 가수분해 실크 단백질 및 천연 식물성분을 포함함을 특징으로 한다.The composition of the present invention is characterized in that in addition to the reducing agents, alkalis, alcohols, humectants and emulsifiers described above, additional components for protecting the hair or the scalp, namely hydrolyzed silk proteins and natural plant components.
상기 가수분해 실크 단백질은 모발을 실리콘 폴리머로 코팅함으로써, 열에 의한 손상을 막아주는 보호 필름을 형성시켜주는 역할을 한다. 상기 가수분해 실크 단백질의 함량은 조성물 총 중량에 대하여 0.0001 내지 5중량%로 포함되는 것이 바람직하다. 상기 범위에서 열에 의한 모발 손상을 완화시키는 효과가 우수하다.The hydrolyzed silk protein serves to form a protective film that prevents heat damage by coating the hair with a silicone polymer. The content of the hydrolyzed silk protein is preferably included in 0.0001 to 5% by weight based on the total weight of the composition. It is excellent in the effect of alleviating hair damage by heat in the above range.
본 발명의 조성물에 포함될 수 있는 천연 식물성분으로는 알로에 베라(Aloe vera)잎 추출물이 바람직하며, 두피 및 모발에 영양을 공급해주는 공지의 천연물 추출물을 이용할 수 있다.As a natural plant component that may be included in the composition of the present invention, Aloe vera leaf extract is preferable, and a known natural product extract that provides nutrition to the scalp and hair may be used.
알로에 베라의 학명은 알로에 발바덴시스 밀러(Aloe barba-densis miller)로서 80가지 이상의 유효 성분들을 함유하고 있다. 상기 알로에 베라 추출물은 두피에 수분 보호막을 생성하여 두피의 보습 및 진정효과가 매우 우수하며, 상처 치유 및 세포 재생에도 우수한 효과를 나타낸다. 특히 상기 알로에 베라 추출물은 비만세포(Mast cell)에서 히스타민(Histimine), 물질 P(Substance P)등의 알러지 유발물질의 유리를 억제하는 효과가 있어 두피의 염증 및 알러지 예방/완화에 유용하게 사용될 수 있다.Aloe vera's scientific name is Aloe barba-densis miller, which contains more than 80 active ingredients. The aloe vera extract has a very good moisturizing and soothing effect of the scalp by creating a water barrier on the scalp, and also shows an excellent effect on wound healing and cell regeneration. In particular, the aloe vera extract has the effect of inhibiting the release of allergens such as histamine (Histimine), substance P (Substance P) in mast cells can be useful for preventing / alleviating inflammation and allergy of the scalp have.
헤나는 1~5m의 높이까지 자라는 Lawsonia inermis라고 알려진 식물로서, 이 식물의 잎사귀는 탄닌산이라는 자연 염색 속성을 지니고 있어 잎사귀를 햇볕에 말려 곱게 빻아 분말로 사용하기도 한다. 상기 헤나는 손상된 모발을 건강하게 개선시켜 주고, 인체에 무해한 천연재료로 두피의 화끈거림이나 따끔함이 없으며, 모발의 손질을 용이하게 해주고, 두피를 중화시킴으로써 과다피지분비를 억제하며, 머리끝 갈라짐을 방지하고, 모발의 탄력성과 선명한 빛깔을 부여하는 것으로 알려져 있다.
Henna is a plant known as Lawsonia inermis that grows to a height of 1 to 5 meters. The leaf has a natural dyeing property called tannic acid, which is dried in the sun and ground finely to use as a powder. The henna improves the damaged hair healthily, there is no harm or scalp of the scalp with natural ingredients harmless to the human body, facilitates the care of the hair, neutralizes the scalp, inhibits excessive sebum secretion, and prevents hair splitting It is known to prevent and give hair elasticity and vivid color.
본 발명의 조성물에 포함되는 상기 알로에 베라잎 추출물 및 헤나 추출물의 각 함량은 조성물의 제형이나 기호도에 따라 달라질 수 있으나, 조성물 총 중량에 대하여 각각 0.0001 내지 10 중량%으로 함유되는 것이 바람직하다.Each content of the aloe vera leaf extract and henna extract included in the composition of the present invention may vary depending on the formulation or preference of the composition, it is preferably contained in 0.0001 to 10% by weight relative to the total weight of the composition.
또한, 본 발명의 조성물에 포함되는 알로에 베라잎 및 헤나는 자연상태 그대로, 건조상태 또는 건조물을 세절하거나 분말상태로 하여 통상적인 추출 방법, 예를 들면 열수 추출 또는 유기용매로 추출하여 사용할 수 있다.In addition, the aloe vera leaf and henna included in the composition of the present invention may be used as it is in a natural state, dried or dried in fine or powdered form, using a conventional extraction method such as hot water extraction or an organic solvent.
본 발명의 조성물에 사용하는 천연물 추출물의 통상적인 제조방법은, 건조한 식물을 세절한 후, 건조 식물 무게의 약 3배 내지 20배의 물, 저급 알콜 또는 이들의 혼합용매, 유기용매, 또는 1,3-부틸렌글리콜과 무수알콜의 혼합용매로 실온 내지 100℃의 추출온도에서 약 6시간 내지 10일 동안 열수추출, 냉침추출, 초음파 추출 또는 환류냉각 추출 등의 추출방법에 의하여 1회 내지 5회 반복하여 추출한 후, 추출물을 여과하여 제조하거나, 상기 추출물을 추가로 감압농축 또는 동결건조시켜 사용할 수 있다. 이때, 상기 저급알콜은 C1 내지 C4의 탄소수를 갖는 저급알콜을 포함하며, 상기 유기용매는 에틸아세테이트, 클로로포름, 헥산, 디클로로메탄과 같은 비극성 용매를 포함하고, 용매를 생약 무게의 3배 이상을 사용하는 것이 바람직한 추출효과를 나타내며, 20배 이상을 사용할 때는 용매가 추출량에 비하여 많이 소요되는 경향이 있다.
Conventional methods for producing natural extracts for use in the compositions of the present invention, after cutting the dry plants, water of about 3 to 20 times the weight of the dry plant, lower alcohol or a mixed solvent, organic solvent, or 1, 1 to 5 times with a mixed solvent of 3-butylene glycol and anhydrous alcohol by extraction methods such as hot water extraction, cold extraction, ultrasonic extraction or reflux cooling extraction for about 6 hours to 10 days at the extraction temperature of room temperature to 100 ℃ After repeated extraction, the extract may be prepared by filtration, or the extract may be further concentrated under reduced pressure or lyophilized. At this time, the lower alcohol includes a lower alcohol having a carbon number of C 1 to C 4 , the organic solvent includes a non-polar solvent such as ethyl acetate, chloroform, hexane, dichloromethane, the solvent is at least three times the weight of the herbal medicine It is preferable to use the same, and when using 20 times or more, the solvent tends to take much more than the extraction amount.
본 발명의 조성물은 상기한 구성성분들 외에 두피 및 모발에 영양을 공급해줄 수 있는 다른 천연물 추출물, 바람직하게는 당약 추출물, 시카카이 추출물, 녹차 추출물 또는 인디언 구즈베리 추출물을 단독으로 또는 혼합하여 추가로 포함할 수 있다.In addition to the above components, the composition of the present invention may further be used alone or in combination with other natural product extracts, such as sugar extracts, shikakai extracts, green tea extracts or Indian gooseberries extracts, which may provide nutrition to the scalp and hair. It may include.
또한, 본 발명의 조성물은 천연물 추출물 외에도, 두피 및 모발에 영양을 공급해줄 수 있는 공지의 물질, 예를 들어, 철분, 칼슘, 망간, 아미노산, 염산 피리독신, 비오틴, 비타민 B1, 비타민 B2, 비타민 B6, 비타민 D 및 엽산 등의 비타민 또는 비타민 전구체, 폴리쿼터늄-7, 트리세틸모늄클로라이드, 세틸트리메칠암모늄클로라이드, 세테아릴알코올, 케라틴 등을 추가로 포함할 수 있으며, 바람직하게는 두피 및 모발의 보습 및 보호 기능을 하는 것으로 알려진 판테놀, 피탄트리올, 토코페릴아세테이트, 올리브오일, 호호바오일, 또는 동백오일을 추가로 포함할 수 있다.
In addition, the composition of the present invention, in addition to natural extracts, known substances that can nourish the scalp and hair, for example, iron, calcium, manganese, amino acids, pyridoxine hydrochloride, biotin, vitamin B1, vitamin B2, vitamin B6 , Vitamin D and vitamin precursors such as vitamin D and folic acid, polyquaternium-7, tricetylmonium chloride, cetyltrimethylammonium chloride, cetearyl alcohol, keratin and the like may be further included, preferably scalp and Panthenol, phytantriol, tocopheryl acetate, olive oil, jojoba oil, or camellia oil, which are known to serve as a moisturizing and protective function of hair, may further be included.
한편, 본 발명의 조성물에 포함되는 각 구성 성분은 조성물 총 중량을 기준으로 환원제 0.1~30중량%, 알칼리제 0.1~10중량%, 알콜 0.1~50중량%, 보습제 0.1~20중량%, 유화제 0.1~10중량%, 가수분해 실크 단백질 0.0001~5중량%, 알로에 베라잎 추출물 0.1~10중량% 및 헤나 추출물 0.1~10중량%으로 함유되는 것이 바람직하다. 또한, 더욱 바람직하게는 L-시스테인 염류 0.1~8중량%, DL-시스테인 염류 0.1~8중량%, 티오글리콜산 0.1~8중량%, 모노에탄올아민 0.1~8중량%, 에틸알콜 0.1~50중량%, 디메치콘 0.1~10중량%, 아모디메치콘 0.1~10중량% 및 라우레스-23 0.1~10중량%으로 조성될 수 있다.
On the other hand, each component contained in the composition of the present invention is 0.1 to 30% by weight of reducing agent, 0.1 to 10% by weight of alkaline agent, 0.1 to 50% by weight of alcohol, 0.1 to 20% by weight of moisturizer, 0.1 to emulsifier based on the total weight of the composition It is preferably contained in 10% by weight, 0.0001-5% by weight of hydrolyzed silk protein, 0.1-10% by weight of aloe vera leaf extract and 0.1-10% by weight of henna extract. More preferably, 0.1 to 8% by weight of L-cysteine salt, 0.1 to 8% by weight of DL-cysteine salt, 0.1 to 8% by weight of thioglycolic acid, 0.1 to 8% by weight of monoethanolamine, 0.1 to 50% by weight of ethyl alcohol %, Dimethicone 0.1 to 10% by weight, amodimethicone 0.1 to 10% by weight and laureth-23 may be composed of 0.1 to 10% by weight.
본 발명의 조성물은 일반적인 두피 및 모발용 외용제제에 배합될 수 있는 기제 성분을 필요에 따라 추가로 포함할 수 있다. 구체적으로는 용해보조제, 점증제, pH 조정제, 방부제, 산화방지제, 금속이온봉쇄제, 살균제, 항염증제, 항미생물제, 용제, 착색제 또는 착향제 등을 포함할 수 있다.The composition of the present invention may further include a base component that can be blended in general scalp and external preparation for hair. Specifically, dissolution aids, thickeners, pH adjusters, preservatives, antioxidants, metal ion sequestrants, fungicides, anti-inflammatory agents, antimicrobial agents, solvents, colorants or flavoring agents may be included.
본 발명의 조성물에 포함될 수 있는 용해보조제는 이소프로필 미리스테이트, 폴리에틸렌 글리콜, 중쇄 지방산 트리글리세리드, 탄화수소, 글리콜류 등이 될 수 있다. 또한, 점증제는 메틸셀룰로스, 하이드록시에틸셀룰로스, 카라기난, 카르복시메틸셀룰로스, 하이드록시메틸셀룰로스 등의 수용성 고분자 화합물이 될 수 있다. 또한, pH 조정제는 구체적으로 구연산, 수산화나트륨, 트리에탄올아민, 구연산나트륨, 인산, 인산나트륨, 젖산 등이 가능하다.Dissolution aids that may be included in the composition of the present invention may be isopropyl myristate, polyethylene glycol, medium chain fatty acid triglycerides, hydrocarbons, glycols and the like. In addition, the thickener may be a water-soluble high molecular compound such as methyl cellulose, hydroxyethyl cellulose, carrageenan, carboxymethyl cellulose, hydroxymethyl cellulose and the like. In addition, the pH adjusting agent may be specifically citric acid, sodium hydroxide, triethanolamine, sodium citrate, phosphoric acid, sodium phosphate, lactic acid and the like.
방부제는 벤조산, 파라옥시안식향산에스테르, 메칠클로로이소치아졸리논의 혼합물, 페녹시에탄올, 디엠디엠히단토인 등이 될 수 있으며, 산화방지제는 구체적으로 디부틸히드록시톨루엔, 아스코르빈산 등이 가능하다. 또한, 금속이온봉쇄제는 에칠렌디아민테트라초산디나트륨,에칠렌디아민테트라초산테트라나트륨 등이 가능하며, 살균제는 구체적으로 클로르헥시딘 글루코네이트, 4급 암모늄염, 피록톤올아민, 아연피리치온 현탁액, 요도프로피닐 부틸카바메이트, 살리실산 등이 될 수 있다.Preservatives may be benzoic acid, paraoxybenzoic acid esters, mixtures of methylchloroisothiazolinone, phenoxyethanol, DMDM hydantoin, and the like, and antioxidants may specifically include dibutylhydroxytoluene, ascorbic acid, and the like. Examples of the metal ion sequestrant include disodium ethylenediamine tetraacetate, tetranodium ethylenediamine tetraacetate, and the like. Specifically, the disinfectant may be chlorhexidine gluconate, quaternary ammonium salt, pyrrothonol amine, zinc pyrithione suspension, urethropropinyl Butylcarbamate, salicylic acid, and the like.
또한, 항염증성분으로는 글리시리진산모노암모늄, 글리시리진산디칼륨, 스테아릴글리시리지네이트, 카모마일, 알파 비사보롤, 알란토인 및 이들의 혼합물 등이 가능하며, 항균(항미생물)성분은 구체적으로 페녹시에탄올, 클로르헥시딘, 클로르헥시딘 글루코네이트, 피록톤올아민, 케토코나졸, 아르니카추출물, 요도프로피닐부틸카바메이트, 벤잘코늄클로라이드, 벤젠토늄클로라이드, 벤조산 및 그의 염, 벤질알코올, 라벤다, 로즈마리, 살리실산, 트리클로카르반, 아연피리치온 현탁액 및 그들의 혼합물 등을 사용할 수 있다. 또한, 착색제와 착향제는 두피 및 모발용 제제에 사용되는 통상의 기제들을 사용할 수 있다.
In addition, anti-inflammatory components include monoammonium glycyrrhinate, dipotassium glycyrrhinate, stearyl glycyrizinate, chamomile, alpha bisabolol, allantoin, and mixtures thereof, and antibacterial (antimicrobial) components are specifically phenoxy. Ethanol, chlorhexidine, chlorhexidine gluconate, pyroxtonolamine, ketoconazole, arnica extract, iodopropynylbutylcarbamate, benzalkonium chloride, benzenetonium chloride, benzoic acid and salts thereof, benzyl alcohol, lavender, rosemary, salicylic acid, triclocarban, zinc Pyrithione suspensions, mixtures thereof and the like can be used. In addition, colorants and flavoring agents can be used conventional bases used in the preparation for scalp and hair.
본 발명의 상기 조성물은 4.0 내지 8.0 범위의 pH를 갖는 것이 바람직하며, 더욱 바람직하게는 약 6.5의 pH를 갖는다. 이러한 pH는 조성물 내에 포함되는 구성성분들, 예를 들면, 환원제, 알칼리제 및 pH조절제 등의 농도 및 함량 조절을 통해 조정될 수 있다. 상기 범위의 pH에서 본 발명의 모발 스타일링 개선용 조성물이 안정적으로 분산되며, 모발 및 두피자극을 효과적으로 억제할 수 있다.
The composition of the present invention preferably has a pH in the range of 4.0 to 8.0, more preferably has a pH of about 6.5. Such pH may be adjusted through concentration and content control of the components included in the composition, such as reducing agents, alkaline agents and pH adjusting agents. The composition for improving hair styling of the present invention is stably dispersed at a pH in the above range, and hair and scalp stimulation can be effectively suppressed.
또 다른 양태로서, 본 발명은 상기한 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물을 함유하는 모발 스타일링 제제에 관한 것이다.In still another aspect, the present invention relates to a hair styling preparation containing the above-described permanent wave and a composition for improving hair styling having a straight volume.
본 발명의 상기 조성물은 상기 주요 구성성분 이외에 안정화제, 용해화제, 안료 및 향료와 같은 통상적인 보조제 및 담체를 포함할 수 있으며, 담체와 함께 제형화하여 모발 스타일링 제제로 제조될 수 있다.The composition of the present invention may include, in addition to the main components, conventional adjuvants and carriers such as stabilizers, solubilizers, pigments and flavors, and may be formulated with the carrier to prepare a hair styling formulation.
본 발명의 조성물은 당업계에서 통상적으로 제조되는 어떠한 제형으로도 제조될 수 있으며, 바람직하게는 유액, 크림, 페이스트, 겔, 화장수, 로션, 스프레이 등의 모발처리용 화장품으로 제형화될 수 있다. 구체적으로는 헤어토너, 헤어로션, 헤어크림, 헤어스프레이, 헤어무스, 헤어젤 등의 제형을 가질 수 있으나, 1제형 액상 타입을 갖도록 제제화되는 것이 가장 바람직하다.
The composition of the present invention may be prepared in any formulation commonly prepared in the art, and may be preferably formulated into a hair treatment cosmetic such as emulsion, cream, paste, gel, lotion, lotion, spray, and the like. Specifically, hair toner, hair lotion, hair cream, hair spray, hair mousse, hair gel, etc. may have a formulation, but is most preferably formulated to have a one-part liquid type.
본 발명의 조성물 제형이 페이스트, 크림 또는 겔인 경우에는 담체 성분으로서 동물섬유, 식물섬유, 왁스, 파라핀, 전분, 트라칸트, 셀룰로오스 유도체, 폴리에틸렌 글리콜, 실리콘, 벤토나이트, 실리카, 탈크 또는 산화아연 등이 이용될 수 있다.When the composition formulation of the present invention is a paste, cream or gel, animal fibers, plant fibers, waxes, paraffins, starches, tracantes, cellulose derivatives, polyethylene glycols, silicones, bentonites, silicas, talc or zinc oxide are used as carrier components. Can be.
또한, 본 발명의 조성물 제형이 스프레이인 경우에는 담체 성분으로서 락토스, 탈크, 실리카, 알루미늄 히드록시드, 칼슘 실리케이트 또는 폴리아미드 파우더가 이용될 수 있고, 클로로플루오로히드로카본, 프로판/부탄 또는 디메틸 에테르와 같은 추진체를 포함할 수 있다.In addition, when the composition formulation of the present invention is a spray, lactose, talc, silica, aluminum hydroxide, calcium silicate or polyamide powder may be used, and chlorofluorohydrocarbon, propane / butane or dimethyl ether may be used. It may include a propellant such as.
본 발명의 조성물 제형이 용액 또는 유탁액의 경우에는 담체 성분으로서 용매, 용매화제 또는 유탁화제가 이용되고, 예컨대 물, 에탄올, 이소프로판올, 에틸 카보네이트, 에틸 아세테이트, 벤질 알코올, 벤질 벤조에이트, 프로필렌 글리콜, 1,3-부틸글리콜 오일, 글리세롤 지방족 에스테르, 폴리에틸렌 글리콜 또는 소르비탄의 지방산 에스테르를 이용할 수 있다. 또한, 본 발명의 제형이 현탁액인 경우에는 담체 성분으로서 물, 에탄올 또는 프로필렌 글리콜과 같은 액상희석제, 에톡실화 이소스테아릴 알코올, 폴리옥시에틸렌 소르비톨 에스테르 및 폴리옥시에틸렌 소르비탄 에스테르와 같은 현탁제, 미소결정성 셀룰로오스, 알루미늄 메타히드록시드, 벤토나이트, 아가 또는 트라칸트 등을 이용할 수 있다.
When the composition formulation of the present invention is a solution or emulsion, a solvent, solvating or emulsifying agent is used as the carrier component, such as water, ethanol, isopropanol, ethyl carbonate, ethyl acetate, benzyl alcohol, benzyl benzoate, propylene glycol, Fatty acid esters of 1,3-butylglycol oil, glycerol aliphatic esters, polyethylene glycols or sorbitan can be used. Further, when the formulation of the present invention is a suspension, liquid carrier diluents such as water, ethanol or propylene glycol, suspending agents such as ethoxylated isostearyl alcohol, polyoxyethylene sorbitol ester and polyoxyethylene sorbitan ester, Crystalline cellulose, aluminum metahydroxy, bentonite, agar or tracant and the like can be used.
또 다른 양태로서, 본 발명은 (a) 모발을 세척한 후, 건조하는 단계; (b) 본 발명의 조성물을 건조된 모발에 도포하는 단계; 및 (c) 헤어 스타일링 기기로 모발을 웨이브 또는 스트레이트하여 스타일링하는 단계;를 포함하며, 상기 스타일링의 볼륨은 하루 내지 이틀 정도 지속되는 것을 특징으로 하는, 모발 스타일링 방법에 관한 것이다.In still another aspect, the present invention provides a method for cleaning a hair comprising: (a) washing the hair and then drying the hair; (b) applying the composition of the present invention to dried hair; And (c) styling the hair by wave or straightening the hair with a hair styling device, wherein the volume of the styling lasts for one to two days.
본 발명의 상기 모발 스타일링 방법은 세척 및 건조된 모발에 본 발명의 조성물을 도포한 후, 별도의 세척과정 없이 바로 드라이, 아이롱, 롯드 및 고데기 등의 헤어 스타일링 기기로 모발을 웨이브 또는 스트레이트하는 것만으로도 원하는 형태로 간편하게 스타일링할 수 있는 특징이 있다. 이때, 상기 헤어 스타일링 기기는 열을 가한 상태에서 이용하는 것이 바람직하다. 또한, 상기 조성물의 헤어 스타일링 볼륨은 모발을 세발하지 않는 한 장시간 지속될 수 있으나, 바람직하게는 하루 내지 이틀 정도 지속되고, 이후에는 원래 상태로 회복된다.
In the hair styling method of the present invention, after applying the composition of the present invention to the washed and dried hair, just wave or straight hair with a hair styling device, such as dry, iron, rod and curling iron, without a separate washing process There is also a feature that can be easily styled in the desired form. In this case, the hair styling device is preferably used in a state of applying heat. In addition, the hair styling volume of the composition may last for a long time as long as the hair is not triturated, but preferably lasts for one to two days, and then returns to its original state.
이하, 본 발명의 바람직한 실시예를 통해 본 발명의 구성 및 작용을 더욱 상세히 설명하기로 한다. 다만, 하기 실시예는 본 발명의 이해를 돕기 위한 것으로, 본 발명의 범위가 하기 실시예에 한정되지는 않는다. 여기에 기재되지 않은 내용은 이 기술 분야에서 숙련된 자이면 충분히 기술적으로 유추할 수 있는 것이므로 그 설명을 생략하기로 한다.
Hereinafter, the configuration and operation of the present invention will be described in more detail with reference to preferred embodiments of the present invention. However, the following examples are provided to aid understanding of the present invention, and the scope of the present invention is not limited to the following examples. Details that are not described herein will be omitted since the description can be inferred by those skilled in the art.
실시예 1~3 및 비교예 1~3. 모발 스타일링 개선용 제제의 제조Examples 1-3 and Comparative Examples 1-3. Preparation of preparations for improving hair styling
하기 표 1의 실시예1~3, 및 비교예 1~3의 구성성분을 각 조성으로 혼합하여 이를 포함하는 모발 스타일링 개선용 제제를 각각 제조하였다. 구체적으로 실시예 1~3은 본원 발명에 따른 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물을 포함하도록 하였으며, 각 제제는 액상 제형을 갖도록 제조하였다.
Tables 1 to 3, and Comparative Examples 1 to 3, the components of the composition was mixed to each composition to prepare a hair styling improvement comprising the same. Specifically Examples 1 to 3 were to include a composition for improving hair styling having a permanent wave and a straight volume according to the present invention, each formulation was prepared to have a liquid formulation.
실험예Experimental Example 1. 웨이브 형성 효율 시험 1. Wave Forming Efficiency Test
상기 실시예 1 내지 3, 및 비교예 1 내지 3에서 제조한 각각의 제제를 사용하여 웨이브 형성 효율을 시험하였다.Wave formation efficiency was tested using the respective formulations prepared in Examples 1-3 and Comparative Examples 1-3 above.
웨이브 형성 효율 측정은 키르비 법에 의한 도 3 및 도 4의 웨이브 형성 시험 기구에 의하여 측정하였다. 구체적으로, 길이 15~20cm 건강 모발 조각(Swatch) 묶음을 도 3의 플라스틱 기구 한쪽에 고정시키고, 교대로 핀봉에 지그재그로 걸어 나머지 한쪽을 고정시켰다. 핀봉에 고정시킨 모발을 실시예 1~3 및 비교예 1~3의 제제가 담긴 샤렛에 침적 후 45℃의 항온조에 2분 동안 방치시켰다. 방치 후 고정시킨 모발을 풀고 건조하여 웨이브가 형성된 모발을 눈금 달리 유리판에 자연스럽게 고정시켜 다음 수학식 1에 따라 웨이브 형성 효율을 산출하였으며, 그 결과를 하기 표 5에 나타내었다.
The wave formation efficiency measurement was measured by the wave formation test apparatus of FIGS. 3 and 4 by the Kirby method. Specifically, a bundle of 15-20 cm long healthy hair Swatch was fixed to one side of the plastic apparatus of FIG. 3 and alternately zigzag to the pin rod to fix the other side. The hair fixed to the pin bar was immersed in a shalet containing the formulations of Examples 1 to 3 and Comparative Examples 1 to 3 and left in a thermostat at 45 ° C. for 2 minutes. After standing, the fixed hair was loosened and dried to naturally fix the hair on which the wave was formed on the glass plate differently from the grid, and the wave forming efficiency was calculated according to the following Equation 1, and the results are shown in Table 5 below.
상기 수학식 1에서, a는 기구의 제 1번 봉과 제 6번 봉 사이의 거리이고, b는 웨이브가 형성된 모발의 5개 산의 거리이고, c는 웨이브가 형성된 모발의 5개 산을 직선으로 하였을 때의 거리를 나타낸다.
In Equation 1, a is the distance between the first rod and the sixth rod of the instrument, b is the distance of five peaks of the waved hair, and c is a straight line of the five peaks of the waved hair. The distance when it is shown is shown.
실험예Experimental Example 2. 웨이브 지속성 시험 2. Wave persistence test
웨이브가 형성된 모발 묶음 조각(Swatch)을 30% 소듐라우릴설페이트 용액(pH=8.5), 상기 제조된 실시예 1~3 및 비교예 1~3의 제제가 각각 담긴 시험관에 담근 후 45℃ 항온에서 20분간 방치시켰다. 방치 후 시험관에서 꺼내어 건조시킨 후, 눈금 달린 유리판에 자연스럽게 고정시켜 웨이브 형성 효율식으로 지속성 시험 후의 웨이브 효율을 산출하고 다음 수학식 2의 다음 웨이브 지속성 유지율을 산출하였으며, 그 결과를 다음 표 5에 나타내었다.
The wave-formed hair bundle (Swatch) was immersed in a test tube containing 30% sodium lauryl sulfate solution (pH = 8.5), the preparations of Examples 1 to 3 and Comparative Examples 1 to 3, respectively, at 45 ° C. at a constant temperature. It was left for 20 minutes. After being left out of the test tube and left to dry, it was naturally fixed on a graduated glass plate, and the wave efficiency after the sustainability test was calculated by the wave formation efficiency formula, and the next wave persistence retention ratio of the following Equation 2 was calculated, and the results are shown in Table 5 below. It was.
실험예Experimental Example 3. 모발 손상 시험 3. hair damage test
1) 길이 15~20cm의 탈색모, 염색모, 정상 모발 조각(Swatch)을 삼푸하고 타올 드라이하였다. 타올 건조한 모발에 상기 실시예1~3 및 비교예1~3 제제를 균일하게 도포한 후 롤에 일정한 힘으로 감고 2분 방치하면서 드라이로 열을 가한 후, 건조한 모발 조각과 처리 전 모발 조각을 가지고 섬프(Sump)법으로 머리카락을 탁본하여 현미경으로 관찰하여 피질(Cuticle)층의 손상 정도를 관찰하였으며, 그 결과를 다음 표 5에 나타내었다.1) 15-20cm in length, bleached hair, dyed hair, normal hair swatch (Swatch) was swallowed and towel dry. After uniformly applying the formulation of Examples 1 to 3 and Comparative Examples 1 to 3 on the towel dry hair, and then wound with a constant force on a roll and left to heat for 2 minutes, after drying with dry hair pieces and hair pieces before treatment The hair was collected by the sump method and observed under a microscope to observe the degree of damage of the cuticle layer. The results are shown in Table 5 below.
2) 상기 1)에서 사용한 것과 동일 모델의 모발을 2 등분하여(Half Test) 삼푸하고 타올 건조한 모발에 상기 실시예1~3 및 비교예1~3 제제를 균일하게 도포한 후 롯드에 일정한 힘으로 감고 2분 방치하면서 드라이로 열을 가한 후 건조한 모발 조각에 대한 빗질 감으로 상대 비교하였다.
2) After splitting the hair of the same model as used in 1) above (Half Test), apply the formulations of Examples 1 to 3 and Comparative Examples 1 to 3 uniformly to dry and towel-dried hair with a constant force on the rod. After drying for 2 minutes while drying, the relative comparison was performed by combing dry hair pieces.
실험예 4. 시술 후 냄새 및 볼륨 유지효과 측정Experimental Example 4. Measurement of odor and volume retention effect after procedure
상기 웨이브 형성 효율시험(실험예 1)을 끝낸 각각의 모발 조각(Swatch)과, 웨이브 지속성 시험(실험예 2)을 끝낸 각각의 모발 조각(Swatch)을 가지고 20 명이 시술 후 냄새 및 볼륨유지 효과를 관능 측정하였다.Each hair piece (Swatch) that completed the wave formation efficiency test (Experimental Example 1) and each hair piece (Swatch) that completed the wave persistence test (Experimental Example 2) has a odor and volume retention effect after 20 people Sensory measurements were made.
10대, 20대, 30대, 40대, 50대의 여자 모델을 각각 4명씩 선정하여 모발에 쎈타파트로 2 등분하여 실시예 1~3의 제제와, 비교예 1~3의 제제를 사용하여 퍼머넌트 웨이브 후 전문 미용사로부터 관능 측정하였다. 관능측정법으로는 직접 관능법으로 다음 표 2 및 표 3에 의하여 하기 표 5와 같은 결과를 얻었다.
Four female models in their teens, twenties, thirties, forties, and fifties were selected, and each was divided into two parts by hair tapping on the hair, and the permanents were prepared using the formulations of Examples 1 to 3 and the formulations of Comparative Examples 1 to 3. Sensory measurements were made from professional hairdressers after the wave. As a sensory measurement method, the results as shown in Table 5 below were obtained by the following direct sensory methods.
실험예Experimental Example 5. 5. 알러지allergy 반응 완화효과 시험 Response Mitigation Effect Test
본 발명의 알러지 반응에 대한 완화효과를 확인하기 위하여 각 추출물을 글리세린과 계면활성제를 이용한 간단한 제형에 혼합하여 사람 피부의 알러지 반응 억제 효과를 평가하였다. 시험 대상은 10~50대 남자 및 여자로 하였으며, 귀의 뒤쪽 머리카락이 난 주변의 피부를 비누 등으로 깨끗이 씻고, 히스타민 유리촉진제인 컴파운드 48/80을 도포하여 피부를 자극하여 알러지 반응을 일으켰다. 그 다음에 실시예1~3 및 비교예 1~3을 각각 동전 크기로 바르고, 48시간 방치 후 물로 씻은 후, 그 주위 피부의 반점, 홍점, 검은 반점, 부어오름, 가려움 등을 관찰하여 하기 표 4의 기준을 통해 결정하여 그 결과를 하기 표 5에 나타내었다.
In order to confirm the alleviating effect on the allergic reaction of the present invention, each extract was mixed with a simple formulation using glycerin and a surfactant to evaluate the allergic reaction inhibitory effect of human skin. The test subjects were males and females in their 10's and 50's. The skin around the back of the ear was washed with soap, etc. and the compound 48/80, a histamine glass accelerator, was applied to irritate the skin and cause an allergic reaction. Then apply Examples 1 to 3 and Comparative Examples 1 to 3 in the same size, and after 48 hours, washed with water, and then observed the spots, red spots, black spots, swelling, itching, etc. of the surrounding skin Determined through the criteria of 4 and the results are shown in Table 5 below.
각 실험예 1 내지 5의 실험결과를 하기 표 5에 나타내었다.
The experimental results of each of Experimental Examples 1 to 5 are shown in Table 5 below.
(%)Wave Forming Efficiency
(%)
(%)Wave persistence
(%)
상기 표 5에 나타난 바와 같이, 본 발명에 따른 실시예 1~3의 제제를 사용하여 펌 시술을 한 경우는 비교예 1~3의 제제를 사용하여 펌 시술을 한 경우와 비교하여 모발 손상이 적고, 두피 자극에 의한 알러지성 피부염을 효과적으로 완화시킬 수 있었다. 또한 빠른 시간 내에 안정적, 볼륨 및 탄력성이 우수한 컬 및 스트레이트를 형성할 뿐 아니라, 모발의 볼륨 유지력이 향상되고 시술 후 이취가 거의 없음을 확인할 수 있었다.As shown in Table 5, when the perm treatment using the formulations of Examples 1 to 3 according to the present invention is less hair damage than when the perm treatment using the formulations of Comparative Examples 1 to 3 In addition, allergic dermatitis caused by scalp irritation could be effectively alleviated. In addition, it was found that curling and straightening were excellent in forming stability, volume and elasticity in a short time, and the volume retention of the hair was improved and there was almost no off-flavor after the procedure.
일반적으로 펌 시술시, 웨이브를 부여할 경우나 스트레이트 효과를 부여할 경우에는 사용되는 기구의 모양만 상이 할 뿐 사용되는 약제 및 방치시간은 동일하므로 스트레이트너 제제로서의 실험예는 기재하지 않았으나, 그 효과는 동일하였다.
In general, when applying a wave or applying a straight effect when performing a perm treatment, only the shape of the apparatus used is different, and thus the chemicals used and the standing time are the same, so the experimental example as a straightener formulation is not described. Was the same.
Claims (12)
Reducing agent, alkali agent, alcohol, moisturizer, emulsifier, hydrolyzed silk protein, aloe vera leaf extract and henna extract, comprising a permanent wave and straight volume hair styling improvement composition.
상기 환원제는 시스테인, 시스테인 염류, 아세틸시스테인, 티오글리콜산, 티오글리콜산 염류, 티오아세트산, 티오글리세롤 및 이들의 혼합물로 이루어진 군으로부터 선택되고,
상기 알칼리제는 에탄올아민, 수산화나트륨, 수산화칼륨, 탄산나트륨, 탄산칼륨 및 이들의 혼합물로 이루어진 군으로부터 선택되고,
상기 알콜은 에틸알콜, 프로필알콜, 이소프로필알콜, 부틸알콜 및 이들의 혼합물로부터 선택되고,
상기 보습제는 디메치콘, 아모디메치콘, 디메치콘코폴리올 및 이들의 혼합물에서 선택되고,
상기 유화제는 라우레스-23이 선택되는 것을 특징으로 하는, 퍼머넌트웨이브 및 스트레이트 볼륨을 갖는 모발 스타일링 개선용 조성물.
The method of claim 1,
The reducing agent is selected from the group consisting of cysteine, cysteine salts, acetylcysteine, thioglycolic acid, thioglycolic acid salts, thioacetic acid, thioglycerol and mixtures thereof,
The alkali agent is selected from the group consisting of ethanolamine, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate and mixtures thereof,
The alcohol is selected from ethyl alcohol, propyl alcohol, isopropyl alcohol, butyl alcohol and mixtures thereof,
The humectant is selected from dimethicone, amodimethicone, dimethicone copolyol and mixtures thereof,
The emulsifier is Laures-23 is selected, the composition for improving hair styling having a permanent wave and straight volume.
The hair styling improvement composition of claim 1, further comprising one or more extracts selected from the group consisting of a medicinal extract, a shikakai extract, a green tea extract, and an Indian gooseberry extract.
The composition for improving hair styling of claim 1, further comprising panthenol, phytantriol, tocopheryl acetate, olive oil, jojoba oil or camellia oil.
According to claim 1, each component is 0.1 to 30% by weight reducing agent, 0.1 to 10% by weight, 0.1 to 10% by weight of alcohol, 0.1 to 50% by weight of alcohol, 0.1 to 20% by weight of moisturizer, 0.1 to 10% by weight based on the total weight of the composition , 0.0001-5% by weight of hydrolyzed silk protein, 0.1-10% by weight of aloe vera leaf extract and 0.1-10% by weight of henna extract, the composition for improving hair styling having a permanent wave and straight volume.
The hair styling improvement composition of claim 1, wherein each of the aloe vera leaf extract and the henna extract is 0.0001 to 10% by weight based on the total weight of the composition.
The composition for improving hair styling of claim 1, wherein the cysteine is L-cysteine or DL-cysteine, and the cysteine salt is L-cysteine hydrochloride or DL-cysteine hydrochloride.
The method according to claim 1 or 7, wherein 0.1 to 8% by weight of L-cysteine salt, 0.1 to 8% by weight of DL-cysteine salt, 0.1 to 8% by weight of thioglycolic acid, 0.1 to 8% by weight of monoethanolamine, ethyl alcohol Hair styling with permanent wave and straight volume, characterized in that it is composed of 0.1 to 50% by weight, dimethicone 0.1 to 10% by weight, amodimethicone 0.1 to 10% by weight and laureth-23 0.1 to 10% by weight. Improvement composition.
According to claim 1, wherein the composition is characterized in that it has a pH in the range of 4.0 to 8.0, the composition for improving hair styling having a permanent wave and straight volume.
A hair styling formulation containing the composition of claim 1.
The hair styling preparation of claim 10, wherein the preparation is a one-part liquid type.
(b) 제1항의 조성물을 건조된 모발에 도포하는 단계; 및
(c) 헤어 스타일링 기기로 모발을 웨이브 또는 스트레이트하여 스타일링하는 단계;를 포함하며, 상기 스타일링의 볼륨은 하루 내지 이틀 정도 지속되는 것을 특징으로 하는, 모발 스타일링 방법.
(a) washing the hair and then drying it;
(b) applying the composition of claim 1 to dried hair; And
(c) styling the hair by wave or straightening the hair with a hair styling device, wherein the volume of the styling lasts for one to two days.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016098956A1 (en) * | 2014-12-19 | 2016-06-23 | 이보미 | Dry-type permanent straightening and volumizing agent |
| WO2016171464A1 (en) * | 2015-04-20 | 2016-10-27 | (주)이지희컴퍼니 | Composition for scalp and hair, containing green tea water |
| KR20210025991A (en) * | 2019-08-28 | 2021-03-10 | (주)홈앤살롱 | Procedure Method of Clinic for Repairing Damaged Hair |
| KR20210025992A (en) * | 2019-08-28 | 2021-03-10 | (주)홈앤살롱 | Procedure Method for Minimizing Hair Damage |
| KR102416946B1 (en) * | 2021-10-25 | 2022-07-05 | 이진선 | Composition for Permanent Waving Comprising Graphene |
| KR102577048B1 (en) * | 2023-03-16 | 2023-09-12 | 자이언트코리아 주식회사 | Mist composition for improving hair gloss and moisturizing power |
-
2012
- 2012-05-31 KR KR1020120058701A patent/KR20130134856A/en not_active Ceased
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016098956A1 (en) * | 2014-12-19 | 2016-06-23 | 이보미 | Dry-type permanent straightening and volumizing agent |
| WO2016171464A1 (en) * | 2015-04-20 | 2016-10-27 | (주)이지희컴퍼니 | Composition for scalp and hair, containing green tea water |
| KR20210025991A (en) * | 2019-08-28 | 2021-03-10 | (주)홈앤살롱 | Procedure Method of Clinic for Repairing Damaged Hair |
| KR20210025992A (en) * | 2019-08-28 | 2021-03-10 | (주)홈앤살롱 | Procedure Method for Minimizing Hair Damage |
| KR102416946B1 (en) * | 2021-10-25 | 2022-07-05 | 이진선 | Composition for Permanent Waving Comprising Graphene |
| KR102577048B1 (en) * | 2023-03-16 | 2023-09-12 | 자이언트코리아 주식회사 | Mist composition for improving hair gloss and moisturizing power |
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