EP2797869A4 - Préparation de sels d'acides carboxyliques à insaturation alpha,beta-éthylénique par carboxylation catalytique d'alcènes - Google Patents

Préparation de sels d'acides carboxyliques à insaturation alpha,beta-éthylénique par carboxylation catalytique d'alcènes

Info

Publication number: EP2797869A4
Authority: EP; European Patent Office
Prior art keywords: alkenes; beta; alpha; preparation; ethylenically unsaturated
Prior art date: 2011-12-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP12861287.6A

Other languages

German (de)

English (en)

Other versions

EP2797869A1 (fr

Inventor

Michael Limbach

Ronald Lindner

Michael Ludwik Lejkowski

Takeharu Kageyama

Gabriella Eva Bodizs

Stephan Schunk

Cornelia Futter

Jörg Rother

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

BASF SE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2011-12-29

Filing date

2012-12-27

Publication date

2015-08-05

2012-12-27 Application filed by BASF SE filed Critical BASF SE

2012-12-27 Priority to EP12861287.6A priority Critical patent/EP2797869A4/fr

2014-11-05 Publication of EP2797869A1 publication Critical patent/EP2797869A1/fr

2015-08-05 Publication of EP2797869A4 publication Critical patent/EP2797869A4/fr

Status Withdrawn legal-status Critical Current

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/08—Formation or introduction of functional groups containing oxygen of carboxyl groups or salts, halides or anhydrides thereof
- C07B41/10—Salts, halides or anhydrides of carboxyl groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)

EP12861287.6A 2011-12-29 2012-12-27 Préparation de sels d'acides carboxyliques à insaturation alpha,beta-éthylénique par carboxylation catalytique d'alcènes Withdrawn EP2797869A4 (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
EP12861287.6A EP2797869A4 (fr)	2011-12-29	2012-12-27	Préparation de sels d'acides carboxyliques à insaturation alpha,beta-éthylénique par carboxylation catalytique d'alcènes

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP11196025		2011-12-29
EP12861287.6A EP2797869A4 (fr)	2011-12-29	2012-12-27	Préparation de sels d'acides carboxyliques à insaturation alpha,beta-éthylénique par carboxylation catalytique d'alcènes
PCT/IB2012/057750 WO2013098772A1 (fr)	2011-12-29	2012-12-27	Préparation de sels d'acides carboxyliques à insaturation α,β-éthylénique par carboxylation catalytique d'alcènes

Publications (2)

Publication Number	Publication Date
EP2797869A1 EP2797869A1 (fr)	2014-11-05
EP2797869A4 true EP2797869A4 (fr)	2015-08-05

Family

ID=48696433

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP12861287.6A Withdrawn EP2797869A4 (fr)	2011-12-29	2012-12-27	Préparation de sels d'acides carboxyliques à insaturation alpha,beta-éthylénique par carboxylation catalytique d'alcènes

Country Status (6)

Country	Link
EP (1)	EP2797869A4 (fr)
JP (1)	JP6122030B2 (fr)
CN (1)	CN104011004B (fr)
CA (1)	CA2862155A1 (fr)
IN (1)	IN2014CN04656A (fr)
WO (1)	WO2013098772A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9416087B2 (en)	2014-10-08	2016-08-16	Chevron Phillips Chemical Company Lp	Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en)	2014-10-08	2017-08-08	Chevron Phillips Chemical Company Lp	Methods for the production of α,β-unsaturated carboxylic acids and salts thereof

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WO2013186238A1 (fr)	2012-06-13	2013-12-19	Basf Se	Procédé de production de cétones macrocycliques
CN104418719B (zh) *	2013-08-30	2016-04-13	中国石油化工股份有限公司	一种丙烯酸的合成方法
DE102014203951A1 (de) *	2014-03-05	2015-09-10	Evonik Degussa Gmbh	Synthese von alpha,beta-ungesättigten Carbonsäuren (Meth)acrylaten aus Olefinen
JP6635948B2 (ja) *	2014-05-16	2020-01-29	ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ	不飽和カルボン酸塩を調製する方法
WO2015173295A1 (fr) *	2014-05-16	2015-11-19	Basf Se	Préparation d'un sel d'acide carboxylique insaturé à partir d'un alcène et de dioxyde de carbone à l'aide d'un complexe de métal de transition immobilisé de manière covalente
WO2015173296A1 (fr) *	2014-05-16	2015-11-19	Basf Se	Préparation d'un sel d'acide carboxylique insaturé à partir d'un alcène et de dioxyde de carbone à l'aide d'une base hétérogène
CN106458824B (zh) *	2014-05-16	2020-10-16	巴斯夫欧洲公司	使用芳基氧化物制备不饱和羧酸盐的方法
WO2015173307A1 (fr)	2014-05-16	2015-11-19	Basf Se	Préparation d'un sel d'acide carboxylique insaturé à partir d'un alcène et de dioxyde de carbone faisant appel à un réservoir d'alcalinité hétérogène
JP6253570B2 (ja) *	2014-12-15	2017-12-27	旭化成株式会社	有機酸の製造方法
JP6272791B2 (ja) *	2015-02-24	2018-01-31	旭化成株式会社	有機酸の製造方法
JP6808649B2 (ja) *	2015-05-13	2021-01-06	ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆＳｅ	不飽和カルボン酸塩の製造方法
CN113402375B (zh) *	2015-12-15	2024-04-02	切弗朗菲利浦化学公司	由金属内酯和阴离子聚电解质形成α,β-不饱和羧酸和其盐
EP3426627A1 (fr) *	2016-04-06	2019-01-16	Chevron Phillips Chemical Company LP	Procédés de production d'acides carboxyliques , -insaturés et de sels de ceux-ci
JP6878457B2 (ja) *	2016-04-11	2021-05-26	ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆＳｅ	不飽和カルボン酸塩を製造する方法
JP6814573B2 (ja) *	2016-08-26	2021-01-20	株式会社日本触媒	不飽和カルボン酸塩の製造方法
US20180362435A1 (en) *	2017-06-14	2018-12-20	Chevron Phillips Chemical Company Lp	High porosity aromatic resins as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
US10544080B2 (en)	2017-06-14	2020-01-28	Chevron Phillips Chemical Company Lp	Continuous process for the conversion of olefins and carbon dioxide to acrylates via solution phase reactor
US10550061B2 (en)	2017-06-14	2020-02-04	Chevron Phillips Chemical Company Lp	Sulfur oxoacid-substituted and phosphorus oxoacid-substituted polyaromatic resins and salts thereof as promoters in acrylate production from coupling reactions of olefins and carbon dioxide
JP7019912B2 (ja)	2017-12-25	2022-02-16	ピーティーティーグローバルケミカルパブリックカンパニーリミテッド	二酸化炭素およびオレフィンからの不飽和カルボン酸塩およびその誘導体の生成プロセスのための触媒組成物
US20210017114A1 (en) *	2018-03-28	2021-01-21	Sekisui Chemical Co., Ltd.	METHOD FOR PRODUCING alpha,ß-UNSATURATED CARBOXYLATE
US11174213B2 (en)	2018-10-12	2021-11-16	Chevron Phillips Chemical Company, Lp	Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates
CN112745210B (zh) *	2019-10-30	2022-02-15	中国科学院大连化学物理研究所	一种制备α,β-不饱和羧酸化合物的方法
EP4121407B1 (fr) *	2020-03-20	2024-03-06	Basf Se	Procédé catalytique pour la préparation d'un sel d'acide carboxylique alpha, beta-insaturé
CN115959987B (zh) *	2022-12-16	2025-05-09	华东理工大学	一种用于二氧化碳和乙烯制备不饱和羧酸盐的催化剂组合物

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2011107559A2 (fr) *	2010-03-03	2011-09-09	Basf Se	Préparation de sels d'acides carboxyliques éthyléniquement insaturés par carboxylation d'alcènes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4435598A (en) *	1977-10-28	1984-03-06	National Distillers And Chemical Corporation	Process for the catalytic oxidation of propylene to acrylic acid
US20090299094A1 (en) *	2005-06-13	2009-12-03	Mitsubishi Rayon Co., Ltd.	Process for producing alpha, beta-unsaturated carboxylic acid

2012
- 2012-12-27 WO PCT/IB2012/057750 patent/WO2013098772A1/fr not_active Ceased
- 2012-12-27 CN CN201280064974.5A patent/CN104011004B/zh not_active Expired - Fee Related
- 2012-12-27 IN IN4656CHN2014 patent/IN2014CN04656A/en unknown
- 2012-12-27 JP JP2014549615A patent/JP6122030B2/ja active Active
- 2012-12-27 CA CA2862155A patent/CA2862155A1/fr not_active Abandoned
- 2012-12-27 EP EP12861287.6A patent/EP2797869A4/fr not_active Withdrawn

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2011107559A2 (fr) *	2010-03-03	2011-09-09	Basf Se	Préparation de sels d'acides carboxyliques éthyléniquement insaturés par carboxylation d'alcènes

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DAVID C. GRAHAM ET AL: "Production of Acrylic Acid through Nickel-Mediated Coupling of Ethylene and Carbon DioxideA DFT Study", ORGANOMETALLICS, vol. 26, no. 27, 1 December 2007 (2007-12-01), pages 6784 - 6792, XP055008539, ISSN: 0276-7333, DOI: 10.1021/om700592w *
H. HOBERG ET AL: "A l-Oxa-2-nickela-5-cyclopentanone from Ethene and Carbon Dioxide: Preparation, Structure, and Reactivity", ANGEWANDTE CHEMIE. INTERNATIONAL EDITION., vol. 26, no. 8, 1987, DEVCH VERLAG, WEINHEIM., pages 771 - 773, ISSN: 0570-0833 *
MICHAEL L. LEJKOWSKI ET AL: "The First Catalytic Synthesis of an Acrylate from CO2 and an Alkene - A Rational Approach", CHEMISTRY - A EUROPEAN JOURNAL, vol. 18, no. 44, 20 September 2012 (2012-09-20), pages 14017 - 14025, XP055131168, ISSN: 0947-6539, DOI: 10.1002/chem.201201757 *
See also references of WO2013098772A1 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US9416087B2 (en)	2014-10-08	2016-08-16	Chevron Phillips Chemical Company Lp	Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9725393B2 (en)	2014-10-08	2017-08-08	Chevron Phillips Chemical Company Lp	Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9783478B2 (en)	2014-10-08	2017-10-10	Chevron Phillips Chemical Company Lp	Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US9896405B2 (en)	2014-10-08	2018-02-20	Chevron Phillips Chemical Company Lp	Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US10155712B2 (en)	2014-10-08	2018-12-18	Chevron Phillips Chemical Company Lp	Methods for the production of α,β-unsaturated carboxylic acids and salts thereof
US10155711B2 (en)	2014-10-08	2018-12-18	Chevron Phillips Chemical Company Lp	Methods for the production of alpha, beta-unsaturated carboxylic acids and salts thereof

Also Published As

Publication number	Publication date
IN2014CN04656A (fr)	2015-09-18
CN104011004A (zh)	2014-08-27
CN104011004B (zh)	2016-04-20
JP6122030B2 (ja)	2017-04-26
CA2862155A1 (fr)	2013-07-04
JP2015503547A (ja)	2015-02-02
WO2013098772A1 (fr)	2013-07-04
EP2797869A1 (fr)	2014-11-05

Publication	Publication Date	Title
EP2797869A4 (fr)	2015-08-05	Préparation de sels d'acides carboxyliques à insaturation alpha,beta-éthylénique par carboxylation catalytique d'alcènes
SG11201502255UA (en)	2015-04-29	Methods for controlling dual catalyst olefin polymerizations
EP2755763A4 (fr)	2015-07-15	Catalyseur innovant permettant d'augmenter les rendements en propylène d'une unité de craquage catalytique fluide
EP2764917A4 (fr)	2015-04-29	Procédé de réduction de l'augmentation du rapport d'oxydation de so2 d'un catalyseur de dénitration
GB201009656D0 (en)	2010-07-21	Carboxylation catalysts
ZA201404265B (en)	2018-11-28	Preparation of an olefin oligomerization catalyst
EP2696971A4 (fr)	2014-11-26	Procédé de production d'un catalyseur pour l'oxydation d'éthylène en oxyde d'éthylène
SG11201601450UA (en)	2016-04-28	Catalyst for producing an unsaturated carboxylic acid by gas phase oxidation of an unsaturated aldehyde
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SG11201400090UA (en)	2014-03-28	Process for the preparation of olefins
PL2780323T3 (pl)	2017-11-30	Sposób otrzymywania kwasu chinolinokarboksylowego
SG11201401754RA (en)	2014-09-26	Activation of dual catalyst systems
EP2844646A4 (fr)	2016-03-23	Catalyseur pour l'époxydation d'alcènes
GB201508069D0 (en)	2015-06-24	Catalytic cracking catalyst preparation method
JP2014500383A5 (ja)	2014-08-14	オレフィン重合反応用の触媒の組成物として使用するハロゲン化マグネシウム担体の調製方法
EP2696972A4 (fr)	2014-12-10	Catalyseur contenant du zinc, pour la production d'oxyde d'éthylène
SG11201400091XA (en)	2014-03-28	Process for the preparation of olefins

Legal Events

Date	Code	Title	Description
2014-10-03	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
2014-11-05	17P	Request for examination filed	Effective date: 20140729
2014-11-05	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
2015-04-08	DAX	Request for extension of the european patent (deleted)
2015-08-05	RA4	Supplementary search report drawn up and despatched (corrected)	Effective date: 20150702
2015-08-05	RIC1	Information provided on ipc code assigned before grant	Ipc: C07B 41/08 20060101ALI20150626BHEP Ipc: C07B 41/10 20060101ALI20150626BHEP Ipc: C07C 51/15 20060101AFI20150626BHEP Ipc: C07C 51/41 20060101ALI20150626BHEP
2018-10-05	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: EXAMINATION IS IN PROGRESS
2018-11-07	17Q	First examination report despatched	Effective date: 20181009
2019-07-12	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN
2019-08-14	18D	Application deemed to be withdrawn	Effective date: 20190220