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EP3071719A4 - Procédé pour la récupération de métaux terres rares à partir de déchets sulfates - Google Patents

Procédé pour la récupération de métaux terres rares à partir de déchets sulfates Download PDF

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Publication number
EP3071719A4
EP3071719A4 EP14863833.1A EP14863833A EP3071719A4 EP 3071719 A4 EP3071719 A4 EP 3071719A4 EP 14863833 A EP14863833 A EP 14863833A EP 3071719 A4 EP3071719 A4 EP 3071719A4
Authority
EP
European Patent Office
Prior art keywords
sulphates
waste
rare earth
earth metals
recovering rare
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP14863833.1A
Other languages
German (de)
English (en)
Other versions
EP3071719A1 (fr
Inventor
Pertti Koukkari
Jarno MÄKINEN
Malin BOMBERG
Anna LEHTONEN
Mona Arnold
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VTT Technical Research Centre of Finland Ltd
Original Assignee
VTT Technical Research Centre of Finland Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VTT Technical Research Centre of Finland Ltd filed Critical VTT Technical Research Centre of Finland Ltd
Publication of EP3071719A1 publication Critical patent/EP3071719A1/fr
Publication of EP3071719A4 publication Critical patent/EP3071719A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B59/00—Obtaining rare earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00—Magnetic separation
    • B03C1/002—High gradient magnetic separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00—Magnetic separation
    • B03C1/005—Pretreatment specially adapted for magnetic separation
    • B03C1/015—Pretreatment specially adapted for magnetic separation by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00—Magnetic separation
    • B03C1/02—Magnetic separation acting directly on the substance being separated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/288—Sulfides
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/488—Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/18—Extraction of metal compounds from ores or concentrates by wet processes with the aid of microorganisms or enzymes, e.g. bacteria or algae
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Manufacturing & Machinery (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Microbiology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Analytical Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Removal Of Specific Substances (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
EP14863833.1A 2013-11-22 2014-11-21 Procédé pour la récupération de métaux terres rares à partir de déchets sulfates Withdrawn EP3071719A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20136167A FI125550B (en) 2013-11-22 2013-11-22 Method for recovering rare earth metals from waste sulphates
PCT/FI2014/050891 WO2015075317A1 (fr) 2013-11-22 2014-11-21 Procédé pour la récupération de métaux terres rares à partir de déchets sulfates

Publications (2)

Publication Number Publication Date
EP3071719A1 EP3071719A1 (fr) 2016-09-28
EP3071719A4 true EP3071719A4 (fr) 2017-08-09

Family

ID=53179019

Family Applications (1)

Application Number Title Priority Date Filing Date
EP14863833.1A Withdrawn EP3071719A4 (fr) 2013-11-22 2014-11-21 Procédé pour la récupération de métaux terres rares à partir de déchets sulfates

Country Status (5)

Country Link
EP (1) EP3071719A4 (fr)
CN (1) CN105765091B (fr)
CA (1) CA2930349A1 (fr)
FI (1) FI125550B (fr)
WO (1) WO2015075317A1 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102017008035A1 (de) 2016-09-05 2018-03-08 Technische Universität Ilmenau Vorrichtung und Verfahren zur Separation von magnetisch anziehbaren Teilchen aus Fluiden
CN108117224B (zh) * 2016-11-29 2021-01-05 中国石油化工股份有限公司 一种脱硫废水的预处理方法
CN109425549B (zh) * 2017-08-21 2021-03-02 北新集团建材股份有限公司 一种分析石膏品位的方法
CN109957523B (zh) * 2017-12-25 2021-02-23 有研工程技术研究院有限公司 一株寡营养硫酸盐还原菌及其用于河道底泥重金属污染修复的工艺
DE102018113358B4 (de) 2018-06-05 2022-12-29 Technische Universität Ilmenau Vorrichtung und Verfahren zur kontinuierlichen separaten Entnahme von magnetisch anziehbaren und magnetisch abstoßbaren Teilchen aus einem strömenden Fluid
CN110028258A (zh) * 2019-05-16 2019-07-19 西南科技大学 一种钛石膏中铁硫资源分别利用的方法
CN110184460B (zh) * 2019-06-28 2020-12-15 四川省乐山锐丰冶金有限公司 一种氯化镨钕料液中除铝离子的方法
US10954582B2 (en) * 2019-07-17 2021-03-23 West Virginia University Systems and processes for recovery of high-grade rare earth concentrate from acid mine drainage
CN110918251B (zh) * 2019-10-31 2021-08-03 昆明理工大学 高梯度磁场脱除磷石膏中杂质的方法和装置
CN110961248B (zh) * 2019-11-29 2022-03-04 南华大学 一种含钪铀矿中分离钪、铀的方法
CN115572740B (zh) * 2022-09-30 2024-07-23 武汉工程大学 一种利用硫酸盐还原菌群分解磷石膏生成硫化钙的方法
CN118479655A (zh) * 2024-05-22 2024-08-13 湖北大学 一种利用磷石膏协同硫细菌处理废水回收磷的方法和产品

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL272533A2 (en) * 1988-05-16 1989-02-20 Politechnika Krakowska Method of recovering lanthanides from phospogypsum wastes
US5034201A (en) * 1989-09-20 1991-07-23 Rhone-Poulenc Chimie Recovery of rare earth values from gypsum
FI101787B (fi) * 1995-11-29 1998-08-31 Kemira Oyj Kipsin puhdistusmenetelmä
CN101597688A (zh) * 2008-06-03 2009-12-09 贵州光大能源发展有限公司 从磷石膏中回收稀土的一种方法
RU2416654C1 (ru) * 2009-11-10 2011-04-20 Закрытое акционерное общество "Российские редкие металлы" Способ извлечения редкоземельных металлов из фосфогипса

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2170736B (en) * 1984-12-19 1988-02-03 Bio Separation Ltd Process for magnetic separation of metals from aqueous media
PL157981B1 (pl) * 1989-03-09 1992-07-31 Sposób biochemiczny otrzymywania metali rzadkich z fosfogipsów PL
CN1017418B (zh) * 1989-03-15 1992-07-15 甘肃稀土公司 从稀土溶液中分离重金属的方法
GB9402976D0 (en) * 1994-02-16 1994-04-06 British Nuclear Fuels Plc Process for the treatment of contaminated land
GB2304301B (en) 1995-08-16 2000-06-14 Univ Southampton Magnetic separation
FI120819B (fi) 2008-04-09 2010-03-31 Kemira Oyj Menetelmä kipsin puhdistamiseksi
RU2412265C1 (ru) 2009-07-16 2011-02-20 Закрытое Акционерное Общество "Твин Трейдинг Компани" Способ извлечения редкоземельных элементов из фосфогипса
US20140166788A1 (en) 2011-09-26 2014-06-19 Gary Pearse Method and system for magnetic separation of rare earths
JP5704078B2 (ja) * 2012-01-06 2015-04-22 住友金属鉱山株式会社 希土類元素の回収方法
CN103274369A (zh) * 2013-05-20 2013-09-04 包头市红天宇稀土磁材有限公司 稀硫酸制取浓硫酸及固体产物的循环方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL272533A2 (en) * 1988-05-16 1989-02-20 Politechnika Krakowska Method of recovering lanthanides from phospogypsum wastes
US5034201A (en) * 1989-09-20 1991-07-23 Rhone-Poulenc Chimie Recovery of rare earth values from gypsum
FI101787B (fi) * 1995-11-29 1998-08-31 Kemira Oyj Kipsin puhdistusmenetelmä
CN101597688A (zh) * 2008-06-03 2009-12-09 贵州光大能源发展有限公司 从磷石膏中回收稀土的一种方法
RU2416654C1 (ru) * 2009-11-10 2011-04-20 Закрытое акционерное общество "Российские редкие металлы" Способ извлечения редкоземельных металлов из фосфогипса

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
KOEN BINNEMANS ET AL: "Recycling of rare earths: a critical review", JOURNAL OF CLEANER PRODUCTION, vol. 51, 1 July 2013 (2013-07-01), pages 1 - 22, XP055109592, ISSN: 0959-6526, DOI: 10.1016/j.jclepro.2012.12.037 *
SATO N ET AL: "A new recycle process of uranium from spent fuel by selective sulfurization", PROCEEDINGS OF SESSIONS AND SYMPOSIA SPONSORED BY THE EXTRACTION AND PROCESSING DIVISION OF THE MINERALS, METALS AND MATERIALS SOCIETY HELD DURING THE 2006 TMS ANNUAL MEETING 2006 MINERALS,, vol. 2006, 12 March 2006 (2006-03-12), pages 973 - 977, XP009194441, ISBN: 978-0-87339-613-4 *
See also references of WO2015075317A1 *

Also Published As

Publication number Publication date
CN105765091B (zh) 2018-10-09
EP3071719A1 (fr) 2016-09-28
WO2015075317A1 (fr) 2015-05-28
FI125550B (en) 2015-11-30
FI20136167A7 (fi) 2015-05-23
CA2930349A1 (fr) 2015-05-28
CN105765091A (zh) 2016-07-13

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