ES2106437T3 - Dispersion de ligante acuoso para revestimientos de secado fisico y su utilizacion. - Google Patents
Dispersion de ligante acuoso para revestimientos de secado fisico y su utilizacion.Info
- Publication number
- ES2106437T3 ES2106437T3 ES94120194T ES94120194T ES2106437T3 ES 2106437 T3 ES2106437 T3 ES 2106437T3 ES 94120194 T ES94120194 T ES 94120194T ES 94120194 T ES94120194 T ES 94120194T ES 2106437 T3 ES2106437 T3 ES 2106437T3
- Authority
- ES
- Spain
- Prior art keywords
- groups
- isocyanate
- molecular weight
- weight
- dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000006185 dispersion Substances 0.000 title abstract 5
- 238000001035 drying Methods 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 229920002635 polyurethane Polymers 0.000 abstract 2
- 239000004814 polyurethane Substances 0.000 abstract 2
- 229920005749 polyurethane resin Polymers 0.000 abstract 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 125000005587 carbonate group Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000003010 ionic group Chemical group 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical group OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/53—Base coat plus clear coat type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
- C08F290/14—Polymers provided for in subclass C08G
- C08F290/147—Polyurethanes; Polyureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/675—Low-molecular-weight compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
DISPERSION DE AGLOMERANTE ACUOSA, LOS MEDIOS DE RECUBRIMIENTO QUE LA CONTIENEN Y SU UTILIZACION, EN PARTICULAR PARA LACADO ESTRATIFICADO. LA DISPERSION CONTIENE: A) 45 HASTA 95 % EN PESO DE POLIURETANO, OBTENIBLE MEDIANTE POLIMERIZACION INICIADA RADICALMENTE DE MACROMONOMEROS DE POLIURETANO CON UN CONTENIDO EN GRUPOS CARBOXIL, GRUPOS FOSFONICOS Y/O GRUPOS SULFONICOS Y GRUPOS VINILO EN PRESENCIA DE UNO O MULTIPLES MONOMEROS NO SATURADOS COPOLIMERIZABLES, EN FORMA DE UNA DISPERSION ACUOSA Y B) 5 HASTA 55 % EN PESO DE RESINA DE POLIURETANO CONTENIENDO GRUPOS IONICOS LIBRES DE GRUPOS DE UREA Y DE GRUPOS CARBONATO CON UNA MEDIA NUMERICA DE LA MASA MOLAR (MN) DESDE 10.000 HASTA 300.000 Y UN INDICE DE ACIDEZ DESDE 5 HASTA 50 EN FORMA DE UNA DISPERSION ACUOSA OBTENIBLE MEDIANTE TRATAMIENTO DE UN PREPOLIMERO DE POLIURETANO QUE CONTIENE GRUPOS OH, CON UN INDICE OH DESDE 5 HASTA 75 Y UNA MEDIA NUMERICA DE LA MASA MOLAR (MN) DESDE 5.000 HASTA 50.000, MEDIANTE TRANSFORMACION EN MEDIO ORGANICO A) CON COMPUESTOS REACTIVOS ISOCIANATO CON UN INDICE DE ACIDEZ DESDE 0 HASTA 10, EN FORMA DE A1) 70 HASTA 100 % EN PESO DE POLIOLES, CON UN PESO MOLECULAR DESDE 500 HASTA 6.000, CONJUNTAMENTE CON A2) 30 HASTA 0 % EN PESO DE UNO O MULTIPLES COMPUESTOS DIFERENTES DE A1) CON AL MENOS DOS GRUPOS REACTIVOS CON ISOCIANATO, CON UN PESO MOLECULAR DESDE 60 HASTA 400, CON B) PRODUCTOS DE REACCION QUE CONTIENEN GRUPOS ISOCIANATO A PARTIR DE B1) COMPUESTOS CON DOS GRUPOS REACTIVOS CON ISOCIANATOS Y AL MENOS UN GRUPO ANIONICO O CON CAPACIDAD DE FORMACION DE ANIONES Y B2) DIISOCIANATOS ORGANICOS EN UNA RELACION EN CANTIDAD DE TAL MODO, QUE LA RELACION MOLAR DE LOS GRUPOS REACTIVOS CON ISOCIANATO DE B1) CON RESPECTO A LOS GRUPOS ISOCIANATO DE B2) SE ENCUENTRA DESDE 1 : 1,5 HASTA 1 : 2,5, ASI COMO C) POLISOCIANATOS CON AL MENOS DOS GRUPOS ISOCIANATO LIBRES POR MOLECULA, EN UNA CANTIDAD DE TAL MODO, QUE LA RELACION MOLAR DE LOS GRUPOS OH DEL COMPONENTE A) CON RESPECTO A LOS GRUPOS NCO DE LOS COMPONENTES B) Y C) SE ENCUENTRA DESDE 1,01 : 1 HASTA 3 : 1 DE FORMA QUE LOS PREPOLIMEROS QUE SE OBTIENEN A PARTIR DE A), B) Y C) SE TRANSFORMAN EN MEDIO ORGANICO O EN FASE ACUOSA DE UN ALARGAMIENTO DE CADENA DESPUES DE LA TRANSFORMACION CON D) ISOCIANATOS POLIFUNCIONALES CON UNA FUNCIONALIDAD EN GRUPOS NCO LIBRES DE AL MENOS 1,8, EN PROPORCIONES TALES, QUE LA RESINA DE POLIURETANO ELABORADA MUESTRA LA MEDIA NUMERICA DESEADA DE LA MASA MOLAR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4344063A DE4344063C1 (de) | 1993-12-23 | 1993-12-23 | Wäßrige Bindemitteldispersion für physikalisch trocknende Überzugsmittel und deren Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2106437T3 true ES2106437T3 (es) | 1997-11-01 |
Family
ID=6505922
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94120194T Expired - Lifetime ES2106437T3 (es) | 1993-12-23 | 1994-12-20 | Dispersion de ligante acuoso para revestimientos de secado fisico y su utilizacion. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5556912A (es) |
| EP (1) | EP0661321B1 (es) |
| JP (1) | JPH07216300A (es) |
| AT (1) | ATE156152T1 (es) |
| CA (1) | CA2137955C (es) |
| DE (2) | DE4344063C1 (es) |
| DK (1) | DK0661321T3 (es) |
| ES (1) | ES2106437T3 (es) |
| GR (1) | GR3024530T3 (es) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19535452A1 (de) * | 1995-09-23 | 1997-03-27 | Herberts Gmbh | Verfahren zur Effektlackierung genarbter Kunststoffteile |
| DE19643802A1 (de) * | 1996-10-30 | 1998-05-07 | Herberts Gmbh | Wäßrige Bindemitteldispersion für physikalisch trocknende Überzugsmittel und deren Verwendung |
| DE19645761A1 (de) * | 1996-11-06 | 1998-05-07 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hybrid-Dispersionen |
| DE19716020A1 (de) * | 1997-04-17 | 1998-10-22 | Basf Ag | Dispersionen enthaltend ein Polyurethan und ein strahlenhärtbares Präpolymer |
| DE19750451A1 (de) * | 1997-11-14 | 1999-05-27 | Herberts & Co Gmbh | Verfahren zur Herstellung von Mehrschichtlackierungen |
| EP1152018A1 (en) * | 1999-04-01 | 2001-11-07 | Nihon Parkerizing Co., Ltd. | Aqueous coating composition for metal sheets, use thereof, surface-treated metal sheets and surface treating method |
| TW510916B (en) * | 1998-12-21 | 2002-11-21 | Bayer Ag | Aqueous reacitve filler compositions |
| US6306947B1 (en) * | 1999-05-27 | 2001-10-23 | Nippon Polyurethane Industry Co., Ltd. | Printing ink and paint composed of an aqueous emulsion of self-emulsifiable urethane copolymer |
| DE10020195A1 (de) * | 2000-04-25 | 2001-10-31 | Basf Ag | PU-modifizierte Miniemulsionspolymerisate |
| US6451896B1 (en) | 2000-04-28 | 2002-09-17 | E. I. Du Pont De Nemours And Company | Coating system for the preparation of aqueous coating compositions |
| MXPA04000820A (es) * | 2001-07-27 | 2004-05-21 | Merquinsa Mercados Quimicos S | Termoplastico de poliuretano ionomerico. |
| AU2003251678A1 (en) * | 2002-08-13 | 2004-03-11 | Akzo Nobel Coatings International B.V. | Multilayer coating system comprising thiol-funcitonal compounds |
| US20060128876A1 (en) * | 2004-12-10 | 2006-06-15 | Josef Huybrechts | Aqueous coating compositions |
| US20060216525A1 (en) * | 2005-03-24 | 2006-09-28 | Josef Huybrechts | Aqueous coating compositions |
| US20060228556A1 (en) * | 2005-04-08 | 2006-10-12 | Fenn David R | Electrodepositable coating compositions and methods for their production |
| DE102005045228A1 (de) | 2005-09-22 | 2007-04-05 | Basf Coatings Ag | Verwendung von Phosphonsäurediestern und Diphosphonsäurediestern sowie silangruppenhaltige, härtbare Gemische, enthaltend Phosphonsäurediester und Diphosphonsäurediester |
| DE102005045150A1 (de) | 2005-09-22 | 2007-04-05 | Basf Coatings Ag | Verwendung von Phosphonsäurediestern und Diphosphonsäurediestern sowie thermisch härtbare Gemische, enthaltend Phosphonsäurediester und Diphosphonsäurediester |
| US7393556B2 (en) * | 2005-11-07 | 2008-07-01 | E.I. Du Pont De Nemours And Company | Process for the production of a multilayer vehicle repair coating |
| DE102006024823A1 (de) | 2006-05-29 | 2007-12-06 | Basf Coatings Ag | Verwendung von härtbaren Gemischen, enthaltend silangruppenhaltige Verbindungen sowie Phosphonsäurediester oder Diphosphonsäurediester, als Haftvermittler |
| US7732006B2 (en) | 2006-08-28 | 2010-06-08 | Quest Optical, Incorporated | Coating composition and optical mar-resistant tintable coating |
| DE102007014720A1 (de) | 2007-03-23 | 2008-09-25 | Basf Coatings Japan Ltd., Yokohama | Phosphonat-haltiges Zweikomponenten-Lacksystem, dessen Herstellung und Verwendung |
| SE0701095L (sv) * | 2007-05-04 | 2008-11-05 | Perstorp Specialty Chem Ab | Isocyanatterminerad polymer och dess användning i en strålningshärdande polyuretandispersion |
| US9234068B2 (en) * | 2007-10-02 | 2016-01-12 | The Hong Kong University of Science and Technologhy | Method for preparing aqueous polyacrylate modified polyurethane dispersions |
| US8865831B2 (en) * | 2007-10-19 | 2014-10-21 | Axalta Coating Systems Ip Co., Llc | Two-component coating compositions |
| WO2009051962A1 (en) * | 2007-10-19 | 2009-04-23 | E. I. Du Pont De Nemours And Company | Process for painting substrates |
| WO2010078232A1 (en) | 2008-12-30 | 2010-07-08 | E. I. Du Pont De Nemours And Company | Waterborne coating composition containing polytrimethylene ether diol |
| JP5384963B2 (ja) * | 2009-02-05 | 2014-01-08 | 株式会社イノアックコーポレーション | 導光シート及び柔軟性導光体形成用組成物 |
| KR101728568B1 (ko) * | 2009-06-10 | 2017-04-19 | 코베스트로 도이칠란드 아게 | 폴리(thf)-기재 폴리우레탄 분산액 |
| EP2514778B1 (en) | 2009-09-28 | 2013-10-16 | Coatings Foreign IP Co. LLC | Liquid two-component coating compositions |
| EP2635647A1 (en) * | 2010-11-05 | 2013-09-11 | Coatings Foreign IP Co. LLC | Waterborne coating composition containing low molecular weight polytrimethylene ether glycol |
| EP2468830A1 (en) | 2010-12-27 | 2012-06-27 | Cytec Surface Specialties, S.A. | Radiation Curable Polyurethane Compositions |
| EP2468782A1 (en) * | 2010-12-27 | 2012-06-27 | Cytec Surface Specialties, S.A. | Radiation curable compositions |
| JP2014522423A (ja) | 2011-05-03 | 2014-09-04 | コーティングス フォーリン アイピー カンパニー, エルエルシー | 二成分系塗料組成物 |
| MX344743B (es) | 2011-05-03 | 2017-01-05 | Coatings Foreign Ip Co Llc | Compuesto de catalizador para composiciones de recubrimiento de dos componentes. |
| EP2586835B1 (en) * | 2011-08-25 | 2019-08-21 | Rohm and Haas Company | Thickened aqueous dispersions and coated substrate provided therefrom |
| CN104428337B (zh) * | 2012-06-26 | 2017-08-11 | 涂料外国Ip有限公司 | 用于施加多层涂层的方法 |
| EP2869939B1 (en) | 2012-07-05 | 2016-11-23 | Coatings Foreign IP Co. LLC | Process for the production of an oem base coat/clear top coat multi-layer coating |
| CN104540867B (zh) | 2012-08-10 | 2017-03-22 | 涂料外国Ip有限公司 | 水基双组分涂料组合物 |
| US9499718B2 (en) * | 2013-03-21 | 2016-11-22 | Axalta Coating Systems Ip Co., Llc | Process for the production of an OEM base coat/clear top coat multi-layer coating |
| WO2015089370A1 (en) | 2013-12-13 | 2015-06-18 | Avery Dennison Corporation | Water based printable coatings |
| ES2708202T3 (es) * | 2015-06-25 | 2019-04-09 | Covestro Deutschland Ag | Dispersiones de poliuretano desprovistas de urea |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2734576A1 (de) * | 1977-07-30 | 1979-02-08 | Bayer Ag | Verfahren zur herstellung von waessrigen dispersionen oder loesungen von isocyanat-polyadditionsprodukten |
| DE3005034A1 (de) * | 1980-02-11 | 1981-08-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von ueberzuegen |
| US4467078A (en) * | 1982-08-02 | 1984-08-21 | The B. F. Goodrich Company | Electron beam curable polyurethane compositions |
| JPS63108020A (ja) * | 1986-06-12 | 1988-05-12 | Toyobo Co Ltd | 放射線硬化型樹脂 |
| CA2007847C (en) * | 1989-01-18 | 1998-04-21 | Yasuhiro Fujii | Aqueous thermoplastic coating composition for plastics materials and coating method using same |
| DE3936794A1 (de) * | 1989-11-04 | 1991-05-08 | Bayer Ag | Waessriges ueberzugsmittel und die verwendung von in wasser dispergierbaren polyurethanpolyharnstoffen als bindemittel |
| DE4010176A1 (de) * | 1990-03-30 | 1991-10-02 | Basf Lacke & Farben | Verfahren zur herstellung einer mehrschichtigen lackierung und waessriger lack |
| US5095069A (en) * | 1990-08-30 | 1992-03-10 | Ppg Industries, Inc. | Internally-curable water-based polyurethanes |
| DE4031732A1 (de) * | 1990-10-06 | 1992-04-09 | Basf Ag | Strahlenhaertbare, waessrige bindemitteldispersionen |
| DE4122265A1 (de) * | 1991-07-05 | 1993-01-07 | Hoechst Ag | Polyurethan-dispersionen |
| DE4122266A1 (de) * | 1991-07-05 | 1993-01-07 | Hoechst Ag | Polyurethan-dispersionen |
-
1993
- 1993-12-23 DE DE4344063A patent/DE4344063C1/de not_active Expired - Fee Related
-
1994
- 1994-12-13 CA CA002137955A patent/CA2137955C/en not_active Expired - Lifetime
- 1994-12-20 EP EP94120194A patent/EP0661321B1/de not_active Expired - Lifetime
- 1994-12-20 ES ES94120194T patent/ES2106437T3/es not_active Expired - Lifetime
- 1994-12-20 DK DK94120194.9T patent/DK0661321T3/da active
- 1994-12-20 DE DE59403556T patent/DE59403556D1/de not_active Expired - Lifetime
- 1994-12-20 AT AT94120194T patent/ATE156152T1/de active
- 1994-12-21 US US08/361,202 patent/US5556912A/en not_active Expired - Lifetime
- 1994-12-22 JP JP6319590A patent/JPH07216300A/ja active Pending
-
1997
- 1997-08-22 GR GR970402171T patent/GR3024530T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2137955A1 (en) | 1995-06-24 |
| GR3024530T3 (en) | 1997-12-31 |
| CA2137955C (en) | 2005-08-30 |
| DE4344063C1 (de) | 1995-06-08 |
| EP0661321A1 (de) | 1995-07-05 |
| DK0661321T3 (da) | 1998-01-26 |
| JPH07216300A (ja) | 1995-08-15 |
| EP0661321B1 (de) | 1997-07-30 |
| US5556912A (en) | 1996-09-17 |
| ATE156152T1 (de) | 1997-08-15 |
| DE59403556D1 (de) | 1997-09-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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