ES8105680A1 - Procedimiento continuo de recuperacion flobal del uranio, torio y trio y tierras raras contenidos en una fase acuosa a- cida. - Google Patents
Procedimiento continuo de recuperacion flobal del uranio, torio y trio y tierras raras contenidos en una fase acuosa a- cida.Info
- Publication number
- ES8105680A1 ES8105680A1 ES495176A ES495176A ES8105680A1 ES 8105680 A1 ES8105680 A1 ES 8105680A1 ES 495176 A ES495176 A ES 495176A ES 495176 A ES495176 A ES 495176A ES 8105680 A1 ES8105680 A1 ES 8105680A1
- Authority
- ES
- Spain
- Prior art keywords
- aqueous phase
- solvent
- uranium
- organic
- recovery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000008346 aqueous phase Substances 0.000 title abstract 4
- 229910052770 Uranium Inorganic materials 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000011084 recovery Methods 0.000 title abstract 2
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 title abstract 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 3
- 239000002904 solvent Substances 0.000 abstract 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000012074 organic phase Substances 0.000 abstract 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 abstract 1
- 229910052776 Thorium Inorganic materials 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 239000008240 homogeneous mixture Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B59/00—Obtaining rare earth metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/408—Mixtures using a mixture of phosphorus-based acid derivatives of different types
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0204—Obtaining thorium, uranium, or other actinides obtaining uranium
- C22B60/0217—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
- C22B60/0252—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries
- C22B60/026—Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes treatment or purification of solutions or of liquors or of slurries liquid-liquid extraction with or without dissolution in organic solvents
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0291—Obtaining thorium, uranium, or other actinides obtaining thorium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
- C22B60/0295—Obtaining thorium, uranium, or other actinides obtaining other actinides except plutonium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
PROCEDIMIENTO CONTINUO PARA LA RECUPERACION GLOBAL DE URANIO, TORIO, YTRIO Y TIERRAS RARAS CONTENIDOS EN UNA FASE ACUOSA ACIDA. LA DISOLUCION ACIDA SE EXTRAE CON UNA MEZCLA HOMOGENEA, CONSTITUIDA POR UN ACIDO DI-(ALCOHILFENIL)-FOSFORICO EXENTO DEL DERIVADO MONO-(ALCOHILFENI)-FOSFORICO Y UN DISOLVENTE ORGANICO INERTE QUE CONTIENE UN AGENTE SOLVATANTE O UN AGENTE MODIFICADOR, OBTENIENDOSE UNA FASE ORGANICA CARGADA DE LOS ELEMENTOS A RECUPERAR. ESTA FASE ORGANICA SE EXTRAE CON UNA FASE ACUOSA DE ACIDO FLUORHIDRICO AL 3-10 POR 100 QUE CONTIENE ACIDO FOSFORICO O SULFURICO. LA FASE ORGANICA SE RECICLA DESPUES DE LAVADA Y LA FASE ACUOSA SE CONCENTRA POR EVAPORACION. EL CONDENSADO DE AGUA Y ACIDO FLUORHIDRICO SE RECICLA Y DEL CONCENTRADO SE SEPARAN LOS METALES EN FORMA DE SALES. 1
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7923517A FR2465687A1 (fr) | 1979-09-21 | 1979-09-21 | Procede de recuperation globale de l'uranium, des terres rares, du thorium et de l'yttrium contenus dans une solution acide |
| FR8003349A FR2476057A2 (fr) | 1979-09-21 | 1980-02-15 | Perfectionnement au procede de recuperation globale de l'uranium, des terres rares, du thorium et de l'yttrium contenus dans une solution acide |
| FR8014081A FR2485506A2 (fr) | 1979-09-21 | 1980-06-25 | Procede de recuperation globale de l'uranium, des terres rares, du thorium et de l'yttrium applique au traitement de phosphogypse |
| FR8014082A FR2485509A2 (fr) | 1979-09-21 | 1980-06-25 | Procede de recuperation globale de l'uranium, des terres rares, du thorium et de l'yttrium applique au traitement de solutions epuisees d'acide phosphorique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES495176A0 ES495176A0 (es) | 1981-06-16 |
| ES8105680A1 true ES8105680A1 (es) | 1981-06-16 |
Family
ID=27446409
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES495176A Expired ES8105680A1 (es) | 1979-09-21 | 1980-09-19 | Procedimiento continuo de recuperacion flobal del uranio, torio y trio y tierras raras contenidos en una fase acuosa a- cida. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0026132B1 (es) |
| BR (1) | BR8006026A (es) |
| CA (1) | CA1142364A (es) |
| DE (1) | DE3064641D1 (es) |
| ES (1) | ES8105680A1 (es) |
| FI (1) | FI68038C (es) |
| GR (1) | GR70004B (es) |
| IL (1) | IL61073A (es) |
| MA (1) | MA18955A1 (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2539549B1 (fr) * | 1983-01-17 | 1988-10-14 | Rhone Poulenc Chim Base | Procede de recuperation globale de l'uranium, de l'yttrium, du thorium et des terres rares contenus dans une phase organique |
| FR2562059B1 (fr) * | 1984-04-02 | 1989-12-01 | Rhone Poulenc Spec Chim | Procede de separation des terres rares par extraction liquide-liquide |
| JPS63206312A (ja) * | 1987-02-23 | 1988-08-25 | Mitsubishi Kasei Corp | 希土類元素の抽出法 |
| FR2678644A1 (fr) * | 1991-07-02 | 1993-01-08 | Rhone Poulenc Chimie | Procede de recuperation globale du thorium et des terres rares en milieu nitrate. |
| JP5720583B2 (ja) * | 2012-01-13 | 2015-05-20 | 信越化学工業株式会社 | 液−液抽出装置、これを用いた多段液−液抽出装置及び希土類元素の多段連続抽出装置 |
| RU2538863C2 (ru) * | 2013-03-05 | 2015-01-10 | Открытое акционерное общество "Объединенная химическая компания "УРАЛХИМ" | Способ реэкстракции редкоземельных металлов из органических растворов и получение концентрата редкоземельных металлов |
| RU2528573C1 (ru) | 2013-03-05 | 2014-09-20 | Открытое акционерное общество "Объединенная химическая компания "УРАЛХИМ" | Способ извлечения редкоземельных металлов и получения строительного гипса из фосфогипса полугидрата |
| RU2528576C1 (ru) | 2013-03-05 | 2014-09-20 | Открытое акционерное общество "Объединенная химическая компания "УРАЛХИМ" | Способ извлечения редкоземельных металлов и получения строительного гипса из фосфогипса полугидрата |
| RU2543160C2 (ru) | 2013-03-18 | 2015-02-27 | Открытое акционерное общество "Объединенная химическая компания "УРАЛХИМ" | Способ сернокислотного разложения рзм-содержащего фосфатного сырья |
| RU2665512C1 (ru) * | 2017-05-02 | 2018-08-30 | Акционерное общество "Ведущий научно-исследовательский институт химической технологии" | Способ переработки фосфогипса |
| EP3875618A1 (en) * | 2020-03-06 | 2021-09-08 | Yara International ASA | Method for selective separation of thorium and cerium from a solid concentrate comprising same and one or more further rare earth metals and acidic rare earth solution thereof |
| CN114609236B (zh) * | 2022-03-21 | 2025-04-22 | 中国工程物理研究院核物理与化学研究所 | 一种含铀物质中稀土元素分离回收方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3737513A (en) * | 1970-07-02 | 1973-06-05 | Freeport Minerals Co | Recovery of uranium from an organic extractant by back extraction with h3po4 or hf |
| JPS53128596A (en) * | 1977-04-14 | 1978-11-09 | Doryokuro Kakunenryo | Method of recovering uranium from wet phosphoric acid |
-
1980
- 1980-09-12 EP EP80401307A patent/EP0026132B1/fr not_active Expired
- 1980-09-12 DE DE8080401307T patent/DE3064641D1/de not_active Expired
- 1980-09-17 FI FI802930A patent/FI68038C/fi not_active IP Right Cessation
- 1980-09-18 IL IL61073A patent/IL61073A/xx unknown
- 1980-09-19 CA CA000360675A patent/CA1142364A/fr not_active Expired
- 1980-09-19 BR BR8006026A patent/BR8006026A/pt unknown
- 1980-09-19 GR GR62923A patent/GR70004B/el unknown
- 1980-09-19 MA MA19156A patent/MA18955A1/fr unknown
- 1980-09-19 ES ES495176A patent/ES8105680A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE3064641D1 (en) | 1983-09-29 |
| EP0026132B1 (fr) | 1983-08-24 |
| IL61073A (en) | 1984-10-31 |
| MA18955A1 (fr) | 1981-04-01 |
| BR8006026A (pt) | 1981-03-31 |
| EP0026132A1 (fr) | 1981-04-01 |
| FI802930A7 (fi) | 1981-03-22 |
| FI68038C (fi) | 1985-07-10 |
| GR70004B (en) | 1987-01-19 |
| CA1142364A (fr) | 1983-03-08 |
| ES495176A0 (es) | 1981-06-16 |
| FI68038B (fi) | 1985-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES8105680A1 (es) | Procedimiento continuo de recuperacion flobal del uranio, torio y trio y tierras raras contenidos en una fase acuosa a- cida. | |
| ES8301651A1 (es) | Procedimiento para extractar valores metalicos de soluciones acuosas de sales metalicas que contienen aniones haluro o pseudo-haluro. | |
| DK314582A (da) | Fremgangsmaade til flydende/flydende ekstraktion af tungmetalioner fra sure,vandige oploesninger | |
| GB1240766A (en) | Irradiated nuclear fuel recovery process | |
| BR8001155A (pt) | Processo continuo de recuperacao do uranio contido em um acido fosforico impuro | |
| ES8500337A1 (es) | Procedimiento para recuperar uranio del acido fosforico obtenido por via humeda. | |
| AR246947A1 (es) | Procedimiento para la recuperacion de acido citrico. | |
| ES2051238B1 (es) | Procedimiento de aprovechamiento del alpechin para la obtencion de acidos, fenoles, alcoholes y derivados mediante extraccion en contracorriente. | |
| DK149136C (da) | Fremgangsmaade til selektiv udvinding af indium fra indiumholdige vandige sulfatoploesninger | |
| MX159243A (es) | Procedimiento para la purificacion de acido fosforico de procedimiento en humedo | |
| BR8801283A (pt) | Processo de separacao de terras raras contidas em uma solucao aquosa | |
| GB1131910A (en) | Technetium-99m | |
| FR2359790A1 (fr) | Procede pour la preparation de phosphates | |
| ES8207588A1 (es) | Perfeccionamientos introducidos en un procedimiento de recu-peracion del uranio (vi) contenido en un acido fosforico impuro | |
| ES2039667T3 (es) | Procedimiento de recuperacion de galio contenido en soluciones acuosas muy basicas por extraccion liquido-liquido. | |
| DE3364504D1 (en) | Process for the removal of cadmium from acid solutions, especially those containing p2o5 | |
| GB1025866A (en) | Method for recovery of cesium and strontium values | |
| GB1209272A (en) | Cleaning of phosphoric acid | |
| ES8603961A1 (es) | Procedimiento para extractar contenidos metalicos en soluciones acuosas de sales metalicas | |
| GB1186953A (en) | Method of Preparing Vanillin from Eugenol | |
| ES470068A1 (es) | Un procedimiento de purificacion y de desfluoracion de un acido fosforico impuro | |
| GB930966A (en) | Separation of curium and americium | |
| Barthel et al. | Separation and Recovery of Copper and Zinc from Sulfuric Acid Solutions of Metal Salts by Solvent Extraction | |
| ES462265A1 (es) | Un metodo para recuperar uranio. | |
| ES8101021A1 (es) | Procedimiento para la purificacion de una solucion acuosa deacido fosforico de procedimiento en humedo |