ES2194361T3 - Procedimiento y compuestos intermedios para la preparacion de un herbicida de triazol. - Google Patents
Procedimiento y compuestos intermedios para la preparacion de un herbicida de triazol.Info
- Publication number
- ES2194361T3 ES2194361T3 ES98953627T ES98953627T ES2194361T3 ES 2194361 T3 ES2194361 T3 ES 2194361T3 ES 98953627 T ES98953627 T ES 98953627T ES 98953627 T ES98953627 T ES 98953627T ES 2194361 T3 ES2194361 T3 ES 2194361T3
- Authority
- ES
- Spain
- Prior art keywords
- formula
- compound
- triazol
- herbicide
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- QWENRTYMTSOGBR-UHFFFAOYSA-N 1H-1,2,3-Triazole Chemical compound C=1C=NNN=1 QWENRTYMTSOGBR-UHFFFAOYSA-N 0.000 title 1
- 230000002363 herbicidal effect Effects 0.000 title 1
- 239000004009 herbicide Substances 0.000 title 1
- JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000005708 Sodium hypochlorite Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 125000001475 halogen functional group Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
- C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D249/12—Oxygen or sulfur atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento para preparar el Compuesto E con la fórmula **(Fórmula)** en la que X e Y son iguales o diferentes y se seleccionan independientemente entre halo, alquilo, cicloalquilo, alcoxi, nitro y grupos heterocíclicos y R es un grupo alquilo o haloalquilo que tiene 1 a 10 átomos de carbono, que comprende la combinación del Compuesto Intermedio D con la fórmula **(Fórmula)** en la que X, Y y R se definen igual que para el Compuesto E, con 1 a 5 equivalentes molares (eq M) de un ácido alcanóico, 1 a 9 eq M de hipoclorito de sodio y 1 a 5 eq M de una base, estando expresadas las cantidades de todos los reactivos en relación con 1, 0 eq M del Compuesto Intermedio D y recuperando el Compuesto E.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6227397P | 1997-10-16 | 1997-10-16 | |
| US09/172,157 US6077959A (en) | 1998-10-14 | 1998-10-14 | Process for the preparation of a triazolinone herbicide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2194361T3 true ES2194361T3 (es) | 2003-11-16 |
Family
ID=26742057
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES98953627T Expired - Lifetime ES2194361T3 (es) | 1997-10-16 | 1998-10-16 | Procedimiento y compuestos intermedios para la preparacion de un herbicida de triazol. |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US6194583B1 (es) |
| EP (1) | EP1036068B1 (es) |
| JP (1) | JP2001519418A (es) |
| KR (1) | KR100528761B1 (es) |
| CN (1) | CN1159301C (es) |
| AR (1) | AR017346A1 (es) |
| AT (1) | ATE234292T1 (es) |
| AU (1) | AU1095599A (es) |
| BR (1) | BR9814927A (es) |
| CZ (1) | CZ297607B6 (es) |
| DE (1) | DE69812160T2 (es) |
| ES (1) | ES2194361T3 (es) |
| HU (1) | HUP0003989A3 (es) |
| IL (1) | IL135632A (es) |
| PL (1) | PL342143A1 (es) |
| WO (1) | WO1999019308A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102174026B (zh) * | 2011-03-11 | 2012-12-05 | 浙江省诸暨合力化学对外贸易有限公司 | 一种唑草酮的制备方法 |
| CN103483280A (zh) * | 2013-09-13 | 2014-01-01 | 南京工业大学 | 一种合成唑草酮酯的方法 |
| CN104003949A (zh) * | 2014-03-31 | 2014-08-27 | 济南先达化工科技有限公司 | 一种唑草酮的制备方法 |
| US9856201B2 (en) | 2014-06-04 | 2018-01-02 | Monsanto Technology Llc | 3,6-dichlorosalicylic acid compounds and related synthetic processes |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT65179B (en) * | 1975-06-09 | 1977-11-18 | Takeda Chemical Industries Ltd | Alpha/chlorocarboxylic acids |
| CA1331463C (en) * | 1988-08-31 | 1994-08-16 | Kathleen Megan Poss | Herbicidal triazolinones |
| US5208212A (en) * | 1988-08-31 | 1993-05-04 | Fmc Corporation | Herbicidal compositions containing triazolinones |
| US5125958A (en) * | 1988-08-31 | 1992-06-30 | Fmc Corporation | Herbicidal triazolinones |
| JP3824648B2 (ja) * | 1995-08-21 | 2006-09-20 | エフ エム シー コーポレーション | 殺草性エチルα−2−ジクロロ−5−〔4−(ジフルオロメチル)−4,5−ジヒドロ−3−メチル−5−オキソ−1H−1,2,4−トリアゾール−1−イル〕−4−フルオロベンゼンプロパノエートの製造方法 |
| US5621112A (en) * | 1996-07-18 | 1997-04-15 | Fmc Corporation | Process for the preparation of the herbicide ethyl α-2-dichloro-5-[4-(Difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-yl]-4-fluorobenzenepropanoate |
-
1998
- 1998-10-16 WO PCT/US1998/021911 patent/WO1999019308A1/en not_active Ceased
- 1998-10-16 BR BR9814927-0A patent/BR9814927A/pt not_active Application Discontinuation
- 1998-10-16 CN CNB988102617A patent/CN1159301C/zh not_active Expired - Fee Related
- 1998-10-16 CZ CZ20001325A patent/CZ297607B6/cs not_active IP Right Cessation
- 1998-10-16 AR ARP980105144A patent/AR017346A1/es active IP Right Grant
- 1998-10-16 PL PL98342143A patent/PL342143A1/xx not_active Application Discontinuation
- 1998-10-16 IL IL13563298A patent/IL135632A/xx not_active IP Right Cessation
- 1998-10-16 ES ES98953627T patent/ES2194361T3/es not_active Expired - Lifetime
- 1998-10-16 HU HU0003989A patent/HUP0003989A3/hu unknown
- 1998-10-16 AT AT98953627T patent/ATE234292T1/de not_active IP Right Cessation
- 1998-10-16 KR KR10-2000-7003965A patent/KR100528761B1/ko not_active Expired - Fee Related
- 1998-10-16 AU AU10955/99A patent/AU1095599A/en not_active Abandoned
- 1998-10-16 EP EP98953627A patent/EP1036068B1/en not_active Expired - Lifetime
- 1998-10-16 DE DE69812160T patent/DE69812160T2/de not_active Expired - Fee Related
- 1998-10-16 JP JP2000515881A patent/JP2001519418A/ja active Pending
-
2000
- 2000-03-15 US US09/525,394 patent/US6194583B1/en not_active Expired - Fee Related
- 2000-10-16 US US09/688,406 patent/US6268506B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0003989A3 (en) | 2002-01-28 |
| DE69812160D1 (de) | 2003-04-17 |
| CN1159301C (zh) | 2004-07-28 |
| KR100528761B1 (ko) | 2005-11-15 |
| PL342143A1 (en) | 2001-05-21 |
| AR017346A1 (es) | 2001-09-05 |
| IL135632A (en) | 2005-03-20 |
| ATE234292T1 (de) | 2003-03-15 |
| EP1036068A1 (en) | 2000-09-20 |
| HK1032055A1 (en) | 2001-07-06 |
| DE69812160T2 (de) | 2003-12-18 |
| WO1999019308A1 (en) | 1999-04-22 |
| IL135632A0 (en) | 2001-05-20 |
| HUP0003989A2 (en) | 2001-03-28 |
| US6268506B1 (en) | 2001-07-31 |
| KR20010031099A (ko) | 2001-04-16 |
| EP1036068B1 (en) | 2003-03-12 |
| BR9814927A (pt) | 2000-09-05 |
| CN1280573A (zh) | 2001-01-17 |
| AU1095599A (en) | 1999-05-03 |
| JP2001519418A (ja) | 2001-10-23 |
| CZ20001325A3 (cs) | 2000-09-13 |
| CZ297607B6 (cs) | 2007-02-07 |
| US6194583B1 (en) | 2001-02-27 |
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