FR2673640A1 - New compositions for household use, processes for their preparation and their applications especially in the field of household maintenance - Google Patents
New compositions for household use, processes for their preparation and their applications especially in the field of household maintenance Download PDFInfo
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- FR2673640A1 FR2673640A1 FR9102740A FR9102740A FR2673640A1 FR 2673640 A1 FR2673640 A1 FR 2673640A1 FR 9102740 A FR9102740 A FR 9102740A FR 9102740 A FR9102740 A FR 9102740A FR 2673640 A1 FR2673640 A1 FR 2673640A1
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- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims description 3
- 238000012423 maintenance Methods 0.000 title description 8
- 238000002360 preparation method Methods 0.000 title description 2
- 238000004040 coloring Methods 0.000 claims abstract description 11
- 239000002537 cosmetic Substances 0.000 claims description 5
- 238000010790 dilution Methods 0.000 claims description 5
- 239000012895 dilution Substances 0.000 claims description 5
- 239000000443 aerosol Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 230000002951 depilatory effect Effects 0.000 description 6
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- LDKDGDIWEUUXSH-UHFFFAOYSA-N Thymophthalein Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3C(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C LDKDGDIWEUUXSH-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 230000003796 beauty Effects 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 230000008034 disappearance Effects 0.000 description 3
- 210000004209 hair Anatomy 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 2
- MRDOFVRMTNWMDA-UHFFFAOYSA-N 2-bromo-4-[3-(3-bromo-4-hydroxy-2,5-dimethylphenyl)-1,1-dioxo-2,1$l^{6}-benzoxathiol-3-yl]-3,6-dimethylphenol Chemical compound BrC1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=C(Br)C(O)=C(C)C=2)C)=C1C MRDOFVRMTNWMDA-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- CBMCZKMIOZYAHS-NSCUHMNNSA-N [(e)-prop-1-enyl]boronic acid Chemical compound C\C=C\B(O)O CBMCZKMIOZYAHS-NSCUHMNNSA-N 0.000 description 1
- 239000002696 acid base indicator Substances 0.000 description 1
- 230000016571 aggressive behavior Effects 0.000 description 1
- 230000002009 allergenic effect Effects 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- CNYFJCCVJNARLE-UHFFFAOYSA-L calcium;2-sulfanylacetic acid;2-sulfidoacetate Chemical compound [Ca+2].[O-]C(=O)CS.[O-]C(=O)CS CNYFJCCVJNARLE-UHFFFAOYSA-L 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000007793 ph indicator Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- SMUQFGGVLNAIOZ-UHFFFAOYSA-N quinaldine Chemical compound C1=CC=CC2=NC(C)=CC=C21 SMUQFGGVLNAIOZ-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- LZTRCELOJRDYMQ-UHFFFAOYSA-N triphenylmethanol Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)C1=CC=CC=C1 LZTRCELOJRDYMQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/45—Colour indicators, e.g. pH- or Redox indicators
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
- A61Q9/04—Depilatories
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
La présente invention concerne de nouvelles compositions à usage ménager, leur procédé de préparation et leurs applications notamment dans le domaine de l'entretien ménager. The present invention relates to new compositions for household use, their preparation process and their applications in particular in the field of household maintenance.
On dispose de plus en plus dans la vie courante de produits toujours plus actifs ; cependant parfois cette forte activité va de pair avec une certaine agressivite ou des effets indésirables. Ever more active products are available in everyday life; however sometimes this strong activity goes hand in hand with a certain aggressiveness or undesirable effects.
En particulier, les produits de nettoyage ou d'entretien sanitaire sont parfois des produits alcalins incolores, et/ou de couleur blanche comme la grande majorité des appareils sanitaires. Le risque est donc important que la peau entre en contact avec ces produits qu'on aurait oublié d'éliminer, par exemple par rinçage. On pourrait envisager l'utilisation de produits d'entretien colorés, cependant ceux-ci colorent également de façon indélébile, par exemple les joints, notamment poreux, ou certaines parties des sanitaires. In particular, cleaning or sanitary maintenance products are sometimes colorless alkaline products, and / or white in color like the vast majority of sanitary appliances. There is therefore a significant risk that the skin will come into contact with these products that we would have forgotten to eliminate, for example by rinsing. One could consider the use of colored cleaning products, however these also color indelibly, for example the joints, in particular porous, or certain parts of the sanitary facilities.
Par ailleurs, il serait intéressant de connaître le moment auquel les produits ont fini d'exercer leur action, afin, par exemple, de ne pas attendre plus longtemps que nécessaire et ainsi gagner du temps et éviter qu'à la longue s'installe une agressivité quelconque. In addition, it would be interesting to know the moment when the products finished exercising their action, in order, for example, not to wait longer than necessary and thus save time and avoid that in the long run a any aggression.
C'est pourquoi la présente demande concerne des nouvelles compositions à usage ménager, caractérisées en ce qu'elles renferment un indicateur coloré en quantité telle que lors de l'utilisation prévue de cette composition l'on observe un virage de cet indicateur coloré. This is why the present application relates to new compositions for household use, characterized in that they contain a colored indicator in quantity such that during the intended use of this composition there is a shift in this colored indicator.
Par "composition à usage ménager" on entend notamment les produits d'entretien, tels que produits pour la vaisselle, nettoyants ammoniaqués, détergents, nettoyants pour fours, et particulièrement les produits d'entretien sanitaire tels que pour baignoires, WC, bidets, et les produits d'entretien des sols. By "composition for household use" is meant in particular cleaning products, such as dishwashing products, ammonia cleaners, detergents, oven cleaners, and in particular sanitary cleaning products such as for baths, toilets, bidets, and floor care products.
L'on entend également les produits cosmétiques, notamment ceux pour lesquels une durée d'action déterminée est requise, tels que, par exemple, les masques de beauté et en particulier les dépilatoires. We also mean cosmetic products, in particular those for which a determined duration of action is required, such as, for example, beauty masks and in particular depilatories.
On entend également d'autres produits tels que les colles et de manière générale les produits tant à usage privé que professionnel que l'on trouve habituellement chez les particuliers. We also mean other products such as glues and in general products for both private and professional use that are usually found in individuals.
Par indicateur coloré l'on entend les indicateurs de pH bien connus, encore appelés indicateurs acide-base. Ce sont généralement des colorants organiques avec un caractère acido-basique présentant à l'état nondissocié une autre couleur et une autre constitution que sous forme ionique. By colored indicator is meant the well-known pH indicators, also called acid-base indicators. They are generally organic dyes with an acid-base character presenting in the nondissociated state another color and another constitution than in ionic form.
Ces indicateurs peuvent être soit colorés et changer de couleur, soit colorés et virer à l'incolore, soit encore être incolores et virer à une couleur. On peut citer, par exemple, l'acide picrique, le pentaméthoxy 2,2' , 2", 4,4 '-triphénylcarbinol, le dinitro-2,4-phénol, le rouge Congo, le dinitro-2,5-phénol, le bleu de bromoxylénol, la tétrabromo-4,5,6,7-phtaléine, la phénolphtaléine ou la thymolphtaléine, le rouge de quinaldine, le nitro-2phénol, le nitro-3-phénol, le nitro-4-phénol. These indicators can be either colored and change color, or colored and turn colorless, or even be colorless and turn color. We can cite, for example, picric acid, pentamethoxy 2,2 ', 2 ", 4,4' -triphenylcarbinol, dinitro-2,4-phenol, Congo red, dinitro-2,5-phenol , bromoxylenol blue, tetrabromo-4,5,6,7-phthalein, phenolphthalein or thymolphthalein, quinaldine red, nitro-2phenol, nitro-3-phenol, nitro-4-phenol.
Par "utilisation prévue" l'on entend l'utilisation habituelle qui est faite de ladite composition. Par exemple pour un produit d'entretien sanitaire, notamment pour baignoires, habituellement l'on pulvérise ladite composition sur les parois de la baignoire et généralement sur les carrelages alentours, puis après une durée d'action variable, généralement de plusieurs minutes, on rince ladite composition, habituellement à l'aide de la douche. A titre d'autre exemple, on étale un produit dépilatoire sur la zone à épiler et au bout de quelques minutes on élimine par raclage le produit ainsi que les poils, puis on rince soigneusement la zone traitée. By "intended use" means the usual use which is made of said composition. For example for a sanitary maintenance product, in particular for baths, usually said composition is sprayed on the walls of the bath and generally on the surrounding tiles, then after a variable duration of action, generally of several minutes, it is rinsed said composition, usually using the shower. As another example, a depilatory product is spread over the area to be epilated and after a few minutes the product and the hairs are scraped off, then the treated area is thoroughly rinsed.
Le virage d'un indicateur coloré est un phénomène bien connu, généralement obtenu par addition d'un acide ou d'une base provoquant une modification de la couleur de 11 indicateur ; cette modification n'est habituellement pas brutale à un pH donné, mais continue dans une plage de pH caractéristique pour chaque indicateur. Dans le cadre de la présente invention, il n'y aura généralement pas addition d'un acide ou d'une base lors de l'utilisation prévue. Selon le cas, le virage pourra être obtenu par dilution, par exemple à grande eau, ou encore grâce à la disparition du produit qui, dans la composition, procurait le pH correspondant à la coloration de base de la composition. Par exemple, dans la cas du nettoyant sanitaire précité, le virage est obtenu par l'effet de dilution réalisé lors du rinçage.Dans le cas d'un dépilatoire, également basique, le virage sera obtenu grâce à la disparition progressive du principe actif qui détruit les pilosités, mais en même temps se dégrade au fur et à mesure qu'il remplit sa fonction. The turning of a colored indicator is a well-known phenomenon, generally obtained by adding an acid or a base causing a change in the color of the indicator; this change is usually not abrupt at a given pH, but continues within a characteristic pH range for each indicator. In the context of the present invention, there will generally be no addition of an acid or a base during the intended use. Depending on the case, the toning can be obtained by dilution, for example with large water, or also by the disappearance of the product which, in the composition, provided the pH corresponding to the basic coloring of the composition. For example, in the case of the aforementioned sanitary cleaner, the toning is obtained by the dilution effect produced during rinsing. In the case of a depilatory treatment, also basic, the toning will be obtained thanks to the progressive disappearance of the active principle which destroys the pilosity, but at the same time degrades as it fulfills its function.
Dans le cas d'un détartrant, par exemple pour
WC, le même phénomène est observé lors du rinçage et/ou si le calcaire est en quantité suffisante pour faire remonter le pH au-delà de la zone de virage.In the case of a descaler, for example for
WC, the same phenomenon is observed during rinsing and / or if the limescale is in sufficient quantity to raise the pH beyond the turning zone.
Les compositions à usage ménager selon l'invention se présenteront de préférence sous forme d'un aérosol. The compositions for household use according to the invention will preferably be in the form of an aerosol.
La quantité d'indicateur coloré que renferme les compositions ci-dessus peut aller de 0,0001 à 1,0 % en poids de la composition, notamment de 0,001 à 0,1 % et plus particulièrement de 0,002 à 0,008 %. La quantité suffisante pour observer nettement l'effet de (dé) coloration désiré peut être déterminée facilement par l'homme de l'art à laide de quelques expérimentations simples telles que des essais à concentration croissante. The quantity of colored indicator contained in the above compositions can range from 0.0001 to 1.0% by weight of the composition, in particular from 0.001 to 0.1% and more particularly from 0.002 to 0.008%. The amount sufficient to clearly observe the desired (de) coloring effect can be easily determined by those skilled in the art using a few simple experiments such as increasing concentration tests.
Parmi les compositions selon l'invention on retient notamment celles caractérisées en ce que le virage de l'indicateur coloré est obtenu par dilution. On peut citer notamment les nettoyants, produits d'entretien de sols et de sanitaires. On retient également celles carac térisées en ce que le virage est obtenu par simple action normale de la composition elle-même au bout d'un certain temps. On retient alors plus particulièrement les produits d'entretien pour fours, les détartrants, les dépilatoires et les masques de beauté. Among the compositions according to the invention, in particular, those characterized in that the change in color indicator is obtained by dilution. Mention may in particular be made of cleaners, floor and sanitary maintenance products. We also retain those characterized in that the turn is obtained by simple normal action of the composition itself after a certain time. We then retain more particularly the cleaning products for ovens, descalers, depilatories and beauty masks.
Parmi les compositions ci-dessus, on retient celles renfermant un indicateur coloré à l'origine, virant au non-coloré (par non-coloré, l'on entend ici les compositions incolores ou blanches). A cet égard, on retient plus particulièrement la phénolphtaléine, la tétrabromo-4,5,6,7-phtaléine, et tout particulièrement la thymolphtalêine et le pentaméthoxy-2,2',2",4,4' triphénylcarbinol. On retient tout autant celles dont l'indicateur n'est pas coloré (blanc ou incolore) et qui virent à une certaine couleur. A cet égard, on retient tout particulièrement l'acide picrique, le rouge quinaldine, les dinitro2,4 ou -2,5-phénol, ou encore le nitro-2-phénol. Among the above compositions, we retain those containing an indicator originally colored, turning to non-colored (by non-colored, we mean here colorless or white compositions). In this regard, phenolphthalein, tetrabromo-4,5,6,7-phthalein, and more particularly thymolphthalein and pentamethoxy-2,2 ', 2 ", 4,4' triphenylcarbinol, are used in particular. as much those whose indicator is not colored (white or colorless) and which turn to a certain color. In this regard, we particularly note picric acid, quinaldin red, dinitro2,4 or -2,5 -phenol, or even nitro-2-phenol.
Les indicateurs ci-dessus peuvent être employés tant seuls qu'en mélange, de manière soit à renforcer le changement de coloration, soit encore à ajuster la zone de virage à une valeur prédéterminée de pH de la composition à colorer. The above indicators can be used both alone and as a mixture, so as either to reinforce the change in color, or else to adjust the turning zone to a predetermined pH value of the composition to be colored.
Parmi les compositions de l'invention on retient également les compositions destinées à l'entretien (produits d'entretien) et de même les produits destinés à l'utilisation cosmétique (produits cosmétiques). Dans ce dernier cas, l'indicateur coloré est non allergisant et atoxique par voie cutanée. L'homme de l'art peut sélectionner de tels indicateurs à l'aide de quelques tests simples, bien connus des dermatologues notamment. Among the compositions of the invention, the compositions intended for maintenance (maintenance products) and likewise the products intended for cosmetic use (cosmetic products) are also retained. In the latter case, the colored indicator is non-allergenic and non-toxic through the skin. Those skilled in the art can select such indicators using a few simple tests, well known to dermatologists in particular.
On pourra selectionner l'indicateur coloré ou le mélange d'indicateurs coloré de manière à obtenir le virage selon le cas dans une zone proche du pH naturel de la composition, soit alors éloigné lorsque l'on veut, dans le cas d'un changement de pH par dilution, que le rinçage soit particulièrement soigné. It will be possible to select the colored indicator or the mixture of colored indicators so as to obtain the shift, as the case may be, in an area close to the natural pH of the composition, or then distant when desired, in the case of a change pH by dilution, that the rinsing is particularly careful.
La présente invention a également pour objet un procédé de préparation des compositions ci-dessus décrites, caractérisé en ce que l'on ajoute un indicateur coloré à une composition à usage ménager pour obtenir la composition attendue. Cette addition d'indicateur coloré pourra se faire selon le cas à la fin du procédé d'élaboration de la composition ou encore au cours de celle-ci, selon les méthodes bien connues en elles-mêmes. The present invention also relates to a process for preparing the compositions described above, characterized in that a colored indicator is added to a composition for household use to obtain the expected composition. This addition of colored indicator may be done, as the case may be, at the end of the process for preparing the composition or even during the latter, according to methods well known in themselves.
Les compositions selon l'invention présentent de remarquables avantages. Dans le cas d'un nettoyant ménager ou industriel, par exemple, les surfaces à nettoyer sont souvent de couleur blanche ou pâle ( sanitaires de salles de bains, éviers...) et comportent généralement des joints en ciment, mortier, plâtre ou matière poreuse. Il est donc utile de colorer de tels produits pour savoir précisément où ils ont été appliqués, de manière notamment à économiser le produit et avoir un impact réduit sur ltenvironnement par diminution des rejets. Mais, les colorants habituels confèrent aux produits une coloration permanente et peuvent aussi durablement colorer les joints ci-dessus. Les compositions selon l'invention permettent de pallier ces problèmes. The compositions according to the invention have remarkable advantages. In the case of a household or industrial cleaner, for example, the surfaces to be cleaned are often white or pale in color (bathroom sanitary ware, sinks, etc.) and generally include joints in cement, mortar, plaster or material. porous. It is therefore useful to color such products to know precisely where they have been applied, in particular so as to save the product and have a reduced impact on the environment by reducing discharges. However, the usual dyes give the products a permanent color and can also permanently color the above joints. The compositions according to the invention make it possible to overcome these problems.
C'est pourquoi la présente invention a aussi pour objet l'application d'un indicateur coloré à la coloration temporaire d'un produit à usage ménager. Par coloration temporaire l'on entend, comme déjà précisé cidessus, que le produit peut-être coloré ou non-coloré à l'origine, puis se décolore ou au contraire se colore. This is why the present invention also relates to the application of a colored indicator to the temporary coloring of a product for household use. By temporary coloring is meant, as already specified above, that the product may be colored or uncolored at the origin, then discolour or, on the contrary, color.
La présente demande a encore notamment pour objet l'application des indicateurs colorés à la coloration temporaire de produits ménagers tels que produits pour la vaisselle, nettoyants ammoniaqués, détergents, nettoyants à four, et particulièrement des produits d'entretien de sanitaires, tels que baignoires, WC, bidets, lavabos, et des sols. The present application also relates in particular to the application of colored indicators to the temporary coloring of household products such as dishwashing products, ammonia cleaners, detergents, oven cleaners, and in particular sanitary maintenance products, such as bathtubs , WC, bidets, sinks, and floors.
La présente demande a tout autant pour objet l'application d'un indicateur coloré à la coloration temporaire d'un produit cosmétique tel qu'un masque de beauté et en particulier un dépilatoire. The present application is just as much the application of a colored indicator to the temporary coloring of a cosmetic product such as a beauty mask and in particular a depilatory.
Les exemples qui suivent illustrent l'invention sans toutefois la limiter. The examples which follow illustrate the invention without however limiting it.
EXEMPLE 1
A. On a préparé un nettoyant ménager, notamment pour sanitaire, sous forme d'aérosol, ayant la composition suivante, exprimée en pourcentage pondéral
% en poids
eau déminéralisée 84,23
EDTA 4,3
butylglycol 1,9
amino méthyl propanol 1,0
octylphénol 9-10 OE 1,0
ammonium quaternaire 0,4
ammoniaque d = 1,180g/ml 0,12
parfum 0,25
alcool éthylique 0,495
thymolphtaléine 0,005
inhibiteurs de corrosion 1,3
butane 1,2 bar 5,0
B. Utilisation
On pulvérise sur les parois intérieures d'une baignoire, sur le carrelage environnant et sur les joints encrassés le produit ci-dessus. L'agréable couleur bleue de la mousse permet de vérifier instantanément quelles surfaces ont été effectivement traitées et quel est l'épaisseur appliquée, permettant ainsi des retouches si nécessaire.On laisse agir le produit. Environ 1 heure et demie plus tard la coloration est toujours présente et permet de se rendre compte qu'il est nécessaire de rincer le produit avant utilisation de la baignoire. On asperge d'eau à l'aide de la douche le produit qui est éliminé et dont la coloration bleue disparait tant sur la baignoire que sur les carrelages et les joints environnants.EXAMPLE 1
A. A household cleaner, in particular for sanitary cleaning, was prepared in the form of an aerosol, having the following composition, expressed as a percentage by weight
% in weight
demineralized water 84.23
EDTA 4.3
butylglycol 1.9
amino methyl propanol 1.0
octylphenol 9-10 OE 1.0
quaternary ammonium 0.4
ammonia d = 1,180g / ml 0.12
perfume 0.25
ethyl alcohol 0.495
thymolphthalein 0.005
corrosion inhibitors 1.3
butane 1.2 bar 5.0
B. Use
The above product is sprayed on the interior walls of a bathtub, on the surrounding tiles and on dirty joints. The pleasant blue color of the foam makes it possible to instantly check which surfaces have been effectively treated and which thickness is applied, thus allowing touch-ups if necessary. About 1 hour and a half later the coloring is still present and makes it possible to realize that it is necessary to rinse the product before using the bathtub. The product which is eliminated and whose blue color disappears both on the bathtub and on the tiles and surrounding joints is sprayed with water using the shower.
EXEMPLE 2
A. On a préparé un gel détartrant pour WC, ayant un pH d'environ 1,9, selon la composition pondérale suivante exprimée en pourcentage
% en poids
eau déminéralisée 92,79
alcool isopropylique 1,15
acide citrique 4,00
carboxyméthyl cellulose 0,20
octylphénol 9-10 OE 1,85 pentaméthoxy-2,2' ,2",4,4'-
triphénylcarbinol 0,01
B. Utilisation
On applique sur les parois d'une cuvette de WC très entartrée le gel de couleur rouge ci-dessus. La couleur permet de visualiser les parties traitées. La disparition de la coloration permet de vérifier que le produit a bien agi. On tire la chasse pour éliminer le gel.EXAMPLE 2
A. A descaling gel for WC, having a pH of about 1.9, was prepared according to the following weight composition expressed as a percentage
% in weight
demineralized water 92.79
isopropyl alcohol 1.15
citric acid 4.00
carboxymethyl cellulose 0.20
octylphenol 9-10 OE 1.85 pentamethoxy-2,2 ', 2 ", 4,4'-
triphenylcarbinol 0.01
B. Use
The above red gel is applied to the walls of a very scaled toilet bowl. The color allows to visualize the treated parts. The disappearance of the coloring makes it possible to verify that the product has acted well. We flush to remove the gel.
EXEMPLE 3
On a préparé une crème dépilatoire selon la composition pondérale suivante exprimée en pourcentage
% en poids
Thioglycolate de calcium
tri hydraté 6,0
Carbonate de calcium 21,0
Hydroxyde de calcium 1,5
Alcool céthylique 4,5
Lauryl sulfate de sodium 0,5
Silicate de sodium à d = 1,417 g/ml 3,5
Parfum 0,5
% en poids
Phénolphtaléine 0,005
Eau qsp 100 %
On applique sur la zone à épiler en couche épaisse la crème pour recouvrir les poils à éliminer. On laisse agir 5 à 15 minutes en fonction de la résistance des poils. On racle la crème à l'aide d'une spatule, puis on rince à l'eau jusqu'à disparition de la coloration rose violette. EXAMPLE 3
A depilatory cream was prepared according to the following weight composition expressed as a percentage
% in weight
Calcium thioglycolate
tri hydrated 6.0
Calcium carbonate 21.0
Calcium hydroxide 1.5
Cethyl alcohol 4.5
Sodium lauryl sulfate 0.5
Sodium silicate at d = 1.417 g / ml 3.5
Perfume 0.5
% in weight
Phenolphthalein 0.005
Water qs 100%
The cream is applied to the area to be epilated in a thick layer to cover the hairs to be removed. It is left to act for 5 to 15 minutes depending on the resistance of the hairs. The cream is scraped with a spatula, then rinsed with water until the purple pink color disappears.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9102740A FR2673640B1 (en) | 1991-03-07 | 1991-03-07 | NEW HOUSEHOLD COMPOSITIONS, THEIR PREPARATION PROCESS AND THEIR APPLICATIONS, PARTICULARLY IN THE FIELD OF HOUSEHOLD CARE. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9102740A FR2673640B1 (en) | 1991-03-07 | 1991-03-07 | NEW HOUSEHOLD COMPOSITIONS, THEIR PREPARATION PROCESS AND THEIR APPLICATIONS, PARTICULARLY IN THE FIELD OF HOUSEHOLD CARE. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2673640A1 true FR2673640A1 (en) | 1992-09-11 |
| FR2673640B1 FR2673640B1 (en) | 1994-08-19 |
Family
ID=9410455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR9102740A Expired - Fee Related FR2673640B1 (en) | 1991-03-07 | 1991-03-07 | NEW HOUSEHOLD COMPOSITIONS, THEIR PREPARATION PROCESS AND THEIR APPLICATIONS, PARTICULARLY IN THE FIELD OF HOUSEHOLD CARE. |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2673640B1 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999060089A1 (en) * | 1998-05-18 | 1999-11-25 | The Procter & Gamble Company | Implement containing cleaning composition and disappearing dye |
| US6677287B1 (en) | 1998-05-18 | 2004-01-13 | The Procter & Gamble Company | Implement containing cleaning composition and disappearing dye |
| WO2005103217A1 (en) * | 2004-04-21 | 2005-11-03 | Henkel Kommanditgesellschaft Auf Aktien | Consumption indicator for machine dishwashing agents |
| GB2415135A (en) * | 2004-06-15 | 2005-12-21 | Reckitt Benckiser | Improvements in and relating to depilatory compositions |
| FR2902322A1 (en) * | 2006-06-15 | 2007-12-21 | A2P Sas Soc Par Actions Simpli | Acid-based exfoliating composition useful for cosmetic treatment of the skin comprises a colored pH indicator |
| US20140158166A1 (en) * | 2012-12-10 | 2014-06-12 | Milliken & Company | Cleaning composition and method for using the same |
| EP3135751A1 (en) * | 2015-08-24 | 2017-03-01 | Ipc | Detergent composition containing a visual disinfection indicator |
| WO2019110092A1 (en) * | 2017-12-05 | 2019-06-13 | Toys Trend Ltd. | Bubble composition |
| GB2597800A (en) * | 2020-08-07 | 2022-02-09 | Sasha Sherbert Ltd | Hair removal formulation |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2020274035B2 (en) | 2019-05-10 | 2023-02-02 | Ecolab Usa Inc. | pH sensitive color indicator for sanitizing applications |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3595798A (en) * | 1967-12-18 | 1971-07-27 | Lever Brothers Ltd | Cleansing compositions |
| US3650831A (en) * | 1969-03-10 | 1972-03-21 | Armour Dial Inc | Method of cleaning surfaces |
| FR2108419A5 (en) * | 1970-09-23 | 1972-05-19 | Unilever Nv | |
| FR2115825A5 (en) * | 1970-11-25 | 1972-07-07 | Dainichiseika Color Chem | Detergent composition |
| DE2133710A1 (en) * | 1971-07-07 | 1973-01-25 | Krisp Kg Kukirol | Dental prosthetic cleaning agent - a blue tablet contg perborate and an indigo dye redox indicator |
| FR2404067A1 (en) * | 1977-09-27 | 1979-04-20 | Exterma Germ Prod | TREATMENT PROCESS FOR CONTROLLING THE PRESENCE OF AN IMPREGNATION PRODUCT IN A SUBSTRATE, ESPECIALLY IN A CLOTH IMPREGNATED WITH DISINFECTANT, CLOTH THUS TREATED AND HYGIENE ARTICLE CONSTITUTED OF SUCH A CLOTH |
| US4248827A (en) * | 1978-06-12 | 1981-02-03 | The Procter & Gamble Company | Method for sanitizing toilets |
| US4308625A (en) * | 1978-06-12 | 1982-01-05 | The Procter & Gamble Company | Article for sanitizing toilets |
| EP0369500A2 (en) * | 1988-10-18 | 1990-05-23 | The Procter & Gamble Company | Acid liquid fabric softener changing colour when diluted |
-
1991
- 1991-03-07 FR FR9102740A patent/FR2673640B1/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3595798A (en) * | 1967-12-18 | 1971-07-27 | Lever Brothers Ltd | Cleansing compositions |
| US3650831A (en) * | 1969-03-10 | 1972-03-21 | Armour Dial Inc | Method of cleaning surfaces |
| FR2108419A5 (en) * | 1970-09-23 | 1972-05-19 | Unilever Nv | |
| FR2115825A5 (en) * | 1970-11-25 | 1972-07-07 | Dainichiseika Color Chem | Detergent composition |
| DE2133710A1 (en) * | 1971-07-07 | 1973-01-25 | Krisp Kg Kukirol | Dental prosthetic cleaning agent - a blue tablet contg perborate and an indigo dye redox indicator |
| FR2404067A1 (en) * | 1977-09-27 | 1979-04-20 | Exterma Germ Prod | TREATMENT PROCESS FOR CONTROLLING THE PRESENCE OF AN IMPREGNATION PRODUCT IN A SUBSTRATE, ESPECIALLY IN A CLOTH IMPREGNATED WITH DISINFECTANT, CLOTH THUS TREATED AND HYGIENE ARTICLE CONSTITUTED OF SUCH A CLOTH |
| US4248827A (en) * | 1978-06-12 | 1981-02-03 | The Procter & Gamble Company | Method for sanitizing toilets |
| US4308625A (en) * | 1978-06-12 | 1982-01-05 | The Procter & Gamble Company | Article for sanitizing toilets |
| EP0369500A2 (en) * | 1988-10-18 | 1990-05-23 | The Procter & Gamble Company | Acid liquid fabric softener changing colour when diluted |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999060089A1 (en) * | 1998-05-18 | 1999-11-25 | The Procter & Gamble Company | Implement containing cleaning composition and disappearing dye |
| US6677287B1 (en) | 1998-05-18 | 2004-01-13 | The Procter & Gamble Company | Implement containing cleaning composition and disappearing dye |
| WO2005103217A1 (en) * | 2004-04-21 | 2005-11-03 | Henkel Kommanditgesellschaft Auf Aktien | Consumption indicator for machine dishwashing agents |
| GB2415135A (en) * | 2004-06-15 | 2005-12-21 | Reckitt Benckiser | Improvements in and relating to depilatory compositions |
| FR2902322A1 (en) * | 2006-06-15 | 2007-12-21 | A2P Sas Soc Par Actions Simpli | Acid-based exfoliating composition useful for cosmetic treatment of the skin comprises a colored pH indicator |
| WO2014092865A3 (en) * | 2012-12-10 | 2014-09-12 | Milliken & Company | Cleaning composition and method for using the same |
| US20140158166A1 (en) * | 2012-12-10 | 2014-06-12 | Milliken & Company | Cleaning composition and method for using the same |
| US9688946B2 (en) | 2012-12-10 | 2017-06-27 | Milliken & Company | Cleaning composition and method for using the same |
| US10435650B2 (en) | 2012-12-10 | 2019-10-08 | Milliken & Company | Cleaning composition and method for using the same |
| EP3135751A1 (en) * | 2015-08-24 | 2017-03-01 | Ipc | Detergent composition containing a visual disinfection indicator |
| FR3040394A1 (en) * | 2015-08-24 | 2017-03-03 | Ipc | DETERGENT COMPOSITION CONTAINING A VISUAL DISINFECTION LAMP |
| WO2019110092A1 (en) * | 2017-12-05 | 2019-06-13 | Toys Trend Ltd. | Bubble composition |
| GB2597800A (en) * | 2020-08-07 | 2022-02-09 | Sasha Sherbert Ltd | Hair removal formulation |
| GB2597800B (en) * | 2020-08-07 | 2023-08-16 | Sasha Sherbert Ltd | Hair removal formulation |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2673640B1 (en) | 1994-08-19 |
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