ES2033175A1 - Obtencion en continuo de sales fertilizantes con derivados de estroncio y yeso. - Google Patents
Obtencion en continuo de sales fertilizantes con derivados de estroncio y yeso.Info
- Publication number
- ES2033175A1 ES2033175A1 ES909001964A ES9001964A ES2033175A1 ES 2033175 A1 ES2033175 A1 ES 2033175A1 ES 909001964 A ES909001964 A ES 909001964A ES 9001964 A ES9001964 A ES 9001964A ES 2033175 A1 ES2033175 A1 ES 2033175A1
- Authority
- ES
- Spain
- Prior art keywords
- strontium
- carbonate
- ammonium
- gypsum
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052602 gypsum Inorganic materials 0.000 title abstract 2
- 239000010440 gypsum Substances 0.000 title abstract 2
- 150000003839 salts Chemical class 0.000 title abstract 2
- 150000003437 strontium Chemical class 0.000 title abstract 2
- 238000010924 continuous production Methods 0.000 title 1
- 238000000034 method Methods 0.000 abstract 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 2
- 239000001099 ammonium carbonate Substances 0.000 abstract 2
- 235000012501 ammonium carbonate Nutrition 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 abstract 2
- 229910000018 strontium carbonate Inorganic materials 0.000 abstract 2
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 abstract 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 abstract 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 abstract 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 239000001166 ammonium sulphate Substances 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 abstract 1
- 239000004571 lime Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/18—Nitrates of ammonium
- C01C1/185—Preparation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/26—Carbonates or bicarbonates of ammonium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/186—Strontium or barium carbonate
- C01F11/187—Strontium carbonate
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/36—Nitrates
- C01F11/38—Preparation with nitric acid or nitrogen oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/46—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C1/00—Ammonium nitrate fertilisers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Fertilizers (AREA)
- Paints Or Removers (AREA)
- Non-Portable Lighting Devices Or Systems Thereof (AREA)
Abstract
PROCESO DE OBTENCION DE SALES FERTILIZANTES Y DERIVADOS DE ESTRONCIO, POR VIA HUMEDA, PARTIENDO DE MINERAL EN FORMA DE SULFATO DE ESTRONCIO, AL CUAL SE LE HACE REACCIONAR CON EXCESO DE CARBONATO AMONICO. ESTA REACCION SE EFECTUA EN FORMA CONTINUA Y CON FLUJOS DE REACTIVOS EN CONTRACORRIENTE. EL EXCESO DE CARBONATO AMONICO UTILIZADO, SE RECUPERA PARA REINTEGRARLO NUEVAMENTE EN EL PROCESO Y DEJAR AISLADO EL SULFATO AMONICO QUE SE PUEDE TRATAR EN REGIMEN CONTINUO CON CARBONATO U OXIDO DE CAL, RECUPERANDO LOS GASES DESPRENDIDOS EN LA REACCION Y OBTENIENDO COMO PRODUCTO FINAL SULFATO DE CAL (YESO). EN UNA SEGUNDA FASE SE HACE REACCIONAR EN CONTINUO EL CARBONATO DE ESTRONCIO OBTENIDO CON ACIDO NITRICO PARA OBTENER NITRATO DE ESTRONCIO, PARTE DEL CUAL SE CARBONATA CON GASES (COSI2 Y NHSI3) DANDO LUGAR A UN CARBONATO DE ESTRONCIO PRECIPITADO Y UNA SOLUCION DE NITRATO AMONICO.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES9001964A ES2033175B1 (es) | 1990-07-20 | 1990-07-20 | Obtencion en continuo de sales fertilizantes con derivados de estroncio y yeso. |
| AU80099/91A AU8009991A (en) | 1990-07-20 | 1991-07-03 | Continuous production of fertilizing salts with derivatives of strontium and gypsum |
| PCT/ES1991/000039 WO1992001630A1 (es) | 1990-07-20 | 1991-07-03 | Obtencion en continuo de sales fertilizantes con derivados de estroncio y yeso |
| JP3511359A JPH05501396A (ja) | 1990-07-20 | 1991-07-03 | ストロンチウムの派生物と石膏派生物を伴う化学肥料塩の連続生成方法 |
| EP19910911661 EP0495937A1 (en) | 1990-07-20 | 1991-07-03 | Continuous production of fertilizing salts with derivatives of strontium and gypsum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES9001964A ES2033175B1 (es) | 1990-07-20 | 1990-07-20 | Obtencion en continuo de sales fertilizantes con derivados de estroncio y yeso. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2033175A1 true ES2033175A1 (es) | 1993-03-01 |
| ES2033175B1 ES2033175B1 (es) | 1994-03-01 |
Family
ID=8268242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES9001964A Expired - Lifetime ES2033175B1 (es) | 1990-07-20 | 1990-07-20 | Obtencion en continuo de sales fertilizantes con derivados de estroncio y yeso. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0495937A1 (es) |
| JP (1) | JPH05501396A (es) |
| AU (1) | AU8009991A (es) |
| ES (1) | ES2033175B1 (es) |
| WO (1) | WO1992001630A1 (es) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2109863A1 (es) * | 1995-02-17 | 1998-01-16 | Bruno S A | Procedimiento perfeccionado de obtencion de sales de estroncio y derivados fertilizantes. |
| ES2181543A1 (es) * | 2000-07-17 | 2003-02-16 | Quimica Del Estroncio S A | Procedimiento para la obtencion de nitrato de estroncio. |
| ES2182638A1 (es) * | 2000-07-17 | 2003-03-01 | Quimica Del Estroncio S A | Procedimiento para la obtencion de carbonato de estroncio. |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2121695B1 (es) * | 1996-10-15 | 1999-07-01 | Domytec S L | Procedimiento para la obtencion conjunta de carbonato de estroncio de alta pureza y nitrato potasico calidad fertilizante a partir de minerales de celestita. |
| WO2001077021A1 (en) * | 2000-04-12 | 2001-10-18 | Tübitak-Marmara Research Center | Production of strontium carbonate from celestite |
| US7749483B2 (en) | 2006-12-15 | 2010-07-06 | Honeywell International Inc. | Method for producing alkaline earth metal oxides |
| US8758719B2 (en) | 2012-08-10 | 2014-06-24 | Sparstane Technologies LLC | Process for converting FGD gypsum to ammonium sulfate and calcium carbonate |
| PL421318A1 (pl) * | 2017-04-14 | 2018-10-22 | Ferin Spółka Z Ograniczoną Odpowiedzialnością | Sposób zagospodarowania fosfogipsów |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES411211A1 (es) * | 1972-02-15 | 1975-12-01 | Albright & Wilson | Un metodo para separar calcio de sulfato de estoncio yno debario impuros. |
| ES2006338A6 (es) * | 1988-02-29 | 1989-04-16 | Philopatent Sa | Proceso de obtencion de sales de estroncio y derivados fertilizantes. |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4421729A (en) * | 1982-01-11 | 1983-12-20 | Fmc Corporation | Preparation of strontium carbonate |
| US4666688A (en) * | 1986-02-03 | 1987-05-19 | Excel-Mineral Company, Inc. | Method for recovery and conversion of strontium sulfate to strontium carbonate from low and medium grade celestite ores |
-
1990
- 1990-07-20 ES ES9001964A patent/ES2033175B1/es not_active Expired - Lifetime
-
1991
- 1991-07-03 EP EP19910911661 patent/EP0495937A1/en not_active Withdrawn
- 1991-07-03 JP JP3511359A patent/JPH05501396A/ja active Pending
- 1991-07-03 WO PCT/ES1991/000039 patent/WO1992001630A1/es not_active Ceased
- 1991-07-03 AU AU80099/91A patent/AU8009991A/en not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES411211A1 (es) * | 1972-02-15 | 1975-12-01 | Albright & Wilson | Un metodo para separar calcio de sulfato de estoncio yno debario impuros. |
| ES2006338A6 (es) * | 1988-02-29 | 1989-04-16 | Philopatent Sa | Proceso de obtencion de sales de estroncio y derivados fertilizantes. |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2109863A1 (es) * | 1995-02-17 | 1998-01-16 | Bruno S A | Procedimiento perfeccionado de obtencion de sales de estroncio y derivados fertilizantes. |
| ES2181543A1 (es) * | 2000-07-17 | 2003-02-16 | Quimica Del Estroncio S A | Procedimiento para la obtencion de nitrato de estroncio. |
| ES2182638A1 (es) * | 2000-07-17 | 2003-03-01 | Quimica Del Estroncio S A | Procedimiento para la obtencion de carbonato de estroncio. |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0495937A1 (en) | 1992-07-29 |
| WO1992001630A1 (es) | 1992-02-06 |
| JPH05501396A (ja) | 1993-03-18 |
| AU8009991A (en) | 1992-02-18 |
| ES2033175B1 (es) | 1994-03-01 |
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