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ES2025769T3 - Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles. - Google Patents

Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles.

Info

Publication number
ES2025769T3
ES2025769T3 ES198888202019T ES88202019T ES2025769T3 ES 2025769 T3 ES2025769 T3 ES 2025769T3 ES 198888202019 T ES198888202019 T ES 198888202019T ES 88202019 T ES88202019 T ES 88202019T ES 2025769 T3 ES2025769 T3 ES 2025769T3
Authority
ES
Spain
Prior art keywords
procedure
hydrogels
preparing
hydrotreatment catalysts
wolframino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198888202019T
Other languages
English (en)
Inventor
Richard Alan Kemp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Application granted granted Critical
Publication of ES2025769T3 publication Critical patent/ES2025769T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PROCEDIMIENTO PARA LA PREPARACION DE CATALIZADORES DE HIDROTRATAMIENTO MUY ACTIVOS, INCORPORANDO UN COMPUESTO ELEGIDO DEL GRUPO QUE CONSTA DE NIQUEL, COBALTO Y SUS MEZCLAS, UN METAL PESADO ELEGIDO DEL GRUPO QUE CONSTA DE MOLIBDENO, WOLFRAMINO Y SUS MEZCLAS, Y UNA CANTIDAD ESTABILIZANTE DE FOSFORO EN UN HIDROGEL DE ALUMINA. EL CATALIZADOR CALCINADO FINAL TIENE UN AREA SUPERFICIAL DE 300 M2/G POR LO MENOS, POR LO MENOS EL 20 % DEL VOLUMEN DE POROS EN POROS QUE TIENEN DIAMETROS MAYORES QUE 35 NM Y POR LO MENOS 20 % DEL VOLUMEN DE POROS EN POROS QUE TIENEN DIAMETROS MENORES QUE 7 NM.
ES198888202019T 1987-09-24 1988-09-14 Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles. Expired - Lifetime ES2025769T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/100,663 US4810686A (en) 1987-09-24 1987-09-24 Hydrotreating catalysts prepared from hydrogels

Publications (1)

Publication Number Publication Date
ES2025769T3 true ES2025769T3 (es) 1992-04-01

Family

ID=22280893

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198888202019T Expired - Lifetime ES2025769T3 (es) 1987-09-24 1988-09-14 Procedimiento para preparar catalizadores de hidrotratamiento a partir de hidrogeles.

Country Status (10)

Country Link
US (1) US4810686A (es)
EP (1) EP0309046B1 (es)
JP (1) JP2949346B2 (es)
AT (1) ATE68723T1 (es)
AU (1) AU602795B2 (es)
CA (1) CA1317276C (es)
DE (1) DE3865795D1 (es)
DK (1) DK172341B1 (es)
ES (1) ES2025769T3 (es)
ZA (1) ZA887092B (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4880523A (en) * 1987-09-24 1989-11-14 Shell Oil Company Process for hydrotreating hydrocarbon feeds
JP3606590B2 (ja) * 1990-08-03 2005-01-05 アクゾ ノーベル ナムローゼ フェンノートシャップ 水素化触媒、その調製法及びその使用法
US5227353A (en) * 1991-07-24 1993-07-13 Mobil Oil Corporation Hydroprocessing catalyst composition
US5462651A (en) * 1994-08-09 1995-10-31 Texaco Inc. Hydrodearomatization of hydrocarbon oils using novel "phosphorus treated carbon" supported metal sulfide catalysts
US6015485A (en) * 1994-05-13 2000-01-18 Cytec Technology Corporation High activity catalysts having a bimodal mesopore structure
CA2510100C (en) * 1994-05-13 2006-09-26 Shell Oil Company High activity gamma alumina catalysts
AU701761B2 (en) * 1994-05-13 1999-02-04 Shell Oil Company High activity catalysts
US5472595A (en) * 1994-08-09 1995-12-05 Texaco Inc. Process for hydrodearomatization of hydrocarbon oils using carbon supported metal sulfide catalysts promoted by phosphate
US6508999B1 (en) 2000-11-21 2003-01-21 Shell Oil Company Aluminum trihydroxide phase
FR2862548B1 (fr) * 2003-11-20 2007-11-09 Eurecat Europ Retrait Catalys Regeneration hors site de catalyseurs de reformage
CZ305662B6 (cs) * 2014-06-30 2016-01-27 Unipetrol Výzkumně Vzdělávací Centrum, A. S. Způsob výroby molybdenového katalyzátoru s dalším aktivním kovem
BR102016022467B1 (pt) * 2016-09-28 2022-02-01 Petróleo Brasileiro S.A. - Petrobras Processo para preparação de um catalisador à base de níquel, catalisador à base de níquel, e, seu uso em um processo de reforma a vapor
CN114602483B (zh) * 2022-03-10 2023-08-18 福州大学 一种催化裂化汽油加氢脱硫催化剂及其制备方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3390100A (en) * 1964-02-14 1968-06-25 American Cyanamid Co Process for the preparation of extrudates from hydrogels
US4019978A (en) * 1972-08-29 1977-04-26 Laporte Industries Limited Process for the production of alumina
US3864461A (en) * 1972-08-29 1975-02-04 Laporte Industries Ltd Process for the production of alumina
JPS50123588A (es) * 1974-02-07 1975-09-29
US4082695A (en) * 1975-01-20 1978-04-04 Mobil Oil Corporation Catalyst for residua demetalation and desulfurization
US4036784A (en) * 1975-05-30 1977-07-19 Uop Inc. Method of producing an extruded catalyst composition
GB1550684A (en) * 1975-08-28 1979-08-15 Mobil Oil Corp Demetalation-desulphurisation catalyst and the preparation and use thereof
US4094820A (en) * 1977-03-11 1978-06-13 Union Oil Company Of California Manufacture of cobalt and/or nickel-molybdenum-alumina catalysts
US4124537A (en) * 1977-09-12 1978-11-07 Uop Inc. Coextruded catalytic composite
US4192736A (en) * 1978-11-29 1980-03-11 Chevron Research Company Removal of indigenous metal impurities from an oil with phosphorus oxide-promoted alumina
US4328127A (en) * 1980-09-16 1982-05-04 Mobil Oil Corporation Residua demetalation/desulfurization catalyst
US4404097A (en) * 1980-09-16 1983-09-13 Mobil Oil Corporation Residua demetalation/desulfurization catalyst and methods for its use
US4456699A (en) * 1981-06-17 1984-06-26 Standard Oil Company (Indiana) Catalyst and support, and their methods of preparation
JPS61138537A (ja) * 1984-12-11 1986-06-26 Nikki Universal Co Ltd 水素化脱硫触媒の製造方法
US4717704A (en) * 1986-10-28 1988-01-05 Shell Oil Company Hydrotreating catalysts prepared from hydrogels
US4717706A (en) * 1986-10-28 1988-01-05 Shell Oil Company Wide-pore hydrogel-derived catalysts
CA1312595C (en) * 1986-10-28 1993-01-12 Richard Alan Kemp Process for the preparation of hydrotreating catalysts from hydrogels
US4717705A (en) * 1986-10-28 1988-01-05 Shell Oil Company Hydrotreating catalysts prepared from hydrogels
DE3865794D1 (de) * 1987-09-24 1991-11-28 Shell Int Research Hydroraffinationskatalysator, ausgehend von hydrogelen, verfahren zur herstellung und verwendung.

Also Published As

Publication number Publication date
DK525888A (da) 1989-03-25
DE3865795D1 (de) 1991-11-28
CA1317276C (en) 1993-05-04
US4810686A (en) 1989-03-07
EP0309046B1 (en) 1991-10-23
JPH01115456A (ja) 1989-05-08
DK525888D0 (da) 1988-09-22
EP0309046A1 (en) 1989-03-29
AU2273388A (en) 1989-04-06
ZA887092B (en) 1989-09-27
DK172341B1 (da) 1998-04-06
JP2949346B2 (ja) 1999-09-13
AU602795B2 (en) 1990-10-25
ATE68723T1 (de) 1991-11-15

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