ES2282630T3 - Material de carbono con polimero conductor sulfonado injertado para aplicaciones de pila de combustible. - Google Patents
Material de carbono con polimero conductor sulfonado injertado para aplicaciones de pila de combustible. Download PDFInfo
- Publication number
- ES2282630T3 ES2282630T3 ES03729097T ES03729097T ES2282630T3 ES 2282630 T3 ES2282630 T3 ES 2282630T3 ES 03729097 T ES03729097 T ES 03729097T ES 03729097 T ES03729097 T ES 03729097T ES 2282630 T3 ES2282630 T3 ES 2282630T3
- Authority
- ES
- Spain
- Prior art keywords
- sulfonated
- composition
- conductive polymer
- polymer
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000446 fuel Substances 0.000 title claims abstract description 85
- 239000003575 carbonaceous material Substances 0.000 title claims abstract description 73
- 229920000642 polymer Polymers 0.000 title claims abstract description 70
- 239000004020 conductor Substances 0.000 title claims description 37
- 239000000203 mixture Substances 0.000 claims abstract description 119
- 229920001940 conductive polymer Polymers 0.000 claims abstract description 105
- 229910052751 metal Inorganic materials 0.000 claims abstract description 89
- 239000002184 metal Substances 0.000 claims abstract description 89
- 238000000034 method Methods 0.000 claims abstract description 82
- 239000012528 membrane Substances 0.000 claims abstract description 68
- 239000000178 monomer Substances 0.000 claims abstract description 49
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 40
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 7
- 239000006229 carbon black Substances 0.000 claims description 102
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 70
- 239000000463 material Substances 0.000 claims description 64
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 60
- 229910052799 carbon Inorganic materials 0.000 claims description 45
- 229920000767 polyaniline Polymers 0.000 claims description 39
- 229920000128 polypyrrole Polymers 0.000 claims description 37
- 239000003795 chemical substances by application Substances 0.000 claims description 27
- 229910052697 platinum Inorganic materials 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 21
- 239000007800 oxidant agent Substances 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 230000001590 oxidative effect Effects 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 15
- 238000006116 polymerization reaction Methods 0.000 claims description 15
- 238000006277 sulfonation reaction Methods 0.000 claims description 15
- 229920000557 Nafion® Polymers 0.000 claims description 12
- 239000003638 chemical reducing agent Substances 0.000 claims description 12
- -1 platinum halide Chemical class 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 229910002804 graphite Inorganic materials 0.000 claims description 10
- 239000010439 graphite Substances 0.000 claims description 10
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- CWMYWRMDANXCSB-UHFFFAOYSA-N 1-oxoethanesulfonic acid Chemical compound CC(=O)S(O)(=O)=O CWMYWRMDANXCSB-UHFFFAOYSA-N 0.000 claims description 8
- 238000001465 metallisation Methods 0.000 claims description 8
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 claims description 6
- 239000011237 carbonaceous particulate material Substances 0.000 claims description 6
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920000123 polythiophene Polymers 0.000 claims description 6
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 6
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 claims description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 5
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 5
- QCDFRRQWKKLIKV-UHFFFAOYSA-M chloroplatinum Chemical compound [Pt]Cl QCDFRRQWKKLIKV-UHFFFAOYSA-M 0.000 claims description 5
- 229910003472 fullerene Inorganic materials 0.000 claims description 5
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 5
- 229910021392 nanocarbon Inorganic materials 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 5
- 229920000414 polyfuran Polymers 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 229920002863 poly(1,4-phenylene oxide) polymer Polymers 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- INXLGDBFWGBBOC-UHFFFAOYSA-N platinum(2+);dicyanide Chemical compound [Pt+2].N#[C-].N#[C-] INXLGDBFWGBBOC-UHFFFAOYSA-N 0.000 claims description 2
- NWAHZABTSDUXMJ-UHFFFAOYSA-N platinum(2+);dinitrate Chemical compound [Pt+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O NWAHZABTSDUXMJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- JYLNVJYYQQXNEK-UHFFFAOYSA-N 3-amino-2-(4-chlorophenyl)-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(CN)C1=CC=C(Cl)C=C1 JYLNVJYYQQXNEK-UHFFFAOYSA-N 0.000 claims 1
- 125000005001 aminoaryl group Chemical group 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- JOKPITBUODAHEN-UHFFFAOYSA-N sulfanylideneplatinum Chemical compound [Pt]=S JOKPITBUODAHEN-UHFFFAOYSA-N 0.000 claims 1
- 239000010411 electrocatalyst Substances 0.000 abstract description 7
- 238000000429 assembly Methods 0.000 abstract description 3
- 230000000712 assembly Effects 0.000 abstract description 3
- 239000002322 conducting polymer Substances 0.000 abstract 3
- 235000019241 carbon black Nutrition 0.000 description 100
- 239000003054 catalyst Substances 0.000 description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 50
- 239000000725 suspension Substances 0.000 description 39
- 239000000243 solution Substances 0.000 description 31
- 230000003197 catalytic effect Effects 0.000 description 26
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 24
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 24
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 22
- 239000008367 deionised water Substances 0.000 description 21
- 229910021641 deionized water Inorganic materials 0.000 description 21
- 239000003792 electrolyte Substances 0.000 description 21
- 239000007789 gas Substances 0.000 description 17
- 239000000126 substance Substances 0.000 description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 16
- 230000008569 process Effects 0.000 description 16
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 14
- 239000006185 dispersion Substances 0.000 description 14
- 238000003756 stirring Methods 0.000 description 14
- 239000007787 solid Substances 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 9
- 239000003245 coal Substances 0.000 description 9
- 229920005597 polymer membrane Polymers 0.000 description 9
- 239000000779 smoke Substances 0.000 description 9
- 229960000583 acetic acid Drugs 0.000 description 8
- 239000012362 glacial acetic acid Substances 0.000 description 8
- 239000002923 metal particle Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229920000554 ionomer Polymers 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
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- 150000002500 ions Chemical class 0.000 description 6
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- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
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- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 238000004873 anchoring Methods 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 239000002817 coal dust Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
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- 238000011160 research Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000002083 X-ray spectrum Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
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- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
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- 150000003057 platinum Chemical class 0.000 description 2
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- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- DGQQLJUOIVFNLX-UHFFFAOYSA-N 3-methylaniline Chemical compound CC1=CC=CC(N)=C1.CC1=CC=CC(N)=C1 DGQQLJUOIVFNLX-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
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- 125000003010 ionic group Chemical group 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
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- 229910052762 osmium Inorganic materials 0.000 description 1
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- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
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- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
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- 125000001424 substituent group Chemical group 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
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- 229910052723 transition metal Inorganic materials 0.000 description 1
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- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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Applications Claiming Priority (2)
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| US38266502P | 2002-05-23 | 2002-05-23 | |
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| ES2282630T3 true ES2282630T3 (es) | 2007-10-16 |
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| ES03729097T Expired - Lifetime ES2282630T3 (es) | 2002-05-23 | 2003-05-23 | Material de carbono con polimero conductor sulfonado injertado para aplicaciones de pila de combustible. |
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| EP (1) | EP1509930B1 (fr) |
| JP (1) | JP2005527687A (fr) |
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Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7459103B2 (en) | 2002-05-23 | 2008-12-02 | Columbian Chemicals Company | Conducting polymer-grafted carbon material for fuel cell applications |
| US7390441B2 (en) | 2002-05-23 | 2008-06-24 | Columbian Chemicals Company | Sulfonated conducting polymer-grafted carbon material for fuel cell applications |
| US7195834B2 (en) | 2002-05-23 | 2007-03-27 | Columbian Chemicals Company | Metallized conducting polymer-grafted carbon material and method for making |
| DE60311985T2 (de) | 2002-05-23 | 2007-10-25 | Columbian Chemicals Company | Sulfoniertes leitungs-graftpolymerkohlenstoffmaterial für brennstoffzellenanwendungen |
| CA2486765A1 (fr) | 2002-05-23 | 2003-12-04 | Columbian Chemicals Company | Materiau conducteur carbone greffe sur un polymere destine a des applications de pile a combustible |
| US7241334B2 (en) * | 2002-05-23 | 2007-07-10 | Columbian Chemicals Company | Sulfonated carbonaceous materials |
| JP2004022346A (ja) * | 2002-06-17 | 2004-01-22 | Norio Tsubokawa | 燃料電池用電極触媒、燃料電池用電極およびそれを用いた燃料電池 |
| US7220693B1 (en) * | 2002-06-27 | 2007-05-22 | H Power Corporation | Fuel cell catalyst electrodes |
| FR2843399B1 (fr) * | 2002-08-06 | 2004-09-03 | Commissariat Energie Atomique | Polymeres de type polyphenylenes, leur procede de preparation, membranes et dispositif de pile a combustible comprenant ces membranes |
| US7767324B2 (en) * | 2003-05-06 | 2010-08-03 | Gas Technology Institute | Direct methanol fuel cell electrode catalyst |
| WO2004107359A1 (fr) * | 2003-05-23 | 2004-12-09 | Columbian Chemicals Company | Materiau carbone conducteur metallise a polymere greffe |
| US6958308B2 (en) | 2004-03-16 | 2005-10-25 | Columbian Chemicals Company | Deposition of dispersed metal particles onto substrates using supercritical fluids |
| JP4761436B2 (ja) * | 2004-03-31 | 2011-08-31 | 三菱レイヨン株式会社 | カーボンナノチューブ含有重合体、これからなる塗膜を有する複合体、およびそれらの製造方法 |
| KR100590555B1 (ko) * | 2004-07-08 | 2006-06-19 | 삼성에스디아이 주식회사 | 담지 촉매 및 이를 이용한 연료전지 |
| US20060068987A1 (en) * | 2004-09-24 | 2006-03-30 | Srinivas Bollepalli | Carbon supported catalyst having reduced water retention |
| JP4591029B2 (ja) * | 2004-10-12 | 2010-12-01 | コニカミノルタホールディングス株式会社 | 燃料電池用電極触媒の製造方法 |
| US8993193B2 (en) * | 2005-08-05 | 2015-03-31 | GM Global Technology Operations LLC | Sulfonated perfluorosulfonic acid polyelectrolyte membranes |
| JP2007258111A (ja) * | 2006-03-24 | 2007-10-04 | Fujifilm Corp | 燃料電池用触媒材料、触媒膜、電極膜接合体および燃料電池 |
| US20090280381A1 (en) * | 2006-07-07 | 2009-11-12 | World Minerals, Inc. | Diatomaceous Earth Proton Conductor |
| US8318385B2 (en) * | 2006-09-19 | 2012-11-27 | Nanotek Instruments, Inc. | Process for producing fuel cell electrode |
| US8202669B2 (en) * | 2006-10-19 | 2012-06-19 | Nanotek Instruments, Inc. | Electro-catalyst compositions for fuel cells |
| EP2099869B1 (fr) | 2006-10-31 | 2013-05-01 | Sensient Colors Inc. | Pigments modifies et leurs procedes de fabrication et d'utilisation |
| KR100823487B1 (ko) * | 2006-11-01 | 2008-04-21 | 삼성에스디아이 주식회사 | 금속 나노 입자의 제조 방법 |
| US20080182153A1 (en) * | 2007-01-30 | 2008-07-31 | Jang Bor Z | Fuel cell electro-catalyst composite composition, electrode, catalyst-coated membrane, and membrane-electrode assembly |
| US9318762B2 (en) * | 2007-02-12 | 2016-04-19 | Nanotek Instruments, Inc. | Conducting polymer-transition metal electro-catalyst compositions for fuel cells |
| JP4898568B2 (ja) * | 2007-06-15 | 2012-03-14 | 株式会社ノリタケカンパニーリミテド | 触媒層および膜−電極接合体 |
| US7785498B2 (en) * | 2007-07-19 | 2010-08-31 | Nanotek Instruments, Inc. | Method of producing conducting polymer-transition metal electro-catalyst composition and electrodes for fuel cells |
| CA3017708C (fr) | 2007-08-23 | 2021-09-21 | Vincent Shing | Pigments auto-disperses et procedes de preparation et d'utilisation de ceux-ci |
| US20090061473A1 (en) * | 2007-08-29 | 2009-03-05 | Rajiv Krishna Saxena | Measurement of Carbonaceous Particles in Biological Samples |
| JP5350739B2 (ja) * | 2007-10-29 | 2013-11-27 | フロンティアカーボン株式会社 | フラーレン誘導体の製造方法及びフラーレン誘導体 |
| WO2009101635A1 (fr) * | 2008-02-12 | 2009-08-20 | Council Of Scientific & Industrial Research | Composition à conductivité protonique améliorée |
| US8221938B2 (en) * | 2008-08-08 | 2012-07-17 | GM Global Technology Operations LLC | Method of making a stable hydrophilic coating/surface on carbon-based materials for fuel cell applications |
| US8816023B2 (en) * | 2008-08-13 | 2014-08-26 | Ppg Industries Ohio, Inc | Lightweight particles and compositions containing them |
| US8233830B2 (en) * | 2009-01-27 | 2012-07-31 | Xerox Corporation | Polypyrrole containing intermediate transfer components |
| JP5423108B2 (ja) * | 2009-04-03 | 2014-02-19 | トヨタ自動車株式会社 | 燃料電池 |
| US9221986B2 (en) | 2009-04-07 | 2015-12-29 | Sensient Colors Llc | Self-dispersing particles and methods for making and using the same |
| FR2962806B1 (fr) * | 2010-07-16 | 2012-09-28 | Commissariat Energie Atomique | Electrode de reference miniature |
| US8840687B2 (en) * | 2010-08-23 | 2014-09-23 | Corning Incorporated | Dual-layer method of fabricating ultracapacitor current collectors |
| NZ592081A (en) * | 2011-04-05 | 2013-11-29 | Auckland Uniservices Ltd | Polymerization method and product |
| US20130177823A1 (en) * | 2012-01-05 | 2013-07-11 | K Tube Technology LLC | Systems, Devices, and/or Methods for Power Generation from Water |
| US20130288155A1 (en) * | 2012-04-30 | 2013-10-31 | Samsung Sdi Co., Ltd. | Support for electrode catalyst and method of manufacturing the same, electrode catalyst and fuel cell |
| CN102755901B (zh) * | 2012-07-17 | 2014-03-19 | 天津理工大学 | 一种用于缩合反应的复合固体酸催化剂的制备和应用 |
| JP6100516B2 (ja) * | 2012-12-17 | 2017-03-22 | デンカ株式会社 | 窒素含有カーボンブラック、その製造方法及びそれを用いた燃料電池用触媒 |
| US11271198B2 (en) | 2016-01-25 | 2022-03-08 | HYDRO-QUéBEC | Core-shell electrode material particles and their use in electrochemical cells |
| RU2647846C1 (ru) * | 2016-10-19 | 2018-03-21 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Тамбовский государственный технический университет" (ФГБОУ ВО "ТГТУ") | Способ получения водного раствора полианилина |
| US10084220B2 (en) * | 2016-12-12 | 2018-09-25 | Nanotek Instruments, Inc. | Hybrid solid state electrolyte for lithium secondary battery |
| JP6314261B2 (ja) * | 2017-01-25 | 2018-04-18 | デンカ株式会社 | アセチレンブラック及びそれを用いた燃料電池用触媒 |
| JP6915453B2 (ja) * | 2017-08-24 | 2021-08-04 | 三菱ケミカル株式会社 | 炭素微粒子分散液 |
| JP7006497B2 (ja) * | 2018-05-11 | 2022-02-10 | トヨタ自動車株式会社 | 燃料電池用触媒層及びその製造方法 |
| CN109970568B (zh) * | 2019-05-21 | 2022-09-02 | 扬州工业职业技术学院 | 一种3-氨基邻苯二甲酸二甲酯的合成工艺 |
| CN112838252A (zh) * | 2019-11-25 | 2021-05-25 | 嘉应学院 | 一种燃料电池用高质子电导率的质子交换膜及其制备方法与应用 |
| CN114447382B (zh) * | 2020-10-31 | 2024-05-31 | 中国石油化工股份有限公司 | 一种含有同心轴微观结构的质子交换膜及其制备方法 |
| TWI766800B (zh) * | 2021-09-03 | 2022-06-01 | 行政院原子能委員會核能研究所 | 液流電池碳表面電極優化方法 |
| KR20230151606A (ko) * | 2022-04-26 | 2023-11-02 | 현대자동차주식회사 | 페로브스카이트 화합물을 포함하는 고분자 전해질막 연료전지용 첨가제 및 이를 포함하는 고분자 전해질막 연료전지 |
Family Cites Families (101)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3279935A (en) | 1963-06-11 | 1966-10-18 | Ashland Oil Refining Company | Oxidation of carbon black |
| US3442679A (en) | 1966-06-27 | 1969-05-06 | Cabot Corp | Sulfonated carbon blacks |
| US3519452A (en) | 1967-03-09 | 1970-07-07 | Cabot Corp | Sulfonated carbon black pigmented compositions |
| US3528840A (en) | 1967-11-15 | 1970-09-15 | Huber Corp J M | Sulfonated carbon black |
| US4014844A (en) | 1970-06-26 | 1977-03-29 | Agence Nationale De Valorisation De La Recherche (Anvar) | Process for grafting polymers on carbon black through free radical mechanism |
| US3870841A (en) | 1972-10-02 | 1975-03-11 | Exxon Research Engineering Co | Flexible polymeric compositions comprising a normally plastic polymer sulfonated to about 0.2 to about 10 mole % sulfonate |
| US3853933A (en) | 1974-01-14 | 1974-12-10 | Gen Electric | Continuous process for producing polysiloxane oils utilizing a carbon black catalyst |
| GB1543204A (en) | 1976-02-20 | 1979-03-28 | Shell Int Research | Method for the preparation of a catalyst suitable for fuel cell electrodes |
| US4241112A (en) | 1978-08-08 | 1980-12-23 | Akopian Leonid A | Method for applying polymer coating composition |
| US4237323A (en) | 1979-06-08 | 1980-12-02 | Aliev Sakhib M O | Method for preparing α-naphthol |
| JPS5975943A (ja) | 1982-10-25 | 1984-04-28 | Showa Denko Kk | 電導性重合体組成物の製造方法 |
| US4582731A (en) | 1983-09-01 | 1986-04-15 | Battelle Memorial Institute | Supercritical fluid molecular spray film deposition and powder formation |
| US4734227A (en) | 1983-09-01 | 1988-03-29 | Battelle Memorial Institute | Method of making supercritical fluid molecular spray films, powder and fibers |
| US4552786A (en) | 1984-10-09 | 1985-11-12 | The Babcock & Wilcox Company | Method for densification of ceramic materials |
| US4610938A (en) | 1985-07-24 | 1986-09-09 | Electric Power Research Institute | Acid fuel cell |
| US4737384A (en) | 1985-11-01 | 1988-04-12 | Allied Corporation | Deposition of thin films using supercritical fluids |
| JPS62109821A (ja) | 1985-11-08 | 1987-05-21 | Mitsui Toatsu Chem Inc | 複素五員環式化合物重合体組成物の製造方法 |
| US4731408A (en) | 1985-12-20 | 1988-03-15 | Polaroid Corporation | Processable conductive polymers |
| US4714569A (en) | 1986-07-22 | 1987-12-22 | Toska Co., Ltd. | Process for preparing conductive coating composition |
| US4880711A (en) | 1987-11-16 | 1989-11-14 | International Fuel Cells Corporation | Ternary fuel cell catalyst containing platinum and gallium |
| FR2628431B1 (fr) | 1988-03-11 | 1992-01-10 | Rhone Poulenc Chimie | Nouveaux polyesters sulfones greffes, leur procede de preparation et leur application a l'encollage des fils et fibres textiles |
| US5137991A (en) * | 1988-05-13 | 1992-08-11 | The Ohio State University Research Foundation | Polyaniline compositions, processes for their preparation and uses thereof |
| US5009854A (en) | 1988-08-31 | 1991-04-23 | Columbian Chemicals Company | Axial reactor with coaxial oil injection |
| US5093439A (en) | 1989-10-19 | 1992-03-03 | Ohio State University Research Foundation | Processes for preparation of sulfonated polyaniline compositions and uses thereof |
| EP0433229B1 (fr) | 1989-12-11 | 1994-01-26 | Ciba-Geigy Ag | Procédé de teinture du cuir |
| JPH03245850A (ja) | 1990-02-23 | 1991-11-01 | Hitachi Ltd | 燃料改質触媒及びそれを用いた燃料電池 |
| US5068161A (en) | 1990-03-30 | 1991-11-26 | Johnson Matthey Public Limited Company | Catalyst material |
| US4970093A (en) | 1990-04-12 | 1990-11-13 | University Of Colorado Foundation | Chemical deposition methods using supercritical fluid solutions |
| EP0466261B1 (fr) | 1990-07-10 | 1995-10-04 | Agfa-Gevaert N.V. | Meilleure stabilisation de dispersions d'oxydes métalliques et/ou de noir de carbone dans l'eau |
| GB9109751D0 (en) | 1991-05-04 | 1991-06-26 | Johnson Matthey Plc | Improved catalyst material |
| US5356538A (en) | 1991-06-12 | 1994-10-18 | Idaho Research Foundation, Inc. | Supercritical fluid extraction |
| EP0536915B1 (fr) | 1991-10-08 | 1999-05-26 | Americhem, Inc. | Procédé pour préparer un polymère intrinsèquement conducteur et articles d'une composition polymère thermoplastique contenant celui-ci |
| JPH05144444A (ja) * | 1991-11-25 | 1993-06-11 | Toshiba Corp | 燃料電池およびそれに用いる電極の製造方法 |
| US5250163A (en) | 1991-11-27 | 1993-10-05 | The Ohio State University Research Foundation | Proton concentration sensor/modulator for sulfonated and hydroxylated polyaniline electrodes |
| US5639441A (en) | 1992-03-06 | 1997-06-17 | Board Of Regents Of University Of Colorado | Methods for fine particle formation |
| US6132645A (en) * | 1992-08-14 | 2000-10-17 | Eeonyx Corporation | Electrically conductive compositions of carbon particles and methods for their production |
| US5498372A (en) * | 1992-08-14 | 1996-03-12 | Hexcel Corporation | Electrically conductive polymeric compositions |
| US5334292A (en) | 1992-08-17 | 1994-08-02 | Board Of Regents, The University Of Texas System | Conducting polymer films containing nanodispersed catalyst particles: a new type of composite material for technological applications |
| US5759944A (en) | 1993-04-20 | 1998-06-02 | Johnson Matthey Public Limited Company | Catalyst material |
| US5589108A (en) | 1993-12-29 | 1996-12-31 | Nitto Chemical Industry Co., Ltd. | Soluble alkoxy-group substituted aminobenzenesulfonic acid aniline conducting polymers |
| JPH0822827A (ja) | 1994-07-07 | 1996-01-23 | Toshiba Corp | 燃料電池用電極とその製造方法 |
| US5595689A (en) | 1994-07-21 | 1997-01-21 | Americhem, Inc. | Highly conductive polymer blends with intrinsically conductive polymers |
| US5548060A (en) | 1994-08-08 | 1996-08-20 | Penn State Research Foundation, Inc. | Sulfonation of polyphosphazenes |
| US5554739A (en) | 1994-12-15 | 1996-09-10 | Cabot Corporation | Process for preparing carbon materials with diazonium salts and resultant carbon products |
| IL116379A (en) | 1994-12-15 | 2003-12-10 | Cabot Corp | Aqueous inks and coatings containing modified carbon products |
| IL116377A (en) | 1994-12-15 | 2003-05-29 | Cabot Corp | Reaction of carbon black with diazonium salts, resultant carbon black products and their uses |
| IL116376A (en) | 1994-12-15 | 2001-03-19 | Cabot Corp | Aqueous ink jet ink compositions containing modified carbon products |
| US5571311A (en) | 1994-12-15 | 1996-11-05 | Cabot Corporation | Ink jet ink formulations containing carbon black products |
| DE19517598C1 (de) | 1995-05-13 | 1997-01-02 | Degussa | Platin-Aluminium-Legierungskatalysator und dessen Verwendung in Brennstoffzellen |
| US5683829A (en) | 1995-05-22 | 1997-11-04 | Sarangapani; Shantha | Redox promoters for methonol fuel cells |
| JP3373712B2 (ja) | 1995-07-14 | 2003-02-04 | 三菱化学株式会社 | カーボンブラック |
| US5606724A (en) | 1995-11-03 | 1997-02-25 | Idaho Research Foundation, Inc. | Extracting metals directly from metal oxides |
| US5707432A (en) | 1996-06-14 | 1998-01-13 | Cabot Corporation | Modified carbon products and inks and coatings containing modified carbon products |
| US5837045A (en) | 1996-06-17 | 1998-11-17 | Cabot Corporation | Colored pigment and aqueous compositions containing same |
| US5928419A (en) | 1996-10-07 | 1999-07-27 | Toyo Ink Manufacturing Co., Ltd. | Surface-treated organic pigment and process for the production thereof |
| US5789027A (en) | 1996-11-12 | 1998-08-04 | University Of Massachusetts | Method of chemically depositing material onto a substrate |
| US5976233A (en) | 1996-11-13 | 1999-11-02 | Canon Kabushiki Kaisha | Water-based pigment ink, and ink-jet recording method and instruments using the same |
| DE69721748T2 (de) | 1996-12-30 | 2004-03-11 | Hydro-Québec, Montréal | Oberflächenmodifizierte kohlenstoffmaterialien |
| JPH10214630A (ja) * | 1997-01-30 | 1998-08-11 | Asahi Glass Co Ltd | 固体高分子型燃料電池 |
| US5939334A (en) | 1997-05-22 | 1999-08-17 | Sharp Laboratories Of America, Inc. | System and method of selectively cleaning copper substrate surfaces, in-situ, to remove copper oxides |
| ES2202591T3 (es) | 1997-08-20 | 2004-04-01 | Idaho Research Foundation, Inc. | Metodo para disociar metales o para disociar compuestos metalicos. |
| JP3245850B2 (ja) | 1997-08-25 | 2002-01-15 | 住友電気工業株式会社 | 光ファイバ心線の被覆除去装置 |
| US5993996A (en) | 1997-09-16 | 1999-11-30 | Inorganic Specialists, Inc. | Carbon supercapacitor electrode materials |
| US5871671A (en) | 1997-10-14 | 1999-02-16 | Monsanto Company | Intrinsically conductive polymer/plasticizer blends with enhanced conductivity |
| JPH11166049A (ja) * | 1997-12-01 | 1999-06-22 | Japan Carlit Co Ltd:The | 導電性複合体の製造方法 |
| US6548202B2 (en) | 1998-03-06 | 2003-04-15 | Ballard Power System, Inc. | Carbon-supported catalysts for fuel cells |
| JP4250249B2 (ja) | 1998-04-01 | 2009-04-08 | キヤノン株式会社 | インクジェット用インク、インクカートリッジ、記録ユニット、インクセット、画像記録方法及び画像記録装置 |
| EP1024524A2 (fr) | 1999-01-27 | 2000-08-02 | Matsushita Electric Industrial Co., Ltd. | Depôt des couches dielectriques utilisant du CO2 supercritique |
| US6117581A (en) | 1999-03-15 | 2000-09-12 | Ford Global Technologies, Inc. | Fuel cell electrode comprising conductive zeolite support material |
| FR2791580B1 (fr) | 1999-04-02 | 2001-05-04 | Centre Nat Rech Scient | Procede pour l'enrobage de particules |
| AU6396900A (en) * | 1999-08-20 | 2001-03-19 | Medis El Ltd. | A new class of electrocatalysts and a gas diffusion electrode based thereon |
| US6478987B1 (en) | 1999-09-20 | 2002-11-12 | Honda Giken Kogyo Kabushiki Kaisha | Proton conducting polymer, method for producing the same, solid polymer electrolyte and electrode |
| JP2001160407A (ja) * | 1999-09-20 | 2001-06-12 | Honda Motor Co Ltd | プロトン伝導性ポリマーおよびその製造方法、高分子固体電解質、ならびに電極 |
| US6399202B1 (en) | 1999-10-12 | 2002-06-04 | Cabot Corporation | Modified carbon products useful in gas diffusion electrodes |
| US6280871B1 (en) | 1999-10-12 | 2001-08-28 | Cabot Corporation | Gas diffusion electrodes containing modified carbon products |
| CA2393812C (fr) | 1999-12-10 | 2011-11-22 | Nitto Denko Corporation | Pile a combustible |
| AU1685801A (en) | 1999-12-17 | 2001-06-25 | Paul Scherrer Institut | Method for cross-linking carbon or carbon material such as industrial carbon black and active carbon, use thereof in the production of electrochemical double layer capacitor electrodes |
| WO2001062862A1 (fr) | 2000-02-23 | 2001-08-30 | Seiko Epson Corporation | Procede servant a preparer une dispersion de pigment, dispersion de pigments obtenue au moyen de ce procede et encre d'imprimante a jet d'encre contenant cette dispersion |
| US7507687B2 (en) | 2000-03-22 | 2009-03-24 | Cabot Corporation | Electrocatalyst powders, methods for producing powder and devices fabricated from same |
| JP2001283865A (ja) | 2000-03-31 | 2001-10-12 | Toray Ind Inc | 電極触媒層、膜−電極複合体およびそれらの製造方法並びにそれらを用いた燃料電池 |
| US6599356B2 (en) | 2000-06-28 | 2003-07-29 | Seiko Epson Corporation | Method for manufacturing pigment dispersed liquid, and pigment dispersed liquid, and ink for ink-jet printer recording using said pigment dispersed liquid |
| JP2002025564A (ja) * | 2000-07-06 | 2002-01-25 | Matsushita Electric Ind Co Ltd | 高分子電解質型燃料電池とその製造方法 |
| ATE495890T1 (de) | 2000-07-06 | 2011-02-15 | Cabot Corp | Druckplatten mit modifizierten pigmentprodukten |
| US6451375B1 (en) | 2001-01-05 | 2002-09-17 | International Business Machines Corporation | Process for depositing a film on a nanometer structure |
| US7541308B2 (en) | 2001-04-11 | 2009-06-02 | Cabot Corporation | Fuel cells and other products containing modified carbon products |
| US20030022055A1 (en) | 2001-04-11 | 2003-01-30 | Jameel Menashi | Fuel cells and other products containing modified carbon products |
| JP2002331739A (ja) | 2001-05-09 | 2002-11-19 | Fuji Xerox Co Ltd | インクジェット記録方法およびインクジェット記録装置 |
| US6863391B2 (en) | 2001-05-10 | 2005-03-08 | Canon Kabushiki Kaisha | Liquid composition, ink set, method of forming a colored section on recording medium and ink-jet recording apparatus |
| JP2003037435A (ja) | 2001-07-25 | 2003-02-07 | Nippon Hoso Kyokai <Nhk> | アンテナ装置及びこれを用いた受信装置 |
| JP3630138B2 (ja) | 2001-12-27 | 2005-03-16 | ブラザー工業株式会社 | キースイッチ装置 |
| CA2486765A1 (fr) * | 2002-05-23 | 2003-12-04 | Columbian Chemicals Company | Materiau conducteur carbone greffe sur un polymere destine a des applications de pile a combustible |
| US7241334B2 (en) | 2002-05-23 | 2007-07-10 | Columbian Chemicals Company | Sulfonated carbonaceous materials |
| US7195834B2 (en) | 2002-05-23 | 2007-03-27 | Columbian Chemicals Company | Metallized conducting polymer-grafted carbon material and method for making |
| US7459103B2 (en) | 2002-05-23 | 2008-12-02 | Columbian Chemicals Company | Conducting polymer-grafted carbon material for fuel cell applications |
| DE60311985T2 (de) | 2002-05-23 | 2007-10-25 | Columbian Chemicals Company | Sulfoniertes leitungs-graftpolymerkohlenstoffmaterial für brennstoffzellenanwendungen |
| US7390441B2 (en) | 2002-05-23 | 2008-06-24 | Columbian Chemicals Company | Sulfonated conducting polymer-grafted carbon material for fuel cell applications |
| EP1536500A4 (fr) | 2002-08-16 | 2010-09-01 | Takeo Yamaguchi | Electrode pour pile a combustible, pile a combustible comprenant l'electrode et procede de production de l'electrode |
| TWI312353B (en) * | 2002-12-26 | 2009-07-21 | Ind Tech Res Inst | Polymer chain grafted carbon nanocapsule |
| US7601425B2 (en) | 2003-03-07 | 2009-10-13 | The Curators Of The University Of Missouri | Corrosion resistant coatings containing carbon |
| WO2004107359A1 (fr) | 2003-05-23 | 2004-12-09 | Columbian Chemicals Company | Materiau carbone conducteur metallise a polymere greffe |
| US20060068987A1 (en) | 2004-09-24 | 2006-03-30 | Srinivas Bollepalli | Carbon supported catalyst having reduced water retention |
-
2003
- 2003-05-23 DE DE60311985T patent/DE60311985T2/de not_active Expired - Fee Related
- 2003-05-23 CA CA002486790A patent/CA2486790A1/fr not_active Abandoned
- 2003-05-23 KR KR10-2004-7018938A patent/KR20050014828A/ko not_active Withdrawn
- 2003-05-23 CN CNB038117746A patent/CN100339913C/zh not_active Expired - Fee Related
- 2003-05-23 AU AU2003233657A patent/AU2003233657A1/en not_active Abandoned
- 2003-05-23 EP EP03729097A patent/EP1509930B1/fr not_active Expired - Lifetime
- 2003-05-23 US US10/445,074 patent/US7413683B2/en not_active Expired - Fee Related
- 2003-05-23 JP JP2004508430A patent/JP2005527687A/ja active Pending
- 2003-05-23 ES ES03729097T patent/ES2282630T3/es not_active Expired - Lifetime
- 2003-05-23 WO PCT/US2003/016320 patent/WO2003100884A2/fr not_active Ceased
- 2003-05-23 BR BRPI0311226-8A patent/BR0311226A/pt not_active Application Discontinuation
- 2003-05-23 AT AT03729097T patent/ATE354856T1/de not_active IP Right Cessation
- 2003-05-23 EA EA200401549A patent/EA011179B1/ru not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN100339913C (zh) | 2007-09-26 |
| ATE354856T1 (de) | 2007-03-15 |
| US7413683B2 (en) | 2008-08-19 |
| US20040110051A1 (en) | 2004-06-10 |
| EP1509930B1 (fr) | 2007-02-21 |
| EP1509930A2 (fr) | 2005-03-02 |
| WO2003100884A2 (fr) | 2003-12-04 |
| DE60311985T2 (de) | 2007-10-25 |
| EA200401549A1 (ru) | 2005-10-27 |
| JP2005527687A (ja) | 2005-09-15 |
| DE60311985D1 (de) | 2007-04-05 |
| EP1509930A4 (fr) | 2005-09-28 |
| EA011179B1 (ru) | 2009-02-27 |
| CA2486790A1 (fr) | 2003-12-04 |
| KR20050014828A (ko) | 2005-02-07 |
| CN1656572A (zh) | 2005-08-17 |
| WO2003100884A3 (fr) | 2004-05-06 |
| BR0311226A (pt) | 2008-01-29 |
| AU2003233657A1 (en) | 2003-12-12 |
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