ES2120119T3 - Polimeros hidrosolubles de (met)acrilamida, acido carboxilico alifatico etilenicamente insaturado o una sal del mismo y monomero de polivinilo, y su uso como aditivos de resistencia en seco para papel. - Google Patents
Polimeros hidrosolubles de (met)acrilamida, acido carboxilico alifatico etilenicamente insaturado o una sal del mismo y monomero de polivinilo, y su uso como aditivos de resistencia en seco para papel.Info
- Publication number
- ES2120119T3 ES2120119T3 ES95118396T ES95118396T ES2120119T3 ES 2120119 T3 ES2120119 T3 ES 2120119T3 ES 95118396 T ES95118396 T ES 95118396T ES 95118396 T ES95118396 T ES 95118396T ES 2120119 T3 ES2120119 T3 ES 2120119T3
- Authority
- ES
- Spain
- Prior art keywords
- water
- acrylamide
- met
- paper
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000178 monomer Substances 0.000 title abstract 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 title abstract 2
- 239000000654 additive Substances 0.000 title abstract 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 title abstract 2
- 150000003839 salts Chemical class 0.000 title 1
- 229920002554 vinyl polymer Polymers 0.000 title 1
- 229920003169 water-soluble polymer Polymers 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 2
- 229920001897 terpolymer Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000012966 redox initiator Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polymerization Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
UN TERPOLIMERO SOLUBLE EN AGUA CONSISTE ESENCIALMENTE DEL PRODUCTO DE POLIMERIZACION DE LOS SIGUIENTES MONOMEROS: (A) (MET)ACRILAMIDA, (B) UN ACIDO CARBOXILICO ALIFATICO ETILENICAMENTE NO SATURADO O UNA SAL DEL MISMO, Y (C) UN MONOMERO DE POLIVINILO, SOLUBLE EN AGUA, EN DONDE (C) COMPRENDE <0,07% MOLAR BASADO EN LOS MONOMEROS TOTALES; UNA SOLUCION DEL 1% DEL TERPOLIMERO ES CAPAZ DE PASAR A TRAVES DE UNA CRIBA DE MALLA 200 SUSTANCIALMENTE SIN RETENCION DE SOLIDOS DE POLIMERO, Y EL TERPOLIMERO TIENE UNA VISCOSIDAD ESPECIFICA REDUCIDA DE UNOS 3,0 DECILITROS/G O MENOS. EL PROCESO PARA PREPARAR EL POLIMERO INCLUYE EL PASO DE AÑADIR CONTINUAMENTE AMBOS COMPONENTES DE UN INICIADOR DE REDOX. EL TERPOLIMERO ES UTIL COMO UN ADITIVO DE RESISTENCIA A LA SEQUEDAD PARA PAPEL.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/344,831 US5543446A (en) | 1994-11-23 | 1994-11-23 | Water-soluble acrylamide/acrylic acid polymers and their use as dry strength additives for paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2120119T3 true ES2120119T3 (es) | 1998-10-16 |
Family
ID=23352246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES95118396T Expired - Lifetime ES2120119T3 (es) | 1994-11-23 | 1995-11-22 | Polimeros hidrosolubles de (met)acrilamida, acido carboxilico alifatico etilenicamente insaturado o una sal del mismo y monomero de polivinilo, y su uso como aditivos de resistencia en seco para papel. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US5543446A (es) |
| EP (1) | EP0713890B1 (es) |
| JP (1) | JP3841861B2 (es) |
| KR (1) | KR100400146B1 (es) |
| CN (1) | CN1085982C (es) |
| AT (1) | ATE168386T1 (es) |
| AU (1) | AU696666B2 (es) |
| BR (1) | BR9505503A (es) |
| CA (1) | CA2163477C (es) |
| DE (1) | DE69503459T2 (es) |
| ES (1) | ES2120119T3 (es) |
| FI (1) | FI116527B (es) |
| NO (1) | NO954719L (es) |
| TW (1) | TW370533B (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9426025D0 (en) * | 1994-12-22 | 1995-02-22 | Smith Philip L U | Oil and gas field chemicals |
| US7317053B1 (en) | 2000-07-10 | 2008-01-08 | Hercules Incorporated | Compositions for imparting desired properties to materials |
| ZA200105884B (en) * | 2000-08-04 | 2002-05-13 | Armstrong World Ind Inc | Fibrous sheet enhancement. |
| US6723204B2 (en) * | 2002-04-08 | 2004-04-20 | Hercules Incorporated | Process for increasing the dry strength of paper |
| US6939443B2 (en) * | 2002-06-19 | 2005-09-06 | Lanxess Corporation | Anionic functional promoter and charge control agent |
| JP5072514B2 (ja) * | 2007-09-26 | 2012-11-14 | ダイヤニトリックス株式会社 | 水溶性重合体の製造方法 |
| CA2743510A1 (en) * | 2008-11-21 | 2010-05-27 | Buckman Laboratories International, Inc. | Method for controlling enzymatic decomposition of peroxide and products thereof |
| WO2011057044A2 (en) | 2009-11-06 | 2011-05-12 | Hercules Incorporated | Surface application of polymers and polymer mixtures to improve paper strength |
| US9458273B2 (en) | 2012-04-04 | 2016-10-04 | Rhodia Operations | Method for synthesizing polymers from acrylic acid, one of the salts of same or the mixture thereof |
| CN109181671B (zh) | 2013-01-31 | 2020-08-25 | 艺康美国股份有限公司 | 用于提高油采收的流动性控制聚合物 |
| US10442980B2 (en) | 2014-07-29 | 2019-10-15 | Ecolab Usa Inc. | Polymer emulsions for use in crude oil recovery |
| CN104389237B (zh) * | 2014-09-24 | 2016-08-17 | 浙江九本环保技术有限公司 | 一种造纸涂布用生物质胶黏剂及其制备方法和应用 |
| TW201739983A (zh) | 2016-01-14 | 2017-11-16 | 亞齊羅馬Ip公司 | 丙烯酸酯共聚物之用途、使用其之具有纖維素纖維之基材之製造方法及其基板 |
| MX2021005066A (es) | 2018-11-02 | 2021-06-15 | Buckman Laboratories Int Inc | Sintesis de polimero repulpable con resistencia a la humedad temporal para aplicacion tisular. |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA547577A (en) * | 1957-10-15 | L. Azorlosa Julian | Preparation of paper product | |
| CA477265A (en) * | 1951-09-25 | Hercules Powder Company | Preparation of paper products | |
| US2661309A (en) * | 1948-11-18 | 1953-12-01 | Hercules Powder Co Ltd | Coated paper and method of producing same |
| US3061595A (en) * | 1959-11-24 | 1962-10-30 | American Cyanamid Co | Polymerization promoter system for water-soluble polymers |
| US3247171A (en) * | 1963-04-08 | 1966-04-19 | Dow Chemical Co | Process for hydrolyzing a cross-linked acrylamide polymer and the product thereby |
| US3332922A (en) * | 1963-05-13 | 1967-07-25 | Calgon Corp | Acrylamide polymers prepared in the presence of a redox catalyst system wherein a constant free-radical concentration is maintained |
| US4059552A (en) * | 1974-06-21 | 1977-11-22 | The Dow Chemical Company | Cross-linked water-swellable polymer particles |
| US4525527A (en) * | 1982-01-25 | 1985-06-25 | American Colloid Company | Production process for highly water absorbable polymer |
| JPS6350597A (ja) * | 1986-08-12 | 1988-03-03 | 住友化学工業株式会社 | 紙力増強剤 |
| JPH028207A (ja) * | 1988-06-27 | 1990-01-11 | Harima Chem Inc | ポリマー水溶液 |
| JPH02139494A (ja) * | 1988-11-17 | 1990-05-29 | Harima Chem Inc | 製紙用添加剤 |
| JP2905248B2 (ja) * | 1990-03-28 | 1999-06-14 | 荒川化学工業株式会社 | 表面紙力剤 |
| JP3089661B2 (ja) * | 1990-11-09 | 2000-09-18 | 三井サイテック株式会社 | 紙の製造法 |
| JP3100443B2 (ja) * | 1991-12-19 | 2000-10-16 | 三井化学株式会社 | 紙の表面強度改良剤 |
-
1994
- 1994-11-23 US US08/344,831 patent/US5543446A/en not_active Expired - Lifetime
-
1995
- 1995-11-20 FI FI955580A patent/FI116527B/fi not_active IP Right Cessation
- 1995-11-21 KR KR1019950042465A patent/KR100400146B1/ko not_active Expired - Fee Related
- 1995-11-22 ES ES95118396T patent/ES2120119T3/es not_active Expired - Lifetime
- 1995-11-22 AU AU39014/95A patent/AU696666B2/en not_active Ceased
- 1995-11-22 AT AT95118396T patent/ATE168386T1/de not_active IP Right Cessation
- 1995-11-22 CA CA002163477A patent/CA2163477C/en not_active Expired - Fee Related
- 1995-11-22 DE DE69503459T patent/DE69503459T2/de not_active Expired - Lifetime
- 1995-11-22 EP EP95118396A patent/EP0713890B1/en not_active Expired - Lifetime
- 1995-11-22 NO NO954719A patent/NO954719L/no unknown
- 1995-11-23 CN CN95121849A patent/CN1085982C/zh not_active Expired - Fee Related
- 1995-11-23 BR BR9505503A patent/BR9505503A/pt not_active Application Discontinuation
- 1995-11-24 JP JP30607395A patent/JP3841861B2/ja not_active Expired - Fee Related
-
1996
- 1996-01-06 TW TW085100121A patent/TW370533B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| FI955580L (fi) | 1996-05-24 |
| TW370533B (en) | 1999-09-21 |
| KR960017706A (ko) | 1996-06-17 |
| US5543446A (en) | 1996-08-06 |
| CA2163477A1 (en) | 1996-05-24 |
| JP3841861B2 (ja) | 2006-11-08 |
| ATE168386T1 (de) | 1998-08-15 |
| AU3901495A (en) | 1996-05-30 |
| AU696666B2 (en) | 1998-09-17 |
| NO954719L (no) | 1996-05-24 |
| JPH08208762A (ja) | 1996-08-13 |
| FI116527B (fi) | 2005-12-15 |
| CA2163477C (en) | 2000-01-11 |
| EP0713890A3 (en) | 1996-07-17 |
| EP0713890B1 (en) | 1998-07-15 |
| DE69503459T2 (de) | 1998-11-26 |
| NO954719D0 (no) | 1995-11-22 |
| DE69503459D1 (de) | 1998-08-20 |
| CN1085982C (zh) | 2002-06-05 |
| FI955580A0 (fi) | 1995-11-20 |
| CN1139121A (zh) | 1997-01-01 |
| KR100400146B1 (ko) | 2003-12-11 |
| EP0713890A2 (en) | 1996-05-29 |
| BR9505503A (pt) | 1997-10-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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