ES2196464T3 - Procedimiento para la recuperacion de acido sulfurico de productos secundarios que contienen sulfatos de un proceso para la preparacion de acido 2-hidroxi-4-metiltiobutirico (mha). - Google Patents
Procedimiento para la recuperacion de acido sulfurico de productos secundarios que contienen sulfatos de un proceso para la preparacion de acido 2-hidroxi-4-metiltiobutirico (mha).Info
- Publication number
- ES2196464T3 ES2196464T3 ES98122921T ES98122921T ES2196464T3 ES 2196464 T3 ES2196464 T3 ES 2196464T3 ES 98122921 T ES98122921 T ES 98122921T ES 98122921 T ES98122921 T ES 98122921T ES 2196464 T3 ES2196464 T3 ES 2196464T3
- Authority
- ES
- Spain
- Prior art keywords
- sulfuric acid
- mha
- recovery
- hydrolysis
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title abstract 14
- 238000000034 method Methods 0.000 title abstract 3
- 238000011084 recovery Methods 0.000 title abstract 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 abstract 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- 230000007062 hydrolysis Effects 0.000 abstract 4
- 238000006460 hydrolysis reaction Methods 0.000 abstract 4
- PICCHNWCTUUCAQ-UHFFFAOYSA-N 2-hydroxypentanethioic s-acid Chemical compound CCCC(O)C(O)=S PICCHNWCTUUCAQ-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 2
- WWILHZQYNPQALT-UHFFFAOYSA-N 2-methyl-2-morpholin-4-ylpropanal Chemical compound O=CC(C)(C)N1CCOCC1 WWILHZQYNPQALT-UHFFFAOYSA-N 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
- C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/58—Recovery of sulfur dioxide from acid tar or the like or from any waste sulfuric acid
- C01B17/585—Recovery of sulfur dioxide from acid tar or the like or from any waste sulfuric acid from ammonium sulfate containing sulfuric acid solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/745—Preparation from sulfates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
- C07C319/26—Separation; Purification; Stabilisation; Use of additives
- C07C319/28—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
Abstract
LA INVENCION TRATA DE UN PROCEDIMIENTO PARA LA RECUPERACION DE ACIDO SULFURICO A PARTIR DE PRODUCTOS QUE CONTIENEN AZUFRE, QUE SE FORMAN EN PROCESOS PARA LA OBTENCION DEL ACIDO 2 HIDROXI - 4 - METILTIOBUTILICO (MHA), TENIENDO EL ACIDO SULFURICO UNA CALIDAD, QUE SE PUEDE VOLVER A UTILIZAR DIRECTAMENTE EN TALES COMPUESTOS. PARA ESTE OBJETO SE LLEVA GAS DE COMBUSTION QUE CONTIENE SO 2 A TRAVES DE UNA DISOLUCION DE H 2 O SUB,2 ACIDA DE AZUFRE, EN LA CUAL EL SO 2 SE OXIDA PARA DAR ACIDO SULFURICO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19754562A DE19754562A1 (de) | 1997-12-09 | 1997-12-09 | Verfahren zur Rückgewinnung von Schwefelsäure aus schwefelhaltigen Nebenprodukten eines Prozesses zur Herstellung von 2-Hydroxy-4-methylthiobuttersäure (MHA) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2196464T3 true ES2196464T3 (es) | 2003-12-16 |
Family
ID=7851227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98122921T Expired - Lifetime ES2196464T3 (es) | 1997-12-09 | 1998-12-02 | Procedimiento para la recuperacion de acido sulfurico de productos secundarios que contienen sulfatos de un proceso para la preparacion de acido 2-hidroxi-4-metiltiobutirico (mha). |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6146612A (es) |
| EP (1) | EP0922670B1 (es) |
| JP (1) | JP4511647B2 (es) |
| KR (1) | KR19990063023A (es) |
| CN (1) | CN1119280C (es) |
| AT (1) | ATE236078T1 (es) |
| AU (1) | AU735555B2 (es) |
| BR (1) | BR9805253A (es) |
| CA (1) | CA2255483A1 (es) |
| DE (2) | DE19754562A1 (es) |
| ES (1) | ES2196464T3 (es) |
| ID (1) | ID21414A (es) |
| PL (1) | PL330168A1 (es) |
| SG (1) | SG73595A1 (es) |
| TR (1) | TR199802563A2 (es) |
| TW (1) | TW522139B (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6017563A (en) | 1997-07-25 | 2000-01-25 | Novus International, Inc. | Process for optimizing milk production |
| AU6525700A (en) | 1999-08-05 | 2001-03-05 | Novus International Inc | Reductive combustion of ammonium salts of sulfuric acid |
| DE19963509A1 (de) * | 1999-12-28 | 2001-07-05 | Merck Patent Gmbh | Verfahren zur Herstellung hochreiner Schwefelsäure |
| CN114053839B (zh) * | 2020-08-05 | 2023-06-23 | 中冶长天国际工程有限责任公司 | 一种含氰srg气体清洁治理及热风炉尾气净化的方法和系统 |
| CN117862142A (zh) * | 2024-03-11 | 2024-04-12 | 招远市招金金合科技有限公司 | 一种高铁硫酸送化渣回收精炼设备 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2106950A5 (es) * | 1970-09-30 | 1972-05-05 | Air Liquide | |
| US3760061A (en) * | 1971-03-02 | 1973-09-18 | Du Pont | High-strength acid containing h2o2 to scrub so2 |
| BE794918A (fr) * | 1972-02-04 | 1973-08-02 | Oxysynthese | Procede d'epuration de fumees industrielles, de produit de combustion et d'efflents gazeux avant rejet a l'atmosphere |
| US3917798A (en) * | 1973-09-24 | 1975-11-04 | Du Pont | SO{HD 2{B abatement |
| JPS59108995A (ja) * | 1982-12-14 | 1984-06-23 | 日立造船株式会社 | 放射性廃棄物から硫酸を製造する方法 |
| ES2005784A6 (es) * | 1988-02-22 | 1989-03-16 | Desarrollo Tecnico Ind S A Soc | Un procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metil-tiobutirico. |
| DE4036899C2 (de) * | 1990-11-20 | 2001-10-25 | Degussa | Verfahren zur Entschwefelung von SO¶2¶ enthaltenden feuchten Abgasen und Vorrichtung zur Durchführung des Verfahrens |
| US5498790A (en) * | 1993-06-09 | 1996-03-12 | Novus International, Inc. | Regeneration of sulfuric acid from sulfate by-products of 2-hydroxy-4-(methylthio)butyric acid manufacture |
| BR9508383A (pt) * | 1994-07-11 | 1997-12-23 | Degussa | Processo para a obtenção de ácido 2-hidróxi-4-metiltiobutírico (mha) mha e seu emprego |
| DE4428608C1 (de) * | 1994-08-12 | 1996-02-29 | Degussa | Verfahren zur Gewinnung von 2-Hydroxy-4-methylthiobuttersäure (MHA) |
| US5595713A (en) * | 1994-09-08 | 1997-01-21 | The Babcock & Wilcox Company | Hydrogen peroxide for flue gas desulfurization |
| DE19525054C2 (de) * | 1995-07-10 | 1999-02-25 | Freudenberg Carl Fa | Verfahren zur Herstellung eines Radialwellendichtrings |
| JPH09315806A (ja) * | 1996-05-28 | 1997-12-09 | Mitsubishi Gas Chem Co Inc | 硫酸および過酸化水素を含む廃液からの硫酸の回収方法 |
-
1997
- 1997-12-09 DE DE19754562A patent/DE19754562A1/de not_active Withdrawn
-
1998
- 1998-12-02 ES ES98122921T patent/ES2196464T3/es not_active Expired - Lifetime
- 1998-12-02 AT AT98122921T patent/ATE236078T1/de not_active IP Right Cessation
- 1998-12-02 DE DE59807725T patent/DE59807725D1/de not_active Expired - Lifetime
- 1998-12-02 EP EP98122921A patent/EP0922670B1/de not_active Expired - Lifetime
- 1998-12-04 TW TW087120218A patent/TW522139B/zh active
- 1998-12-07 JP JP34721598A patent/JP4511647B2/ja not_active Expired - Fee Related
- 1998-12-08 CA CA002255483A patent/CA2255483A1/en not_active Abandoned
- 1998-12-08 US US09/206,948 patent/US6146612A/en not_active Expired - Lifetime
- 1998-12-08 PL PL98330168A patent/PL330168A1/xx unknown
- 1998-12-08 ID IDP981593A patent/ID21414A/id unknown
- 1998-12-08 AU AU96987/98A patent/AU735555B2/en not_active Ceased
- 1998-12-08 SG SG1998005332A patent/SG73595A1/en unknown
- 1998-12-09 TR TR1998/02563A patent/TR199802563A2/xx unknown
- 1998-12-09 CN CN98123185A patent/CN1119280C/zh not_active Expired - Fee Related
- 1998-12-09 BR BR9805253-5A patent/BR9805253A/pt not_active IP Right Cessation
- 1998-12-09 KR KR1019980054761A patent/KR19990063023A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| CA2255483A1 (en) | 1999-06-09 |
| TR199802563A2 (xx) | 1999-06-21 |
| CN1119280C (zh) | 2003-08-27 |
| SG73595A1 (en) | 2000-06-20 |
| JP4511647B2 (ja) | 2010-07-28 |
| AU9698798A (en) | 1999-07-01 |
| AU735555B2 (en) | 2001-07-12 |
| EP0922670B1 (de) | 2003-04-02 |
| EP0922670A1 (de) | 1999-06-16 |
| BR9805253A (pt) | 2000-02-01 |
| ATE236078T1 (de) | 2003-04-15 |
| DE19754562A1 (de) | 1999-06-10 |
| ID21414A (id) | 1999-06-10 |
| JPH11246207A (ja) | 1999-09-14 |
| CN1223230A (zh) | 1999-07-21 |
| DE59807725D1 (de) | 2003-05-08 |
| TW522139B (en) | 2003-03-01 |
| KR19990063023A (ko) | 1999-07-26 |
| US6146612A (en) | 2000-11-14 |
| PL330168A1 (en) | 1999-06-21 |
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