FR2322650A1 - Hydrodesulphurisation catalyst prepn. - by addn. of Gp. VIII and VIB metal cpds. to aluminium chloride hydrosol contg. urea and hexamethylene tetramine - Google Patents
Hydrodesulphurisation catalyst prepn. - by addn. of Gp. VIII and VIB metal cpds. to aluminium chloride hydrosol contg. urea and hexamethylene tetramineInfo
- Publication number
- FR2322650A1 FR2322650A1 FR7527436A FR7527436A FR2322650A1 FR 2322650 A1 FR2322650 A1 FR 2322650A1 FR 7527436 A FR7527436 A FR 7527436A FR 7527436 A FR7527436 A FR 7527436A FR 2322650 A1 FR2322650 A1 FR 2322650A1
- Authority
- FR
- France
- Prior art keywords
- hydrosol
- urea
- hexamethylene tetramine
- vib metal
- viii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052751 metal Inorganic materials 0.000 title abstract 4
- 239000002184 metal Substances 0.000 title abstract 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title abstract 3
- 239000004202 carbamide Substances 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 3
- 235000010299 hexamethylene tetramine Nutrition 0.000 title abstract 3
- 239000004312 hexamethylene tetramine Substances 0.000 title abstract 3
- 229960004011 methenamine Drugs 0.000 title abstract 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 title 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 abstract 2
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 238000001879 gelation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000010763 heavy fuel oil Substances 0.000 abstract 1
- 239000000017 hydrogel Substances 0.000 abstract 1
- 150000004706 metal oxides Chemical group 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A catalyst contg. 5-20 wt.% Gp. VIB metal in oxide form and 0, 1-10 wt.% Gp. VIII metal oxide form, with an Al2O3 carrier, is prepd. by (a) mixing Al(SO4)3 and NH4OH in aq. soln. at pH 5.5-6.5, to ppt. a basic Al sulphate; (b) dissolving the basic Al sulphate and a sol. Gp. VIII metal cpd., which decomposes to the oxide, in an Al chloride hydrosol with wt. ratio Al: Cl' of 0.9-1.4:1;(c) mixing MoO3 or a soluble Gp. VIB metal cpd., which decomposes on heating to the oxide, with an aq. soln. of urea and hexamethylene tetramine, and dissolving the mixt. in the hydrosol; (d) dispersing the hydrosol as droplets in a hot oil bath, to cause gelation of the hydrosol; and (e) ageing the hydrogel spheres at a temp. which causes decompsn. of the residual urea and hexamethylene tetramine, and washing, drying and calcining the aged spheres. The catalyst is used for hydro-desulphurisation of petroleum fractions, e.g. residual fuel oils.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7527436A FR2322650A1 (en) | 1975-09-08 | 1975-09-08 | Hydrodesulphurisation catalyst prepn. - by addn. of Gp. VIII and VIB metal cpds. to aluminium chloride hydrosol contg. urea and hexamethylene tetramine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7527436A FR2322650A1 (en) | 1975-09-08 | 1975-09-08 | Hydrodesulphurisation catalyst prepn. - by addn. of Gp. VIII and VIB metal cpds. to aluminium chloride hydrosol contg. urea and hexamethylene tetramine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2322650A1 true FR2322650A1 (en) | 1977-04-01 |
| FR2322650B1 FR2322650B1 (en) | 1981-04-17 |
Family
ID=9159703
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7527436A Granted FR2322650A1 (en) | 1975-09-08 | 1975-09-08 | Hydrodesulphurisation catalyst prepn. - by addn. of Gp. VIII and VIB metal cpds. to aluminium chloride hydrosol contg. urea and hexamethylene tetramine |
Country Status (1)
| Country | Link |
|---|---|
| FR (1) | FR2322650A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2765118C1 (en) * | 2021-03-24 | 2022-01-25 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Method for obtaining a spherical aluminum oxide carrier |
-
1975
- 1975-09-08 FR FR7527436A patent/FR2322650A1/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2765118C1 (en) * | 2021-03-24 | 2022-01-25 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Method for obtaining a spherical aluminum oxide carrier |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2322650B1 (en) | 1981-04-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |