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ES2119767T3 - Procedimiento catalitico para la alquilacion selectiva de compuestos aromaticos policiclicos. - Google Patents

Procedimiento catalitico para la alquilacion selectiva de compuestos aromaticos policiclicos.

Info

Publication number
ES2119767T3
ES2119767T3 ES91870128T ES91870128T ES2119767T3 ES 2119767 T3 ES2119767 T3 ES 2119767T3 ES 91870128 T ES91870128 T ES 91870128T ES 91870128 T ES91870128 T ES 91870128T ES 2119767 T3 ES2119767 T3 ES 2119767T3
Authority
ES
Spain
Prior art keywords
polycyclic aromatic
compounds
catalyst
selective
polyclic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91870128T
Other languages
English (en)
Inventor
Patrick Pierre Bernard Notte
Georges Marie Joseph Poncelet
Marc Joseph Henri Remy
Pierre Fernand Miche Lardinois
Hoecke Marina Jeanne Madel Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solutia Europe BVBA SPRL
Original Assignee
Solutia Europe BVBA SPRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Solutia Europe BVBA SPRL filed Critical Solutia Europe BVBA SPRL
Application granted granted Critical
Publication of ES2119767T3 publication Critical patent/ES2119767T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/30—Preparation of ethers by reactions not forming ether-oxygen bonds by increasing the number of carbon atoms, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/02—Addition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/861—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only halogen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCESO CATALITICO PARA LA ALQUILACION SELECTIVA DE UN COMPUESTO AROMATICO POLICICLICO QUE COMPRENDE LA REACCION DEL COMPUESTO AROMATICO POLICICLICO CON UN AGENTE ALQUILANTE EN PRESENCIA DE UN CATALIZADOR PARA PRODUCIR, DE ESTE MODO, EL COMPUESTO DESEADO AROMATICO POLICICLICO SUBSTITUIDO DE ALQUILO CON UNA SELECTIVIDAD Y UN RENDIMIENTO MEJORADOS. EL PROCESO ESTA PARTICULARMENTE INDICADO PARA LA DIALQUILACION SELECTIVA DE COMPUESTOS AROMATICOS POLICICLICOS EN LAS POSICIONES PARAONICA DE UNA MORDENITA CON UNA RELACION SI/AL ATOMICA DE, AL MENOS, 5:1, QUE COMPRENDE CLASES DE METALES ADICIONALES EN UN ALUMINIO(DE LA CLASE METAL) METALICO CON UNA RELACION MOLAR DE, AL MENOS, 0,10 Y QUE TIENE UNA SORCION DE BIFENILO DE, AL MENOS, 0,05 GR. DE BIFENILO POR GR. DE CATALIZADOR.
ES91870128T 1991-08-21 1991-08-21 Procedimiento catalitico para la alquilacion selectiva de compuestos aromaticos policiclicos. Expired - Lifetime ES2119767T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP91870128A EP0528096B1 (en) 1991-08-21 1991-08-21 Catalytic process for the selective alkylation of polycyclic aromatic compounds

Publications (1)

Publication Number Publication Date
ES2119767T3 true ES2119767T3 (es) 1998-10-16

Family

ID=8209028

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91870128T Expired - Lifetime ES2119767T3 (es) 1991-08-21 1991-08-21 Procedimiento catalitico para la alquilacion selectiva de compuestos aromaticos policiclicos.

Country Status (14)

Country Link
US (1) US5900519A (es)
EP (1) EP0528096B1 (es)
JP (1) JP3192233B2 (es)
KR (1) KR960010786B1 (es)
AT (1) ATE166638T1 (es)
AU (1) AU649348B2 (es)
BR (1) BR9203253A (es)
CA (1) CA2076503A1 (es)
CZ (1) CZ256092A3 (es)
DE (1) DE69129496T2 (es)
ES (1) ES2119767T3 (es)
HU (1) HU213181B (es)
MX (1) MX9204837A (es)
TW (1) TW294614B (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ258324A (en) * 1992-11-06 1996-08-27 Mobil Oil Corp Method for reducing the mutagenicity of coal tar containing polynuclear aromatic material by contacting it with an alkylating agent and an acid catalyst
JP3758411B2 (ja) * 1999-04-08 2006-03-22 トヨタ自動車株式会社 排ガス浄化用触媒
CN1947416A (zh) * 2004-04-21 2007-04-11 松下电器产业株式会社 数字广播接收设备、方法及其程序
GB0504079D0 (en) * 2005-02-28 2005-04-06 Davy Process Techn Ltd Process
EP2174713A1 (en) * 2008-10-13 2010-04-14 BP Chemicals Limited Dealumination process
WO2011025802A1 (en) * 2009-08-28 2011-03-03 Exxonmobil Research And Engineering Company Reduction of hindered dibenzothiophenes in fcc distillate via transalkylation of recycled naphthalenes
WO2011025803A1 (en) * 2009-08-28 2011-03-03 Exxonmobil Research And Engineering Company Reduction of hindered dibenzothiophenes in fcc products via transalkylaton of recycled long-chain alkylated dibenzothiophenes
CN102909051B (zh) * 2011-08-01 2014-12-31 中国石油化工股份有限公司 含改性丝光沸石的催化剂及其制备方法和应用
CN102909052B (zh) * 2011-08-01 2014-12-10 中国石油化工股份有限公司 含丝光沸石的催化剂及其制备方法和应用
US9238599B2 (en) 2011-12-07 2016-01-19 Exxonmobil Chemical Patents Inc. Alkylaromatic process
CA3054691A1 (en) * 2017-03-10 2018-09-13 Heritage Research Group Safe aromatics
RU2668218C1 (ru) * 2018-06-06 2018-09-27 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" Катализатор и способ алкилирования бифенила олефинами C2-C6
CN114805000B (zh) * 2022-05-23 2023-09-26 煤炭科学技术研究院有限公司 一种萘烷基化制备2-甲基萘的方法
CN115672383B (zh) * 2022-09-08 2024-01-26 宜昌苏鹏科技有限公司 一种具有高选择性合成三甲胺催化剂的制备方法及产品

Family Cites Families (24)

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US3699048A (en) * 1969-07-24 1972-10-17 Benckiser Gmbh Joh A Process of preventing scale and deposit formation in aqueous systems and product
US4204953A (en) * 1974-04-30 1980-05-27 Ciba-Geigy Limited Process for alkaline scaling
FR2519335B1 (fr) * 1982-01-04 1986-05-02 Azote & Prod Chim Production d'hydrocarbures a partir de methanol en presence de catalyseurs du type zeolithe
FR2561946B1 (fr) * 1984-03-30 1986-10-03 Pro Catalyse Nouveau catalyseur d'hydrocraquage destine a la production de distillats moyens
FR2593084B1 (fr) * 1986-01-22 1990-09-28 Inst Francais Du Petrole Catalyseur contenant une mordenite, sa preparation et son application a l'isomerisation de coupes riches en paraffines normales.
JPH06104630B2 (ja) * 1986-11-11 1994-12-21 三井石油化学工業株式会社 アルキル基置換芳香族炭化水素の製造方法
JPS63122645A (ja) * 1986-11-11 1988-05-26 Kureha Chem Ind Co Ltd ビフエニル−４，４’−ジカルボン酸の製造方法
DE3703291A1 (de) * 1987-02-04 1988-08-18 Ruetgerswerke Ag Verfahren zur herstellung von 2,6-dialkylnaphthalin
JPH0764760B2 (ja) * 1987-03-13 1995-07-12 呉羽化学工業株式会社 ビフェニルのパラ選択的アルキル化方法
US4950832A (en) * 1987-07-29 1990-08-21 Nikki Chemical Co., Ltd. Method for preparation of dialkylnaphthalenes and catalyst for the same
US4891448A (en) * 1987-11-23 1990-01-02 The Dow Chemical Company Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers
US5175135A (en) * 1987-11-23 1992-12-29 The Dow Chemical Company Alkylation of aromatic compounds to alkylates enriched in the linear substituted isomers
US5004841A (en) * 1987-11-23 1991-04-02 The Dow Chemical Company Alkylation of aromatic compounds to alkylates enriched in the linear-substituted isomers
US4950817A (en) * 1988-03-19 1990-08-21 Bayer Aktiengesellschaft Process for the preparation of 4,4'-dihalobiphenyls
US5026942A (en) * 1988-10-05 1991-06-25 Catalytica, Inc. Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts
US5003120A (en) * 1988-10-05 1991-03-26 Catalytica, Inc. Process for selective manufacture of 2,6-diisopropylnaphthalenes with equilibration reactor
US5003122A (en) * 1988-10-05 1991-03-26 Catalytica, Inc. Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts
FR2638157B1 (fr) * 1988-10-26 1991-04-19 Inst Francais Du Petrole Procede de production d'alkylbenzenes utilisant un catalyseur a base de mordenite modifiee
US5026940A (en) * 1989-09-08 1991-06-25 Catalytica, Inc. Manufacture of 4,4'-diisopropylbiphenyl
WO1991008181A1 (fr) * 1989-12-05 1991-06-13 Osaka Gas Company Limited Procede de production de 4,4'-diisopropylbiphenyle
JPH06239771A (ja) * 1989-12-22 1994-08-30 Dow Chem Co:The ベンゼンもしくは置換ベンゼンのアルキル化またはアルキル化ベンゼンのトランスアルキル化の方法および触媒組成物
JP2868279B2 (ja) * 1990-04-23 1999-03-10 工業技術院長 アルキルビフェニル類の製造方法
US5320779A (en) * 1991-06-06 1994-06-14 Nalco Chemical Company Use of molybdate as corrosion inhibitor in a zinc/phosphonate cooling water treatment
JPH09108181A (ja) * 1995-10-16 1997-04-28 Olympus Optical Co Ltd 電子内視鏡装置

Also Published As

Publication number Publication date
DE69129496T2 (de) 1998-11-19
EP0528096A1 (en) 1993-02-24
TW294614B (es) 1997-01-01
JP3192233B2 (ja) 2001-07-23
KR960010786B1 (ko) 1996-08-08
DE69129496D1 (de) 1998-07-02
CZ256092A3 (en) 1993-03-17
KR930004232A (ko) 1993-03-22
AU649348B2 (en) 1994-05-19
HUT62544A (en) 1993-05-28
ATE166638T1 (de) 1998-06-15
CA2076503A1 (en) 1993-02-22
MX9204837A (es) 1993-03-01
EP0528096B1 (en) 1998-05-27
AU2115392A (en) 1993-02-25
JPH05271106A (ja) 1993-10-19
HU213181B (en) 1997-03-28
US5900519A (en) 1999-05-04
BR9203253A (pt) 1993-04-06

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