KR20090099164A - Permanent composition containing black mud - Google Patents

Abstract

A hair permanent composition containing a black mud is provided to ensure the effects of deodorization, moisturization, and hair protection and prevent irritation of scalp. A permanent composition comprises 0.5~10 weight% of black mud. The permanent composition contains 1.0 weight% of black mud, 0.2 weight% of etidronic acid, 2.4 weight% of ethanolamine thioglycolate, 8.0 weight% of L-cysteine monohydrochloride, 3.67 weight% of ethanol amine, 2.56 weight% of diethanol amine, 0.2 weight% of PEG-23M, 1.0 weight% of hydrolyzed collagen, 0.1 weight% of perfume and 62.23 weight% of distilled water.

Description

Permanent composition containing black mud {HAIR PERMANENT COMPOSITION COMPRISING BLACK MUD}

The present invention includes a black mud, which is a natural substance, to a permanent composition containing black mud, which can be expected to have a deodorizing effect, a hair protection and moisturizing effect, and a scalp irritation effect while maintaining the inherent wave formation and retention effect of the permanent composition. It is about.

Human hair consists of keratin ("hair keratin"), a tough fibrous protein that is high in sulfur. Hair keratin is exposed to various active substances that damage these structures in everyday life. For example, simple hair grooming and styling can result in loss of cuticle scales and further damage to the hair's endothelial cortex, resulting in hair damage. Permanent (shampooing) causes frictional damage of the cuticle scales, causing the hair protein to be extracted. The ultraviolet light of the sun reduces the mechanical strength of the hair and fades the color of natural hair and the color of the applied hair. Exposure to chlorinated water in the pool oxidizes the hair keratin and increases protein loss during combing or brushing.

The causes of such hair damage are direct exposure to reactive chemicals commonly used by hair stylists, such as wave permanents, hair dyes, bleaches, straighteners, peroxides, thio solutions, and sodium hydroxide. Hair damage is fatal.

In particular, recently, hair has been used as a way of expressing one's own personality, and hair is often dyed, or hair is trimmed using a perm or dry.

The shape of the hair is mainly formed by the cysteine being disulfide bond to become cystine and immobilized. Permanent processing of hair (particularly wave permanent hair processing) involves treating the hair with a permanent liquid (or treatment liquid) containing a reducing agent to cut or heat the disulfide bonds in keratin, and apply tension with a curler or the like. After forming a rod of a desired shape, it is carried out by applying an oxidizing agent (aqueous solution of hydrogen peroxide, alkali bromic acid, perchlorate, polythionate, etc.) to build and fix disulfide bonds between cysteines again. In this way, the hair can be processed straight or curled.

As the reducing agent of the permeate, for example, thioglycolic acid, cysteine, cysteamine, glyceryl thioglycolate, thiolactic acid and the like are used. Typically, a perm liquid containing thioglycolic acid and a perm liquid containing cysteine are used.

The perm solution containing thioglycolic acid has an excellent effect of perming the hair, but the hair is significantly damaged because of its stronger action on the hair compared to cysteine. Therefore, especially in severely damaged hair such as bleached and dyed hair is limited use.

In addition, when thioglycolic acid is used, the degree of permanent formation between the tip of the hair and the hair root is different, and the hair becomes crumbly, the tip splits and breaks.

On the other hand, the permeate containing cysteine has a low degree of damage to the hair, but it is difficult to wind the hair with a normal rod because the action of perming the hair is weak. It is becoming. In the case of severely damaged hair, permanent processing is more difficult than healthy hair. In addition, when cysteine is used, the tip of the hair is cracked or broken, and the gloss disappears. In addition, even if cysteine, which is generally considered to have little damage to hair, is permanently permeated after two or three times, the cause is that the permanent becomes poor, and the cause is flaming in the hair by drying cysteine. It is supposed to be caused.

As such, the conventionally developed products for permanents are mostly made of both chemicals and principal components, which may cause problems with the health of the hair and scalp after the permanent wave procedure. For example, due to the expansion of the hair during the softening process, the cuticle is opened due to the hair's swelling, and the hair's insects and moisture are lost. Had happened. In addition, the permanent liquid contacted the skin of the scalp, face and neck during the wave procedure, causing skin irritation such as burning, irritation or itching.

Permanent products that use a lot of chemicals also smell too much and cause headaches in people who perform permanently. In order to improve this, Korean Laid-Open Patent Publication No. 2000-002954 discloses an example of the ocher powder composition for removing the permanent liquid odor. The disclosed composition comprises 30 to 40% by weight of elvan and 60 to 70% by weight of loess and is further provided with kaolin.

However, the ocher powder composition is mixed with the perm solution, the amount of ganban stone is mixed 30 to 40% by weight, the rigidity of the hair is relatively increased during the permanent procedure, there was a problem in that the flexibility and softness of the hair is inferior. In particular, too little in the permanent solution could not expect the effect, the relatively large amount of the amount of the effect of the permeate is reduced by half the effect of perm-forming ability, rather there is a problem to reduce the gloss of the hair.

Therefore, it can remove the odor of permanent composition, protect and moisturize hair, prevent scalp irritation, and maintain the original wave formation and maintenance effect of permanent composition despite this effect. There is a need for development of permanent compositions.

The purpose of the present invention is to contain the black mud known as a natural organic enzyme together with conventional permanent liquid components, which is not irritating to the human body and has no problem on its safety, and has the inherent wave formation and maintenance effect, but also deodorizing effect, hair It is to provide a permanent composition containing black mud, which can expect a protective and moisturizing effect and an anti-scalp effect.

The permanent composition according to the present invention is characterized by containing black mud. The black mud is included in the permanent composition in an amount of 0.5 to 10 wt%, more preferably 1.0 to 2.0 wt%.

In the present invention, the black mud may be added in the form of an extract, and the black mud extract may be dried in a shade so as to obtain a moisture content of 0.1 to 2% by using a black mud extract, and then, using an extraction solvent such as distilled water or an organic solvent. Obtained by heating extraction at 90 ℃ for 6 to 10 hours.

In addition, the permanent composition according to the present invention, when used with other permanent liquid components, for example 0.2% by weight of ethidronic acid, 2.4% by weight of ethanolamine thioglycolate, 8.0% by weight of L-cysteine monohydrochloride, ethanolamine 3.67 weight%, diethanolamine 2.56 weight%, cetyl, stearyl alcohol, PEG-23, PEG-30, PEG-40, cetyl ether, polyethylene alkyl ether, cetearyl alcohol, stearic acid, mineral oil, bishydr 17.0% by weight of oxyethyl biscetyl malonamide and triethanolamine, 0.2% by weight of PEG-23M, 1.0% by weight of hydrolyzed collagen, 0.01% by weight of L-serine, glycine, DL-alanine, water and propylene glycol, quaternium- 75 1.0% by weight, glycol distearate, sodium laureth sulfate, 0.5% by weight of cocamide MEA and laureth-10, 0.03% by weight gum powder, polyethylene glycol, nonoxynol-40 and propylene glycol in 0.1 Amount%, 1.0% by weight of the silt extract (black mud), 0.1% by weight and 62.23% by distilled water may be made.

The permanent composition containing the black mud of the present invention can be expected to have a deodorizing effect, a hair protection and moisturizing effect, and a scalp irritation effect while still having a wave forming and maintaining effect. Permanent composition of the present invention, unlike the conventional permanent solution, does not have a strong chemical smell and can add softness and shine to the hair, and does not cause itching or tingling on the skin such as scalp and neck during the permanent procedure.

Hereinafter, preferred embodiment of the permanent composition containing the black mud of this invention is described.

Black mud is a natural substance native to Odessa, a port city on the Black Sea coast, and has been fermented for tens of millions of years in the deep seas of the European Black Sea, 200m deep, containing many minerals and minerals. It is known as the mysterious substance of the black color.

Black sea black mud contains a lot of minerals that are beneficial to the human body, such as sulfur, iron, magnesium, silver, potassium, germanium, vitamins, zinc and manganese, as shown in Table 1 below, and Boryeong mud in Korea, Dead Sea mud in Israel and Baikal in Siberia. It contains a lot more minerals than other muds, such as home mud.

(Unit: g / kg) Ingredient Name Black Sea Black Mud Boryeong Mud Dead Sea Mud Baikal Mud Na 1.99 1.47 1.74 0.13 Long soluble Mg 2.05 0.71 0.49 13.6 Water Soluble Mg 261 - - 72.7 Al 13.8 8.89 8.6 6.12 Si 56.6 31.53 32.11 29.2 K 2.22 3.61 4.1 1.27 Ca 2.12 0.7 2.94 13.6 Fe 6.35 4.46 1.71 3.05 Ti 0.63 0.54 0.24 - P 261 - - 0.21 Ge 2.02 - - - Sulfur (S) 1.37 - - -

The various minerals contained in the black mud eliminate the odor of permanent chemicals, add softness and shine to the hair, and do not irritate the skin such as the scalp and neck during the permanent procedure.

Sulfur is the eighth most common element in the human body, and the permanent composition of the present invention can be added to the hair by the black mud's sulfur component to add luster to the hair, make the scalp healthy, and not irritate the scalp. Keratin can dissolve. Sulfur also has degreasing and deodorizing effects.

Silicate, magnesium, zinc, calcium and potassium sulfide prevent the growth and activity of scalp microorganisms such as dandruff. It also revitalizes, relieves itching and keeps your scalp healthy.

Iron and silver to stabilize the nervous system and to relax the heart to stabilize the hair and scalp tired from stress.

Oxygen and germanium promote the supply of oxygen necessary for metabolism of the human body, and inhibit and prevent the components of aging cells to neutralize acidified body fluids and convert them into alkalis. Depending on the germanium in the permanent composition, the natural healing power of the human body may be increased.

Germanium is known to perform oxygen supply, strengthening immunity of the human body, detoxification and heavy metal excretion. Germanium acts as a detoxification agent by inhaling toxic substances, combining them chemically, and then producing other non-toxic substances because of their chemical properties with highly oxidizing oxygen atoms.

Sodium, aluminum and silicon components control the osmotic pressure of the scalp to keep the water balance in balance. In particular, silicon is so deeply related to human hair that it is called a skin mineral and has the function of making hair shiny and smooth.

Black mud is neutral (pH = 7) and harmless to the human body, preventing acidification of the skin and slowing down aging, thus maintaining beauty for a long time.

The black mud may be used without additional treatment when included in the composition, but may be prepared and included in the form of an extract. In the case of using the black mud in the form of an extract, for example, the black mud is collected and dried in a shade so as to have a water content of 0.1 to 2%, and then extracted at 70 to 90 ° C. using an extraction solvent such as distilled water or an organic solvent. Black mud extract may be obtained by heating and extracting for 10 hours.

Black mud is preferably contained in an amount of 0.5 to 10% by weight, and most preferably 1 to 2% by weight in the total composition. If the amount of the black mud is less than 0.5% by weight, it is difficult to expect sufficient deodorizing effect, hair protection and moisturizing effect, and anti-scalp effect, and when it exceeds 10% by weight, the permanent wave formation and retention effect of the permanent may be lowered. Not. In addition, it is more preferable that the black mud is contained in an amount of 1 to 2% by weight in consideration of aspects such as antiseptic power, smell, color change, and the like.

Permanent components other than the black mud may include those conventionally used and those skilled in the art may adjust the content appropriately in consideration of the content of the black mud.

The base material contained in the composition for permanent use of the present invention is not particularly limited, and for example, propylene glycol, cetearyl alcohol, polyoxyethylene oleyl ether, polyoxyethylene cetyl ether, stearamide M, oleic acid, oleyl It may be one or a mixture of two or more selected from alcohol, dimethicone, behenyl alcohol, glyceryl stearate SE.

Hair protectants include sodium methyl stearoyl taurate, hydrolyzed keratin, hydrolyzed collagen, tocopheryl acetate, cetrimonium chloride, glyceryl stearate SE, Fiji-11 methyl ether dimethicone, cyclomethicone, ammonium It may be one kind or a mixture of two or more selected from glycyritate, glyceryl linoleate, linoleic acid, ceramide, mineral oil, polyquaternium-10, quaternium-75, camellia oil and the like.

Alkaline is a component that helps the action of the reducing agent and adjusts the wave strength and is selected from alkalis such as ammonia, ammonium carbonate, ammonium bicarbonate, sodium hydroxide, potassium hydroxide, sodium carbonate, monoethanolamine, prophenolamine, and triethanolamine. Or a mixture of two or more kinds.

Chelating agents are added for the stability of thioglycolic acid, cysteine, hydrogen peroxide, and specifically may be ethylenediaminetetraacetic acid (EDTA) disodium, ethylenediaminetetraacetic acid tetrasodium and the like.

Surfactants are added to the composition to facilitate hair permeation of the permanent liquid, and include anionic surfactants, cationic surfactants, nonionic surfactants, and amphoteric surfactants.

The anionic surfactants in the surfactant are specifically ammonium laurylsulfosuccinate, ammonium lauryl sulfate, sodium cocoyl isionate, sodium lauryl isceionate, sodium lauryl sulfate, triethanolamine lauryl sulfate, sodium la Uryl ether sulfate (1-3 ethylene oxide), and the like.

Among the surfactants, the nonionic surfactant may specifically be polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene, polysorbate 80, hardened castor oil derivative, fatty acid diethanolamide, glyceryl stearate, or the like. .

The cationic surfactant in the surfactant may specifically be a tertiary aliphatic amine salt, alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, or the like.

Among the surfactants, the amphoteric surfactant may specifically be betaine, amidebetaine type, sulfobetaine type, steartrimonium chloride, or the like.

Specifically, the pH adjuster may be any of organic acids such as citric acid, succinic acid, tartaric acid, lactic acid, malic acid, fumaric acid, maleic acid, glycolic acid, and inorganic acids such as hydrochloric acid, sulfuric acid, phosphoric acid, nitric acid, sodium salts of these acids, Potassium salt, ammonium salt, etc. can be used in combination, A triethanolamine, sodium hydroxide, potassium hydroxide, etc. can also be used.

Moisturizing agent may be specifically glycerin, propylene glycol, 1,3-butylene glycol, dipropylene glycol, sorbitol and the like.

The thickener is specifically cetearyl alcohol, stearic acid, methyl cellulose, hydroxyethyl cellulose, hydroxymethyl cellulose, carrageenan, carboxymethyl cellulose, carboxymethylhydroxyguanine, polyquaternium-7, polyquaternium-10, and the like. It can be a water-soluble high molecular compound of.

Preservatives may specifically be benzoic acid, paraoxybenzoic acid esters, mixtures of methylchloroisothiazolinone, phenoxyethanol, DMDM hydantoin and the like.

Antioxidants may specifically be dibutylhydroxytoluene, ascorbic acid and the like.

Fungicides may specifically be chlorhexidine gluconate, quaternary ammonium salts, pyroxtonolamines, zinc pyrithione suspensions, iodopropynyl butylcarbamate, salicylic acid and the like.

The anti-inflammatory component may specifically be monoammonium glycyrrhinate, dipotassium glycyrizine, stearyl glycyrizinate, chamomile, alpha bisabolol, allantoin and mixtures thereof.

The antimicrobial component is specifically phenoxyethanol, chlorhexidine, chlorhexidine gluconate, pyroxtonolamine, ketoconazole, arnica extract, iodopropynylbutylcarbamate, benzalkonium chloride, benzenetonium chloride, benzoic acid and salts thereof, benzyl alcohol, lavender, Rosemary, salicylic acid, triclocarban, zinc pyrithione suspensions and mixtures thereof and the like.

The solvent may be specifically purified water, ethanol, Tween 20, cyclomethicone, mineral oil, dimethicone and the like.

Dissolution aids may specifically be isopropyl myristate, polyethylene glycol, medium chain fatty acid triglycerides, hydrocarbons, glycols, and the like.

Flavoring agents and pigments may use ingredients used in general scalp and hair preparations.

Permanent composition of the present invention can be used for the wave or straight of the hair, it is preferable to use as a transdermal administration method such as directly applied to the hair or sprayed.

The amount of the permanent composition of the present invention can be appropriately adjusted according to the condition of the hair, the age of the user, the length of the hair, and the like, and the application time can also be appropriately adjusted according to the individual. It is preferable to apply | coat about 50-200 ml of contents of once, and about 10-60 minutes of processing hours.

Permanent composition formulation of the present invention is preferably a cream type, liquid type, in addition, it can be prepared in the form of powder, jelly, aerosol and the like.

Black mud and charcoal can be used together to maximize the deodorizing effect. Charcoal is porous and shows deodorizing, dehumidifying and adsorption effects. The cells of the human body continue to oxidize and reduce, and as the body ages, the metabolism becomes weaker and oxidation becomes faster, and the reduction is called "aging". The carbon of char is reduced by generating anions. May delay aging. Pure domestic charcoal removes various wastes deep into the skin with excellent adsorption power, and charcoal rich in various minerals maintains skin circulation and skin elasticity to normalize metabolism, making skin clean and healthy.

Various additives used in the present invention are not limited to those described above, and various kinds of surfactants and other additives which are known in the art may be used.

Hereinafter, the permanent composition containing the black mud will be described in more detail through Examples of the present invention, but the scope of the present invention is not limited to the following Examples.

Example

The black mud used in the examples of the present invention was used in the form of silt extract.

As shown in the following Table 2, in Examples 1 to 3 were added 1.0% by weight, 2.0% by weight and 5.0% by weight of black mud to prepare a permanent composition in a conventional manner. In the case of the comparative example, the permanent composition was prepared without including the black mud extract.

Weight% (w / w) Ingredient Name Example 1 Example 2 Example 3 Comparative example Etidronic acid 0.200 0.200 0.200 0.200 Ethanolamine thioglycolate 2.400 2.400 2.400 2.400 L-cysteine monohydrochloride 8.000 8.000 8.000 8.000 Ethanolamine 3.670 3.670 3.670 3.670 Diethanolamine 2.560 2.560 2.560 2.560 Cetyl, stearyl alcohol, PEG-23, PEG-30, PEG-40, cetyl ether, polyethylene alkyl ether, cetearyl alcohol, stearic acid, mineral oil, bishydroxyethyl biscetyl malonamide and triethanolamine 17.000 17.000 17.000 17.000 PEG-23M 0.200 0.200 0.200 0.200 Hydrolyzed Collagen 1.000 1.000 1.000 1.000 L-serine, glycine, DL-alanine, water and propylene glycol 0.010 0.010 0.010 0.010 Quaternium-75 1.000 1.000 1.000 1.000 Glycol distearate, sodium laureth sulfate, cocamide MEA and laureth-10 0.500 0.500 0.500 0.500 CHARCOAL POWDER 0.030 0.030 0.030 0.030 Polyethylene glycol, nonoxynol-40 and propylene glycol 0.100 0.100 0.100 0.100 Silt Extract (Black Mud) 1.000 2.000 5.000 - Spices 0.100 0.100 0.100 0.100 Distilled water 62.230 61.230 58.230 63.230 sum 100.000 100.000 100.000 100.000 ※ The above ingredients are according to the International Nomenclature of Cosmetic Ingredients (INCI).

Test Example

Permanent compositions of Examples 1 to 3 and Comparative Examples prepared according to the composition shown in Table 2 were tested by dividing 80 adult females into four groups of 20 adult women who had been regularly subjected to permanent treatment.

For each investigator, 1) the degree of deodorization of permanent fluid, 2) the degree of protection and moisturizing of hair, and 3) the degree of prevention of scalp irritation were measured by the following questionnaire (2: very effective, 1: slightly effective). , 0: no difference / not sure, -1: almost no effect, -2: no effect at all). The average of 20 values was obtained.

The above results are summarized in Table 3 below.

division Example 1 Example 2 Example 3 Comparative example Deodorization +1.35 +1.45 1.30 -1.0 Hair protection, moisturizing +1.20 +1.20 +1.05 -0.45 Scalp Stimulation Prevention +1.25 +1.25 +1.35 -0.60

As shown in the results shown in Table 3, the permanent composition of Examples 1 to 3, each containing 1.0% by weight, 2.0% by weight and 5.0% by weight of the black mud, compared to the permanent of the comparative example without the black mud, as a whole, The protection and moisturizing effect of the hair and the scalp irritation effect were remarkably excellent, and Examples 1 and 2, which contained 1 to 2% by weight of black mud, were relatively better in terms of deodorization and hair protection than Example 3. Effect.

As described above, when performing permanent treatment using the permanent composition containing the black mud of the present invention, it removes the smell of chemicals, adds softness and luster to the hair, and does not cause irritation to the skin such as the scalp and neck during the permanent procedure. Could.

Claims (5)

Permanent composition containing black mud. The permanent composition of claim 1, wherein the black mud comprises 0.5 to 10 wt% of the total composition. The permanent composition of claim 1 or 2, wherein the black mud is included in an amount of 1.0 to 2.0 wt% in the total composition. The method according to claim 3, wherein the black mud is contained in 1.0% by weight of the total composition, 0.2% by weight of etidronic acid, 2.4% by weight of ethanolamine thioglycolate, 8.0% by weight of L-cysteine monohydrochloride, 3.67% by weight of ethanolamine %, 2.56 wt% diethanolamine, cetyl, stearyl alcohol, PEG-23, PEG-30, PEG-40, cetyl ether, polyethylene alkyl ether, cetearyl alcohol, stearic acid, mineral oil, bishydroxyethyl bis Cetyl malonamide and triethanolamine 17.0 wt%, PEG-23M 0.2 wt%, hydrolyzed collagen 1.0 wt%, L-serine, glycine, DL-alanine, water and propylene glycol 0.01 wt%, quaternium-75 1.0 wt% %, Glycol Distearate, Sodium Laureth Sulfate, 0.5% by weight of Cocamide MEA and Laureth-10, 0.03% by weight Gumtan Powder, 0.1% by weight polyethylene glycol, Nonoxynol-40 and Propylene Glycol, 0.1% by weight fragrance and Increase It can perming composition containing an amount of 62.23%. The permanent composition according to claim 1 or 2, wherein the black mud is a silt extract.