FI116678B - Fenolinen resolivanerihartsi, valmistus ja käyttö - Google Patents
Fenolinen resolivanerihartsi, valmistus ja käyttö Download PDFInfo
- Publication number
- FI116678B FI116678B FI935132A FI935132A FI116678B FI 116678 B FI116678 B FI 116678B FI 935132 A FI935132 A FI 935132A FI 935132 A FI935132 A FI 935132A FI 116678 B FI116678 B FI 116678B
- Authority
- FI
- Finland
- Prior art keywords
- resin solution
- resin
- adhesive
- potassium carbonate
- plywood
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title claims description 66
- 239000011347 resin Substances 0.000 title claims description 66
- 238000004519 manufacturing process Methods 0.000 title claims description 31
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 3
- 229920003987 resole Polymers 0.000 title description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 45
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 43
- 239000000243 solution Substances 0.000 claims description 39
- 239000011120 plywood Substances 0.000 claims description 38
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 35
- 239000000853 adhesive Substances 0.000 claims description 34
- 230000001070 adhesive effect Effects 0.000 claims description 34
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 31
- 239000011230 binding agent Substances 0.000 claims description 26
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 21
- 229920001568 phenolic resin Polymers 0.000 claims description 14
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 10
- 238000001723 curing Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 239000002685 polymerization catalyst Substances 0.000 claims description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 239000002562 thickening agent Substances 0.000 claims description 6
- 239000002023 wood Substances 0.000 claims description 6
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 229920001187 thermosetting polymer Polymers 0.000 claims description 4
- 238000004026 adhesive bonding Methods 0.000 claims description 2
- 238000003892 spreading Methods 0.000 claims 2
- 238000004132 cross linking Methods 0.000 claims 1
- 230000003247 decreasing effect Effects 0.000 claims 1
- 230000032798 delamination Effects 0.000 claims 1
- 238000013007 heat curing Methods 0.000 claims 1
- 239000006193 liquid solution Substances 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 238000003825 pressing Methods 0.000 claims 1
- 235000011181 potassium carbonates Nutrition 0.000 description 11
- 238000001035 drying Methods 0.000 description 6
- 241000018646 Pinus brutia Species 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 2
- 235000011613 Pinus brutia Nutrition 0.000 description 2
- 235000005018 Pinus echinata Nutrition 0.000 description 2
- 241001236219 Pinus echinata Species 0.000 description 2
- 235000017339 Pinus palustris Nutrition 0.000 description 2
- LOUPRKONTZGTKE-WZBLMQSHSA-N Quinine Chemical compound C([C@H]([C@H](C1)C=C)C2)C[N@@]1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-WZBLMQSHSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 241000208140 Acer Species 0.000 description 1
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- 241000219495 Betulaceae Species 0.000 description 1
- 235000001258 Cinchona calisaya Nutrition 0.000 description 1
- 206010053567 Coagulopathies Diseases 0.000 description 1
- 241000218631 Coniferophyta Species 0.000 description 1
- 241001480079 Corymbia calophylla Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 235000006552 Liquidambar styraciflua Nutrition 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- 244000019397 Pinus jeffreyi Species 0.000 description 1
- 235000013267 Pinus ponderosa Nutrition 0.000 description 1
- 235000013269 Pinus ponderosa var ponderosa Nutrition 0.000 description 1
- 235000013268 Pinus ponderosa var scopulorum Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000219492 Quercus Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- LOUPRKONTZGTKE-UHFFFAOYSA-N cinchonine Natural products C1C(C(C2)C=C)CCN2C1C(O)C1=CC=NC2=CC=C(OC)C=C21 LOUPRKONTZGTKE-UHFFFAOYSA-N 0.000 description 1
- 230000035602 clotting Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229960000948 quinine Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Veneer Processing And Manufacture Of Plywood (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/855,549 US5342880A (en) | 1992-03-20 | 1992-03-20 | Phenolic resol plywood resin, manufacture and use |
| US85554992 | 1992-03-20 | ||
| PCT/US1993/002590 WO1993019120A1 (fr) | 1992-03-20 | 1993-03-19 | Resine de contre-plaque a base de resol phenolique, fabrication et utilisation |
| US9302590 | 1993-03-19 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI935132A0 FI935132A0 (fi) | 1993-11-19 |
| FI935132L FI935132L (fi) | 1994-01-07 |
| FI116678B true FI116678B (fi) | 2006-01-31 |
Family
ID=25321543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI935132A FI116678B (fi) | 1992-03-20 | 1993-11-19 | Fenolinen resolivanerihartsi, valmistus ja käyttö |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5342880A (fr) |
| EP (1) | EP0586668A4 (fr) |
| JP (1) | JPH06507939A (fr) |
| AU (1) | AU661141B2 (fr) |
| CA (1) | CA2103250C (fr) |
| FI (1) | FI116678B (fr) |
| MY (2) | MY112739A (fr) |
| NZ (1) | NZ251226A (fr) |
| WO (1) | WO1993019120A1 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5342880A (en) * | 1992-03-20 | 1994-08-30 | Neste Resins Corporation | Phenolic resol plywood resin, manufacture and use |
| US5763559A (en) * | 1997-01-21 | 1998-06-09 | Georgia-Pacific Resins, Inc. | Phenol-formaldehyde resins modified with guanidine salts |
| US6113729A (en) * | 1998-08-10 | 2000-09-05 | Borden Chemical, Inc. | Wax sizing and resin bonding of a lignocellulosic composite |
| ATE367145T1 (de) * | 1999-12-21 | 2007-08-15 | Kao Corp | Topische kosmetische und pharmazeutische mittel enthaltend spezifische alkoxilierte diester der fumarsäure |
| US6307009B1 (en) | 1999-12-29 | 2001-10-23 | Owens Corning Fiberglas Technology, Inc. | High catalyst phenolic resin binder system |
| WO2002081569A1 (fr) * | 2001-04-04 | 2002-10-17 | The Lubrizol Corporation | Phenols a substitution hydrocarbyle utilises dans des resines destinees a des composites cellulosiques |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA773168A (en) * | 1967-12-05 | W. Spilker Clarence | Non-resinous composition for bonding | |
| US3342776A (en) * | 1966-09-21 | 1967-09-19 | Monsanto Co | Method of preparing aqueous alkaline phenol-aldehyde condensates |
| US3696064A (en) * | 1970-11-09 | 1972-10-03 | Borden Inc | Stable phenolic adhesive mix |
| IT998153B (it) * | 1973-06-15 | 1976-01-20 | Sir Soc Italiana Resine Spa | Composizioni comprendenti resine fenoliche |
| US4194996A (en) * | 1978-10-10 | 1980-03-25 | Uralsky Lesotekhnichesky Institut | Phenol formaldehyde compression moulding composition comprising phenol formaldehyde-wood filler |
| JPS55123644A (en) * | 1979-03-19 | 1980-09-24 | Mitsui Toatsu Chem Inc | Fast-curing phenolic resin composition |
| US4608408A (en) * | 1985-04-24 | 1986-08-26 | Koppers Company, Inc. | Phenol-HCHO-resorcinol resins for use in forming fast curing wood laminating adhesives |
| US4758478A (en) * | 1986-09-30 | 1988-07-19 | Daisy Nick K | Fast curing phenolic resins and bonding methods employing same |
| US5342880A (en) * | 1992-03-20 | 1994-08-30 | Neste Resins Corporation | Phenolic resol plywood resin, manufacture and use |
-
1992
- 1992-03-20 US US07/855,549 patent/US5342880A/en not_active Expired - Lifetime
-
1993
- 1993-03-19 AU AU38156/93A patent/AU661141B2/en not_active Expired
- 1993-03-19 WO PCT/US1993/002590 patent/WO1993019120A1/fr not_active Ceased
- 1993-03-19 CA CA002103250A patent/CA2103250C/fr not_active Expired - Lifetime
- 1993-03-19 NZ NZ251226A patent/NZ251226A/en not_active IP Right Cessation
- 1993-03-19 EP EP19930907620 patent/EP0586668A4/en not_active Withdrawn
- 1993-03-19 JP JP5516771A patent/JPH06507939A/ja active Pending
- 1993-03-20 MY MYPI95003387A patent/MY112739A/en unknown
- 1993-03-20 MY MYPI93000505A patent/MY117262A/en unknown
- 1993-11-19 FI FI935132A patent/FI116678B/fi not_active IP Right Cessation
-
1994
- 1994-06-13 US US08/258,667 patent/US5451657A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| NZ251226A (en) | 1996-06-25 |
| US5451657A (en) | 1995-09-19 |
| CA2103250A1 (fr) | 1993-09-21 |
| JPH06507939A (ja) | 1994-09-08 |
| EP0586668A4 (en) | 1994-06-29 |
| WO1993019120A1 (fr) | 1993-09-30 |
| AU3815693A (en) | 1993-10-21 |
| MY117262A (en) | 2004-06-30 |
| FI935132A0 (fi) | 1993-11-19 |
| US5342880A (en) | 1994-08-30 |
| CA2103250C (fr) | 2002-10-08 |
| FI935132L (fi) | 1994-01-07 |
| AU661141B2 (en) | 1995-07-13 |
| EP0586668A1 (fr) | 1994-03-16 |
| MY112739A (en) | 2001-08-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Patent granted |
Ref document number: 116678 Country of ref document: FI |
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| MA | Patent expired |