JP2004058032A - Method of recovering valuable resource from dust of abandoned automobile shredder - Google Patents
Method of recovering valuable resource from dust of abandoned automobile shredder Download PDFInfo
- Publication number
- JP2004058032A JP2004058032A JP2002247780A JP2002247780A JP2004058032A JP 2004058032 A JP2004058032 A JP 2004058032A JP 2002247780 A JP2002247780 A JP 2002247780A JP 2002247780 A JP2002247780 A JP 2002247780A JP 2004058032 A JP2004058032 A JP 2004058032A
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- specific gravity
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- shredder dust
- plastics
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- 239000000428 dust Substances 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 42
- 230000005484 gravity Effects 0.000 claims abstract description 27
- 238000000926 separation method Methods 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000007667 floating Methods 0.000 claims abstract description 7
- 239000004033 plastic Substances 0.000 claims description 27
- 229920003023 plastic Polymers 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 150000002739 metals Chemical class 0.000 claims description 5
- 206010011906 Death Diseases 0.000 claims description 4
- 238000004062 sedimentation Methods 0.000 claims description 4
- 230000005587 bubbling Effects 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 239000003981 vehicle Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000013049 sediment Substances 0.000 description 8
- 239000002699 waste material Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- -1 ferrous metals Chemical class 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/52—Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Processing Of Solid Wastes (AREA)
- Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
Abstract
Description
【0001】
【発明の属する技術分野】
自動車が廃車になった後、有価物を回収し、又は危険物を除去した後、破砕して鉄スクラップを回収した後、残渣となっているプラスチック類、導線、非鉄金属類を廃自動車シュレッダーダストから有価物として回収する分離・精製システムの技術分野である。具体的に有価物として比重の軽いプラスチック類、比重の重いプラスチック類、導線、その他の種類の金属に分離・精製し、更にフレオン系樹脂及び塩化ビニール系樹脂を除去することにより、プラスチック類を無害な燃料材又はコークスの乾留材又は高炉の還元材の原料として有用物化し、又導線は選別後、銅と被膜材を分離させることを容易にする為に、水の中での比重差を利用して分離・精製する湿式比重選別法によるリサイクルシステムの技術である。
【0002】
【従来の技術】
廃自動車のシュレッダーダストから有用物を回収する実用する技術はない。研究開発段階として乾式法による廃自動車シュレッダーダストの分離・精製を試みているが、実用化技術には至っていない。
【0003】
【発明が解決しようとする課題】
既存の実験段階の技術は乾式法による比重選別を行うとしているが、実際の廃自動車シュレッダーダストには、自動車の構成材料以外に泥土、人間が使用していた残渣物、例えば缶類、食物の残渣等が混入していて、非常に雑多な物質の構成と形状となっている。これらを除去して有用物を回収する為には、洗浄工程と水より軽い浮遊物である木質系、ウレタン系プラスチックを分離処理しておき、更に土砂系物質を洗浄除去した後、更に導線等の長物材料を回収した後に残ったプラスチック類及び金属類を湿式比重選別機により、有用物を回収する方法である。
【0004】
【課題を解決する為の手段】
表1自動車に使用されるプラスチック材料の主要部品(例)と表2シュレッダーダスト(ASR)の材料別構成重量比(例)によれば、多種の材料の存在が判るが、この中から有用材料として回収、又は不要、又は再利用が出来ない材料を分類することが出来る。浮遊物中のハロゲン化物であるウレタン系プラスチック(PUR)及び沈降物に含有された塩化物プラスチック(PVC)がある。又、導線の被膜材の殆んどは塩化物系プラスチック類(PVC系)であり、これらをプロセスの中で除去出来れば、リサイクル利用な材料を有用材料として回収することは有効である。又、PVCは電線被膜材等のリサイクルの利用も出来、有用物として回収することも可能な手段である。
【0005】
前述の前提条件を鑑み、試験用湿式比重選別機により選別試験を行った結果、表3湿式比重選別機による分離種類に示す内容物が回収することが出来た。この試験方法は図1廃自動車シュレッダーダスト有価物回収試験フローに示すように水の中で浮遊物を取外すことで、水より軽いプラスチック類、ウレタン系及びPP、PEが回収される。次に長尺物の繊維プラスチック及び導線を回収する。沈降物中には金属類、重比重プラスチック、ガラス等窯業系材料が混在し、泥土は網下産物として沈下物となる。
【0006】
次に鉄系スクラップは磁力選別を行った結果、表4鉄系及び非鉄系金属の割合に示すように18.7%の残鉄分が含まれていた。
【0007】
残存廃棄材料を湿式の比重選別装置により、比重の重い順に選別したところ、表5非鉄金属中に含まれる比重別材料の割合に示す結果を得た。重比重金属には銅系の非鉄金属が多く含まれていて、長尺物の導線から回収した銅を加えると、ASR中には約3〜5%の銅が残渣として残留しており、有用物の価値が非常に高いものであり、又、湿式比重選別方式は非常に有効な手段であることも判明した。更に比重の重い系統のプラスチックを取出し、その後更に湿式比重選別機により他のプラスチック例えばABSを分離することによりリサイクル材料として利用出来る。
【0008】
この湿式比重選別機の特徴は、材料別に分離・精製する手段として多槽にすることで容易に材料別に回収することが可能であり、図2に示すプラスチックの材料別の分離の場合は、3槽にすることにより例えばPVC、ABS、PS及びPPの高品質の分離回収物を得ることが出来る。
【0009】
【実施の形態】
第1実施の形態
図1による試験結果、ASRからの再利用が可能でない廃棄物を分離し、有用物を回収しリサイクル材料とした品質を精製するシステムは図3のASRの分離・精製システムに示す。図3において、1ASRは2フィードコンベアにより、3浮遊物分離槽に装入され、ASRは空気と水との混合により洗浄されながら沈降物と浮遊物に分離される。沈降物は4バケットエレベータでかき上げられ、ASRは脱水されながら5脱泥スクリーンにより泥土を除去したASRは8湿式比重選別機に運ばれる。一方、浮遊物は6脱水機により7浮遊物プラスチック類として回収される。8は回収物種類により多様で構成されるが、図3の場合は2槽となっている。この実例では1槽目で非鉄金属を回収し、2槽目では重比重プラスチック類を回収する。8の樋先には11脱水スクリーンが設置されていて12軽比重プラスチック類を回収する。尚、13泥土脱水機であり、14脱水泥土ケーキである。
【0010】
第2実施の形態
図3において、ASRから浮遊物体と沈降物体を分離する装置を図4の20浮遊物分離槽に示す。20は浮遊物と沈降物を分離する装置の概念図を示しているが、21脈動バブリング槽と22沈降槽で構成されている。21では24空気室において間欠的に空気を入排気させ、21に気泡状になった空気を間欠的に排出させる槽であり、又、22沈降槽は水より重い物質を沈降させ、又、浮遊物を迅速に排出させる23浮遊物移動装置が付属されている。
【0011】
【発明の効果】
ASR中からと思われる高品位材料を回収することにより再資源物として自動車又は他の機器の材料となり資源の有効利用が可能であり、且つ、単体分離化を促進させることにより、廃プラスチック材料は固形化燃料等において効率のよい材料となる。一方、従来、廃棄処分されたASRが減容することにより、埋立等廃棄処分地の延命に繋がる。
【図面の簡単な説明】
【図1】廃自動車シュレッダーダスト有価物回収試験フロー
【図2】プラスチックの材料別の分離
【図3】ASRの分離・精製システム
【図4】浮遊物分離槽
【表1】自動車に使用されるプラスチック材料の主要部品(例)
【表2】シュレッダーダスト(ASR)の材料構成重量比(例)
【表3】湿式比重選別機による分離種類
【表4】鉄系及び非鉄系金属の割合
【表5】非鉄金属中に含まれる比重別材料の割合
【符号の説明】
1 ASR
2 フィードコンベア
3 浮遊物分離槽
4 バケットエレベータ
5 脱泥スクリーン
6 脱水機
7 浮遊物プラスチック類
8 湿式比重選別機
9 金属類
10 重比重プラスチック類
11 脱水スクリーン
12 軽比重プラスチック類
13 泥土脱水機
14 脱水泥土ケーキ
【0014】
20 浮遊物分離槽
21 脈動バブリング槽
22 沈降槽
23 浮遊物移動装置
24 空気室[0001]
TECHNICAL FIELD OF THE INVENTION
After automobiles are scrapped, valuables or hazardous materials are removed, crushed and iron scraps are collected, and residual plastics, conductive wires, and non-ferrous metals are scrapped into shredder dust. This is the technical field of separation / purification systems for recovering valuable materials from wastewater. Specifically, plastics are harmless by separating and purifying them into valuable materials such as light-weight plastics, heavy-weight plastics, conductors, and other types of metals, and by removing Freon-based resins and vinyl chloride-based resins. Useful as a raw material for safe fuel materials, dry distillation materials for coke or reducing materials for blast furnaces, and use the difference in specific gravity in water to facilitate separation of copper and coating materials after sorting conductors. This is a technology of a recycling system based on the wet specific gravity separation method, which separates and refines.
[0002]
[Prior art]
There is no practical technology to recover useful materials from shredder dust from end-of-life vehicles. At the research and development stage, we are trying to separate and purify waste automobile shredder dust by a dry method, but we have not yet reached a practical application technology.
[0003]
[Problems to be solved by the invention]
Although the existing experimental stage technology says that specific gravity sorting is performed by the dry method, actual scrap car shredder dust includes mud and residue used by humans, such as cans and foods, in addition to automobile material. Residues and the like are mixed in, and the composition and shape of the substance are very various. In order to remove these and collect useful materials, it is necessary to separate the wood and urethane plastics, which are suspended substances that are lighter than water, in the washing process, and further wash and remove sediment-based substances, and then further conduct wires, etc. This is a method of recovering useful materials from plastics and metals remaining after recovering the long material by using a wet specific gravity separator.
[0004]
[Means for solving the problem]
Table 1 The major parts (examples) of plastic materials used in automobiles and Table 2 Shredder dust (ASR) composition ratios by material (examples) indicate that there are many types of materials. Materials that cannot be recovered, unnecessary, or cannot be reused can be classified. There are urethane-based plastics (PUR) which are halides in suspended matter and chloride plastics (PVC) contained in sediment. Most of the coating material of the conductor is chloride plastics (PVC), and if these can be removed in the process, it is effective to recover materials that can be recycled as useful materials. In addition, PVC is a means that can be used for recycling wire coating materials and the like, and can be recovered as useful materials.
[0005]
In consideration of the above-mentioned preconditions, as a result of conducting a sorting test using a test wet specific gravity separator, the contents indicated in Table 3 by the wet specific gravity separator could be recovered. According to this test method, plastics, urethanes, PP, and PE lighter than water are recovered by removing suspended matters in water as shown in the waste vehicle shredder dust valuable resource recovery test flow shown in FIG. Next, the long-sized fiber plastic and the conductive wire are collected. Ceramics such as metals, heavy-duty plastics, and glass are mixed in the sediment, and the mud becomes sediment as a net product.
[0006]
Next, the iron-based scrap was subjected to magnetic force sorting, and as a result, as shown in Table 4, the ratio of iron-based and non-ferrous metal, 18.7% of residual iron was contained.
[0007]
When the remaining waste materials were sorted in order of the specific gravity by a wet specific gravity sorter, the results shown in Table 5 are shown in Table 5 below. Heavy specific gravity metal contains a large amount of copper-based non-ferrous metal, and when copper recovered from long conductors is added, about 3 to 5% of copper remains as a residue in ASR, which is useful. The value of the product is very high, and it has been found that the wet specific gravity sorting method is a very effective means. A plastic of a higher specific gravity is taken out, and then another plastic, for example, ABS is separated by a wet specific gravity separator, so that it can be used as a recycled material.
[0008]
The feature of this wet specific gravity separator is that it is possible to easily recover each material by using multiple tanks as a means for separating and purifying each material. In the case of separation of each plastic material shown in FIG. By using a tank, for example, high-quality separated and recovered products of PVC, ABS, PS and PP can be obtained.
[0009]
Embodiment
First embodiment As a result of the test according to FIG. 1, the system for separating non-reusable waste from ASR, recovering useful materials and purifying the quality as recycled material is shown in FIG. -Shown in purification system. In FIG. 3, 1 ASR is charged into 3 suspended matter separation tanks by 2 feed conveyors, and ASR is separated into sediment and suspended matter while being washed by mixing of air and water. The sediment is lifted by a 4-bucket elevator, and the ASR that has been dewatered while the mud is removed by a 5 de-sludge screen is conveyed to an 8-wet specific gravity separator. On the other hand, the suspended matter is recovered as 7 suspended matter plastics by the 6 dehydrator. Although there are various types of
[0010]
2nd Embodiment In FIG. 3, the apparatus which separates a floating object and a sedimentary object from ASR is shown in 20 floating substance separation tanks of FIG.
[0011]
【The invention's effect】
By recovering high-quality materials that are considered to be from ASR, it becomes a material for automobiles or other equipment as recyclable materials, enabling effective use of resources. It becomes an efficient material for solidified fuel and the like. On the other hand, conventionally, reduction in the volume of ASR that has been disposed of leads to extension of life of landfill sites such as landfills.
[Brief description of the drawings]
Fig. 1 Flow of waste vehicle shredder dust valuable material recovery test. Fig. 2 Separation of plastics by material. Fig. 3 ASR separation / refining system. Fig. 4 Floating material separation tank. Main parts of plastic materials (example)
[Table 2] Material composition weight ratio of shredder dust (ASR) (example)
[Table 3] Separation type by wet specific gravity separator [Table 4] Ratio of ferrous and non-ferrous metals [Table 5] Ratio of specific gravity-specific materials contained in non-ferrous metals [Explanation of symbols]
1 ASR
2
Claims (3)
分別、回収して再資源化物とする方法After dismantling end-of-life vehicles, plastics and metals are separated from shredder dust, which is turned into garbage and disposed of, by a wet-type specific gravity sorter, and recovered to be recycled.
とする方法A method to separate light specific gravity plastic and heavy specific gravity plastic from shredder dust from end-of-life vehicles with a wet-type specific gravity separator to produce recycled materials
動バブリング槽と沈降槽を備え付けたことを特徴としている装置Floating material separation tank for separating substances lighter and heavier than water in shredder dust of end-of-life vehicles is equipped with a pulsating bubbling tank for intermittently discharging air and air bubbles and a sedimentation tank
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002247780A JP2004058032A (en) | 2002-07-24 | 2002-07-24 | Method of recovering valuable resource from dust of abandoned automobile shredder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002247780A JP2004058032A (en) | 2002-07-24 | 2002-07-24 | Method of recovering valuable resource from dust of abandoned automobile shredder |
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| Publication Number | Publication Date |
|---|---|
| JP2004058032A true JP2004058032A (en) | 2004-02-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002247780A Pending JP2004058032A (en) | 2002-07-24 | 2002-07-24 | Method of recovering valuable resource from dust of abandoned automobile shredder |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005334819A (en) * | 2004-05-28 | 2005-12-08 | Osaka Prefecture | Recycling method of shredder dust by wet sorting method |
| JP2006320882A (en) * | 2005-05-17 | 2006-11-30 | Aguro Gijutsu Kk | Selective wet specific gravity sorter |
| JP6192084B1 (en) * | 2017-04-25 | 2017-09-06 | 日本シーム株式会社 | Sorting equipment for waste plastics containing metals |
| JP2023069528A (en) * | 2021-11-05 | 2023-05-18 | 哲大 土田 | Resin recovery method |
| WO2024075742A1 (en) | 2022-10-07 | 2024-04-11 | 株式会社ジェイエスピー | Polypropylene-based resin foamed particles and method for manufacturing same |
-
2002
- 2002-07-24 JP JP2002247780A patent/JP2004058032A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005334819A (en) * | 2004-05-28 | 2005-12-08 | Osaka Prefecture | Recycling method of shredder dust by wet sorting method |
| JP2006320882A (en) * | 2005-05-17 | 2006-11-30 | Aguro Gijutsu Kk | Selective wet specific gravity sorter |
| JP6192084B1 (en) * | 2017-04-25 | 2017-09-06 | 日本シーム株式会社 | Sorting equipment for waste plastics containing metals |
| JP2018183734A (en) * | 2017-04-25 | 2018-11-22 | 日本シーム株式会社 | Sorting equipment for waste plastics containing metals |
| JP2023069528A (en) * | 2021-11-05 | 2023-05-18 | 哲大 土田 | Resin recovery method |
| WO2024075742A1 (en) | 2022-10-07 | 2024-04-11 | 株式会社ジェイエスピー | Polypropylene-based resin foamed particles and method for manufacturing same |
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