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ES2120119T3 - WATER-SOLUBLE POLYMERS OF (MET) ACRYLAMIDE, ETHYLENEICALLY UNSATURATED ALIPHATIC CARBOXYLIC ACID OR A SALT OF THE SAME AND POLYVINYL MONOMER, AND ITS USE AS DRY RESISTANCE ADDITIVES FOR PAPER. - Google Patents

WATER-SOLUBLE POLYMERS OF (MET) ACRYLAMIDE, ETHYLENEICALLY UNSATURATED ALIPHATIC CARBOXYLIC ACID OR A SALT OF THE SAME AND POLYVINYL MONOMER, AND ITS USE AS DRY RESISTANCE ADDITIVES FOR PAPER.

Info

Publication number
ES2120119T3
ES2120119T3 ES95118396T ES95118396T ES2120119T3 ES 2120119 T3 ES2120119 T3 ES 2120119T3 ES 95118396 T ES95118396 T ES 95118396T ES 95118396 T ES95118396 T ES 95118396T ES 2120119 T3 ES2120119 T3 ES 2120119T3
Authority
ES
Spain
Prior art keywords
water
acrylamide
met
paper
carboxylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95118396T
Other languages
Spanish (es)
Inventor
William Rodriguez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hercules LLC
Original Assignee
Hercules LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hercules LLC filed Critical Hercules LLC
Application granted granted Critical
Publication of ES2120119T3 publication Critical patent/ES2120119T3/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Paper (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

UN TERPOLIMERO SOLUBLE EN AGUA CONSISTE ESENCIALMENTE DEL PRODUCTO DE POLIMERIZACION DE LOS SIGUIENTES MONOMEROS: (A) (MET)ACRILAMIDA, (B) UN ACIDO CARBOXILICO ALIFATICO ETILENICAMENTE NO SATURADO O UNA SAL DEL MISMO, Y (C) UN MONOMERO DE POLIVINILO, SOLUBLE EN AGUA, EN DONDE (C) COMPRENDE <0,07% MOLAR BASADO EN LOS MONOMEROS TOTALES; UNA SOLUCION DEL 1% DEL TERPOLIMERO ES CAPAZ DE PASAR A TRAVES DE UNA CRIBA DE MALLA 200 SUSTANCIALMENTE SIN RETENCION DE SOLIDOS DE POLIMERO, Y EL TERPOLIMERO TIENE UNA VISCOSIDAD ESPECIFICA REDUCIDA DE UNOS 3,0 DECILITROS/G O MENOS. EL PROCESO PARA PREPARAR EL POLIMERO INCLUYE EL PASO DE AÑADIR CONTINUAMENTE AMBOS COMPONENTES DE UN INICIADOR DE REDOX. EL TERPOLIMERO ES UTIL COMO UN ADITIVO DE RESISTENCIA A LA SEQUEDAD PARA PAPEL.A WATER-SOLUBLE THERPOLYMER CONSISTS ESSENTIALLY OF THE POLYMERIZATION PRODUCT OF THE FOLLOWING MONOMERS: (A) (MET) ACRYLAMIDE, ETHYLENICALLY UNSATURATED ALIPHATIC CARBOXYLIC ACID, AND (C) A MONOMERO IN WATER, WHERE (C) INCLUDES <0.07% MOLAR BASED ON TOTAL MONOMERS; A 1% TERPOLYMER SOLUTION IS ABLE TO PASS THROUGH A 200 MESH SCREEN WITHOUT RETENTION OF POLYMER SOLIDS, AND THE TERPOLYMER HAS A SPECIFIC REDUCED VISCOSITY OF ABOUT 3.0 DECILITERS / G OR LESS. THE PROCESS TO PREPARE THE POLYMER INCLUDES THE STEP OF CONTINUOUSLY ADDING BOTH COMPONENTS OF A REDOX INITIATOR. THERPOLYMER IS USEFUL AS A DRY RESISTANCE ADDITIVE FOR PAPER.

ES95118396T 1994-11-23 1995-11-22 WATER-SOLUBLE POLYMERS OF (MET) ACRYLAMIDE, ETHYLENEICALLY UNSATURATED ALIPHATIC CARBOXYLIC ACID OR A SALT OF THE SAME AND POLYVINYL MONOMER, AND ITS USE AS DRY RESISTANCE ADDITIVES FOR PAPER. Expired - Lifetime ES2120119T3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/344,831 US5543446A (en) 1994-11-23 1994-11-23 Water-soluble acrylamide/acrylic acid polymers and their use as dry strength additives for paper

Publications (1)

Publication Number Publication Date
ES2120119T3 true ES2120119T3 (en) 1998-10-16

Family

ID=23352246

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95118396T Expired - Lifetime ES2120119T3 (en) 1994-11-23 1995-11-22 WATER-SOLUBLE POLYMERS OF (MET) ACRYLAMIDE, ETHYLENEICALLY UNSATURATED ALIPHATIC CARBOXYLIC ACID OR A SALT OF THE SAME AND POLYVINYL MONOMER, AND ITS USE AS DRY RESISTANCE ADDITIVES FOR PAPER.

Country Status (14)

Country Link
US (1) US5543446A (en)
EP (1) EP0713890B1 (en)
JP (1) JP3841861B2 (en)
KR (1) KR100400146B1 (en)
CN (1) CN1085982C (en)
AT (1) ATE168386T1 (en)
AU (1) AU696666B2 (en)
BR (1) BR9505503A (en)
CA (1) CA2163477C (en)
DE (1) DE69503459T2 (en)
ES (1) ES2120119T3 (en)
FI (1) FI116527B (en)
NO (1) NO954719L (en)
TW (1) TW370533B (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9426025D0 (en) * 1994-12-22 1995-02-22 Smith Philip L U Oil and gas field chemicals
US7317053B1 (en) 2000-07-10 2008-01-08 Hercules Incorporated Compositions for imparting desired properties to materials
ZA200105884B (en) * 2000-08-04 2002-05-13 Armstrong World Ind Inc Fibrous sheet enhancement.
US6723204B2 (en) * 2002-04-08 2004-04-20 Hercules Incorporated Process for increasing the dry strength of paper
US6939443B2 (en) * 2002-06-19 2005-09-06 Lanxess Corporation Anionic functional promoter and charge control agent
JP5072514B2 (en) * 2007-09-26 2012-11-14 ダイヤニトリックス株式会社 Method for producing water-soluble polymer
EP2358938A1 (en) * 2008-11-21 2011-08-24 Buckman Laboratories International, Inc Method for controlling enzymatic decomposition of peroxide and products thereof
WO2011057044A2 (en) 2009-11-06 2011-05-12 Hercules Incorporated Surface application of polymers and polymer mixtures to improve paper strength
US9458273B2 (en) 2012-04-04 2016-10-04 Rhodia Operations Method for synthesizing polymers from acrylic acid, one of the salts of same or the mixture thereof
WO2014120437A1 (en) 2013-01-31 2014-08-07 Ecolab Usa Inc. Mobility control polymers for enhanced oil recovery
US10442980B2 (en) 2014-07-29 2019-10-15 Ecolab Usa Inc. Polymer emulsions for use in crude oil recovery
CN104389237B (en) * 2014-09-24 2016-08-17 浙江九本环保技术有限公司 A kind of papermaking coating biomass adhesive and its preparation method and application
TW201739983A (en) 2016-01-14 2017-11-16 亞齊羅馬Ｉｐ公司 Use of an acrylate copolymer, a method of making a substrate comprising cellulosic fibres by using the same, and the corresponding substrate
EP3873735A1 (en) 2018-11-02 2021-09-08 Buckman Laboratories International, Inc. Synthesis of re-pulpable temporary wet strength polymer for tissue application

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA547577A (en) * 1957-10-15 L. Azorlosa Julian Preparation of paper product
CA477265A (en) * 1951-09-25 Hercules Powder Company Preparation of paper products
US2661309A (en) * 1948-11-18 1953-12-01 Hercules Powder Co Ltd Coated paper and method of producing same
US3061595A (en) * 1959-11-24 1962-10-30 American Cyanamid Co Polymerization promoter system for water-soluble polymers
US3247171A (en) * 1963-04-08 1966-04-19 Dow Chemical Co Process for hydrolyzing a cross-linked acrylamide polymer and the product thereby
US3332922A (en) * 1963-05-13 1967-07-25 Calgon Corp Acrylamide polymers prepared in the presence of a redox catalyst system wherein a constant free-radical concentration is maintained
US4059552A (en) * 1974-06-21 1977-11-22 The Dow Chemical Company Cross-linked water-swellable polymer particles
US4525527A (en) * 1982-01-25 1985-06-25 American Colloid Company Production process for highly water absorbable polymer
JPS6350597A (en) * 1986-08-12 1988-03-03 住友化学工業株式会社 Paper strength enhancer
JPH028207A (en) * 1988-06-27 1990-01-11 Harima Chem Inc Aqueous solution of polymer
JPH02139494A (en) * 1988-11-17 1990-05-29 Harima Chem Inc additives for paper making
JP2905248B2 (en) * 1990-03-28 1999-06-14 荒川化学工業株式会社 Surface paper strength agent
JP3089661B2 (en) * 1990-11-09 2000-09-18 三井サイテック株式会社 Paper manufacturing method
JP3100443B2 (en) * 1991-12-19 2000-10-16 三井化学株式会社 Paper surface strength improver

Also Published As

Publication number Publication date
NO954719L (en) 1996-05-24
AU3901495A (en) 1996-05-30
ATE168386T1 (en) 1998-08-15
BR9505503A (en) 1997-10-28
EP0713890A3 (en) 1996-07-17
FI955580L (en) 1996-05-24
CA2163477A1 (en) 1996-05-24
DE69503459D1 (en) 1998-08-20
JPH08208762A (en) 1996-08-13
AU696666B2 (en) 1998-09-17
FI116527B (en) 2005-12-15
EP0713890A2 (en) 1996-05-29
KR100400146B1 (en) 2003-12-11
JP3841861B2 (en) 2006-11-08
CN1139121A (en) 1997-01-01
TW370533B (en) 1999-09-21
US5543446A (en) 1996-08-06
DE69503459T2 (en) 1998-11-26
CA2163477C (en) 2000-01-11
NO954719D0 (en) 1995-11-22
CN1085982C (en) 2002-06-05
FI955580A0 (en) 1995-11-20
EP0713890B1 (en) 1998-07-15
KR960017706A (en) 1996-06-17

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