ES2554988B1 - Dispositivo electroquímico de almacenamiento de energía - Google Patents

Dispositivo electroquímico de almacenamiento de energía Download PDF

Info

Publication number: ES2554988B1
Authority: ES; Spain
Prior art keywords: metal; air battery; electrode; electrolyte; air
Prior art date: 2011-12-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn - After Issue

Application number

ES201490064A

Other languages

English (en)

Spanish (es)

Other versions

ES2554988A2 (es

ES2554988R1 (es

Inventor

Liya Wang

Lide Mercedes RODRÍGUEZ MARTÍNEZ

Ander Laresgoiti Rementeria

Laida OTAEGUI AMEZTEGUI

Hisashi Tsukamoto

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

FUNDACION CENTRO DE INVESTIGACION COOPERATIVA DE E

Original Assignee

Fundacion Centro De Investig Cooperativa De Energias Alternativas Cic Energigune Fundazioa

Fundacion Centro De Investigacion Cooperativa De Energias Alternativas Cic Energigune Fundazioa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-12-22

Filing date

2012-12-21

Publication date

2018-04-09

2012-12-21 Application filed by Fundacion Centro De Investig Cooperativa De Energias Alternativas Cic Energigune Fundazioa, Fundacion Centro De Investigacion Cooperativa De Energias Alternativas Cic Energigune Fundazioa filed Critical Fundacion Centro De Investig Cooperativa De Energias Alternativas Cic Energigune Fundazioa

2015-12-28 Publication of ES2554988A2 publication Critical patent/ES2554988A2/es

2017-06-26 Publication of ES2554988R1 publication Critical patent/ES2554988R1/es

2018-04-09 Application granted granted Critical

2018-04-09 Publication of ES2554988B1 publication Critical patent/ES2554988B1/es

Status Withdrawn - After Issue legal-status Critical Current

2032-12-21 Anticipated expiration legal-status Critical

Links

238000012983 electrochemical energy storage Methods 0.000 title abstract description 3
229910052751 metal Inorganic materials 0.000 claims abstract description 134
239000002184 metal Substances 0.000 claims abstract description 131
239000003792 electrolyte Substances 0.000 claims abstract description 95
229910052760 oxygen Inorganic materials 0.000 claims abstract description 72
239000001301 oxygen Substances 0.000 claims abstract description 69
239000007787 solid Substances 0.000 claims abstract description 56
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 42
238000000034 method Methods 0.000 claims abstract description 34
239000010416 ion conductor Substances 0.000 claims abstract description 19
238000004146 energy storage Methods 0.000 claims abstract description 9
239000011575 calcium Substances 0.000 claims description 33
-1 oxygen ion Chemical class 0.000 claims description 33
239000011777 magnesium Substances 0.000 claims description 29
150000001875 compounds Chemical class 0.000 claims description 22
239000007789 gas Substances 0.000 claims description 22
229910052684 Cerium Inorganic materials 0.000 claims description 21
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
239000000919 ceramic Substances 0.000 claims description 21
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 21
229910052744 lithium Inorganic materials 0.000 claims description 20
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 19
229910052797 bismuth Inorganic materials 0.000 claims description 19
239000011734 sodium Substances 0.000 claims description 19
229910052727 yttrium Inorganic materials 0.000 claims description 19
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 18
229910052688 Gadolinium Inorganic materials 0.000 claims description 17
229910052772 Samarium Inorganic materials 0.000 claims description 17
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 17
UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 17
229910052749 magnesium Inorganic materials 0.000 claims description 17
239000000203 mixture Substances 0.000 claims description 17
239000000843 powder Substances 0.000 claims description 17
KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 17
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150000002500 ions Chemical class 0.000 claims description 16
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239000000126 substance Substances 0.000 claims description 15
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 14
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239000010949 copper Substances 0.000 claims description 13
239000010436 fluorite Substances 0.000 claims description 13
239000011572 manganese Substances 0.000 claims description 13
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
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VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
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241000968352 Scandia <hydrozoan> Species 0.000 claims description 6
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229910052788 barium Inorganic materials 0.000 claims description 6
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 6
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239000011701 zinc Substances 0.000 claims description 6
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
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CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 5
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SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 3
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238000002360 preparation method Methods 0.000 abstract description 3
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239000010405 anode material Substances 0.000 description 5
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WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
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239000002893 slag Substances 0.000 description 1
229910052979 sodium sulfide Inorganic materials 0.000 description 1
239000004449 solid propellant Substances 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
229910052566 spinel group Inorganic materials 0.000 description 1
229910002076 stabilized zirconia Inorganic materials 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1
238000011282 treatment Methods 0.000 description 1
238000009736 wetting Methods 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
- H01M2300/0074—Ion conductive at high temperature
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/387—Tin or alloys based on tin
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/138—Primary casings; Jackets or wrappings adapted for specific cells, e.g. electrochemical cells operating at high temperature
- H01M50/1385—Hybrid cells
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Hybrid Cells (AREA)
Inert Electrodes (AREA)

ES201490064A 2011-12-22 2012-12-21 Dispositivo electroquímico de almacenamiento de energía Withdrawn - After Issue ES2554988B1 (es)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP11382390		2011-12-22
EP11382390		2011-12-22
PCT/EP2012/076736 WO2013093044A1 (fr)	2011-12-22	2012-12-21	Dispositif de stockage d'énergie électrochimique

Publications (3)

Publication Number	Publication Date
ES2554988A2 ES2554988A2 (es)	2015-12-28
ES2554988R1 ES2554988R1 (es)	2017-06-26
ES2554988B1 true ES2554988B1 (es)	2018-04-09

Family

ID=48667771

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES201490064A Withdrawn - After Issue ES2554988B1 (es)	2011-12-22	2012-12-21	Dispositivo electroquímico de almacenamiento de energía

Country Status (2)

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ES (1)	ES2554988B1 (fr)
WO (1)	WO2013093044A1 (fr)

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DE102012211328A1 (de) *	2012-06-29	2014-01-02	Siemens Aktiengesellschaft	Speicherstruktur einer elektrischen Energiespeicherzelle
US9054394B2 (en)	2013-06-28	2015-06-09	Dynantis Corporation	Secondary alkali metal/oxygen batteries
DE102014002451A1 (de) *	2014-02-25	2015-08-27	Forschungszentrum Jülich GmbH	Elektro-chemischer Energiespeicher sowie Verfahren zum Betreiben desselben
WO2016000067A1 (fr)	2014-07-03	2016-01-07	Uti Limited Partnership	Baceo3 dopé conducteur de protons chimiquement stable
WO2016178187A1 (fr) *	2015-05-06	2016-11-10	Suren Martirosyan	Formation et formatage d'électrode de zinc
CN105762441B (zh) *	2016-02-29	2018-03-20	苏州大学张家港工业技术研究院	基于锂离子固体电解质的锂空气电池的制备方法
WO2017147793A1 (fr) *	2016-03-01	2017-09-08	苏州大学张家港工业技术研究院	Procédé de préparation d'une batterie au lithium-air à base d'électrolytes solides lithium-ion
WO2017152836A1 (fr)	2016-03-08	2017-09-14	北京好风光储能技术有限公司	Cellule pour batterie à pâte au lithium, et module de batterie à pâte au lithium
CN107171018B (zh) *	2016-03-08	2019-03-29	北京好风光储能技术有限公司	一种半固态锂浆料电池
CN108242530B (zh) *	2016-12-23	2022-02-22	北京好风光储能技术有限公司	一种锂浆料电池及其负极片
WO2018184566A1 (fr)	2017-04-07	2018-10-11	北京好风光储能技术有限公司	Système de batterie à suspension épaisse de lithium
CN107093758B (zh) *	2017-04-18	2020-02-11	合肥学院	一种钼酸镧基中温固体氧化物燃料电池电解质材料及其制备方法
CN110649208B (zh) *	2018-09-29	2022-06-17	合肥工业大学	一种锂硫电池复合隔膜及其制备方法
CN110416531B (zh) *	2019-07-26	2022-06-21	长安大学	卤化氧铋水系锌离子二次电池正极及其制备方法与应用
EP4519929A1 (fr)	2022-05-03	2025-03-12	Technische Universität Wien	Cellules secondaires
CN116190867B (zh) *	2022-12-14	2025-12-02	哈尔滨工业大学	一种全开放式长续航火星电池及其制备方法

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2012
- 2012-12-21 ES ES201490064A patent/ES2554988B1/es not_active Withdrawn - After Issue
- 2012-12-21 WO PCT/EP2012/076736 patent/WO2013093044A1/fr not_active Ceased

Also Published As

Publication number	Publication date
ES2554988A2 (es)	2015-12-28
ES2554988R1 (es)	2017-06-26
WO2013093044A1 (fr)	2013-06-27

Publication	Publication Date	Title
ES2554988B1 (es)	2018-04-09	Dispositivo electroquímico de almacenamiento de energía
ES2657427T3 (es)	2018-03-05	Dispositivo de almacenamiento eléctrico que incluye un banco de células de batería de ión-óxido y configuraciones de módulo
US8338025B2 (en)	2012-12-25	Self-sealed metal electrode for rechargeable oxide-ion battery cells
ES2922876T3 (es)	2022-09-21	Pilas de combustible de óxido sólido con capas funcionales catódicas
US9083011B2 (en)	2015-07-14	Solid oxide fuel cell
Inoishi et al.	2013	Mg–air oxygen shuttle batteries using a ZrO2-based oxide ion-conducting electrolyte
TWI688154B (zh)	2020-03-11	具有對固態氧化物燃料電池之退化有改善抗性之固態氧化物燃料電池陰極組合物
EP2761691A1 (fr)	2014-08-06	Électrolyte de pile à combustible à oxyde solide composite
TWI788078B (zh)	2022-12-21	包含耐電解之空氣側電極的固體氧化物電解電池
JP5480656B2 (ja)	2014-04-23	横縞型固体酸化物形燃料電池バンドルおよび燃料電池
KR102564764B1 (ko)	2023-08-07	전기 화학 장치, 에너지 시스템, 및 고체 산화물형 연료 전지
JP2010205619A (ja)	2010-09-16	横縞型固体酸化物形燃料電池セルスタックおよび燃料電池
CN117616603A (zh)	2024-02-27	电化学单电池、电化学单电池装置、模块以及模块收容装置
KR101785376B1 (ko)	2017-10-13	Co2 및 co를 연료로 이용한 충방전 방식의 에너지 저장 장치
CN116093389A (zh)	2023-05-09	包含耐电解空气侧电极的固体氧化物电解槽电池
JP5026057B2 (ja)	2012-09-12	横縞型二次電池及び発電ユニット
JP2004127678A (ja)	2004-04-22	二次電池
CN108701839B (zh)	2021-08-24	电化学反应单体电池和电化学反应电池堆
Guo et al.	2010	A novel design of anode-supported solid oxide fuel cells with Y2O3-doped Bi2O3, LaGaO3 and La-doped CeO2 trilayer electrolyte
JP7525759B1 (ja)	2024-07-30	固体電解質層、電気化学セル、電気化学セル装置、モジュールおよびモジュール収容装置
JP7583227B2 (ja)	2024-11-13	電気化学セル、電気化学セル装置、モジュールおよびモジュール収容装置
Narmandakh et al.	2025	Oxygen Diffusion Measurements on SrO modified Co3O4 as an Active Air Electrode for Reversible Solid Oxide Cell
WO2025070717A1 (fr)	2025-04-03	Cellule électrochimique, dispositif de cellule électrochimique, module et dispositif de réception de module
WO2024225476A1 (fr)	2024-10-31	Couche d'électrolyte solide, cellule électrochimique, dispositif de cellule électrochimique, module et dispositif de stockage de module
WO2024150829A1 (fr)	2024-07-18	Cellule électrochimique, dispositif de cellule électrochimique, module et dispositif de stockage de module

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