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GB1103585A - Improvements in or relating to the processing of clay - Google Patents

Improvements in or relating to the processing of clay

Info

Publication number
GB1103585A
GB1103585A GB8745/64A GB874564A GB1103585A GB 1103585 A GB1103585 A GB 1103585A GB 8745/64 A GB8745/64 A GB 8745/64A GB 874564 A GB874564 A GB 874564A GB 1103585 A GB1103585 A GB 1103585A
Authority
GB
United Kingdom
Prior art keywords
suspension
water
flotation
clay
impurities
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8745/64A
Inventor
Edwin Kenneth Cundy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imerys Minerals Ltd
Original Assignee
English Clays Lovering Pochin Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by English Clays Lovering Pochin Co Ltd filed Critical English Clays Lovering Pochin Co Ltd
Priority to GB8745/64A priority Critical patent/GB1103585A/en
Priority to FR7633A priority patent/FR1425881A/en
Priority to US683149A priority patent/US3450257A/en
Publication of GB1103585A publication Critical patent/GB1103585A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/04—Clay; Kaolin
    • C04B33/06—Rendering lime harmless
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/002—Inorganic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/008—Organic compounds containing oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes
    • B03D1/06—Froth-flotation processes differential
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/10—Eliminating iron or lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/30—Drying methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/007—Modifying reagents for adjusting pH or conductivity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/04—Frothers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02—Ores
    • B03D2203/04—Non-sulfide ores
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S209/00—Classifying, separating, and assorting solids
    • Y10S209/901—Froth flotation; copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Physical Water Treatments (AREA)
  • Degasification And Air Bubble Elimination (AREA)

Abstract

Clay, e.g. kaolin or china clay, is treated to remove titanium mineral impurities by mixing with a suspension of the clay in water a flotation assistant consisting of a water-soluble salt of an alkaline earth (including magnesium) metal or a metal having a sp. gr. greater than 4, an alkali to raise the pH to about 9, a collector for impurities, a frothing agent and subjecting the suspension to a froth flotation process. The suspension may first be deflocculated by adding a deflocculating agent, e.g. sodium silicate, and after adding all the reagents the suspension may be conditioned by agitation. Before flotation is commenced the suspension may be diluted with water to a solids content of 15-20% w./v. The collector for impurities may be oleic acid, the frothing agent pine oil and the alkali ammonium hydroxide. The compounds specified as flotation assistants are water-soluble salts of Ca, Sr, Cu11, Fc11, Pb11, Mn11, and Zn and especially lead acetate, lead nitrate and barium chloride.ALSO:Clay e.g. kaolin or china clay, is treated to remove titanium mineral impurities by mixing with a suspension of the clay in water a flotation assistant consisting of a water soluble salt of an alkaline earth (including magnesium) metal or a metal having a sp.gr. greater than 4, an alkali to raise the pH to about 9, a collector for impurities, a frothing agent and subjecting the suspension to a froth flotation process. The suspension may first be deflocculated by adding a deflocculating agent e.g. sodium silicate, and after adding all the reagents the suspension may be conditioned by agitation. Before flotation is commenced the suspension may be diluted with water to a solids content of 15-20% w/v. The collector for impurities may be oleic acid, the frothing agent pine oil and the alkali ammonium hydroxide. The compounds specified as flotation assistants are water soluble salts of Ca, Sr, CuII, FcII, PbII, MnII, and Zn and especially lead acetate, lead nitrate and barium chloride.
GB8745/64A 1964-03-02 1964-03-02 Improvements in or relating to the processing of clay Expired GB1103585A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB8745/64A GB1103585A (en) 1964-03-02 1964-03-02 Improvements in or relating to the processing of clay
FR7633A FR1425881A (en) 1964-03-02 1965-03-02 Improvements in clay processing
US683149A US3450257A (en) 1964-03-02 1967-11-15 Processing of clay

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8745/64A GB1103585A (en) 1964-03-02 1964-03-02 Improvements in or relating to the processing of clay

Publications (1)

Publication Number Publication Date
GB1103585A true GB1103585A (en) 1968-02-14

Family

ID=9858462

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8745/64A Expired GB1103585A (en) 1964-03-02 1964-03-02 Improvements in or relating to the processing of clay

Country Status (3)

Country Link
US (1) US3450257A (en)
FR (1) FR1425881A (en)
GB (1) GB1103585A (en)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3979282A (en) * 1968-03-11 1976-09-07 English Clays Lovering Pochin & Company Limited Flotation of fine-grained materials
US3770213A (en) * 1972-01-18 1973-11-06 Bethlehem Steel Corp Process for separating carbon from iron-bearing fines in blast furnace flue dusts
US3919079A (en) * 1972-06-28 1975-11-11 David Weston Flotation of sulphide minerals from sulphide bearing ore
US3915391A (en) * 1972-07-17 1975-10-28 Engelhard Min & Chem Recovery of scheelite from ores by flotation
US3964997A (en) * 1973-10-24 1976-06-22 David Weston Concentration of gold, sulphide minerals and uranium oxide minerals by flotation from ores and metallurgical plant products
US3974067A (en) * 1974-10-08 1976-08-10 Anglo-American Clays Corporation Method for improving clay brightness utilizing magnetic separation
US4014709A (en) * 1976-06-08 1977-03-29 Engelhard Minerals & Chemicals Corporation Opacifying pigments and methods for making same
US4098688A (en) * 1976-07-21 1978-07-04 Anglo-American Clays Corporation Brightening of clay by froth flotation
US4492628A (en) * 1982-08-25 1985-01-08 Freeport Kaolin Company Method of treating clay to improve its whiteness
US4501658A (en) * 1982-08-25 1985-02-26 Freeport Kaolin Company Method of conditioning clay for flotation using in situ ferrous activator
US4472271A (en) * 1982-08-25 1984-09-18 Freeport Kaolin Company Froth flotation apparatus and process
US4514288A (en) * 1983-10-13 1985-04-30 Mobil Oil Corporation Ore beneficiation process
US4629556A (en) * 1984-11-29 1986-12-16 Thiele Kaolin Company Purification of kaolin clay by froth flotation using hydroxamate collectors
US5137574A (en) * 1988-12-22 1992-08-11 Ecc America Inc. Method for producing high opacifying kaolin pigment
US5180511A (en) * 1989-09-14 1993-01-19 J.M. Huber Corporation Flotation aid and process for removal of impurities from silicate minerals
US5037534A (en) * 1989-09-14 1991-08-06 J. M. Huber Corporation Flotation aid and process for removal of impurities from silicate minerals
US4997550A (en) * 1989-11-13 1991-03-05 Ecc America Inc. Method for improved flotation of discoloring impurities from kaolinite
US5213687A (en) * 1990-06-04 1993-05-25 Ecc International Inc. Apparatus for filtering mineral slurries
US5223155A (en) * 1990-06-04 1993-06-29 Ecc International Inc. Method for filtering mineral slurries
FI943439A7 (en) * 1992-01-22 1994-09-21 Eec Int Inc Device for filtering mineral sludge
US5332493A (en) * 1992-04-28 1994-07-26 Ecc International Inc. Method for improving rheological properties of kaolin clays
US5371051A (en) * 1993-12-23 1994-12-06 Ecc International Inc. Method for producing high opacifying kaolin pigment
US5454865A (en) * 1993-12-23 1995-10-03 Ecc International Inc. Method for preparing refined kaolin in clay products
US5522986A (en) * 1995-03-03 1996-06-04 Thiele Kaolin Company Process for removing impurities from kaolin clays
US5522924A (en) * 1995-03-17 1996-06-04 Ecc International Inc. Method for producing high brightness low abrasion calcined kaolin pigment
US5685899A (en) * 1995-07-28 1997-11-11 Thiele Kaolin Company Process for conditioning kaolin clays prior to removing impurities
US5810998A (en) * 1997-06-05 1998-09-22 Thiele Kaolin Company Process for improving the brightness of fine-grained kaolin clays
US6186335B1 (en) 1998-03-20 2001-02-13 Thiele Kaolin Company Process for beneficiating kaolin clays
BR9909117A (en) 1998-03-27 2000-12-19 Cytec Tech Corp Process for removing colored clay impurities
US6200377B1 (en) 1999-04-16 2001-03-13 Thiele Kaolin Company Process for beneficiation of mixtures of mineral particles
CA2510075A1 (en) * 2002-12-16 2004-07-22 Imerys Pigments, Inc. Fine platy kaolin composition
JP2006524175A (en) 2003-03-19 2006-10-26 アイメリーズ カオリン，インコーポレーテッド Calcined kaolin with extremely narrow particle size distribution
BRPI0508681A (en) * 2004-03-23 2007-08-21 Imerys Pigments Inc composition, method for reductively bleaching a mineral suspension, and, product
US8016936B2 (en) * 2004-05-03 2011-09-13 Imerys Pigments, Inc. Methods of calcining particulate material
WO2006076012A2 (en) * 2004-05-03 2006-07-20 Imerys Pigments, Inc. Compositions comprising kaolin having nanosize dimensions
US7393462B2 (en) 2004-05-13 2008-07-01 Cytec Technology Corp. Process and reagent for separating finely divided titaniferrous impurities from Kaolin
BRPI0500403A (en) * 2005-01-31 2006-09-12 Vale Do Rio Doce Co fine kaolin processing method
JP4144887B2 (en) * 2005-02-08 2008-09-03 インターナショナル・ビジネス・マシーンズ・コーポレーション Apparatus, method, and program for controlling tape drive
US7780779B2 (en) * 2005-02-23 2010-08-24 Imerys Pigments, Inc. Method for separating mixture of finely divided minerals
WO2006119063A2 (en) * 2005-05-02 2006-11-09 Imerys Pigments, Inc. Methods of heat-treating particulate material
US8083848B2 (en) * 2005-05-03 2011-12-27 Imerys Pigments, Inc. Compositions comprising fine sedimentary kaolin and methods for preparing same
US20090169890A1 (en) * 2005-12-21 2009-07-02 Pruett Robert J High Brightness and Low Abrasion Calcined Kaolin
CN102060303A (en) * 2010-12-03 2011-05-18 孝义市天章铝业有限公司 Method for preparing artificial mullite raw material by bauxite
CN115846052B (en) * 2022-12-20 2024-09-27 武汉理工大学 A method for regulating the spatial configuration of lithium clay agglomerates to improve flotation process

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1029579A (en) * 1911-08-29 1912-06-11 Botho Schwerin Method of separating substances in suspension by washing.
US2105826A (en) * 1935-10-18 1938-01-18 Phosphate Recovery Corp Concentration of nonmetallic minerals
US2249569A (en) * 1940-07-29 1941-07-15 Edgar Brothers Company Treatment of clay by flotation
US2249570A (en) * 1940-07-29 1941-07-15 Edgar Brothers Company Fractionation of clay
US2569680A (en) * 1949-02-04 1951-10-02 Edgar Brothers Company Flotation process for whitening clay
US2661842A (en) * 1950-08-03 1953-12-08 Attapulgus Minerals & Chemical Concentration of phosphate ores
US2861687A (en) * 1955-09-09 1958-11-25 Southwestern Eng Co Flotation of heavy metal oxides
US2894628A (en) * 1956-07-13 1959-07-14 Minerals & Chemicals Corp Of A Clay brightness by flotation
US2990958A (en) * 1958-12-09 1961-07-04 Minerals & Chem Philipp Corp Froth flotation method
US3164549A (en) * 1961-07-31 1965-01-05 Armour & Co Flotation separation of phosphate ores
US3353668A (en) * 1963-12-16 1967-11-21 Mineral & Chemicals Philipp Co Method for improving the brightness of clay
US3337048A (en) * 1964-12-02 1967-08-22 Minerals & Chem Philipp Corp Method for beneficiating clay by flotation
US3224582A (en) * 1965-06-01 1965-12-21 Huber Corp J M Kaolin clay beneficiation

Also Published As

Publication number Publication date
FR1425881A (en) 1966-01-24
US3450257A (en) 1969-06-17

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