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ES2378147T3 - Smoking product - Google Patents

Smoking product Download PDF

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Publication number
ES2378147T3
ES2378147T3 ES06806581T ES06806581T ES2378147T3 ES 2378147 T3 ES2378147 T3 ES 2378147T3 ES 06806581 T ES06806581 T ES 06806581T ES 06806581 T ES06806581 T ES 06806581T ES 2378147 T3 ES2378147 T3 ES 2378147T3
Authority
ES
Spain
Prior art keywords
smoking product
smoke
product according
smoking
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
ES06806581T
Other languages
Spanish (es)
Inventor
David William John Mclaughlin
Bernard Eugene Fitzsimons
Michael Terrace Hollywood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gallaher Ltd
Original Assignee
Gallaher Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gallaher Ltd filed Critical Gallaher Ltd
Application granted granted Critical
Publication of ES2378147T3 publication Critical patent/ES2378147T3/en
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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/041Tobacco smoke filters characterised by their shape or structure with adjustable means for modifying the degree of filtration of the filter
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/061Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/002Cigars; Cigarettes with additives, e.g. for flavouring
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0204Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A24D3/0212Applying additives to filter materials
    • A24D3/0216Applying additives to filter materials the additive being in the form of capsules, beads or the like
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/043Tobacco smoke filters characterised by their shape or structure with ventilation means, e.g. air dilution
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure
    • A24D3/048Tobacco smoke filters characterised by their shape or structure containing additives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/14Use of materials for tobacco smoke filters of organic materials as additive

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Medicinal Preparation (AREA)
  • Manufacture Of Tobacco Products (AREA)

Abstract

A smoking article comprises a distal end which, in use, contains a smoke producing substance. A proximal end has smoke drawn from it during smoking. At least one channel is provided which runs from the proximal end to at least part way towards the distal end. At least one vent hole is arranged such that an airflow path is defined through the vent hole, via the channel and to the proximal end of the smoking article. A smoke supplement composition is housed along the airflow path, such that, when the smoking article is smoked, air is drawn along the airflow path and over the composition so that the composition becomes air born and is delivered to the smoker.

Description

Producto para fumar Smoking product

Campo de la invenci6n Field of the Invention

La presente invenci6n se refiere a un producto para fumar. The present invention relates to a smoking product.

Los productos modernos para fumar pretenden reducir el suministro de alquitran, mon6xido de carbono y otros componentes en fase de vapor. Usando cigarrillos como ejemplo, tipicamente la cuesti6n del suministro controlado se logra modificando la elecci6n de la mezcla, ventilaci6n de la envoltura, ventilaci6n de la boquilla, adsorbentes de filtraci6n y del filtro tales como carbono activado. No obstante, se sabe que estos metodos comprometen el suministro de otros componentes de cigarrillo, o "composiciones de suplemento del humo", por ejemplo aroma. Esto resulta negativo para las caracteristicas tales como sabor, en particular con respecto a productos de tipo bajo contenido de alquitran y alta ventilaci6n. Modern smoking products are intended to reduce the supply of tar, carbon monoxide and other components in the vapor phase. Using cigarettes as an example, typically the issue of controlled supply is achieved by modifying the choice of the mixture, envelope ventilation, nozzle ventilation, filtration and filter adsorbents such as activated carbon. However, it is known that these methods compromise the supply of other cigarette components, or "smoke supplement compositions", for example aroma. This is negative for characteristics such as flavor, in particular with respect to products of low tar content and high ventilation.

Se conocen metodos para combatir el detrimento anteriormente descrito de las calidades tales como el sabor, por ejemplo mediante la introducci6n de aromas adicionales bien en la mezcla o bien en el filtro. Ambas de estas opciones, no obstante, pueden exhibir desventajas tales como reducci6n de la eficacia del filtro debido a la presencia de aroma en (o a la migraci6n de aroma hacia) el filtro o los adsorbentes del filtro, la transferencia incompleta de aroma al fumador (por ejemplo debido a la combusti6n del aroma, o debido a la extracci6n del aroma por parte del filtro), y la diluci6n del aroma por parte de otros vapores producidos por el producto para fumar. Debido a que la introducci6n de aroma adicional resulta un proceso costoso, la maxima transferencia de este aroma al fumador resulta de extrema importancia. Methods to combat the above-described detriment of qualities such as taste are known, for example by introducing additional aromas either in the mixture or in the filter. Both of these options, however, may exhibit disadvantages such as reducing the effectiveness of the filter due to the presence of aroma in (or the migration of aroma to) the filter or adsorbents of the filter, incomplete transfer of aroma to the smoker ( for example due to the burning of the aroma, or due to the extraction of the aroma by the filter), and the dilution of the aroma by other vapors produced by the smoking product. Because the introduction of additional aroma is an expensive process, the maximum transfer of this aroma to the smoker is extremely important.

Por tanto, resulta necesario formular un metodo mejorado para introducir composiciones de suplemento de humo tales como aroma en el interior de productos para fumar, de manera que el detrimento de las calidades tales como sabor que puede acontecer con el suministro controlado de, por ejemplo, alquitran y mon6xido de carbono se pueda solucionar de manera eficaz sin las desventajas anteriormente mencionadas. Therefore, it is necessary to formulate an improved method for introducing smoke supplement compositions such as aroma into smoking products, such that the detriment of qualities such as taste that can occur with the controlled supply of, for example, Tar and carbon monoxide can be solved effectively without the above-mentioned disadvantages.

El documento EP-A-0797931 describe un cigarrillo con filtro y un dispositivo de sujeci6n y ventilaci6n adyacente al filtro. EP-A-0797931 describes a cigarette with filter and a fastening and ventilation device adjacent to the filter.

La presente invenci6n proporciona un producto para fumar que comprende un extremo distal que, durante el uso, contiene una sustancia de producci6n de humo, un extremo proximal desde el cual el humo es extraido durante la acci6n de fumar, y al menos un conducto que se extiende desde el extremo proximal hasta al menos una parte hacia el extremo distal. Al menos un dispositivo de sujeci6n y ventilaci6n se encuentra ubicado de manera tal que la trayectoria del flujo de aire se encuentra definida a traves del dispositivo de sujeci6n y ventilaci6n, por medio del conducto, y hasta el extremo proximal del producto para fumar. Una composici6n de suplemento de humo se encuentra albergada a lo largo de esta trayectoria de flujo de aire, de forma tal que, cuando se fuma el producto para fumar, el aire es extraido a lo largo de la trayectoria de flujo de aire y sobre la composici6n de forma que la composici6n queda suspendida en el aire y es suministrada al fumador. The present invention provides a smoking product comprising a distal end which, during use, contains a smoke-producing substance, a proximal end from which the smoke is extracted during the smoking action, and at least one conduit that is extends from the proximal end to at least one part towards the distal end. At least one clamping and ventilation device is located in such a way that the air flow path is defined through the clamping and ventilation device, through the duct, and to the proximal end of the smoking product. A smoke supplement composition is housed along this air flow path, such that, when the smoking product is smoked, the air is extracted along the air flow path and over the composition so that the composition is suspended in the air and is supplied to the smoker.

Dicho producto para fumar exhibe lo que a continuaci6n se denomina un "sistema de suministro paralelo", es decir, un sistema en el que se suministra una composici6n de suplemento de humo tal como un aroma, nicotina, derivados de nicotina, agentes farmacol6gicamente activos o modificadores de humo en paralelo al, en lugar de en serie con, humo procedente de la sustancia que produce humo. Dicho "sistema de suministro paralelo" mejora el suministro de la composici6n de suplemento de humo, y en el caso del suministro de aroma, esto mejora el aroma del producto para fumar al tiempo que soluciona los problemas asociados con los metodos de mejora de aroma de la tecnica anterior. Said smoking product exhibits what is then called a "parallel supply system", that is, a system in which a smoke supplement composition such as an aroma, nicotine, nicotine derivatives, pharmacologically active agents or Smoke modifiers in parallel to, instead of in series with, smoke from the smoke-producing substance. Said "parallel supply system" improves the supply of the smoke supplement composition, and in the case of the aroma supply, this improves the aroma of the smoking product while solving the problems associated with the methods of improving aroma aroma. The prior art.

En detalle, la presente invenci6n no da lugar a un aumento de la pirolisis o de la combusti6n de la composici6n de suplemento de humo ya que la composici6n soporta, como maximo, unicamente un calentamiento moderado. Se reduce la migraci6n de la composici6n hasta otras partes del producto para fumar ya que la composici6n se encuentra confinada en la trayectoria del flujo de aire, y el suministro de la composici6n no se encuentra impedido por medio de la diluci6n con otros vapores procedentes del producto para fumar - por el contrario el suministro resulta el mas eficaz a valores de elevada diluci6n, es decir, cuando el flujo de aire es elevado. In detail, the present invention does not result in an increase in the pyrolysis or combustion of the smoke supplement composition since the composition supports, at most, only moderate heating. Migration of the composition to other parts of the smoking product is reduced since the composition is confined in the air flow path, and the supply of the composition is not impeded by dilution with other vapors from the product. for smoking - on the contrary the supply is the most effective at high dilution values, that is, when the air flow is high.

Ademas, la composici6n no se encuentra sometida a una filtraci6n importante, existe una cantidad fija de composici6n y actualmente el bloqueo de los orificios de ventilaci6n reduce el suministro de la composici6n en lugar de aumentarlo. In addition, the composition is not subject to significant filtration, there is a fixed amount of composition and currently the blocking of the ventilation holes reduces the supply of the composition instead of increasing it.

Los productos para fumar de acuerdo con la presente invenci6n incluyen puros, cigarrillos, narguiles y pipas, y preferentemente el producto para fumar de la presente invenci6n es un cigarrillo, De manera adicional, esta previsto que los productos para fumar que requieren que el fumador lleve a cabo las etapas finales de su preparaci6n, por The smoking products according to the present invention include cigars, cigarettes, hookahs and pipes, and preferably the smoking product of the present invention is a cigarette. Additionally, it is provided that the smoking products that require the smoker to carry carried out the final stages of its preparation, by

ejemplo tubos huecos ya conformados que contienen un filtro en cuyo interior el fumador introduce el tabaco, tambien se encuentren dentro del alcance de la invenci6n. Tambien estan previstos otros productos para fumar "de liado propio" o "preparaci6n propia" de acuerdo con la invenci6n tales como los productos para fumar que tipicamente usan componentes disponibles comercialmente para su uso en productos para fumar y/o accesorios disponibles comercialmente para su uso junto con los productos para fumar. For example, hollow tubes already formed that contain a filter into which the smoker introduces the tobacco, are also within the scope of the invention. Other "self-bundled" or "self-prepared" smoking products are also provided in accordance with the invention such as smoking products that typically use commercially available components for use in smoking products and / or commercially available accessories for use. along with smoking products.

Las sustancias tipicas que producen humo comprenden materiales de planta secos, por ejemplo tabaco. Typical substances that produce smoke comprise dry plant materials, for example tobacco.

De manera general, la sustancia que produce humo adopta la forma de una masa amorfa o cilindro. La sustancia que produce humo se encuentra albergada en el interior del producto para fumar, tipicamente dentro de la zona hacia el extremo distal del producto para fumar. De manera general, esta zona se extiende a lo largo de la direcci6n de un eje longitudinal del producto para fumar. Cuando la sustancia que produce humo adopta la forma de cilindro, de manera opcional el cilindro de sustancia que produce humo es hueco. In general, the substance that produces smoke takes the form of an amorphous mass or cylinder. The smoke-producing substance is housed inside the smoking product, typically within the area towards the distal end of the smoking product. In general, this area extends along the direction of a longitudinal axis of the smoking product. When the substance that produces smoke takes the form of a cylinder, optionally the cylinder of substance that produces smoke is hollow.

Preferentemente, el producto para fumar comprende un filtro y generalmente dicho filtro se encuentra ubicado en el extremo proximal del producto para fumar. Preferentemente, el filtro se encuentra en el interior o cubriendo el extremo proximal de cualquier zona que contenga la sustancia que produce humo de forma que, durante el uso, el humo procedente de la sustancia que produce humo es filtrado antes de ser suministrado al fumador. Preferably, the smoking product comprises a filter and generally said filter is located at the proximal end of the smoking product. Preferably, the filter is inside or covering the proximal end of any area that contains the smoke-producing substance so that, during use, the smoke from the smoke-producing substance is filtered before being supplied to the smoker.

Tipicamente, al menos un conducto del producto para fumar es considerablemente paralelo a la direcci6n de la extensi6n longitudinal de la zona del producto para fumar que contiene la sustancia que produce humo. No obstante, el menos un conducto es distinto de dicha zona. Typically, at least one conduit of the smoking product is substantially parallel to the direction of the longitudinal extent of the area of the smoking product containing the smoke-producing substance. However, at least one conduit is different from said zone.

Se define una trayectoria de flujo de aire a lo largo del al menos un conducto desde al menos un orificio de ventilaci6n, tipicamente colocado sobre la cara externa del producto para fumar, a traves del conducto hasta el extremo proximal del producto para fumar. An air flow path is defined along the at least one duct from at least one vent hole, typically placed on the outer face of the smoking product, through the duct to the proximal end of the smoking product.

En el caso de que el producto para fumar sea un cigarrillo, tipicamente al menos un orificio de ventilaci6n se encuentra ubicado en el papel de la boquilla del cigarrillo. In the event that the smoking product is a cigarette, typically at least one vent hole is located in the cigarette nozzle paper.

De manera general, el corte transversal del al menos un conducto se encuentra entre 0,1 y 50 % del corte transversal del producto para fumar, preferentemente entre 0,1 y 30 % y mas preferentemente entre 5 y 20 %. A medida que se reduce el corte transversal del al menos un conducto, aumenta la velocidad del aire a traves del conducto, mejorando de este modo el arrastre de la composici6n de suplemento de humo hacia el interior del flujo de aire y por tanto hacia el fumador. Puede ocurrir que algunas formulaciones de composici6n de suplemento de humo (por ejemplo las que comprenden glicerol) requieran algo de calor para contribuir a su transferencia hacia el interior de la corriente de aire, y esto se puede lograr proporcionando la sustancia que produce humo en forma de rodillo hueco, y/o proporcionando un filtro que tenga un nucleo de elevada caida de presi6n, de forma que la corriente de humo caliente pase cerca de la composici6n de suplemento de humo que se encuentra en el perimetro del filtro. In general, the cross section of the at least one duct is between 0.1 and 50% of the cross section of the smoking product, preferably between 0.1 and 30% and more preferably between 5 and 20%. As the cross section of the at least one duct is reduced, the velocity of the air through the duct increases, thereby improving the drag of the smoke supplement composition into the air flow and thus towards the smoker . It may happen that some smoke supplement composition formulations (eg those comprising glycerol) require some heat to contribute to their transfer into the air stream, and this can be achieved by providing the substance that produces smoke in form of hollow roller, and / or providing a filter having a high pressure drop core, so that the hot smoke stream passes near the smoke supplement composition that is in the perimeter of the filter.

Tambien se puede mejorar el arrastre de la composici6n de suplemento de humo hacia el interior del flujo de aire aumentando la longitud del conducto, por ejemplo mediante el uso de conductos que adoptan una configuraci6n de espiral alrededor del producto para fumar. Otra opci6n consiste en aumentar la convoluci6n de la trayectoria de flujo de aire, y/o introducir turbulencia en el interior de la trayectoria de flujo de aire, por ejemplo mediante la introducci6n de hendiduras o tabiques en el interior de los conductos. The dragging of the smoke supplement composition into the air flow can also be improved by increasing the length of the duct, for example by using ducts that adopt a spiral configuration around the smoking product. Another option is to increase the convolution of the air flow path, and / or introduce turbulence inside the air flow path, for example by introducing slits or partitions inside the ducts.

Tipicamente el al menos un conducto de la presente invenci6n se define como una cavidad generalmente c6ncava en el interior de un cuerpo, en el que el cuerpo se encuentra incorporado al interior de un producto para fumar. En este caso, el al menos un conducto se encuentra generalmente conformado mediante presi6n de un cilindro caliente en el interior del cuerpo. De manera alternativa, el al menos un conducto se define por medio de una sustancia envolvente arrugada que se coloca alrededor de un cuerpo formado en el interior del producto para fumar. Typically the at least one conduit of the present invention is defined as a generally concave cavity inside a body, in which the body is incorporated into a smoking product. In this case, the at least one duct is generally formed by pressing a hot cylinder inside the body. Alternatively, the at least one conduit is defined by means of a wrinkled enveloping substance that is placed around a body formed inside the smoking product.

De manera adicional, la trayectoria de flujo de aire comprende una cavidad que, durante el uso, almacena la composici6n de suplemento de humo. De manera alternativa o adicional, la composici6n de suplemento de humo es almacenada en el interior del al menos un conducto. Tipicamente, la composici6n de suplemento de humo se coloca en el interior de la cavidad/conducto usando cualquier medio conocido antes, despues o durante la fabricaci6n, tal como por medio de inyecci6n, empastado, impresi6n o deposici6n. Additionally, the air flow path comprises a cavity that, during use, stores the smoke supplement composition. Alternatively or additionally, the smoke supplement composition is stored inside the at least one duct. Typically, the smoke supplement composition is placed inside the cavity / duct using any means known before, after or during manufacturing, such as by means of injection, filling, printing or deposition.

Tipicamente, la composici6n de suplemento de humo comprende nicotina o un derivado de nicotina, y de manera opcional puede comprender una o mas sustancias que se escogen entre un aromatizante, un agente farmacol6gicamente activo o un modificador de humo. Typically, the smoke supplement composition comprises nicotine or a nicotine derivative, and may optionally comprise one or more substances chosen from a flavoring agent, a pharmacologically active agent or a smoke modifier.

Agentes farmacol6gicamente activos incluyen por ejemplo anti-oxidantes tales como vitamina C 6 E, que actuan para reducir el impacto de los radicales libres dentro del humo. Los modificadores de humo actuan para reducir la cantidad de compuestos no deseados en el humo, preferentemente actuando sobre el humo una vez que ya ha Pharmacologically active agents include for example anti-oxidants such as vitamin C 6 E, which act to reduce the impact of free radicals within the smoke. Smoke modifiers act to reduce the amount of unwanted compounds in the smoke, preferably acting on the smoke once it has already

salido del producto para fumar pero antes de su absorci6n en el interior del cuerpo del fumador. Se puede reducir la cantidad de componentes no deseados por medio de reacci6n quimica del componente no deseado (por ejemplo radicales) con el modificador de humo (por ejemplo un anti-oxidante) con el fin de desactivar el componente no deseado, o por medio de reacci6n del componente no deseado (por ejemplo radicales) con otro componente para desactivar el componente no deseado en el que esta reacci6n esta catalizada por un modificador de humo (por ejemplo un catalizador de hierro). De manera alternativa, el componente no deseado puede ser adsorbido en el interior o puede quedar amalgamado en una matriz de modificador de humo (por ejemplo una matriz de granulos finos de carbono). Dicha absorci6n/amalgamado puede reducir la disponibilidad del componente no deseado y/o modificar el modo en el que el componente no deseado se deposita en el interior de las vias respiratorias del fumador (por ejemplo si las particulas del componente no deseado son fabricadas con un tamafo suficientemente grande, esto particulas seran no respirables). left the smoking product but before its absorption inside the smoker's body. The amount of unwanted components can be reduced by chemical reaction of the unwanted component (for example radicals) with the smoke modifier (for example an anti-oxidant) in order to deactivate the unwanted component, or by means of reaction of the unwanted component (eg radicals) with another component to deactivate the unwanted component in which this reaction is catalyzed by a smoke modifier (for example an iron catalyst). Alternatively, the unwanted component can be adsorbed inside or it can be amalgamated in a smoke modifier matrix (for example a matrix of fine carbon granules). Said absorption / amalgamation can reduce the availability of the unwanted component and / or modify the way in which the unwanted component is deposited inside the smoker's airways (for example if the particles of the unwanted component are manufactured with a Large enough size, this particles will not be breathable).

Cualquiera de las una o mas sustancias y/o cualquiera de nicotina o derivado de nicotina, se puede encapsular o micro-encapsular, tipicamente antes de ser introducidas en el interior de la composici6n de suplemento de humo. Materiales apropiados de encapsulado o micro-encapsulado incluyen almid6n, goma arabiga, glicerol, gelatina, albumina o ciclodextrina. Se puede usar el encapsulado o el micro-encapsulado como metodo para contener compuestos volatiles. Any of the one or more substances and / or any of nicotine or nicotine derivative can be encapsulated or micro-encapsulated, typically before being introduced into the smoke supplement composition. Appropriate encapsulated or micro-encapsulated materials include starch, gum arabic, glycerol, gelatin, albumin or cyclodextrin. Encapsulation or micro-encapsulation can be used as a method to contain volatile compounds.

La composici6n de suplemento de humo puede ademas comprender un material de substrato tal como una red o una pelicula, o tal como particulas s6lidas por ejemplo ciclodextrina. Cualquiera de los nicotina/derivados de nicotina mencionados anteriormente y/o una o mas sustancias (tal como aromatizante, agentes farmacol6gicamente activos The smoke supplement composition may also comprise a substrate material such as a net or a film, or such as solid particles for example cyclodextrin. Any of the nicotine / nicotine derivatives mentioned above and / or one or more substances (such as flavoring, pharmacologically active agents

o modificadores de humo), que pueden estar todos ellos encapsulados de manera opcional como se ha descrito anteriormente, pueden estar incorporados en el interior o pueden encontrarse sobre el material del substrato. De manera opcional, el material de substrato es arrastrado por el aire de ventilaci6n. or smoke modifiers), which may all be optionally encapsulated as described above, may be incorporated inside or may be found on the substrate material. Optionally, the substrate material is entrained by the ventilation air.

De manera opcional, los orificios de ventilaci6n y/o los extremos proximales de los surcos del producto para fumar se encuentran sellados de forma que se puede retirar, de manera que durante el almacenamiento ninguna composici6n de suplemento de humo puede migrar fuera de los conductos y sobre otras partes del producto para fumar, o sobre cualquier filtro o encapsulado. Optionally, the ventilation holes and / or the proximal ends of the furrows of the smoking product are sealed so that it can be removed, so that during storage no smoke supplement composition can migrate out of the ducts and on other parts of the smoking product, or on any filter or encapsulation.

Los elementos de sellado que se pueden retirar apropiados incluyen una manga que se puede retirar para el producto para fumar, por ejemplo una manga que se desliza sobre el extremo proximal del producto. Dicha manga puede estar fabricada de un polimero tal como celofan. De manera alternativa, se puede incorporar una "cinta de rasgado" para los orificios de ventilaci6n y/o los extremos proximales de los conductos, en la que esta "cinta de rasgado" puede estar fabricada de cualquier polimero apropiado tal como celofan. Appropriate removable sealing elements include a sleeve that can be removed for the smoking product, for example a sleeve that slides over the proximal end of the product. Said sleeve may be made of a polymer such as cellophane. Alternatively, a "tear tape" can be incorporated for the ventilation holes and / or the proximal ends of the ducts, in which this "tear tape" can be made of any suitable polymer such as cellophane.

De manera similar, es preferible que los conductos comprendan una barrera impermeable de manera que, durante el uso, la composici6n de suplemento de humo no migre fuera de los conductos de ninguna forma que no sea a lo largo de la trayectoria de flujo de aire durante la acci6n de fumar. Similarly, it is preferable that the ducts comprise an impermeable barrier so that, during use, the smoke supplement composition does not migrate out of the ducts in any way other than along the air flow path during the action of smoking.

A continuaci6n se describen ejemplos de la presente invenci6n haciendo referencia a los dibujos adjuntos, en los que: Examples of the present invention are described below with reference to the accompanying drawings, in which:

La Figura 1 muestra los aspectos de disefo principales de un cigarrillo convencional; Figure 1 shows the main design aspects of a conventional cigarette;

La Figura 2 muestra una cigarrillo convencional con un filtro de compuesto que contiene un adsorbente; Figure 2 shows a conventional cigarette with a compound filter containing an adsorbent;

La Figura 3 muestra las trayectorias principales de flujo de aire de un cigarrillo convencional con un filtro de compuesto; Figure 3 shows the main air flow paths of a conventional cigarette with a compound filter;

La Figura 4 muestra las trayectorias principales de flujo de aire en el interior de un cigarrillo con un sistema de suministro paralelo de acuerdo con la presente invenci6n. Figure 4 shows the main air flow paths inside a cigarette with a parallel supply system according to the present invention.

La Figura 5 muestra un filtro relleno con conductos dispuestos para permitir el suministro paralelo de acuerdo con la presente invenci6n; Figure 5 shows a filter filled with ducts arranged to allow parallel delivery in accordance with the present invention;

La Figura 6 muestra un filtro relleno con conductos alternativos dispuestos para permitir el suministro paralelo de acuerdo con la presente invenci6n; Figure 6 shows a filter filled with alternative ducts arranged to allow parallel delivery in accordance with the present invention;

La Figura 7 muestra el corte transversal de un filtro relleno con conductos para permitir el suministro paralelo de acuerdo con la presente invenci6n; Figure 7 shows the cross-section of a filter filled with ducts to allow parallel delivery in accordance with the present invention;

La Figura 8 muestra un cigarrillo de acuerdo con la presente invenci6n que comprende una cavidad en la cual se almacena la composici6n de suplemento de humo; Figure 8 shows a cigarette according to the present invention comprising a cavity in which the smoke supplement composition is stored;

La Figura 9 muestra una vista en perspectiva del filtro de la Figura 8; Figure 9 shows a perspective view of the filter of Figure 8;

La Figura 10 muestra una cigarrillo de acuerdo con la presente invenci6n que comprende un cilindro de tabaco hueco; y Figure 10 shows a cigarette according to the present invention comprising a hollow tobacco cylinder; Y

La Figura 11 muestra un corte transversal de un cigarrillo de acuerdo con la presente invenci6n, en el que el cigarrillo usa una envoltura de relleno externa arrugada para formar los conductos. Figure 11 shows a cross section of a cigarette according to the present invention, in which the cigarette uses a wrinkled outer filler wrap to form the ducts.

Observando la Figura 1, se muestran aspectos de disefo principales de un cigarrillo 10 convencional. El cigarrillo 10 presenta un extremo proximal 11, y en este extremo proximal 11 se proporciona un filtro 12 de acetato de celulosa cilindrico. Este filtro esta envuelto con una envoltura 13 de relleno poroso y posteriormente esta envuelto con un papel de boquilla 14. El papel de boquilla 14 comprende orificios de ventilaci6n 15 que forman un anillo alrededor del filtro cilindrico. Junto al filtro 12, en su extremo distal, se encuentra el cilindro de tabaco 16. Este cilindro de tabaco 16 se encuentra envuelto con el papel de cigarrillo 17. Looking at Figure 1, main design aspects of a conventional cigarette 10 are shown. The cigarette 10 has a proximal end 11, and a cylindrical cellulose acetate filter 12 is provided at this proximal end 11. This filter is wrapped with a porous filler envelope 13 and subsequently wrapped with a nozzle paper 14. The nozzle paper 14 comprises ventilation holes 15 that form a ring around the cylindrical filter. Next to the filter 12, at its distal end, is the tobacco cylinder 16. This tobacco cylinder 16 is wrapped with cigarette paper 17.

Observando la Figura 2, se muestra un cigarrillo convencional con un filtro de compuesto que contiene un adsorbente. El filtro de compuesto comprende un segmento 22 de acetato de celulosa en el extremo proximal 11 del cigarrillo y un segmento 22 que contiene un adsorbente que se encuentra junto al extremo distal del segmento 22 de acetato de celulosa. En todos los demas aspectos, el cigarrillo es como el que se muestra en la Figura 1. Looking at Figure 2, a conventional cigarette with a compound filter containing an adsorbent is shown. The compound filter comprises a segment 22 of cellulose acetate at the proximal end 11 of the cigarette and a segment 22 containing an adsorbent that is adjacent to the distal end of segment 22 of cellulose acetate. In all other aspects, the cigarette is like the one shown in Figure 1.

La Figura 3 muestra las trayectorias principales de flujo de aire del cigarrillo convencional que se muestra en la Figura 2. En detalle, cuando se fuma el cigarrillo de la Figura 2, el aire es extraido a traves del cilindro de tabaco 16 y a traves del segmento de filtro 22" que contiene adsorbente y hacia el interior del segmento de filtro 22 de acetato de celulosa. En este momento, se extrae aire adicional a traves de los orificios de ventilaci6n 15 y hacia el interior del segmento de filtro 22 de acetato de celulosa. Este aire se mezcla con el aire procedente del segmento de filtro 22" que contiene adsorbente y todo el aire es extraido fuera del extremo proximal 11 del cigarrillo por parte del fumador. Figure 3 shows the main air flow paths of the conventional cigarette shown in Figure 2. In detail, when the cigarette of Figure 2 is smoked, the air is extracted through the tobacco cylinder 16 and through the segment filter 22 "containing adsorbent and into the cellulose acetate filter segment 22. At this time, additional air is drawn through the vent holes 15 and into the cellulose acetate filter segment 22 This air is mixed with the air coming from the filter segment 22 "which contains adsorbent and all the air is extracted outside the proximal end 11 of the cigarette by the smoker.

La Figura 4 muestra las trayectorias principales de flujo de aire dentro del cigarrillo con un sistema de suministro paralelo de acuerdo con la presente invenci6n. En detalle, se extrae el aire a traves del cilindro de tabaco 16 y posteriormente a traves del segmento de filtro 22" que contiene adsorbente y hacia el interior del segmento de filtro 22 de acetato de celulosa como ya se ha descrito con respecto a la Figura 3. El aire es extraido fuera del extremo proximal del cigarrillo 11 por parte del fumador. Al contrario que en la Figura 3, no obstante, el aire adicional que penetra por medio de los orificios de ventilaci6n 15 es extraido a lo largo de los conductos 41 que contienen la composici6n 42 de suplemento de humo. Este aire adicional no se mezcla con el aire procedente del cilindro de tabaco 16, sino que es confinado en los conductos 41 y extraido del extremo proximal del cigarrillo 11 por parte del fumador. Figure 4 shows the main air flow paths within the cigarette with a parallel delivery system in accordance with the present invention. In detail, the air is extracted through the tobacco cylinder 16 and subsequently through the adsorbent filter segment 22 "and into the cellulose acetate filter segment 22 as already described with respect to the Figure 3. The air is drawn out of the proximal end of the cigarette 11 by the smoker, unlike in Figure 3, however, the additional air that penetrates through the ventilation holes 15 is drawn along the ducts 41 containing the smoke supplement composition 42. This additional air is not mixed with the air from the tobacco cylinder 16, but is confined in the ducts 41 and extracted from the proximal end of the cigarette 11 by the smoker.

La Figura 5 muestra un relleno de filtro con conductos para permitir el suministro paralelo de acuerdo con la presente invenci6n. Como puede observarse, considerablemente rectos, se forman los conductos paralelos 41 en el segmento de filtro 22 de acetato de celulosa. Los extremos distales de los conductos 41 se alinean con los orificios de ventilaci6n 15 (no mostrados). Figure 5 shows a filter fill with ducts to allow parallel delivery in accordance with the present invention. As can be seen, considerably straight, parallel conduits 41 are formed in the cellulose acetate filter segment 22. The distal ends of the ducts 41 align with the ventilation holes 15 (not shown).

La Figura 6 muestra un relleno de filtro con conductos alternativos para permitir el suministro paralelo de acuerdo con la presente invenci6n. Al contrario que la Figura 5, los conductos 41 esta dispuestos de forma que se extienden considerablemente en sentido longitudinal al tiempo que tambien exhiben progresi6n radial alrededor del eje del segmento de filtro 22. Esta configuraci6n aumenta la longitud de los conductos 41 y por tanto puede aumentar la capacidad del cigarrillo para suministrar la composici6n de suplemento de humo. Figure 6 shows a filter fill with alternative ducts to allow parallel delivery in accordance with the present invention. In contrast to Figure 5, the ducts 41 are arranged so that they extend considerably longitudinally while also exhibiting radial progression around the axis of the filter segment 22. This configuration increases the length of the ducts 41 and therefore can increase the ability of the cigarette to supply the smoke supplement composition.

La Figura 7 muestra un corte transversal de un relleno de filtro con conductos dispuestos para permitir el suministro paralelo de acuerdo con la presente invenci6n. Como puede verse, los conductos 41 estan formados a partir de depresiones c6ncavas dentro del filtro 22. Figure 7 shows a cross-section of a filter fill with conduits arranged to allow parallel delivery in accordance with the present invention. As can be seen, the ducts 41 are formed from concave depressions within the filter 22.

La Figura 8 muestra un cigarrillo de acuerdo con la presente invenci6n que comprende una cavidad 81 en la cual se almacena la composici6n de suplemento de humo. En detalle, el aire es extraido a traves del cilindro de tabaco 16 y posteriormente a traves del segmento de filtro 22" que contiene adsorbente y hacia el interior del segmento de filtro 22 de acetato de celulosa como ya se ha descrito con respecto a la Figura 3. Este aire es extraido posteriormente fuera del extremo proximal del cigarrillo 11 por parte del fumador. De forma similar a la de la Figura 4, el aire adicional es introducido a traves de orificios de ventilaci6n 15 y pasa sobre la composici6n 42 de suplemento de humo que se encuentra dentro de la cavidad 81. Posteriormente, este aire pasa a lo largo de los conductos 41 y es extraido fuera del extremo proximal del cigarrillo 11 por parte del fumador. Figure 8 shows a cigarette according to the present invention comprising a cavity 81 in which the smoke supplement composition is stored. In detail, the air is extracted through the tobacco cylinder 16 and subsequently through the filter segment 22 "containing adsorbent and into the cellulose acetate filter segment 22 as already described with respect to the Figure 3. This air is subsequently extracted outside the proximal end of the cigarette 11. by the smoker, similar to that of Figure 4, the additional air is introduced through ventilation holes 15 and passes over the composition 42 smoke that is inside the cavity 81. Subsequently, this air passes along the ducts 41 and is extracted outside the proximal end of the cigarette 11 by the smoker.

La Figura 9 muestra una vista en perspectiva del filtro de la Figura 8. Como puede observarse, el filtro 22 de acetato de celulosa comprende una cavidad 81, en conexi6n de flujo de aire con los conductos 41, que se extiende hasta el extremo proximal del cigarrillo 11. La cavidad 81 se alinea con los orificios de ventilaci6n 15 (no mostrados). Figure 9 shows a perspective view of the filter of Figure 8. As can be seen, the cellulose acetate filter 22 comprises a cavity 81, in air flow connection with the ducts 41, which extends to the proximal end of the cigarette 11. The cavity 81 is aligned with the ventilation holes 15 (not shown).

La Figura 10 muestra un cigarrillo de acuerdo con la presente invenci6n que comprende un cilindro de tabaco hueco. Figure 10 shows a cigarette according to the present invention comprising a hollow tobacco cylinder.

En detalle, se extrae el aire a traves del cilindro de tabaco 16 y hacia el interior del nucleo hueco del cilindro 101. Posteriormente, este aire pasa a traves del segmento de filtro 22" que contiene adsorbente y hacia el interior del segmento de filtro 102. Este segmento de filtro 102 comprende un nucleo 103 de caida de alta presi6n y el flujo de aire procedente del segmento de filtro 22" que contiene adsorbente pasa entre el nucleo 103 de caida de alta In detail, the air is extracted through the tobacco cylinder 16 and into the hollow core of the cylinder 101. Subsequently, this air passes through the filter segment 22 "containing adsorbent and into the filter segment 102 This filter segment 102 comprises a high pressure drop core 103 and the flow of air from the adsorbent filter segment 22 "passes between the high drop core 103

5 presi6n y los conductos 41, y posteriormente es extraido fuera del extremo proximal del cigarrillo 11 por parte del fumador. Como se describe con respecto a la Figura 4, el aire adicional que penetra por medio de los orificios de ventilaci6n 15 es extraido a lo largo de los conductos 41 que contienen la composici6n 42 de suplemento de humo. Este aire adicional no se mezcla con al aire procedente del cilindro de tabaco 16 sino que queda confinado en los conductos 41 y es extraido fuera del extremo proximal del cigarrillo 11 por parte del fumador. 5 pressure and the ducts 41, and then it is extracted outside the proximal end of the cigarette 11 by the smoker. As described with respect to Figure 4, the additional air that penetrates through the vent holes 15 is drawn along the ducts 41 containing the smoke supplement composition 42. This additional air is not mixed with the air from the tobacco cylinder 16 but is confined in the ducts 41 and is extracted outside the proximal end of the cigarette 11 by the smoker.

10 La Figura 11 muestra un corte transversal del cigarrillo que usa una envoltura 112 de relleno externo arrugada dispuesta para formar los conductos. En detalle, los conductos 111 estan formados colocando la envoltura 112 de relleno externo arrugada alrededor de la parte exterior del filtro de celulosa 22. La envoltura 112 de relleno externo arrugada se separa del filtro 22 por medio de la envoltura de relleno 113, y los conductos 113 formados por la envoltura 112 de relleno externo arrugada quedan sellados por medio del papel 14 de la boquilla envolvente 10 Figure 11 shows a cross section of the cigarette using a wrinkled outer filler envelope 112 arranged to form the ducts. In detail, the ducts 111 are formed by placing the wrinkled outer filler sheath 112 around the outer part of the cellulose filter 22. The wrinkled outer filler sheath 112 is separated from the filter 22 by means of the filler sheath 113, and the ducts 113 formed by the wrinkled outer filler envelope 112 are sealed by means of the paper 14 of the wrapping nozzle

15 alrededor de la envoltura 12 de relleno externo arrugada. Los surcos se extienden unicamente una parte hacia abajo del filtro y no entran en contacto con el cilindro de tabaco (no mostrado). 15 around the wrinkled outer filler envelope 12. The grooves extend only one part downwards of the filter and do not come into contact with the tobacco cylinder (not shown).

Claims (14)

REIVINDICACIONES 1.-Un producto para fumar que comprende: 1.-A smoking product that includes: un extremo distal que, durante el uso, contiene una sustancia (16) que produce humo y a distal end that, during use, contains a substance (16) that produces smoke and un extremo proximal desde el cual este humo es extraido durante la acci6n de fumar que se caracteriza por: a proximal end from which this smoke is extracted during the smoking action characterized by: al menos un conducto (41) que se extiende desde el extremo proximal hasta al menos una parte hacia el extremo distal; at least one conduit (41) extending from the proximal end to at least one part towards the distal end; al menos un orificio de ventilaci6n (15) dispuesto de forma tal que queda definida una trayectoria de flujo de aire a traves del orificio de ventilaci6n, por medio del conducto, y hacia el extremo proximal del producto para fumar; at least one ventilation hole (15) arranged in such a way that an air flow path is defined through the ventilation hole, by means of the duct, and towards the proximal end of the smoking product; una composici6n (42) de suplemento de humo, estando alojada la composici6n a lo largo de la trayectoria de flujo de aire, de forma tal que, cuando se fuma el producto para fumar, el aire es extraido a lo largo de la trayectoria del flujo de aire y sobre la composici6n de manera que la composici6n pasa a estar suspendida en el aire y es suministrada al fumador. a smoke supplement composition (42), the composition being housed along the air flow path, such that, when the smoking product is smoked, the air is drawn along the flow path of air and on the composition so that the composition becomes suspended in the air and is supplied to the smoker. 2.-El producto para fumar de acuerdo con la reivindicaci6n 1, en el que la composici6n (42) de suplemento de humo comprende nicotina o un derivado de nicotina. 2. The smoking product according to claim 1, wherein the smoke supplement composition (42) comprises nicotine or a nicotine derivative. 3.-El producto para fumar de acuerdo con la reivindicaci6n 1 6 2, en el que la composici6n (42) de suplemento de humo incluye al menos una sustancia entre el grupo de aromatizantes, agentes farmacol6gicamente activos y modificadores de humo. 3. The smoking product according to claim 1, in which the smoke supplement composition (42) includes at least one substance among the group of flavorings, pharmacologically active agents and smoke modifiers. 4.-El producto para fumar de acuerdo con la reivindicaci6n 1, 2 6 3, en el que al menos una sustancia se encuentra encapsulada. 4. The smoking product according to claim 1, 2 or 3, wherein at least one substance is encapsulated. 5.-El producto para fumar de acuerdo con la reivindicaci6n 4, en el que la sustancia se encuentra encapsulada con ciclodextrina. 5. The smoking product according to claim 4, wherein the substance is encapsulated with cyclodextrin. 6.-El producto para fumar de acuerdo con cualquiera de las reivindicaciones 1 a 5, en el que la composici6n (42) de suplemento de humo comprende una red o pelicula. 6. The smoking product according to any of claims 1 to 5, wherein the smoke supplement composition (42) comprises a net or film. 7.-El producto de acuerdo con cualquiera de las reivindicaciones anteriores, en el que la composici6n (42) de suplemento de humo comprende particulas s6lidas. 7. The product according to any of the preceding claims, wherein the smoke supplement composition (42) comprises solid particles. 8.-El producto para fumar de acuerdo con cualquier reivindicaci6n anterior, en el que la composici6n (42) de suplemento de humo se encuentra alojada dentro de cavidades (81) a lo largo de la trayectoria de flujo de aire. 8. The smoking product according to any preceding claim, wherein the smoke supplement composition (42) is housed within cavities (81) along the air flow path. 9.-El producto para fumar de acuerdo con cualquier reivindicaci6n anterior, en el que, durante el almacenamiento, los orificios de ventilaci6n (15) y/o los extremos proximales de los conductos comprenden un sellado que se puede retirar. 9. The smoking product according to any preceding claim, wherein, during storage, the ventilation holes (15) and / or the proximal ends of the ducts comprise a seal that can be removed.
10. 10.
El producto para fumar de acuerdo con cualquiera de las reivindicaciones anteriores, en el que al menos un conducto (41) comprende una barrera impermeable de forma tal que, tanto durante el almacenamiento como durante la acci6n de fumar, la composici6n de suplemento de humo no migra fuera del al menos un conducto de ninguna otra forma de la que se especifica en la reivindicaci6n 1. The smoking product according to any of the preceding claims, wherein at least one conduit (41) comprises an impermeable barrier such that, both during storage and during smoking, the smoke supplement composition does not migrates out of the at least one conduit in any other way as specified in claim 1.
11. eleven.
El producto para fumar de acuerdo con cualquier reivindicaci6n anterior, en el que el producto para fumar es un cigarrillo que comprende un filtro. The smoking product according to any preceding claim, wherein the smoking product is a cigarette comprising a filter.
12.12.
El producto para fumar de acuerdo con la reivindicaci6n 11, en el que los conductos (41) se encuentran definidos dentro del filtro.  The smoking product according to claim 11, wherein the ducts (41) are defined within the filter.
13. 13.
El producto para fumar de acuerdo con cualquiera de las reivindicaciones 11 6 12, en el que los orificios de ventilaci6n (15) se encuentran dentro del papel de boquilla impermeable. The smoking product according to any of claims 11 6 12, wherein the ventilation holes (15) are inside the waterproof nozzle paper.
14. 14.
El producto para fumar de acuerdo con cualquiera de las reivindicaciones 11 a 13, en el que el cigarrillo ademas comprende un cilindro de tabaco (16) con un nucleo hueco. The smoking product according to any of claims 11 to 13, wherein the cigarette further comprises a tobacco cylinder (16) with a hollow core.
ES06806581T 2005-12-15 2006-10-27 Smoking product Active ES2378147T3 (en)

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EP05257731A EP1797780A1 (en) 2005-12-15 2005-12-15 Smoking article
PCT/EP2006/010365 WO2007068309A1 (en) 2005-12-15 2006-10-27 Smoking article

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KR20080077283A (en) 2008-08-21
RU2396062C2 (en) 2010-08-10
EP1797780A1 (en) 2007-06-20
EP1962623B1 (en) 2011-11-30
UA91096C2 (en) 2010-06-25
CN101330841B (en) 2012-01-25
CN101330841A (en) 2008-12-24
RU2008123265A (en) 2010-01-20
CA2632975A1 (en) 2007-06-21
JP2009517056A (en) 2009-04-30
MY145805A (en) 2012-04-30
PL1962623T3 (en) 2012-04-30
WO2007068309A1 (en) 2007-06-21
ATE535161T1 (en) 2011-12-15
EP1962623A1 (en) 2008-09-03
US20080314401A1 (en) 2008-12-25

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