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ES8706842A1 - Collectors and froth flotation processes for metal sulfide ores - Google Patents

Collectors and froth flotation processes for metal sulfide ores

Info

Publication number
ES8706842A1
ES8706842A1 ES553035A ES553035A ES8706842A1 ES 8706842 A1 ES8706842 A1 ES 8706842A1 ES 553035 A ES553035 A ES 553035A ES 553035 A ES553035 A ES 553035A ES 8706842 A1 ES8706842 A1 ES 8706842A1
Authority
ES
Spain
Prior art keywords
collectors
metal sulfide
sulfide
processes
froth flotation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES553035A
Other languages
Spanish (es)
Other versions
ES553035A0 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/641,660 external-priority patent/US4556483A/en
Priority claimed from US06/641,659 external-priority patent/US4556482A/en
Priority claimed from US06/641,658 external-priority patent/US4595493A/en
Priority claimed from US06/641,657 external-priority patent/US4584097A/en
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of ES8706842A1 publication Critical patent/ES8706842A1/en
Publication of ES553035A0 publication Critical patent/ES553035A0/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/012—Organic compounds containing sulfur
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/001—Flotation agents
    • B03D1/004—Organic compounds
    • B03D1/008—Organic compounds containing oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/02—Collectors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00—Specified effects produced by the flotation agents
    • B03D2201/04—Frothers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00—Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02—Ores

Landscapes

  • Manufacture And Refinement Of Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Collector compositions for use in froth flotation processes for the beneficiation of mineral values from base metal sulfide ores comprise at least one hydrocarboxycarbonyl thionocarbamate or thiourea compound selected from compounds of the formulas: < IMAGE > R<1>, R<2> and R<3> being specified. The processes include the use of the collectors which at pH values below 10.0 exhibit unexpectedly high collector activity for base metal sulfide minerals such as copper, lead and zinc and selectively rejects gangue sulfide minerals, such as pyrite and pyrrhotite. The collectors and processes provide excellent metallurgical recoveries of copper sulfide mineral values of high grade at a substantial reduction in lime consumption and reagents costs associated with prior art flotation separation methods. Bulk sulfide flotation methods are also disclosed.
ES553035A 1984-08-17 1986-03-14 Collectors and froth flotation processes for metal sulfide ores Expired ES8706842A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/641,660 US4556483A (en) 1984-08-17 1984-08-17 Neutral hydrocarboxycarbonyl thiourea sulfide collectors
US06/641,659 US4556482A (en) 1984-08-17 1984-08-17 Process for the flotation of base metal sulfide minerals in acid, neutral or mildly alkaline circuits
US06/641,658 US4595493A (en) 1984-08-17 1984-08-17 Process for the flotation of base metal sulfide minerals in acid, neutral or mildly alkaline circuits
US06/641,657 US4584097A (en) 1984-08-17 1984-08-17 Neutral hydrocarboxycarbonyl thionocarbamate sulfide collectors

Publications (2)

Publication Number Publication Date
ES8706842A1 true ES8706842A1 (en) 1987-07-16
ES553035A0 ES553035A0 (en) 1987-07-16

Family

ID=27505238

Family Applications (2)

Application Number Title Priority Date Filing Date
ES546173A Expired ES8701849A1 (en) 1984-08-17 1985-08-14 Collectors and froth flotation processes for metal sulfide ores
ES553035A Expired ES8706842A1 (en) 1984-08-17 1986-03-14 Collectors and froth flotation processes for metal sulfide ores

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES546173A Expired ES8701849A1 (en) 1984-08-17 1985-08-14 Collectors and froth flotation processes for metal sulfide ores

Country Status (10)

Country Link
JP (1) JPS6157254A (en)
KR (1) KR910003051B1 (en)
AU (2) AU570131B2 (en)
BG (1) BG60234B1 (en)
BR (1) BR8503910A (en)
ES (2) ES8701849A1 (en)
FI (1) FI77169C (en)
GB (2) GB2163068B (en)
SE (2) SE465359B (en)
YU (1) YU45737B (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8527214D0 (en) * 1985-11-05 1985-12-11 British Petroleum Co Plc Separation process
GB2267852B (en) * 1992-06-09 1995-12-06 American Cyanamid Co Improved metal recovery by flotation
RU2131303C1 (en) * 1997-03-12 1999-06-10 Институт химии и химико-металлургических процессов Сибирского отделения РАН Copper-nickel sulfide flotation process
RU2133644C1 (en) * 1997-11-03 1999-07-27 Иркутский государственный технический университет Method of concentrating persistent gold-containing sulfide ores
RU2235602C1 (en) * 2002-12-26 2004-09-10 Открытое акционерное общество "Иргиредмет" Method of extraction of non-ferrous and noble metals
US7360656B2 (en) 2005-12-16 2008-04-22 Rohm And Haas Company Method to improve the cleaner froth flotation process
CN101337205B (en) 2008-08-13 2011-04-20 中南大学 Use of diester isosulfocyanate in sulphide ore floation and preparation method thereof
CN101337206B (en) 2008-08-13 2011-02-02 中南大学 Sulphide ore floation collector and use method of diacyl bis-thiourea and preparation method thereof
RU2425720C1 (en) * 2009-12-21 2011-08-10 Общество с ограниченной ответственностью "ТВЭЛЛ" Selective extraction method of copper minerals to concentrates at enrichment of copper-zinc pyrite-containing ores
CN101757985B (en) * 2010-03-04 2013-04-10 中南大学 Mineral flotation collectors
RU2434953C1 (en) * 2010-06-21 2011-11-27 Открытое акционерное общество "Иркутский научно-исследовательский институт благородных и редких металлов и алмазов" ОАО "Иргиредмет" Method of processing gold-containing sulphide concentrates (versions)
CN102516144B (en) * 2011-11-02 2014-11-05 中南大学 Thiourea compound and preparation thereof and application thereof to metal ore floatation
JP7206150B2 (en) * 2019-03-29 2023-01-17 Ｊｘ金属株式会社 Method for removing SiO2 from slurry containing silver and SiO2 and method for purifying silver
CN113751205A (en) * 2021-09-10 2021-12-07 紫金矿业集团股份有限公司 N-tert-butyl ester collecting agent and preparation method thereof

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1211041A (en) * 1967-01-24 1970-11-04 Egyt Gyogyszervegyeszeti Gyar Thiocarbamide derivatives
US3590996A (en) * 1969-02-03 1971-07-06 Dow Chemical Co Floatation of sulfide ores
US3590998A (en) * 1969-02-03 1971-07-06 Dow Chemical Co Flotation of sulfide ores
US3655657A (en) * 1970-02-24 1972-04-11 Du Pont 2 1 4-benzothiadiazine-3-carbamic acid esters
DE2301400C2 (en) * 1973-01-12 1984-12-13 Bayer Ag, 5090 Leverkusen 0-Triazolyl-thionophosphorus (phosphonic) acid esters and ester amides, process for their preparation and their use as insecticides and acaricides
US3907854A (en) * 1973-07-13 1975-09-23 Minerec Corp Dialkyl thionocarbamate method
FR2285397A1 (en) * 1974-09-20 1976-04-16 Roussel Uclaf NEW THIAZOLIC ORGANOPHOSPHORUS DERIVATIVES, PROCESS FOR PREPARATION AND APPLICATION AS PESTICIDES
FR2308629A1 (en) * 1975-04-24 1976-11-19 Roussel Uclaf NEW SUBSTITUTE DERIVATIVES OF THIADIAZOLE, THEIR PREPARATION PROCESS AND THEIR APPLICATION AS HERBICIDES
GB2106804A (en) * 1981-10-08 1983-04-20 American Cyanamid Co Process for the beneficiation of metal sulfides and collector combinations therefor

Also Published As

Publication number Publication date
BR8503910A (en) 1986-05-27
BG60234B2 (en) 1994-01-18
SE8902752L (en) 1989-08-16
AU4626285A (en) 1986-02-20
GB8718337D0 (en) 1987-09-09
BG60234B1 (en) 1994-01-24
AU594845B2 (en) 1990-03-15
JPH0566182B2 (en) 1993-09-21
GB2193660B (en) 1988-09-28
JPS6157254A (en) 1986-03-24
GB2163068B (en) 1988-09-28
ES8701849A1 (en) 1986-12-16
SE8902752D0 (en) 1989-08-16
ES553035A0 (en) 1987-07-16
YU131485A (en) 1987-12-31
KR860001615A (en) 1986-03-20
AU8243587A (en) 1988-03-31
ES546173A0 (en) 1986-12-16
FI853162A0 (en) 1985-08-16
KR910003051B1 (en) 1991-05-17
SE8503850L (en) 1986-02-18
GB2163068A (en) 1986-02-19
FI853162L (en) 1986-02-18
SE8503850D0 (en) 1985-08-16
GB8519737D0 (en) 1985-09-11
FI77169B (en) 1988-10-31
YU45737B (en) 1992-07-20
AU570131B2 (en) 1988-03-03
GB2193660A (en) 1988-02-17
SE465359B (en) 1991-09-02
SE467293B (en) 1992-06-29
FI77169C (en) 1989-02-10

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 20050318