GB1268842A - Production of lower aliphatic mercaptans - Google Patents
Production of lower aliphatic mercaptansInfo
- Publication number
- GB1268842A GB1268842A GB3373969A GB3373969A GB1268842A GB 1268842 A GB1268842 A GB 1268842A GB 3373969 A GB3373969 A GB 3373969A GB 3373969 A GB3373969 A GB 3373969A GB 1268842 A GB1268842 A GB 1268842A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrogen sulphide
- volatile
- sulphide
- alkyl
- dialkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 aliphatic mercaptans Chemical class 0.000 title abstract 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 4
- 238000005406 washing Methods 0.000 abstract 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 239000003039 volatile agent Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 abstract 1
- 125000005233 alkylalcohol group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001983 dialkylethers Chemical class 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
- C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/26—Separation; Purification; Stabilisation; Use of additives
- C07C319/28—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,268,842. Purification of alkyl mercaptan reaction product. DEUTSCHE GOLDUND SILBER-SCHEIDEANSTALT. 4 July, 1969 [4 July, 1968], No. 33739/69. Heading C2C. A process for working up C 1-4 alkyl mercaptans, obtained by the interaction of the corresponding primary alkyl alcohol and hydrogen sulphide under pressure in the presence of a catalyst, comprises separating in a packed or plate column the gas mixture accumulating after reaction (i.e. hydrogen sulphide, unreacted alcohol, alkyl mercaptan, dialkyl sulphide, water, dialkyl ether and inert gases) into volatile and non-volatile fractions under at most 10 atmospheres and at 10 to 140‹ C., and washing out entrained non-volatiles (primarily alkyl mercaptan and dialkyl sulphide) from the volatile fraction using a washing agent, e.g. methanol, flowing in counter current to volatile fraction in the upper part of the separation column or in a separate washing column; the entrained non-volatiles together with washing agent are returned to the separation column and, following removal of hydrogen sulphide and the ether are worked up together with the initial non-volatile fraction in further columns. Mercaptan containing less than 0.02% of hydrogen sulphide is obtained.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681768826 DE1768826B1 (en) | 1968-07-04 | 1968-07-04 | Process for the production of lower aliphatic mercaptans |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1268842A true GB1268842A (en) | 1972-03-29 |
Family
ID=5699875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3373969A Expired GB1268842A (en) | 1968-07-04 | 1969-07-04 | Production of lower aliphatic mercaptans |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5024939B1 (en) |
| AT (1) | AT289048B (en) |
| BE (1) | BE735619A (en) |
| CH (1) | CH525199A (en) |
| DE (1) | DE1768826B1 (en) |
| FR (1) | FR2012271A1 (en) |
| GB (1) | GB1268842A (en) |
| NL (1) | NL146799B (en) |
| RO (1) | RO56554A (en) |
| YU (1) | YU32635B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7326393B2 (en) | 2002-09-26 | 2008-02-05 | Degussa Ag | Process for the conversion of polysulfanes |
| DE102007007458A1 (en) | 2007-02-15 | 2008-08-21 | Evonik Degussa Gmbh | Process for the preparation of methyl mercaptan from dialkyl sulfides and dialkyl polysulfides |
| US7604788B2 (en) | 2002-09-26 | 2009-10-20 | Evonik Degussa Gmbh | Process for the conversion of polysulfanes |
| US7994366B2 (en) | 2007-05-25 | 2011-08-09 | Evonik Degussa Gmbh | Process for continuously preparing methyl mercaptan from carbon- and hydrogen-containing compounds |
| US9745262B2 (en) | 2009-07-20 | 2017-08-29 | Evonik Degussa Gmbh | Process for continuously preparing methyl mercaptan from carbon compounds, sulfur and hydrogen |
| EP3405271A4 (en) * | 2016-01-22 | 2019-08-21 | Arkema, Inc. | PURIFICATION OF MERCAPTANS OR THIOPHENES USING A CLOSED DISTILLATION COLUMN |
| US10562831B2 (en) | 2015-09-21 | 2020-02-18 | Arkema Inc. | Process for making tetrachloropropene by catalyzed gas-phase dehydrochlorination of pentachloropropane |
| CN116940550A (en) * | 2020-12-17 | 2023-10-24 | 阿科玛法国公司 | Method for preparing methyl mercaptan by treating gaseous waste |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2477538A2 (en) * | 1980-03-06 | 1981-09-11 | Rhone Poulenc Ind | Vapour phase prepn. of methyl-mercaptan - from methanol and hydrogen sulphide using activated alumina catalyst |
| DE19654515C1 (en) * | 1996-12-27 | 1998-10-01 | Degussa | Process for the continuous production of methyl mercaptan |
| DE19654516C1 (en) * | 1996-12-27 | 1998-10-01 | Degussa | Process for the separation of the product gas mixture of the catalytic synthesis of methyl mercaptan |
| DE10359636A1 (en) | 2003-12-18 | 2005-07-28 | Degussa Ag | Process for the separation of methylmercaptan from reaction mixtures |
| DE102005016369A1 (en) | 2005-04-09 | 2006-10-12 | Degussa Ag | Process for the continuous production of methyl mercaptan |
| DE102005043151A1 (en) | 2005-09-10 | 2007-03-22 | Degussa Ag | Process for the preparation of methyl mercaptan |
| JP4968207B2 (en) * | 2008-07-31 | 2012-07-04 | 住友化学株式会社 | A method for purifying hydrogen sulfide gas. |
| DE102010064250A1 (en) | 2010-12-28 | 2012-06-28 | Evonik Degussa Gmbh | Process for the preparation of methylmercaptopropionaldehyde |
-
1968
- 1968-07-04 DE DE19681768826 patent/DE1768826B1/en active Pending
-
1969
- 1969-04-18 CH CH588269A patent/CH525199A/en not_active IP Right Cessation
- 1969-04-30 RO RO5987369A patent/RO56554A/ro unknown
- 1969-05-12 NL NL6907265A patent/NL146799B/en not_active IP Right Cessation
- 1969-06-16 FR FR6919988A patent/FR2012271A1/fr not_active Withdrawn
- 1969-06-27 YU YU165569A patent/YU32635B/en unknown
- 1969-07-01 JP JP5210569A patent/JPS5024939B1/ja active Pending
- 1969-07-03 BE BE735619D patent/BE735619A/xx not_active IP Right Cessation
- 1969-07-04 AT AT645869A patent/AT289048B/en not_active IP Right Cessation
- 1969-07-04 GB GB3373969A patent/GB1268842A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7326393B2 (en) | 2002-09-26 | 2008-02-05 | Degussa Ag | Process for the conversion of polysulfanes |
| US7604788B2 (en) | 2002-09-26 | 2009-10-20 | Evonik Degussa Gmbh | Process for the conversion of polysulfanes |
| DE102007007458A1 (en) | 2007-02-15 | 2008-08-21 | Evonik Degussa Gmbh | Process for the preparation of methyl mercaptan from dialkyl sulfides and dialkyl polysulfides |
| US7994366B2 (en) | 2007-05-25 | 2011-08-09 | Evonik Degussa Gmbh | Process for continuously preparing methyl mercaptan from carbon- and hydrogen-containing compounds |
| US9745262B2 (en) | 2009-07-20 | 2017-08-29 | Evonik Degussa Gmbh | Process for continuously preparing methyl mercaptan from carbon compounds, sulfur and hydrogen |
| US10562831B2 (en) | 2015-09-21 | 2020-02-18 | Arkema Inc. | Process for making tetrachloropropene by catalyzed gas-phase dehydrochlorination of pentachloropropane |
| EP3405271A4 (en) * | 2016-01-22 | 2019-08-21 | Arkema, Inc. | PURIFICATION OF MERCAPTANS OR THIOPHENES USING A CLOSED DISTILLATION COLUMN |
| US10807949B2 (en) | 2016-01-22 | 2020-10-20 | Arkema Inc. | Purification of mercaptans or thiophenes using dividing wall column distillation |
| CN116940550A (en) * | 2020-12-17 | 2023-10-24 | 阿科玛法国公司 | Method for preparing methyl mercaptan by treating gaseous waste |
Also Published As
| Publication number | Publication date |
|---|---|
| NL146799B (en) | 1975-08-15 |
| FR2012271A1 (en) | 1970-03-20 |
| JPS5024939B1 (en) | 1975-08-20 |
| DE1768826B1 (en) | 1971-08-26 |
| CH525199A (en) | 1972-07-15 |
| BE735619A (en) | 1969-12-16 |
| AT289048B (en) | 1971-03-25 |
| NL6907265A (en) | 1970-01-06 |
| YU165569A (en) | 1974-10-31 |
| YU32635B (en) | 1975-04-30 |
| RO56554A (en) | 1974-11-11 |
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