FR2267380A1 - Extracting polyvalent metal ions from aqs. soln. - with phosphorus acid cpds. in presence of a neutral sulphate of chloride salt - Google Patents
Extracting polyvalent metal ions from aqs. soln. - with phosphorus acid cpds. in presence of a neutral sulphate of chloride saltInfo
- Publication number
- FR2267380A1 FR2267380A1 FR7511270A FR7511270A FR2267380A1 FR 2267380 A1 FR2267380 A1 FR 2267380A1 FR 7511270 A FR7511270 A FR 7511270A FR 7511270 A FR7511270 A FR 7511270A FR 2267380 A1 FR2267380 A1 FR 2267380A1
- Authority
- FR
- France
- Prior art keywords
- extracting
- sodium
- neutral salt
- metal ions
- polyvalent metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000007935 neutral effect Effects 0.000 title abstract 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title abstract 2
- 229910021645 metal ion Inorganic materials 0.000 title abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 2
- 239000011574 phosphorus Substances 0.000 title abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title 1
- 150000003841 chloride salts Chemical class 0.000 title 1
- 229910021653 sulphate ion Inorganic materials 0.000 title 1
- 150000003839 salts Chemical class 0.000 abstract 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 238000000605 extraction Methods 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 2
- 239000001166 ammonium sulphate Substances 0.000 abstract 2
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 235000011152 sodium sulphate Nutrition 0.000 abstract 2
- UGIWGFXQNPWKPR-UHFFFAOYSA-N 2-ethylhexyl phenyl hydrogen phosphate Chemical compound CCCCC(CC)COP(O)(=O)OC1=CC=CC=C1 UGIWGFXQNPWKPR-UHFFFAOYSA-N 0.000 abstract 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- KHWYXZPBJAFOJR-UHFFFAOYSA-N bis(3-ethylhexyl) hydrogen phosphate Chemical compound CCCC(CC)CCOP(O)(=O)OCCC(CC)CCC KHWYXZPBJAFOJR-UHFFFAOYSA-N 0.000 abstract 1
- 239000001110 calcium chloride Substances 0.000 abstract 1
- 229910001628 calcium chloride Inorganic materials 0.000 abstract 1
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
- 235000011147 magnesium chloride Nutrition 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
- 235000015424 sodium Nutrition 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/385—Thiophosphoric acids, or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3842—Phosphinic acid, e.g. H2P(O)(OH)
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3844—Phosphonic acid, e.g. H2P(O)(OH)2
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/387—Cyclic or polycyclic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Extracting polyvalent metal ions from aq. solns. or suspensions of their salts using an essentially water-insoluble phosphorus acid of general formula (I) (where R1 and R2 are each opt. substd. aliphatic araliphatic or aromatic radicals and R1 and R2 can also be linked to the P atom via an oxygen atom). the solution also contg. at least one neutral salt of sulphuric or hydrochloric acid. Specifically using di (3-ethyl-1-hexyl)phosphate or phenyl (2-ethyl-1-hexyl) phosphate with sodium or magnesium chloride, or sodium or ammonium sulphate as the neutral salt. Particularly for extracting Fe+++ using sodium chloride and/or ammonium chloride and/or calcium chloride as the neutral salt; also extracting Zn using sodium and/or ammonium sulphate. The extraction may also be carried out in the presence of an organic solvent pref. benzene, toluene, xylene, hexane, cyclohexane or heptane. The extraction is pref. carried out at 0-75 degrees C and pH 0-5. Improved extraction is achieved as a result of the neutral salt present.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2417510A DE2417510A1 (en) | 1974-04-10 | 1974-04-10 | PROCESS FOR EXTRACTION OF METALS FROM Aqueous SOLUTIONS WITH ACID PHOSPHORUS COMPOUNDS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2267380A1 true FR2267380A1 (en) | 1975-11-07 |
| FR2267380B1 FR2267380B1 (en) | 1979-03-09 |
Family
ID=5912685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR7511270A Granted FR2267380A1 (en) | 1974-04-10 | 1975-04-10 | Extracting polyvalent metal ions from aqs. soln. - with phosphorus acid cpds. in presence of a neutral sulphate of chloride salt |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS50141579A (en) |
| BE (1) | BE827731A (en) |
| DE (1) | DE2417510A1 (en) |
| FR (1) | FR2267380A1 (en) |
| LU (1) | LU72237A1 (en) |
| NL (1) | NL7504124A (en) |
| NO (1) | NO751058L (en) |
| SE (1) | SE388129B (en) |
| ZA (1) | ZA752252B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2344637A1 (en) * | 1976-03-15 | 1977-10-14 | Mineral Chem Resource Co | TREATMENT OF ZINC BY ION EXCHANGE |
| FR2434869A1 (en) * | 1978-07-24 | 1980-03-28 | Nippon Mining Co | PROCESS FOR SEPARATING COBALT AND NICKEL FROM A SOLUTION CONTAINING THEM |
| EP0023428A1 (en) * | 1979-07-30 | 1981-02-04 | The British Petroleum Company p.l.c. | Liquid-liquid process for extracting metals using organo-phosphorous compounds |
| EP0046933A3 (en) * | 1980-08-28 | 1982-03-24 | Cyanamid Canada Inc. | Extraction process for the selective removal of cobalt (ii) from aqueous solutions |
| EP0156735A1 (en) * | 1984-04-02 | 1985-10-02 | Rhone-Poulenc Chimie | Process for separating rare earths by liquid-liquid extraction |
| USRE48165E1 (en) | 2014-10-17 | 2020-08-18 | Merck Patent Gmbh | Alkenyl (perfluoroalkyl) phosphinic acids |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3140380C2 (en) * | 1981-10-10 | 1985-04-11 | Gebrüder Sulzer AG, Winterthur | Process for the extraction of nickel, high-purity magnesium oxide and cement |
| FI70049C (en) * | 1984-07-03 | 1986-09-12 | Outokumpu Oy | VAETSKE-VAETSKE-EXTRAKTIONSFOERFARANDE FOER AVLAEGSNANDE OCH UTVINNING AV METALLER UR VATTENLOESNINGAR |
-
1974
- 1974-04-10 DE DE2417510A patent/DE2417510A1/en active Pending
-
1975
- 1975-03-26 NO NO751058A patent/NO751058L/no unknown
- 1975-04-07 NL NL7504124A patent/NL7504124A/en unknown
- 1975-04-08 LU LU72237A patent/LU72237A1/xx unknown
- 1975-04-08 JP JP50041924A patent/JPS50141579A/ja active Pending
- 1975-04-09 ZA ZA00752252A patent/ZA752252B/en unknown
- 1975-04-09 BE BE155231A patent/BE827731A/en unknown
- 1975-04-09 SE SE7504086A patent/SE388129B/en unknown
- 1975-04-10 FR FR7511270A patent/FR2267380A1/en active Granted
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2344637A1 (en) * | 1976-03-15 | 1977-10-14 | Mineral Chem Resource Co | TREATMENT OF ZINC BY ION EXCHANGE |
| FR2434869A1 (en) * | 1978-07-24 | 1980-03-28 | Nippon Mining Co | PROCESS FOR SEPARATING COBALT AND NICKEL FROM A SOLUTION CONTAINING THEM |
| EP0023428A1 (en) * | 1979-07-30 | 1981-02-04 | The British Petroleum Company p.l.c. | Liquid-liquid process for extracting metals using organo-phosphorous compounds |
| FR2462481A1 (en) * | 1979-07-30 | 1981-02-13 | British Petroleum Co | METHOD FOR THE LIQUID-LIQUID EXTRACTION OF AQUEOUS SOLUTION-BASED METALS USING ORGANOPHOSPHORUS DERIVATIVES |
| EP0046933A3 (en) * | 1980-08-28 | 1982-03-24 | Cyanamid Canada Inc. | Extraction process for the selective removal of cobalt (ii) from aqueous solutions |
| EP0046940A3 (en) * | 1980-08-28 | 1982-03-24 | Cyanamid Canada Inc. | Extraction process for the selective removal of cobalt (ii) from aqueous solutions |
| EP0236542A3 (en) * | 1980-08-28 | 1987-11-25 | Cyanamid Canada Inc. | Novel organic phosphinic acid compounds and their use for metal extraction |
| EP0156735A1 (en) * | 1984-04-02 | 1985-10-02 | Rhone-Poulenc Chimie | Process for separating rare earths by liquid-liquid extraction |
| US4647438A (en) * | 1984-04-02 | 1987-03-03 | Rhone-Poulenc Specialties Chimiques | Separation of rare earth values by liquid/liquid extraction |
| USRE48165E1 (en) | 2014-10-17 | 2020-08-18 | Merck Patent Gmbh | Alkenyl (perfluoroalkyl) phosphinic acids |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS50141579A (en) | 1975-11-14 |
| LU72237A1 (en) | 1976-03-17 |
| FR2267380B1 (en) | 1979-03-09 |
| ZA752252B (en) | 1976-03-31 |
| SE388129B (en) | 1976-09-27 |
| DE2417510A1 (en) | 1975-10-30 |
| BE827731A (en) | 1975-10-09 |
| NO751058L (en) | 1975-10-13 |
| NL7504124A (en) | 1975-10-14 |
| SE7504086L (en) | 1975-10-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ST | Notification of lapse |