JP3243010B2 - 放射線感受性ハロゲン化銀乳剤及びその製造方法 - Google Patents
放射線感受性ハロゲン化銀乳剤及びその製造方法Info
- Publication number
- JP3243010B2 JP3243010B2 JP27672692A JP27672692A JP3243010B2 JP 3243010 B2 JP3243010 B2 JP 3243010B2 JP 27672692 A JP27672692 A JP 27672692A JP 27672692 A JP27672692 A JP 27672692A JP 3243010 B2 JP3243010 B2 JP 3243010B2
- Authority
- JP
- Japan
- Prior art keywords
- grain
- silver
- emulsion
- tabular grains
- tabular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 221
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 69
- 239000004332 silver Substances 0.000 title claims abstract description 69
- -1 silver halide Chemical class 0.000 title claims abstract description 65
- 230000005855 radiation Effects 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 230000006911 nucleation Effects 0.000 claims abstract description 66
- 238000010899 nucleation Methods 0.000 claims abstract description 66
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 61
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims abstract description 55
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 40
- 150000004820 halides Chemical class 0.000 claims abstract description 21
- 239000002245 particle Substances 0.000 claims description 55
- 239000013078 crystal Substances 0.000 claims description 42
- 239000002612 dispersion medium Substances 0.000 claims description 31
- 230000001747 exhibiting effect Effects 0.000 claims description 14
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 7
- 235000013339 cereals Nutrition 0.000 description 402
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 73
- 239000000243 solution Substances 0.000 description 66
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 51
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 42
- 239000011780 sodium chloride Substances 0.000 description 37
- 229910021607 Silver chloride Inorganic materials 0.000 description 34
- 238000000034 method Methods 0.000 description 34
- 108010010803 Gelatin Proteins 0.000 description 33
- 229920000159 gelatin Polymers 0.000 description 33
- 235000019322 gelatine Nutrition 0.000 description 33
- 235000011852 gelatine desserts Nutrition 0.000 description 33
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 33
- 239000008273 gelatin Substances 0.000 description 31
- 238000001556 precipitation Methods 0.000 description 24
- 229910001961 silver nitrate Inorganic materials 0.000 description 21
- 230000015572 biosynthetic process Effects 0.000 description 19
- 230000005070 ripening Effects 0.000 description 19
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 18
- 229930182817 methionine Natural products 0.000 description 18
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 17
- 238000000576 coating method Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 11
- 239000002609 medium Substances 0.000 description 10
- 206010070834 Sensitisation Diseases 0.000 description 9
- 239000000975 dye Substances 0.000 description 9
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
- 239000003112 inhibitor Substances 0.000 description 9
- 230000008313 sensitization Effects 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 8
- 230000003595 spectral effect Effects 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000003630 growth substance Substances 0.000 description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 230000035945 sensitivity Effects 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 230000002776 aggregation Effects 0.000 description 5
- 210000000988 bone and bone Anatomy 0.000 description 5
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 229940006461 iodide ion Drugs 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000002667 nucleating agent Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 3
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229940006460 bromide ion Drugs 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 230000000877 morphologic effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- 230000001235 sensitizing effect Effects 0.000 description 3
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 229920001059 synthetic polymer Polymers 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- IHWDSEPNZDYMNF-UHFFFAOYSA-N 1H-indol-2-amine Chemical class C1=CC=C2NC(N)=CC2=C1 IHWDSEPNZDYMNF-UHFFFAOYSA-N 0.000 description 2
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 2
- GFFGJBXGBJISGV-UHFFFAOYSA-N Adenine Chemical compound NC1=NC=NC2=C1N=CN2 GFFGJBXGBJISGV-UHFFFAOYSA-N 0.000 description 2
- 229930024421 Adenine Natural products 0.000 description 2
- KLSJWNVTNUYHDU-UHFFFAOYSA-N Amitrole Chemical compound NC1=NC=NN1 KLSJWNVTNUYHDU-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PQOKJLNHZNGSPH-UHFFFAOYSA-J O.O.S(=S)(=S)([O-])[O-].[Au+3].[Na+].S(=S)(=S)([O-])[O-] Chemical compound O.O.S(=S)(=S)([O-])[O-].[Au+3].[Na+].S(=S)(=S)([O-])[O-] PQOKJLNHZNGSPH-UHFFFAOYSA-J 0.000 description 2
- 206010034960 Photophobia Diseases 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229960000643 adenine Drugs 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 150000002391 heterocyclic compounds Chemical class 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 208000013469 light sensitivity Diseases 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003567 thiocyanates Chemical class 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KAMCBFNNGGVPPW-UHFFFAOYSA-N 1-(ethenylsulfonylmethoxymethylsulfonyl)ethene Chemical compound C=CS(=O)(=O)COCS(=O)(=O)C=C KAMCBFNNGGVPPW-UHFFFAOYSA-N 0.000 description 1
- QWENRTYMTSOGBR-UHFFFAOYSA-N 1H-1,2,3-Triazole Chemical compound C=1C=NNN=1 QWENRTYMTSOGBR-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- 229910020314 ClBr Inorganic materials 0.000 description 1
- 235000009300 Ehretia acuminata Nutrition 0.000 description 1
- 244000046038 Ehretia acuminata Species 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- OUCMEZQMXGXUNE-UHFFFAOYSA-H O.O.S(=S)(=S)([O-])[O-].[Au+3].S(=S)(=S)([O-])[O-].S(=S)(=S)([O-])[O-].[Au+3] Chemical compound O.O.S(=S)(=S)([O-])[O-].[Au+3].S(=S)(=S)([O-])[O-].S(=S)(=S)([O-])[O-].[Au+3] OUCMEZQMXGXUNE-UHFFFAOYSA-H 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- XCFIVNQHHFZRNR-UHFFFAOYSA-N [Ag].Cl[IH]Br Chemical compound [Ag].Cl[IH]Br XCFIVNQHHFZRNR-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001260 acyclic compounds Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000002168 alkylating agent Substances 0.000 description 1
- 229940100198 alkylating agent Drugs 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000000586 desensitisation Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002003 electron diffraction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- PKWIYNIDEDLDCJ-UHFFFAOYSA-N guanazole Chemical compound NC1=NNC(N)=N1 PKWIYNIDEDLDCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Inorganic materials [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 239000010956 nickel silver Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000002165 photosensitisation Effects 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 150000004892 pyridazines Chemical class 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 125000000719 pyrrolidinyl group Chemical group 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000010187 selection method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 235000020985 whole grains Nutrition 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions
- G03C1/0053—Tabular grain emulsions with high content of silver chloride
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/04—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with macromolecular additives; with layer-forming substances
- G03C1/047—Proteins, e.g. gelatine derivatives; Hydrolysis or extraction products of proteins
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/07—Substances influencing grain growth during silver salt formation
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
- G03C1/14—Methine and polymethine dyes with an odd number of CH groups
- G03C1/16—Methine and polymethine dyes with an odd number of CH groups with one CH group
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
- G03C1/14—Methine and polymethine dyes with an odd number of CH groups
- G03C1/18—Methine and polymethine dyes with an odd number of CH groups with three CH groups
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/0051—Tabular grain emulsions
- G03C2001/0055—Aspect ratio of tabular grains in general; High aspect ratio; Intermediate aspect ratio; Low aspect ratio
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/015—Apparatus or processes for the preparation of emulsions
- G03C2001/0156—Apparatus or processes for the preparation of emulsions pAg value; pBr value; pCl value; pI value
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03511—Bromide content
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03558—Iodide content
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03594—Size of the grains
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/01—100 crystal face
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Peptides Or Proteins (AREA)
- Medicinal Preparation (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76486891A | 1991-09-24 | 1991-09-24 | |
| US764868 | 1991-09-24 | ||
| US82633892A | 1992-01-27 | 1992-01-27 | |
| US826338 | 2010-06-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05204073A JPH05204073A (ja) | 1993-08-13 |
| JP3243010B2 true JP3243010B2 (ja) | 2002-01-07 |
Family
ID=27117531
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27672692A Expired - Lifetime JP3243010B2 (ja) | 1991-09-24 | 1992-09-22 | 放射線感受性ハロゲン化銀乳剤及びその製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0534395B2 (fr) |
| JP (1) | JP3243010B2 (fr) |
| AT (1) | ATE173341T1 (fr) |
| AU (1) | AU2599492A (fr) |
| DE (1) | DE69227567T3 (fr) |
| DK (1) | DK0534395T3 (fr) |
| ES (1) | ES2123532T3 (fr) |
| WO (1) | WO1993006521A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7984536B2 (en) | 2008-11-11 | 2011-07-26 | Nihon Dempa Kogyo Co., Ltd. | Method of manufacturing a piezoelectric resonator |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5298385A (en) * | 1992-06-15 | 1994-03-29 | Eastman Kodak Company | High chloride folded tabular grain emulsions |
| US5275930A (en) * | 1992-08-27 | 1994-01-04 | Eastman Kodak Company | High tabularity high chloride emulsions of exceptional stability |
| DE69420605T2 (de) * | 1993-03-18 | 2000-04-06 | Eastman Kodak Co. | Farbphotographisches Element mit niedrigem Silbergehalt und Verfahren zur Farbbildherstellung |
| US5443943A (en) * | 1993-03-22 | 1995-08-22 | Eastman Kodak Company | Method of processing originating photographic elements containing tabular silver chloride grains bounded by {100} faces |
| US5264337A (en) * | 1993-03-22 | 1993-11-23 | Eastman Kodak Company | Moderate aspect ratio tabular grain high chloride emulsions with inherently stable grain faces |
| EP0617320A3 (fr) * | 1993-03-22 | 1995-02-01 | Eastman Kodak Co | Emulsions à grains tabulaires contenant des antivoiles et des stabilisants. |
| WO1994022054A1 (fr) * | 1993-03-22 | 1994-09-29 | Eastman Kodak Company | Elements photographiques formant une image couleur |
| US5451490A (en) * | 1993-03-22 | 1995-09-19 | Eastman Kodak Company | Digital imaging with tabular grain emulsions |
| DE69421838T2 (de) * | 1993-03-22 | 2000-06-15 | Eastman Kodak Co., Rochester | Verarbeitungsverfahren für photographische Originalelemente, die tafelförmige Silberchloridkörner begrenzt mit (100) Kornoberfläche enthalten |
| US5310635A (en) * | 1993-03-22 | 1994-05-10 | Eastman Kodak Company | Photographic camera film containing a high chloride tabular grain emulsion with tabular grain {100} major faces |
| JP3270614B2 (ja) * | 1993-03-22 | 2002-04-02 | イーストマン コダック カンパニー | 中位アスペクト比平板状粒子乳剤 |
| JP3058545B2 (ja) * | 1993-04-02 | 2000-07-04 | 富士写真フイルム株式会社 | ハロゲン化銀カラー写真感光材料 |
| JP2982097B2 (ja) * | 1993-04-02 | 1999-11-22 | 富士写真フイルム株式会社 | ハロゲン化銀カラー写真感光材料 |
| JP3151094B2 (ja) * | 1993-04-02 | 2001-04-03 | 富士写真フイルム株式会社 | ハロゲン化銀カラー写真感光材料の画像形成方法 |
| US5314798A (en) * | 1993-04-16 | 1994-05-24 | Eastman Kodak Company | Iodide banded tabular grain emulsion |
| JPH07146522A (ja) * | 1993-09-29 | 1995-06-06 | Fuji Photo Film Co Ltd | ハロゲン化銀乳剤 |
| US5498511A (en) * | 1993-10-25 | 1996-03-12 | Fuji Photo Film Co., Ltd. | Silver halide photographic material |
| EP0653669B1 (fr) * | 1993-11-16 | 1998-02-04 | Agfa-Gevaert N.V. | Emulsion à grains tabulaire riche en chlorire avec des faces majeures (100) |
| US5593820A (en) * | 1993-12-20 | 1997-01-14 | Fuji Photo Film Co., Ltd. | Silver halide emulsion and silver halide photographic material using the same |
| JPH07219100A (ja) * | 1994-02-04 | 1995-08-18 | Fuji Photo Film Co Ltd | ハロゲン化銀乳剤およびこれを用いたハロゲン化銀写真感光材料 |
| EP0670514A3 (fr) * | 1994-02-25 | 1996-01-17 | Eastman Kodak Co | Emulsions comprenant des grains tabulaires (100) ayant une teneur élevée en chlorure et des structures latérales modifiées. |
| US5395746A (en) * | 1994-02-25 | 1995-03-07 | Eastman Kodak Company | Inherently stable high chloride tabular grains with improved blue absorption |
| US5385818A (en) * | 1994-02-25 | 1995-01-31 | Eastman Kodak Company | Process for the preparation of silver halide emulsions and photographic elements containing hollow silver halide grains |
| US5399477A (en) * | 1994-02-25 | 1995-03-21 | Eastman Kodak Company | Silver halide photographic elements |
| US5413904A (en) * | 1994-03-18 | 1995-05-09 | Eastman Kodak Company | High chloride [100] tabular grain emulsions improved emulsions and improved precipitation processes |
| US5434038A (en) * | 1994-03-31 | 1995-07-18 | Eastman Kodak Company | Photographic image display material |
| EP0678772A1 (fr) * | 1994-04-06 | 1995-10-25 | Agfa-Gevaert N.V. | Matériau sensible à la lumière comprenant des grains tabulaires à chlorobromoiodure ou chloroiodure d'argent |
| US5457021A (en) * | 1994-05-16 | 1995-10-10 | Eastman Kodak Company | Internally doped high chloride {100} tabular grain emulsions |
| US5660974A (en) | 1994-06-09 | 1997-08-26 | Eastman Kodak Company | Color developer containing hydroxylamine antioxidants |
| EP0695968A3 (fr) | 1994-08-01 | 1996-07-10 | Eastman Kodak Co | Réduction de la viscosité dans une composition photographique à l'état fondue |
| US5665530A (en) * | 1994-08-30 | 1997-09-09 | Fuji Photo Film Co., Ltd. | Silver halide emulsion and photographic material using the same |
| US5807665A (en) * | 1995-04-14 | 1998-09-15 | Fuji Photo Film Co., Ltd. | Silver halide emulsion |
| US5707793A (en) * | 1995-04-19 | 1998-01-13 | Fuji Photo Film Co., Ltd. | Silver halide emulsion and silver halide photographic material using the same |
| JP3543047B2 (ja) * | 1996-09-09 | 2004-07-14 | 富士写真フイルム株式会社 | ハロゲン化銀乳剤およびハロゲン化銀カラー写真感光材料 |
| JPH11271900A (ja) * | 1998-01-20 | 1999-10-08 | Fuji Photo Film Co Ltd | ハロゲン化銀乳剤 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1507989A (en) * | 1974-12-19 | 1978-04-19 | Ciba Geigy Ag | Photographic emulsions |
| US4386156A (en) * | 1981-11-12 | 1983-05-31 | Eastman Kodak Company | Silver bromide emulsions of narrow grain size distribution and processes for their preparation |
| JPH0789203B2 (ja) * | 1987-04-30 | 1995-09-27 | 富士写真フイルム株式会社 | ハロゲン化銀乳剤および写真感光材料 |
| JPH0242A (ja) * | 1987-10-19 | 1990-01-05 | Fuji Photo Film Co Ltd | ハロゲン化銀写真感光材料 |
-
1992
- 1992-09-02 AU AU25994/92A patent/AU2599492A/en not_active Abandoned
- 1992-09-02 WO PCT/US1992/007549 patent/WO1993006521A1/fr not_active Ceased
- 1992-09-22 JP JP27672692A patent/JP3243010B2/ja not_active Expired - Lifetime
- 1992-09-23 DE DE69227567T patent/DE69227567T3/de not_active Expired - Lifetime
- 1992-09-23 AT AT92116262T patent/ATE173341T1/de not_active IP Right Cessation
- 1992-09-23 DK DK92116262T patent/DK0534395T3/da active
- 1992-09-23 ES ES92116262T patent/ES2123532T3/es not_active Expired - Lifetime
- 1992-09-23 EP EP92116262A patent/EP0534395B2/fr not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7984536B2 (en) | 2008-11-11 | 2011-07-26 | Nihon Dempa Kogyo Co., Ltd. | Method of manufacturing a piezoelectric resonator |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05204073A (ja) | 1993-08-13 |
| EP0534395A1 (fr) | 1993-03-31 |
| AU2599492A (en) | 1993-04-27 |
| EP0534395B1 (fr) | 1998-11-11 |
| DK0534395T3 (da) | 1999-07-26 |
| DE69227567T2 (de) | 1999-05-06 |
| ATE173341T1 (de) | 1998-11-15 |
| DE69227567T3 (de) | 2006-10-26 |
| EP0534395B2 (fr) | 2006-04-12 |
| WO1993006521A1 (fr) | 1993-04-01 |
| ES2123532T3 (es) | 1999-01-16 |
| DE69227567D1 (de) | 1998-12-17 |
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